Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
1998 Vol. 14,No. 03
Published: 15 March 1998
The Inner-sphere Electron Transfer from Benzenitrile Anion Radical to Carbon Dioxide
Guo Jian-Xin, Wang Yan-Ni, Zhang Qi-Yuan
The process of electron transfer (ET) from benzenitrile radical anion to carbon dioxide is studied by the quantum chemic...
1998, 14 (03): 193-197.
Calculations for Electronic Structure of TiC、TiC
Cui Wan-Qiu, Lei Ming
Using the discrete-variational (DV-X_α) method, the electronic structures of TiC ideal crystal, carbon vacancies a...
1998, 14 (03): 198-203.
Calculation of Solid Metal Atom's Electronegativity and its Application(II)
Wang Gui-Chang, Sun Yu-Han, Zhong Bing
In this paper, heat of chemisorption and surface bond energies of diatomic molecules (H2, O2, CO) on some transition met...
1998, 14 (03): 204-209.
Theoretical Studies of Glassy Behavior of C
Crystal at High Pressure
Chen Xiao-Hua, Peng Jing-Cui, Liu Hong, Xia Jin-Tong, Chen Zong-Zhang, Feng Sun-Qi
The orientationally ordered structure in C60 crystal under various pressures has been investigated by using the mo...
1998, 14 (03): 210-213.
Studies of Electrochemical Properties of PAn Doped with Disulfidedisulfonic Acid
Tang Xiao-Hui, Li Yong-Fang, Fang Shi-Bi
One method to improve efficiently polyaniline's electrochemical properties is the comixing of polyaniline with disulfide...
1998, 14 (03): 214-218.
The Adsorption of Methanol,Water and Ethylene on a Niobium Oxide Thin Film
Zhong Chong-Min, Wang-De-Zheng, Takashi Ushikubo, Keisuke Wada
A niobium oxide thin film was obtained by oxidizing Nb(110). UPS was used to characterize the adsorption of methan...
1998, 14 (03): 219-225.
Electrochemical Behavior of the Benzoquinone Compounds with Long Alkyl Side Chain on LB Film
Tan Jun, Sun Yun, Zhao Xin-Sheng, Zou Yong-De, Lin Wei-Zhu, Gu Lian-Quan, Huang Yan-Yi, Huang Chun-Hui
Several ubiquinone, plastquinone analogs with long alkyl side chain were studied on the Langmuir-Blodgett(LB) film...
1998, 14 (03): 226-231.
A Computer Program for Quantized Calculation of Thermal Rate Constants of Unified Statistical Theory
Yin Shu-Xia, Wang Yan, Feng Wen-Lin
A computer program has been developed for calculating thermal rate constants of unified statistical theory by the multi-...
1998, 14 (03): 232-236.
Study on the lsothermal Solubility of Quaternary Systems KCl(K
Wei Xiao-Lan, Zhang Feng-Xing, Guo Zhi-Zhen, Shi Qi-Zhen
The solubilities refraction indices and densities of the saturated solutions of the titled quaternary systems at 25 ℃ ha...
1998, 14 (03): 237-242.
A Novel Synthesis Method for MCM-41 Mesoporous Silica Molecular Sieves
Zhang Zhao-Rong, Suo Ji-Shuan, Zhang Xiao-Ming, Li Shu-Ben
High quality MCM-41mesoporous silica molecular sieves were synthesized in high yield via improved S+X-I+ assembly pathwa...
1998, 14 (03): 243-248.
Studies on the Catalytic Properties for CO Hydrogenation of Supported Cu Catalysts Prepared by SMAI Method
Wu Shi-Hua, Zhu Chang-Ying, Huang Wei-Ping, Wu Wen-Yan
SiO2 and Cr2O3 supported Cu catalysts were prepared by Solvated Metal Atom Impregnation (SMAI) method. XPS measure...
1998, 14 (03): 249-253.
Electrochemical Behavior of Structural Units Co(PPh
Tong Ye-Xiang, Kang Bei-Sheng, Su Jing-Yu, Chen Zhong-Ning, Su Cheng-Yong, Zhang Hua-Xin
Linear sweep voltammetry has been used to study the electrochemical behavior of transition metal structural units Co(PPh...
1998, 14 (03): 254-256.
Hydrolysis of 2,4-Dinitrochlorobenzene in O/W Microemulsions
Shen Ji-Jing, Zhao Zhen-Guo, Ma, J. M.
The catalysis of O/W microemulsions of cetyltrimethylammonium bromide(CTAB),butyl alcohol, benzene and water to the hydr...
1998, 14 (03): 257-260.
Surface Adsorption and Micelle Formation of the Aqueous Mixture of C
He Shao-Guang, Zhao Guo-Xi
The surface adsorption and micellization of the mixed aqueous solution of C7FNa-Et4NBr system have been studied by the d...
1998, 14 (03): 261-266.
Eluent Gel Permeation Chromatography Method for Study of Non-associated Multi-components Solution
Wang Qing-Guo, Cai Li-Xing, Liu Bo, Li Guang-Ya, Hu Ping, Zhang Yu, Cheng Rong-Shi
A polyglycol solution containing different molecular weight PEG components was chosen as test solution. By comparing the...
1998, 14 (03): 267-269.
Multiphoton lonization of Diethylamine:"Ladder Switching"Model
Wei Jie, Fang Li, Zhang Lian-Di, Guo Wen-Yue, Zhang Shu-Dong, Jiang Yun-Yun, Cai Ji-Ye
The multiphoton ionization (MPI) of diethylamine is first reported in this paper. A time-of-flight mass spectrometer was...
1998, 14 (03): 270-274.
Effect of CO on Methanol Synthesis from CO
Li Ji-Tao, Zhang Wei-De, Qu Ze-Tang
The effect of CO on methanol synthesis from CO2 hydrogenation over Cu-Zn-Al catalysts have been investigated by TPSR-MS ...
1998, 14 (03): 275-277.
Study on the Comparison of the Kinetics of Ion Diffusion and Ilon Exchange in Charged Colloid
Li Hang, Chen Ming-Shu
Taking soil colloid and hydrated silica (quartz sand) as the experimental material, the comparative study has been made ...
1998, 14 (03): 278-282.
Sytheses and Structures of Co
-clusters Containing a Bridging Bidentate Ligand
Liu Qi-Wang, Cheng Qing-Min, Liu Shu-Tang, Hu Xiang, Huang Xiao-Ying
By the reaction of Co2(CO)8 with 2-thiohydantoins S-CNHC(O)C(R1) (R2)NC(O)R3(HL), a new cluster with formula Co3(C...
1998, 14 (03): 283-287.