Acta Physico-Chimica Sinica
Acta Physico-Chimica Sinica
2002 Vol. 18,No. 04
Published:15 April 2002
Date of publication: 15 April 2002
Crystal Structure Prediction of a New BEDTTTF Charge Transfer Salt
Guo Sen-Li;Hou Ting-Jun;Xu Xiao-Jie;Zhang Bin;Zhu Dao-Ben
The crystal structure of a new charge transfer salt,(ET)2FeCl4 has been predicted by molecular mechanics.Unit crystal el...
2002, 18 (04): 289-91
Luminescence Character of Rare Earth Complexes with Derivatives of Benzoic Acid
Li Yong;Zhang Ke-Xu;Yi-Zhuang;Tao Dong-Liang;Wang Zhi-Xian;Gao Hong-Cheng;Wu Jin-Guang
A series of Eu,Tb complexes were synthesized with derivatives of benzoic acid as the first ligand and phenanthroline or ...
2002, 18 (04): 292-296
Atom Clusters in Liquid and Amorphous of Ni3Al Alloy
Wang Li;Yi Su;Bian XiuFang
A series of simulation of the evolution of atom clusters in liquid Ni3Al alloy during rapid solidification have been per...
2002, 18 (04): 297-301
Molecular Reaction Dynamics for Pu(
Li Quan;Wang Hong-Yan;Jiang Gang;Zhu Zheng-He
Using Gaussian 98 program with B3LYP method, ground state equilibrium structure of PuCO was optimized and harmonic frequ...
2002, 18 (04): 302-306
Comparison of DFT with
Method on the Study of Intermolecular Interaction of (CH
Tan Jin-Zhi;Xiao He-Ming;Gong Xue-Dong;Li Jin-Shan
The geometries and electronic structures of methyl nitrate and its dimers have been calculated by DFT method at the B3LY...
2002, 18 (04): 307-314
Interactions between the Hydrophobicallymodified Watersoluble Amphoteric Cellulosic Graft Copolymer and Clay
Zhang Jian;Zhang Li-Ming;Li Zhuo-Mei;Xie Xu-Ming;Li Jian;Luo Ping-Ya
Hydrophobicallymodified watersoluble polymers are essentially hydrophilic polymers which also contain a small proporti...
2002, 18 (04): 315-320
Promotion Effects of CeO
and Pd on Ni/
Yang Yong-Lai;Xu Heng-Yong;Li Wen-Zhao
The influence of the addition of ntype semiconductor oxide CeO2 and noble metal Pd to Ni/γAl2O3 catalyst on carbon dep...
2002, 18 (04): 321-325
Preliminary Exploration of Touggard′s Method Used for the Background
Gong Hai-Ning;Shen Hua;Huang Hui-Zhong;Wu Nian-Zu
Both the mechanism of the background generated and the derivation process of Tougaard’s method used for subtracting back...
2002, 18 (04): 326-331
Study on the Effect and Mechanism of the Coupling between Microwave and Photocatalysis
Li Dan-Zhen;Zheng Yi;Fu Xian-Zhi
The TiO2 and /TiO2 catalysts were prepared by solgel method and charaterized by Xray diffraction, N2 absorption analys...
2002, 18 (04): 332-335
Correlation between Liquid and Solid Structure of Fe
Teng Xin-Ying;Ye Yi-Fu;Shi Zhi-Qiang;Wang Huan-Rong;Qin Jing-Yu
Using hightemperature θθ Xray diffractometer,the liquid structure of Fe68Si32 alloy was investigated and the structur...
2002, 18 (04): 336-339
Synthesis and Activation Mechanism of Coke Based Super Activated Carbons
Xing Wei;Zhang Ming-Jie;Yan Zi-Feng
Coke based super activated carbons (SAC) with higher surface area were synthesized by means of KOH thermoactivation.The...
2002, 18 (04): 340-345
Transient Electron Polarization of Anthraquinone/Hydrogendonor/2,2,6,6tetramethylpiperidinyloxyl
Zhang Xian-Yi;Xu Xin-Sheng;Lu Tong-Xing;Cui Zhi-Feng;Li Hai-Yang
The chemically induced dynamic electron polarization(CIDEP) of the antheraquinone(AQ)/ethylene glycol(EG) and AQ/EG/2,2,...
2002, 18 (04): 346-349
Localized Corrosion Study of Al 2024T3 Alloy by Scanning Micro reference Electrode Technique
Shao Min-Hua;Fu Yan;Hu Rong-Gang;Lin Chang-Jian
The scanning microreference electrode (SMRE) technique and scanning electron microscopy (SEM) were applied to investigat...
2002, 18 (04): 350-354
Synthesis and Properties of Hydrophobic ＆ Antireflective Silica Coating
Zhang Ye;Wu Dong;Sun Yu-Han;Peng Shao-Yi
Organic methylmodified silica sols were obtained by Hydrolysis and cocondensation reactions occurred in basecatalyzed...
2002, 18 (04): 355-358
Structure and Electrical Properties of Gold Nanowires Grown with Electrochemical Deposition
Liu Hong-Wen;Hou Shi-Min;Zhang Geng-Min;Shen Zi-Yong;Liu Wei-Mim;Wu Jin-Lei;Xue Zeng-Quan;Emmanuel Roy;Kui-Yu Zhang
Gold nanowires with 90 nm diameter were prepared by electrodeposition on polycarbonate membrane template. Transmission e...
2002, 18 (04): 359-363
Solid State Synthesis, Characterization and Properties of Oxygenated Polyamine Co Complexes
Cao Yan-Xia;Yue Fan;Wang Ji-De;Chi Yao-Ling
Two cobalt complexes with diethylenetriamine(dien) and triethylenetetramine(trien) as ligands were synthesized by solid...
2002, 18 (04): 364-367
Synthesis of Photocatalytic Activity TiO
Thin Films at LowTemperature
Zhao Wen-Kuan;Fang You-Ling
Anatase TiO2 thin films were obtained on a substrate at lowtemperature by addition of H3BO3 into （NH4）2TiF6 solution su...
2002, 18 (04): 368-371
Two Phases Separation and Its Reliability Analysis of Semicrystalline Polyethylene Terephthalate
Guo Li-Ping;Han Fu-Tian;Cheng Zhi-Xu
The Xray diffraction whole pattern (XDWP) data of semicrystalline poly(ethylene terephthalate) PET2 sample were collect...
2002, 18 (04): 372-376
Solubilization Kinetics of Benzene in Pluronic F127 and P123 Aqueous Micellar Solutions
Zhao Jian-Xi;Ye Xiang-Yu
A new approach has been developed to obtain the data of solubilization kinetics,in which the micelles are not separated ...
2002, 18 (04): 377-380
AC Impedance Analysis of Supercapacitors Utilizing Carbon Nanotube Electrodes
Liang Kui;Chen Ai;Feng Zhe-Sheng;Ye Zhi-Xiang
AC impedance analysis is employed to study frequencyresponse characteristics of supercapacitors utilizing carbon nanotu...
2002, 18 (04): 381-384