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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
2006 Vol. 22,No. 05
Published:28 April 2006
Date of publication: 28 April 2006
Current column
ARTICLE
Note
ARTICLE
Characterization and Activity of TiO
2
/wAC Composite Photocatalyst Prepared by Acid Catalyzed Hydrolysis Method
CHEN Xiao-Yun;LIU Shou-Xin;CHEN Xi;SUN Cheng-Lin
TiO2/ AC (activated carbon) composite photocatalysts were prepared by acid catalyzed hydrolysis method followed by calci...
2006, 22 (05): 517-522.
DOI: 10.3866/PKU.WHXB20060501
5888
Abstract/Metrics
6164
PDF(1143KB)
Phase Structures and Electrochemical Properties of V
2.1
TiNi
0.4
Zr
x
(x= 0~0.06) Hydrogen Storage Electrode Alloys*
CHEN Li-Xin;LI Lu;WANG Xin-Hua;DAI Fa-Bang;ZHENG Fang-Ping;LEI Yong-Quan
The phase structures and electrochemical properties of the V2.1TiNi0.4Zrx (x =0 ~0.06) hydrogen storage electrode alloys...
2006, 22 (05): 523-527.
DOI: 10.1016/S1872-1508(06)60018-1
4514
Abstract/Metrics
4076
PDF(748KB)
Preparation of Three-dimensionally Ordered Macroporous SiC Patterns
WANG Hao;LI Xiao-Dong;KIM Dong-Pyo
Three-dimensionally ordered macroporous(3DOM) SiC patterns were fabricated successfully on silicon substrate using poly...
2006, 22 (05): 528-531.
DOI: 10.3866/PKU.WHXB20060503
4771
Abstract/Metrics
6258
PDF(975KB)
Synthesis and Application of Ce-doped Mesoporous TiO
2
ZHANG Xue-Hong;TANG Xing-Hua;CHENG Xin-Sun
Mesoporous TiO2-CeO2(m-TiO2-CeO2) was synthesized using n-cetylpyridinium chloride(C16PyCl) as a structure-directing age...
2006, 22 (05): 532-537.
DOI: 10.3866/PKU.WHXB20060504
5032
Abstract/Metrics
4997
PDF(1086KB)
Structure and Potential Energy Function of PdN and PdN
2
Molecules*
ZHU Yu;JIANG Gang;FANG Fang;YU Gui-Feng;ZHU Zheng-He
Based on the relativistic effective cores potential (RECP/SDD) for Pd atom and AUG-cc-pVTZ basisfunction for N atom, the...
2006, 22 (05): 538-541.
DOI: 10.1016/S1872-1508(06)60019-3
5039
Abstract/Metrics
4741
PDF(203KB)
The π-complexation Mechanisms of Cu(I), Ag(I)/Zeolites for Desulfurization
ZHOU Dan-Hong;WANG Yu-Qing;HE Ning;YANG Gang
Density functional theory has been employed to investigate the π-complexation adsorption of aromatic sulfur compounds s...
2006, 22 (05): 542-547.
DOI: 10.3866/PKU.WHXB20060506
5324
Abstract/Metrics
4537
PDF(629KB)
Adsorption and Aggregative Structures of an Organic Cation [C
18
mim]
+
of the Ionic Liquid in the Interlayer of Montmorillonite
Ding Yun-Sheng;Wang Seng-Shan;Zha Min;Wang Zhi-Gang
An organic cation [C18mim]+ formed from [C18mim]Br, one type of ionic liquids, can go into the interlayer of sodium mont...
2006, 22 (05): 548-551.
DOI: 10.1016/S1872-1508(06)60020-X
5928
Abstract/Metrics
3896
PDF(190KB)
In-situ Synthesis and Tribology Property of Oleic Acid-modified CuS Nanoparticles
ZHU Hong;WANG Bin;SHEN Jing-Mei;KANG Xiao-Hong;GUO Hong-Fan;ZHU Lei
Oleic acid-modified CuS nanoparticles, which can be placed in a long stretch of time without any occurrence of nanoparti...
2006, 22 (05): 552-556.
DOI: 10.3866/PKU.WHXB20060508
5159
Abstract/Metrics
5225
PDF(1112KB)
Theoretical Study of Stereodynamics for the Reaction S(
1
D)+D
2
ZHANG Zhi-Hong;CHEN Mao-Du;CONG Shu-Lin;HAN Ke-Li
Stereodynamics for the S(1D)+D2 reaction have been studied at a collision energy of 22.18 kJ·mol-1 on an ab initio poten...
2006, 22 (05): 557-561.
DOI: 10.3866/PKU.WHXB20060509
4320
Abstract/Metrics
3700
PDF(190KB)
Application of ABEEM/MM Model to Study the Properties of the Water Clusters (H
2
O)
n
(n=11~16)
QIAN Ping;YANG Zhong-Zhi
ABEEM/MM model has been applied to compute various properties characterizing the larger water clusters (H2O)n (n=11~16),...
2006, 22 (05): 561-568.
DOI: 10.3866/PKU.WHXB20060510
4647
Abstract/Metrics
4382
PDF(597KB)
Preparation and Characterization of Anatase-Brookite TiO
2
Film on the PET Surface
ZHOU Li-Jun;YAN Shan-Shan;TIAN Bao-Zhu;CHEN Feng;ZHANG Jin-Long;HUANG Jia-Zhen
TiO2 thin films were prepared on modified PET(poly(ethylene terephthalate)) substrates by an improved gol-gel method. Th...
2006, 22 (05): 569-573.
DOI: 10.3866/PKU.WHXB20060511
4949
Abstract/Metrics
4848
PDF(586KB)
Comparison between the Electrical Conductivities of La
0.8
Sr
0.2
Ga
0.8
Mg
0.2
O
3
and La
0.8
Sr
0.2
Ga
0.8
Mg
0.15
Co
0.05
O
3
WU Ling-Li;WANG Shi-Zhong;LIANG Ying
La0.8Sr0.2Ga0.8Mg0.2O3(LSGM8282) and La0.8Sr0.2Ga0.8Mg0.15Co0.05O3 (LSGMC5) are two kinds of excellent electrolytes for ...
2006, 22 (05): 574-578.
DOI: 10.3866/PKU.WHXB20060512
4892
Abstract/Metrics
3923
PDF(200KB)
The Phase Behaviors of Temperature- and pH-sensitive Poly(methacrylic acid-g-N, N-diethylacrylamide) Dilute Aqueous Solutions
YU Juan-Li;LIU Shou-Xin;FANG Yu;GAO Gai-Ling;WANG Ming-Zhen
Several temperature-and pH-sensitive poly(methacrylic acid-g-N, N-diethylacrylamide) (P(MAA-g-DEAM))graft copolymerswith...
2006, 22 (05): 579-583.
DOI: 10.3866/PKU.WHXB20060513
4849
Abstract/Metrics
3794
PDF(358KB)
Synthesis of TiO
2
/[[gamma]]r-Al
2
O
3
and Effect of CuO Loading on NO Reduction
LI Hui-Juan;JIANG Xiao-Yuan;ZHENG Xiao-Ming
TiO2/[alpha]-Al2O3 was prepared with TiCl4 as starting material, and the catalytic activities of CuO/TiO2/[alpha]-Al2O3 ...
2006, 22 (05): 584-589.
DOI: 10.3866/PKU.WHXB20060514
4887
Abstract/Metrics
4049
PDF(281KB)
Preparation of Co-YSZ/HAp Nano-composite Coating on Ti Substrate by Electrochemical Method
WANG Zhou-Cheng;HUANG Long-Men;TANG Yi;NI Yong-Jin;LIN Chang-Jian
Co-YSZ/HAp nano-composite coating and nano-HAp single coating were deposited on Ti substrate using the combination of el...
2006, 22 (05): 590-595.
DOI: 10.3866/PKU.WHXB20060515
3801
Abstract/Metrics
4189
PDF(1707KB)
Chemical Composition and Reaction Mechanisms for Secondary Organic Aerosol from Photooxidation of Ethylbenzene
HUANG Ming-Qiang;HAO Li-Qing;ZHOU Liu-Zhou;GU Xue-Jun;WANG Zhen-Ya;FANG Li;ZHANG Wei-Jun
A laboratory study was carried out to investigate the secondary organic aerosol (SOA) products from photooxidation of th...
2006, 22 (05): 596-601.
DOI: 10.3866/PKU.WHXB20060516
5296
Abstract/Metrics
4756
PDF(274KB)
The Differential Interference Angle of Λ-Related Quantum Interference of
1
Π-state Diatom
LI Yong-Qing;LI Jian;SONG Peng;MA Feng-Cai
Collisional quantum interference (CQI) on rotational energy transfer was observed by Sha et al.(J. Chem.Phys., 1995, 102...
2006, 22 (05): 602-607.
DOI: 10.3866/PKU.WHXB20060517
2791
Abstract/Metrics
3253
PDF(155KB)
Absolute Asymmetry Synthesis and Resolution Mechanism of Chiral cis-bromoamminebis(ethylenediamine) cobalt(III) Bromide
ZHANG Hui;WANG Xian-Ying;CHEN Lei-Qi;FANG Xue-Ming;GAO Jing-Xing XU Zhi-Gu(608)
The absolute asymmetric synthesis of the title complexes Λ-(+)D-cis-[CoBr(NH3)(en)2]Br2(1) and Δ-(-)D-cis-[...
2006, 22 (05): 608-615.
DOI: 10.1016/S1872-1508(06)60021-1
5095
Abstract/Metrics
4224
PDF(328KB)
Phase Equilibrium of the ErCl
3
-CdCl
2
- HCl-H
2
O System at 25 ℃ and Characterization of New Compounds
ZHUO Li-Hong;QIAO Zhan-Ping;GUO Ying-Chen;WANG Hui
The equilibriumsolubility of the quaternary systemErCl3-CdCl2-HCl-H2O was determined at 298K and the corresponding equil...
2006, 22 (05): 616-621.
DOI: 10.1016/S1872-1508(06)60022-3
3844
Abstract/Metrics
3042
PDF(368KB)
Scoring Function for the Other-type Protein Complexes
SHEN Long-Zhu;LI Chun-Hua MA Xiao-Hui;CHANG Shan;CHEN Wei-Zu;WANG Cun-Xin;
Based on the conclusion that different complexes have distinctive chemo-physical characters at interfaces,a specific sco...
2006, 22 (05): 622-626.
DOI: 10.1016/S1872-1508(06)60023-5
4112
Abstract/Metrics
3946
PDF(221KB)
Note
Y
2
O
3
Nanoparticle/Carbon Nanotube Composite: Preparation and Catalytic Performance for Decomposition of Ammonium Perchlorate
ZHOU Long-Mei;LIU Hong-Ying; LI Feng-Sheng
Y2O3 nanoparticle /carbon nanotube composite has been prepared by chemical liquid deposition. Y2O3 nanoparticle /carbon ...
2006, 22 (05): 627-630.
DOI: 10.3866/PKU.WHXB20060521
5271
Abstract/Metrics
4859
PDF(856KB)
The Molecular Configuration and Its Influential Factors of Al
3+
Cross-linked Polyacrylamide Gel
LU Xiang-Guo;WANG Wei
The chemical composition, percolation performace, and microscopic configuration of“intramolecular cross鄄linked”gel syst...
2006, 22 (05): 631-634.
DOI: 10.3866/PKU.WHXB20060522
4197
Abstract/Metrics
4171
PDF(279KB)
Electrochemical Behavior of Nitrobenzene on Pt Micro-disk Electrode in Aprotic Medium
MA Chun-An;SHENG Jiang-Feng;WANG Xiao-Juan;ZHANG Cheng;WANG Lian-Bang
In a three-electrode system, dimethylformamide (DMF) and tetrabutyl ammoniumperchlorate (TBAP) used as solvent and suppo...
2006, 22 (05): 635-637.
DOI: 10.3866/PKU.WHXB20060523
5686
Abstract/Metrics
5054
PDF(187KB)
The Influcence of Alcohol Cryoprotec-tants on Eutectic Crystallization of NaCl Aqueous Solutions Studied by DSC
ZHOU Guo-Yan;HU Tong-Ji;GAO Cai;HUA Ze-Zhao
In order to investigate the effect of cryoprotective agent(CPA) on the eutectic crystallization of salt solution,differe...
2006, 22 (05): 638-643.
DOI: 10.3866/PKU.WHXB20060524
4885
Abstract/Metrics
4031
PDF(236KB)
Fabrication of Silver Nanoshells on Modified Polystyrene Microspheres through Electroless Plating Approach
LIU Hui-Yu;CHEN Dong;TANG Fang-Qiong;LING Hui;REN Xiang-Ling
Modified polystyrene microspheres with silver shells were prepared by a novel electroless plating approach using complex...
2006, 22 (05): 644-648.
DOI: 10.3866/PKU.WHXB20060525
5379
Abstract/Metrics
6137
PDF(843KB)