Acta Physico-Chimica Sinica
Acta Physico-Chimica Sinica
2006 Vol. 22,No. 03
Published:10 March 2006
Date of publication: 10 March 2006
Photoeletrochemical Behavior of Polypyrrole Nanofiber Array Electrodes
LIU Ling; ZHAO Yao-Min; YANG Jie; ZHAO Chong-Jun; JIANG Zhi-Yu
Polypyrrole (PPy) nano-fiber array electrodes were fabricated by electrochemical deposition of PPy in the pores of anodi...
2006, 22 (03): 261-264
Theoretical Studies on the Reaction Mechanism of Au
) and N
LÜ Ling-Ling; WANG Yong-Cheng
The reaction of Au+(1S, 3D) ions with N2O(1Σ+) are studied by means of B3LYP/6-311+G*(the basis set of Au+ is(8s7p6d)/[6...
2006, 22 (03): 265-269
Study on the Adsorption of Water on Na
ZSM-5 Type Zeolite: Molecular Simulation
GUO Xiang-Dan; HUANG Shi-Ping; TENG Jia-Wei; XIE Zai-Ku
Molecular dynamic (MD) quench method and grand canonical Monte Carlo method (GCMC) are used to study the adsorption of w...
2006, 22 (03): 270-274
Reaction of Active Nitrogen with SO
WANG Hong-Mei; TANG Xiao-Shuan; ZHANG Wei-Jun; CHU Yan-Nan; ZHOU Shi-Kang
The reactions of active nitrogen with SO2 and SOCl2 have been studied on a flowing afterglow apparatus. The emissions ra...
2006, 22 (03): 275-279
Synthesis, Characterization and Thermochemistry Properties of RE(III) and 2-oxo-propionic Acid Salicyloyl Hydrazone Complexes
CHEN Feng-Ying; CAO Wen-Kai; HE Shui-Yang; WANG Bao-Huai; ZHANG You-Min
A series of new light rare earth complexes of RE(C10H9N2O4)(C10H8N2O4)•nH2O (RE = La, Ce, Pr, Nd, Sm, Eu, Gd) have ...
2006, 22 (03): 280-285
A Study of CaSiO
∶Pb, Mn Phosphors Coated by ZnO∶Al
ZHAO Jing; LI Huai-Xiang; WANG An-He; ZHOU Hong-Wei; ZUO Xiang-Qing
CaSiO3∶Pb, Mn phosphor particles with red-luminescence were prepared by aqueous co-deposition reaction. Surface modifica...
2006, 22 (03): 286-290
SERS Study of the Electrooxidation of Formic Acid on Pt-Ru/GC
ZHONG Qi-Ling; HUANG Peng; ZHANG Bing; YANG Xiong-Yuan; DING Yue-Min; ZHOU Hai-Hui; REN Bin; TIAN Zhong-Qun
The electrooxidation behavior of formic acid on Pt-Ru/GC electrode was investigated by CV, multi-potential steps and SER...
2006, 22 (03): 291-295
Complex Permittivity and Permeability Spectra of Different Kinds of Carbon Nanotubes
ZHANG Zeng-Fu; LUO Guo-Hua; FAN Zhuang-Jun; XIANG Rong; ZHOU Li; WEI Fei
Carbon nanotubes (CNTs), with well defined one-dimension nanoscale tubular structure, have potential applications for el...
2006, 22 (03): 296-300
The Corrosion Behaviors of Mg
=0.04～0.1) Hydrogen Storage Alloy Electrodes
TIAN Qi-Feng; ZHANG Yao; TAN Zhi-Cheng; SUN Li-Xian; XU Fen; YUAN Hua-Tang
The effects of partial substitution of Pd for Mg on the corrosion behaviors of Mg0.9－xTi0.1PdxNi(x=0.04～0.1)hydrogen sto...
2006, 22 (03): 301-305
Electrocatalytic Reductive Dechlorination of 2,4,5-PCB in Aqueous Solution by Palladium-modified Titanium Mesh as Cathode
YANG Bo; YU Gang; HUANG Jun
Electrocatalytic reductive dechlorination of 2,4,5-PCB(PCB: polychlorinated biphenyls) in aqueous solution containing me...
2006, 22 (03): 306-311
The Cooperative Inhibition Effects of Alkaline Earth Metal Ions and EDTA on the Corrosion of Pure Aluminum in an Alkaline Solution
SHAO Hai-Bo; WANG Xiao-Yan; WANG Jian-Ming; WANG Jun-Bo; ZHANG Jian-Qing; CAO Chu-Nan
The cooperative effects of alkaline earth metal ions and EDTA(ethylenediamine tetraacetic acid) on the corrosion inhibit...
2006, 22 (03): 312-315
Study on Oxidation Properties of New ACNT/C Nanocomposites
LI Zhi; GONG Qian-Ming; LIANG Ji; HUANG Qi-Zhong; HUANG Bai-Yun
Aligned carbon nanotube/carbon (ACNT/C) nanocomposites were fabricated by traditional chemical vapor infiltration (CVI) ...
2006, 22 (03): 316-321
Reverse Micelle Formation of C
-heptane and Their Solubilization for Water
ZHENG Ou; ZHAO Jian-Xi; FU Xian-Ming
The critical reverse micelle concentrations of quaternary ammonium Gemini surfactants C12-s-C12•2Br (s=2, 3, 4, 5, ...
2006, 22 (03): 322-325
Dendritic Bis-(8-hydroxyquinoline) Derivatives: Studies on the Fluorescence Quenching and Decay
ZHANG Lu; YOU Chang-Jiang; CHEN Jin-Ping; YANG Guo-Qiang; LI Yi
The fluorescence quenching and the fluorescence decay of a series of dendritic bis-(8-hydroxyquinoline) derivatives (Gn-...
2006, 22 (03): 326-329
The Effect of Reactive Pressure to Fe:NiO
Film as Anode Catalytic Film in Hydrogen Producing System by Solar Cell
LI Hai-Ling; WANG Wen-Jing; KANG Guo-Hu; HUANG Jin-Zhao; XU Zheng
By changing the sputtering conditions, Fe∶NiOx films with different catalytic behaviors were fabricated. With the increa...
2006, 22 (03): 330-334
Effect of Butyl Sultone on the Li-ion Battery Performance and Interface of Graphite Electrode
XU Meng-Qing; ZUO Xiao-Xi; LI Wei-Shan; ZHOU Hao-Jie; LIU Jian-Sheng; YUAN Zhong-Zhi
Effect of butyl sultone (BS) on the graphite interface of lithium ion battery in carbonate-based electrolytes is studied...
2006, 22 (03): 335-340
Study on Removal of the Barrier between Al Substrate and Porous Anodic Alumina by Electrochemical Approach
XU Guo-Rong; REN Feng-Lian; SI Shi-Hui; YI Qing-Feng
An electrochemical method to remove barrier of porous anodic alumina (PAA) is presented. The barrier of PAA was dissolve...
2006, 22 (03): 341-344
Textural and Structure Characterizations of Ce
Prepared by Citric Acid Sol-Gel Method
YE Qing; XU Bo-Qing
Textural and structure characterizations of Ce1－xMnxO2 (0≤x≤1) samples were studied by N2 adsorption/desorption, XRD and...
2006, 22 (03): 345-349
Self-assembling of Microsphere through Template
ZHU Jian-Hua; SHI Jin-Xia; LI Heng; HE Ping-Sheng
Linear and zigzag micro-beads were arranged by means of micro-molding in capillary (MIMIC), the mechanism of self-assemb...
2006, 22 (03): 350-354
Hysteresis Loops Predictions by Revised LDFT in Slits
LIU Mei-Tang; MU Bo-Zhong
The lattice density functional theory (LDFT) for a Gibbs ensemble system of monoatomic molecules adsorbed in finite-widt...
2006, 22 (03): 355-358
Pharmacophore Model Construction of
YAN Hao; JIANG Feng-Chao
The pharmacophore model of γ-secretase inhibitors was established by the Catalyst software with the training set of Benz...
2006, 22 (03): 359-364
Synthesis and Characterization of Monodisperse TiO
WANG Peng; CHEN Dong; LIU Jian-Shu; TANG Fang-Qiong
The monodisperse spherical particles of TiO2 were prepared by sol-gel process in mixed solvents at low temperature. The ...
2006, 22 (03): 365-368
Fluorescence Characterization of Tb3+-Polydimethylsiloxane Complex
CAO Zhi-Jian; ZHANG Jun-Song; XU Juan; LU Tian-Hong; LI Cun; HUANG Xiao-Hua
The measurement of the fluorescence, UV-Vis absorption, FTIR and XPS spectroscopy demonstrated that the oxygen atom in p...
2006, 22 (03): 369-372
Heterogeneous Electrocatalytic Reduction of Furfural on Nanocrystalline TiO
-CNT Complex Film Electrode in DMF Solution
CHU Dao-Bao; ZHANG Li-Yan; ZHANG Jin-Hua; ZHANG Xiu-Mei; YIN Xiao-Juan
The precursor Ti(OEt)4 was prepared by anodic dissolution of metallic titanium in absolute ethanol and directly hydrolyz...
2006, 22 (03): 373-377
The Preparation of Copper Electrodeposits with (110) Lattice Plane Fully Preferred Orientation
GU Min; XIAN Xiao-Hong
The electrodeposition conditions for the preparation of copper deposits with fully preferred orientation were investigat...
2006, 22 (03): 378-382
Electrochemical Properties of SnSe Thin Film Electrode Fabricated by Pulsed Laser Deposition
XUE Ming-Zhe; CHENG Sun-Chao; YAO Jia; FU Zheng-Wen
SnSe thin film has been successfully fabricated by using pulsed laser ablation of mixed target of Sn and Se. The structu...
2006, 22 (03): 383-387
Study on Quantitative Structure-Activity Relationship by 3D Holographic Vector of Atomic Interaction Field
LIANG Gui-Zhao; MEI Hu; ZHOU Peng; ZHOU Yuan; LI Zhi-Liang
A novel method based on three-dimensional holographic vector of atomic interaction field (3D-HoVAIF) was employed to exp...
2006, 22 (03): 388-390