Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
1999 Vol. 15,No. 03
Published:15 March 1999
Date of publication: 15 March 1999
Theoretical Study of Rection of HOCl and HCl on Water Clusters
Xu Si-Chuan, Zhao Xin-Sheng
1999, 15 (03): 193-197.
Preparation and Structural Characterization of Self-assembled Monolayers from a New Series of Mercapto Contained Azobenzene Derivatives
Li Hai-Ying, Zhang Hao-Li, Zhang Jin, Liu Zhong-Fan
Self Assembled Monolayers(SAMs) of a series of mercapto contained azobenzene derivatives with the structure of CnH2n+1Az...
1999, 15 (03): 198-203.
Ab Initio Calculation on Oxamidato-bridged Binuclear Copper(II) Complex as Structural Unit
Zheng Kang-Cheng, Chen Zhong-Ning, Huang Jia-Duo, Liu Han-Qin
The investigation of the cis-trans conformations and their singlet and triplet electronic configurations of the oxamidat...
1999, 15 (03): 204-209.
Solute Diffusion in the Dynamic Network of Gel
Liu Hong-Bin, Ren Yan, Wang Yu-Xin, Wang Shi-Chang, An Ying-Li, Zuo Ju
A study was carried out both theoretically and experimentally on the solute diffusion in gel networks. The emphasi...
1999, 15 (03): 210-215.
The Influence of Alcohol on the Aggregation Behavior of DDAHPS Molecules in Water
Shen Qiang, Li Gan-Zuo, Huang Yan-Zhang, Ye Jian-Ping
The influence of alcohol on the aggregation behavior of the zwitterionic surfactant (dodecyldimethylammonium hydroxyl pr...
1999, 15 (03): 216-221.
The Photoelectrochemical Properties of Composite Titanium Dioxide and Ferric Oxide Nanocrystalline Electrodes
Wang Yan-qin, Cheng Hu-Min, Ma Ji-Ming
The photoelectrochemical behaviors of the mutual modified nanocrystalline Fe 2O 3 and TiO 2 electrodes prepared by diffe...
1999, 15 (03): 222-227.
Thermodynamics of Deoxidation of High Purity Niobium
Liu Sheng-Feng, Lin Jian-Hua, Su Mian-Zeng
Starting niobium samples with different oxygen contents were produced by arc melting and electron beam melting respectiv...
1999, 15 (03): 228-233.
Mossbuer Spectroscopic Studies of Fe
O-Based Catalysts for Ethylbenzene Dehydrogenation
Zhu Yi-Xiang, Chen Rong-Qin, Feng Lei, Wang Jun
Fe 2O 3 K 2O Catalysts with different content of K 2O and calcined at different temperature were characterized by using ...
1999, 15 (03): 234-240.
Synthesis,Structural Characterization and Reaction of the Chiral Clusters
Ding Er-Run, Wu Shu-Lin, Li Qing-Shan, Yin Yuan-Qi
Several chiral clusters RuCoMo(μ-3 S)(CO) 8C 5H 4C(O)R were synthesized by the thermal reaction of the precursor (&mu...
1999, 15 (03): 241-246.
Mechanism of Reaction HNCO+OH->H
Shi Tu-Jin, Li Zong-He, Liu Ruo-Zhuang
The mechanism of the reaction HNCO +OH→H2 O +NCO has been studied by using ab initio MO method(at UMP4/6 31G** leve...
1999, 15 (03): 247-252.
Rapid-Mixing Stopped-Flow Studies of lron Porphrin Enzyme-Mimic Systems
Xia Chun-Gu, Li Zhen, Wei Chi-Li, Li Shu-Ben
The reactions of different iron porphrin complexes Fe Ⅲ(TPP)Cl [tetraphenylporphinatoiron(III) chloride],Fe Ⅲ(TMOPP)Cl [...
1999, 15 (03): 253-258.
UV Photolysis of Oxalyl Chloride and 2,3-butanedione Studied by Time-resolved FTIR
Li Qiang, Li Hong-Zhi, Kong Fan-Ao
The photodissociation of oxalyl chloride and 2,3 butanedione at 193nm and 248nm have been studied by Time resolved FTIR ...
1999, 15 (03): 259-264.
Determinstion of Standard Transfer Entropies of RbCl from H
O to Mixtures of H
Li Lin-Wei, Chu De-Ying, Liu Rui-Lin
The standard electromotive forces of the reversible cells consisted of the Corning monovalent general cation selective e...
1999, 15 (03): 265-268.
Thermodynamical and Electrochemical Properties of CTAB/C
Guo Rong, Shen Ming, Liu Tian-Qing
Distribution coefficient K of C n H 2 n +1 OH between micellar phase and water phase in CTAB/C n OH/H 2O O/W system incr...
1999, 15 (03): 269-273.
Microcalorimetric and Nonequlibrium Thermodynamic Studies on the Gemination and Growth of Seeds
Zhou Pei-Jiang, Hu Yun-Chu, Ling Xing-Yuan, Yang Feng, Song Zhao-Hua, Qu Song-Sheng, Zhu Ying-Guo
The thermograms of the germination and growth of rice and tree seeds were determined and studied by using a newly ...
1999, 15 (03): 274-278.
Raman Study of the Electrochromic V
Guan Zi-Sheng, Yang Yong-An, Ma Ying, Yao Jian-Nian
The amorphous V 2O 5 films prepared by vacuum evaporation are unstable and easily dissolved by electrolyte during the el...
1999, 15 (03): 279-283.
Alternative Copolymerization of CO and Ethylene Catalyzed by Palladium(II)
Luo He-Kuan, Li Da-Gang
With high presure in situ 1H NMR technique, the alternative copolymerization of CO with ethylene catalyzed by Pd(Ⅱ)-DPPP...
1999, 15 (03): 284-288.