Acta Physico-Chimica Sinica
Acta Physico-Chimica Sinica
2005 Vol. 21,No. 06
Published:15 June 2005
Date of publication: 15 June 2005
Photo-induced Intra-complex Reactions in Ca
WANG Dong-sheng; HAN Keli; YANG Shi-he
Laser induced reaction of Ca+--tertbutylamine complex was studied by reflection time of flight spectrum (RTOF). Differen...
2005, 21 (06): 583 -585
Surface Modification of Potassium Titanate Whiskers with
WANG Chang-song; FENG Xin; LU Xiao-hua
The surface modification of potassium titanate whiskers (PTW) with n-octadecyltrichlorosilane (OTS) through self-assembl...
2005, 21 (06): 586 -590
Study on the Phase Separation Behavior of Poly(
-diethylacrylamide) and P(
-hydroxymethylacrylamide) Dilute Aqueous Solutions
CHEN Yong; LIU Ming-zhu; JIN Shu-ping; CHEN Shi-lan
The phase transition behaviors of poly(N,N-diethylacrylamide)(PDEA) and P(N,N-diethylacrylamideco-N-hydroxymethylacrylam...
2005, 21 (06): 591 -595
Quantum Chemistry-ANN Methods Study on
g of Polyacrylates
LIU Wan-qiang; WANG Xue-ye; LI Xin-fang; LONG Qing-ping; WEN Xiao-hong; LI Jianjun
The mechanism and affecting factors of the glass transition for polymers have been analyzed. The structural units of thi...
2005, 21 (06): 596 -601
Pd-Ni Nanowires Prepared by Electrochemical Step-edge Decoration
YUAN Juan; XIAO Yao-kun; YU Gang; HU Bo-nian; YE Li-yuan
The arrays of Pd-Ni nanowires were prepared on highly oriented pyrolytic graphite by electrochemical step-edge decoratio...
2005, 21 (06): 602 -606
Degradation of Polyethylene Film by Fe
XIONG Yu-hua; LI Feng-yi
Nano-sized TiO2 doped with different percentage of Fe3+was prepared quickly by sol-gel process and was first used as pho...
2005, 21 (06): 607 -611
Electrochemical Deposition and Characterization of Zinc Oxide Thin Films
CHEN Zhi-gang; TANG Yi-wen; ZHANG Li-sha; CHEN Zheng-hua; JIA Zhi-jie
This paper investigates reaction mechanism and electrochemical behavior of ZnO thin films deposited on transparent condu...
2005, 21 (06): 612 -615
Kinetics Study of Zeolite in Hydrothermal Solutions
ZHANG Xue-tong; ZHANG Rong-hua
In this paper, we conducted a series of experiments on zeolite in water and in acidic solutions using a continuous stirr...
2005, 21 (06): 616 -621
The Photocatalytic Property of Anodized Al2O3 Film on Al Surface
SHAO Yu; DAI Wen-xin; WANG Xu-xu; DING Zheng-xin; LIU Ping; FU Xian-zhi
An alumina film(AAO/Al) was prepared on Al plate surface by anodic oxidation. The photodecompositions of oleic acid and ...
2005, 21 (06): 622 -626
The Preparation and Characterization of PAn-PEG-PAn Rod-coil Triblock Copolymers
MA Hui-ru; GUAN Jian-guo; LU Guo-jun; YUAN Run-zhang
PAn-PEG-PAn rod-coil triblock copolymers were prepared by chemical oxidation copolymerization of aniline and α,ω-bis(p-a...
2005, 21 (06): 627 -631
Differential Accurate Fixed-node Quantum Monte Carlo Method
A novel quantum Monte Carlo(QMC) differential approach was proposed, which can be used to directly compute the energy di...
2005, 21 (06): 632 -636
Synthesis, Growth Mechanism and Microstructure of ZnO Nanocables
HE Jian; HUANG Yun-hua; ZHANG Yue; GU You-song; JI Zhen; ZHOU Cheng
ZnO nanocables were synthesized on gold coated silicon(100) substrate by zinc powder evaporation at 550 ℃. The source ma...
2005, 21 (06): 637 -640
Preparation and Magnetic Properties of Amorphous Co-Pt Alloy Nanowire Arrays
LI Hua; XU Cai-ling; ZHAO Guang-yu; LI Hu-lin
Highly ordered amorphous Co-Pt alloy nanowire arrays are prepared by electrodepositing it into anodized aluminum disks w...
2005, 21 (06): 641 -645
Study on the Scondary Bonding and Coordination Polyhedra in Crystal of Antimony(III) Complexonate Family
HU Sheng-zhi; CHEN Ming-dan; ROBERTSON B. E.
Thirty coordination polyhedra, reflecting the presence of a stereoactive lone electron pair, in the crystal structures o...
2005, 21 (06): 646 -652
The Reaction Mechanism for the Synthesis of 1-methoxy-2-propanol on MgO Catalyst
ZHANG Wen-yu; DONG Qing-nian; ZHAO Ning; WEI Wei; SUN Yu-han
The addition of propylene oxide with methanol was carried out over MgO and a detailed mechanism of the reaction was inve...
2005, 21 (06): 653 -657
Analytical Potential Energy Functions for the Electronic States
of BH Molecule
XIE An-dong; SHI De-heng; ZHU Zun-lue; ZHU Zheng-he
The energies, equilibrium geometries and harmonic frequencies of three electronic states (the ground state X 1Σ+, the fi...
2005, 21 (06): 658 -662
Crystal Defect Behaviors in CeO
-based Electrolyte Doped with Alkaline Earth Oxides
MA Zhi-fang; LIANG Guang-chuan; LIANG Jin-sheng
The defect behaviors, such as defect complex formation and oxygen vacancy migration in ceria doped with alkaline earth o...
2005, 21 (06): 663 -667
Synthesis and Characterization of ZnO Nanomaterials with Different Morphologies in Ionic Liquids
CAO Jie-ming; WANG Jun; FANG Bao-qing; ZHENG Ming-bo; LU Hong-xia; CHANG Xin; WANG Hai-yan
ZnO nano/microstructures of different morphologies have been synthesized by using Zn(OH)42- and different ionic liquids...
2005, 21 (06): 668 -672
Study on Acrylonitrile Graft Copolymerization on Surfaces of Polystyrene Microspheres
ZHANG Kai; FU Qiang; HUANG Yu-hong; ZHOU De-hui
Functional polymer microspheres with micron size, due to their excellent properties such as small size, narrow size dist...
2005, 21 (06): 673 -676
Effect of Trace Water on Electronic Absorption Spectra of Substituted Phthalocyaninatozincs in Solvents
LIN Mei-jin; WANG Jun-dong; CHEN Nai-sheng; HUANG Jin-ling
The electronic absorption spectra of six different alkoxy substituted phthalocyaninatozincs in different solvents have b...
2005, 21 (06): 677 -680
Isothermal Cure Kinetics of Epoxy Resin/Montmorillionite Composites Cured by Acid Anhydride
YANG Chao; JIANG Xue-liang; SUN Kang
The isothermal cure kinetics of the epoxy resin (EP)/montmorillionite composites, with anhydride as curing agent, was st...
2005, 21 (06): 681 -685
An All-electron FLAPW Study of Geometric and Electronic Structures for
LI Gan; LAI Xin-chun; SUN Ying
The full potential linear augmented plane wave（FLAPW） method is used to study geometric and electronic structure of δ-Pu...
2005, 21 (06): 686 -689
Molecular Nanostructures on Metal Surfaces and Their Properties
YAN Hui-juan; WAN Li-jun
This paper summarized our recent results in the construction of organic molecular nanostructures on metal surfaces. The ...
2005, 21 (06): 690 -696
Development and Application of Electrolyte based on Ionic Liquid in Dye-sensitized Solar Cells
PAN Xu; DAI Song-yuan; WANG Kong-jia; SHI Cheng-wu; GUO Li
The development and application of electrolyte based on ionic liquids in dye-sensitized solar cells (hereafter DSCs) wer...
2005, 21 (06): 697 -702