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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
2002 Vol. 18,No. 10
Published: 15 October 2002
Current column
ARTICLE
Note
ARTICLE
Synthesis, Characterization and Thermochemical Properties of La(III) with Salicylaldehyde-1H- benzotriazol-1-aceylhydrazone
He Shui-Yang;Cao Wen-Kai;Hu Ting;Zhao Jian-She;Zhang Wei-Ping;Xue Gang-Lin;Hu Rong-Zu
A new rare earth complex La(C15H12N5O2)( C15H11N5O2)•2.5H2O has been synthesized. Attempts have been made to ascer...
2002, 18 (10): 865-870.
DOI: 10.3866/PKU.WHXB20021001
5990
Abstract/Metrics
3310
PDF(2117KB)
A Debate on the Parity-Violating Energy Difference of D-and L-Alanine
Wang Wen-Qing;Sun Lin;Min Wei;Wang Zhe-Ming
The chiral purity of biochemical monomers——only L-amino acids are present in proteins and D-sugars in the DNA and RNA of...
2002, 18 (10): 871-877.
DOI: 10.3866/PKU.WHXB20021002
5282
Abstract/Metrics
3190
PDF(750KB)
The Effect of MoO
3
in Ag-Mo-P-O Catalysts on Oxidative Dehydrogenation of Propane
Zhang Xin;Wan Hui-Lin;Weng Wei-Zheng;Yi Xiao-Dong
A series of AMP catalysts with different composition were prepared. These catalysts have been characterized by XRD, H2-T...
2002, 18 (10): 878-883.
DOI: 10.3866/PKU.WHXB20021003
5901
Abstract/Metrics
3335
PDF(1482KB)
The Coating Process of Nano-scale Hydrous Silica Film on TiO
2
Particles by Chemical Deposition in Aqueous Solution
Qin Cao;Wang Ting-Jie;Jin Yong
The coating process of nano-scale hydrous silica film on TiO2 pigmentary particles by chemical deposition in aqueous sol...
2002, 18 (10): 884-889.
DOI: 10.3866/PKU.WHXB20021004
7361
Abstract/Metrics
4513
PDF(1819KB)
Quantum Chemical Study on the Mechanism of Enantioselective Alkynylation of
Li Ming;He Rong-Xing
The semi empirical molecular orbital computations of the enontioselective alkynylation of benzaldehyde catalyzed by oxaz...
2002, 18 (10): 890-895.
DOI: 10.3866/PKU.WHXB20021005
4216
Abstract/Metrics
2921
PDF(1177KB)
Surface Structural Morphology of TiO
2
Nano-Films
Sun Zhen-Fan;Li Yu-Guang
A TiO2 reverse micelle solution was prepared by mixing water-Triton X-100-cyclohexane reverse micelle with a mixture of ...
2002, 18 (10): 896-900.
DOI: 10.3866/PKU.WHXB20021006
5489
Abstract/Metrics
5391
PDF(1608KB)
Catalytic Reduction of SO
2
by CO on Sulfided CoMo/ Al
2
O
3
-TiO
2
Catalysts
Zhang Wen-Hua;Peng Jiang-Jie;Ma Yun-Sheng;Hao Li-Qing;Zhuang Shu-Xian
The catalytic reduction of SO2 by CO has been systematically investigated over the sulfided CoMo catalysts (4.0%CoO, 15....
2002, 18 (10): 901-906.
DOI: 10.3866/PKU.WHXB20021007
5796
Abstract/Metrics
3250
PDF(1925KB)
de novo Design and Conformational Studies of a
β
-hairpin Forming Peptide
Sha Yin-Lin;Li Yin-Ling;Qiu Yang;Wang Qi;Lai Lu-Hua;Tang You-Qi
A 12-residue peptide (R1G2T3F4W5V6d-P7S8V9N10Y11F12, β2) with cross-strand amino acid pairs V6V9, F4Y11 and Y3F12, predi...
2002, 18 (10): 907-910.
DOI: 10.3866/PKU.WHXB20021008
5646
Abstract/Metrics
2920
PDF(572KB)
The Synthesis of Mesoporous Molecular Sieve MCM-48 Using Two Surfactants as Co-template
Zhai Shang-Ru;Pu Min;Gong Yan-Jun;Zhang Ye;Wu Dong;Sun Yu-Han
A convenient synthesis of mesoporous molecular sieve MCM-48 by hydrothermal method using nonionic surfactant p-Octyl pol...
2002, 18 (10): 911-915.
DOI: 10.3866/PKU.WHXB20021009
5561
Abstract/Metrics
3499
PDF(1887KB)
The Stability with Time-on-Stream of NaBr-Promoted KY Zeolite Catalyst for the Oxidative Methylation of Toluene with Methane
Zhou Ling-Ping;Li Wei;Tao Ke-Yi;Li He-Xuan;Li Xuan-Wen
The stability with time-on-stream of NaBr-promoted KY zeolite catalyst for the oxidative methylation of toluene with met...
2002, 18 (10): 916-919.
DOI: 10.3866/PKU.WHXB20021010
5793
Abstract/Metrics
2955
PDF(1608KB)
Phase Behavior of Mixed Aqueous Solution of Octyltrimethylamonium Bromide and Sodium Octyl Sulfate
Hu Shang-Lin;Jia Xiao-Fei;Dai Le-Rong
The phase behavior of aqueous mixture of octyltrimethylamonium bromide (OTAB) and sodium octyl sulfate (SOS)was studied....
2002, 18 (10): 920-923.
DOI: 10.3866/PKU.WHXB20021011
6109
Abstract/Metrics
3487
PDF(1704KB)
Rank Analysis on Two-dimensional Kinetic Data and Its Related Application
Chen Di-Zhao;Liang Yi-Zeng;Xu Cheng-Jian
In this paper, it has been elaborately elucidated that many instances of co linearity and the relationship among the ran...
2002, 18 (10): 924-929.
DOI: 10.3866/PKU.WHXB20021012
6098
Abstract/Metrics
3149
PDF(1853KB)
Note
Preparation and Characterization of Fe Nanowire Arrays in Porous Anodic Aluminum
Yao Su-Wei;Chi Guang-Jun;Cui Lan;Fan Jun;Zhang Wei-Guo;Wang Hong-Zhi
Fe nanowire arrays have been prepared by electrodeposition in porous anodic aluminum oxide template from a composite ele...
2002, 18 (10): 930-933.
DOI: 10.3866/PKU.WHXB20021013
5247
Abstract/Metrics
4270
PDF(1601KB)
Fabrication of Composite Scanning Micro pH Electrode and Its Application in Localized Corrosion
Shao Min-Hua;Huang Ruo-Shuang;Hu Rong-Gang;Lin Chang-Jian
A novel composite scanning micro pH electrode was fabricated. The IrOx-pH electrode produced in a carbonate melts exhibi...
2002, 18 (10): 934-937.
DOI: 10.3866/PKU.WHXB20021014
4875
Abstract/Metrics
3115
PDF(1739KB)
New Method of Preparing NiP and NiPB Amorphous Alloys Using Nickel Hypophosphite as Reactant
Ma Yan-Feng;Li Wei;Zhang Ming-Hui;Zhang Bao-Gui;Tao Ke-Yi
NiP and NiPB amorphous alloys were prepared by chemical reduction method using nickel hypophosphite as reactant. Their p...
2002, 18 (10): 938-942.
DOI: 10.3866/PKU.WHXB20021015
5385
Abstract/Metrics
3202
PDF(1542KB)
A New Method to Prepare CdS Nanowire Arrays
Wang Yin-Hai;Xu Yan-Qi;Cai Wei-Li;Mo Ji-Mei
CdS nanowire arrays were prepared by a new electrochemical method. XRD and TEM measurements show that CdS nanowires were...
2002, 18 (10): 943-946.
DOI: 10.3866/PKU.WHXB20021016
5446
Abstract/Metrics
3357
PDF(1728KB)
Low Temperature Heat Capacities and Thermodynamic Functions of Potassium Dichromate
Nan Zhao-Dong;Tan Zhi-Cheng;Sun Li-Xian
The molar heat capacities (Cp,m) of crystalline potassium dichromate (K2Cr2O7) were measured with a precision automated ...
2002, 18 (10): 947-951.
DOI: 10.3866/PKU.WHXB20021017
5486
Abstract/Metrics
3305
PDF(1201KB)
Thermodynamic Stability of PuH
2
(g) Molecules
Li Quan;Xu Cheng-Gang;Wang Hong-Yan;Zhu Zheng-He
Based on the relativistic effective core potential (RECP) for Pu atom and 6-311G* basis sets for H atom, the thermodynam...
2002, 18 (10): 952-955.
DOI: 10.3866/PKU.WHXB20021018
5739
Abstract/Metrics
3212
PDF(1304KB)
Mechanism of Na
2
SeO
3
Reduction and Adsorption on Fe Electrode
Fu De-Xue;Miao Juan;Wang Yun-Yan;Shu Yu-De
It is found by experiment that Na2SeO3 can improve the current efficiency remarkably. The reaction mechanism of the prom...
2002, 18 (10): 956-960.
DOI: 10.3866/PKU.WHXB20021019
5395
Abstract/Metrics
3762
PDF(1496KB)