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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1997 Vol. 13,No. 07
Published: 15 July 1997
Current column
Communication
ARTICLE
Note
Communication
Reductive Property of LaNi
5
-based Alloys
Hong Cun-Mao,Yang Yong
At room temperature, LaNi5-based multicomponent alloys can easily react with Cu2+ aqueous solution (such as the CuSO4 so...
1997, 13 (07): 577-579.
DOI: 10.3866/PKU.WHXB19970701
4919
Abstract/Metrics
2431
PDF(394KB)
ARTICLE
Mechanistic Study on the Effects of Preparation Parameters on the Structure Property of ZrO
2
Aerogels
Wang Yuan-Yang,Wu Dong,Fan Yan-Zhen,Sun Yu-Han,Chen Song-Ying
The mechanism for the effects of titration order, ageing medium and ammonia concentration on the properties of ZrO2 aero...
1997, 13 (07): 580-585.
DOI: 10.3866/PKU.WHXB19970702
5398
Abstract/Metrics
2769
PDF(899KB)
The Laser Induced Fluorescence Spectra of Eu(III) and Tb(III) Complexes with Mixed
β
-diketone and Organic Ligands
Shang Hai-Rong,Zhao Xin-Sheng,Tang You-Qi,Liu De-Wen,Bao Chun-Yun
The emission spectra and their lifetimes of the complexes of Eu(Ⅲ) and Tb(Ⅲ) with mixed β-diketone and organic liga...
1997, 13 (07): 586-592.
DOI: 10.3866/PKU.WHXB19970703
5250
Abstract/Metrics
2642
PDF(1032KB)
Studies on the Sturctures of Microemulsions
Hao Jing-Cheng,Wang Han-Qing,Ge Jin-Huan
The isothermal phase diagram for the system sodium dodecyle sulfonate/n-butanol/20% styrene/water has been determined at...
1997, 13 (07): 593-597.
DOI: 10.3866/PKU.WHXB19970704
6781
Abstract/Metrics
2593
PDF(801KB)
The Thermal Stability and Electrochemical Behaviors of A Novel Macrocyclic Dinuclear Nickel(III) Complex
Zhou Yu-Ming,Ge Yu-Hua,Gou Shao-Hua,Ju Huang-Xian,Liu Ju-Zheng
A new macrocyclic dinuclear nickel(Ⅲ) complex, prepared by the condensation of 2,6-diformylpyridine N-oxide with 1,3-dia...
1997, 13 (07): 598-602.
DOI: 10.3866/PKU.WHXB19970705
5943
Abstract/Metrics
2387
PDF(743KB)
The Visible Spectra and Electronic Effects in Axial Coordination Reaction of Zinc Porphyrin Complexes
Ruan Wen-Juan,Zhu Zhi-Ang,Chen Hong-Wei,Bu Xian-He,Zhang Zhi-Hui,Shao Ying,Chen
A thermodynamic study is reported for the coordination reaction of three new metal imidazolate complexes of unsymm...
1997, 13 (07): 603-611.
DOI: 10.3866/PKU.WHXB19970706
6293
Abstract/Metrics
2554
PDF(1463KB)
AM1 Study on the Thermolyses Mechanism of TNAZ and Its Derivatives
Zhang Jiao-Qiang,Zhu Chun-Hua,Gong Xue-Dong,Xiao He-Ming
SCF-MO-AM1 method has been employed to investigate the molecular geometries, electronic structures and thermolyses mecha...
1997, 13 (07): 612-616.
DOI: 10.3866/PKU.WHXB19970707
7417
Abstract/Metrics
2482
PDF(706KB)
Abnormal Pressure Effects of H
2
Three-photon Resonant Enhanced Ionization Spectroscopy
Zhang Gui-Qiu,Sha Guo-He,Xu Ji-Jun,Knott W.Proch D
The three-photon resonant ionization spectroscopy of H2 B1∑u+-X1∑g+ (12,0) and C1Ⅱu-X1∑g+ (2,0) exhibits abn...
1997, 13 (07): 617-620.
DOI: 10.3866/PKU.WHXB19970708
5269
Abstract/Metrics
2401
PDF(700KB)
Ab initio
Calculation of Linear C
n
Al
-
(n=1~11)
Liu Zhao-Yang,Huang Rong-Bin,Zheng Lan-Sun
Carbon cluster anions with an aluminum atom, CnAl-, were produced from laser ablation in the previous experiment. In thi...
1997, 13 (07): 621-625.
DOI: 10.3866/PKU.WHXB19970709
5324
Abstract/Metrics
2747
PDF(842KB)
A QSAR Research Method Based on Pseudoreceptor Model
Chen Hong-Ming,Zhou Jia-Ju,Xie Gui-Rong,Ren Tian-Rui
In this paper, PARM algorithm which can be used in QSAR research was put forward. In this algorithm, a set of pseudo ato...
1997, 13 (07): 626-631.
DOI: 10.3866/PKU.WHXB19970710
5587
Abstract/Metrics
2664
PDF(947KB)
Kinetics of Irreversible Reactions on Platinum Single Crystal Electrodes
Yang Yi-Yun,Sun Shi-Gang
The dissociative adsorption and oxidation of formic acid on Pt(100) single crystal electrode were investigated by using ...
1997, 13 (07): 632-636.
DOI: 10.3866/PKU.WHXB19970711
5435
Abstract/Metrics
2643
PDF(872KB)
Note
Determination of the Optimum Acidity of Bacteria Growth by Microcalorimetric Method
Liu Yong-Jun,Liu Ying,Sun Hai-Tao,Nan Zhao-Dong,Zhang Hong-Lin
The bacterial growth thermogram curves under different acidities were determined. From these thermogram curves, the grow...
1997, 13 (07): 637-639.
DOI: 10.3866/PKU.WHXB19970712
5313
Abstract/Metrics
2460
PDF(430KB)
Nonlinear Dynamic Phenomena in SCN
-
-BrO
3
-
-H
+
System
Huang Zhen-Yan,Hong Ying-Jun,Xu Hai-Han
The SCN--BrO3-H+ system has been studied in the batch and CSTR. In the CSTR the system displays sustained oscillations a...
1997, 13 (07): 640-642.
DOI: 10.3866/PKU.WHXB19970713
4576
Abstract/Metrics
2572
PDF(449KB)
Studies on Model Compound of Purple Acid Phosphatases Hydrolysis of ATP
Wang Tian-Zhi,Wu Ding-Quan,Huang Zai-Yin,Qu Song-Sheng,Li Dong-Feng,Liao Zhan-Ru
Studies on the thermokinetic properties of model compound of Purple acid phosphatases (Na2[Fe2(μ-O)(μ-OAC)2(IDA)2]...
1997, 13 (07): 643-646.
DOI: 10.3866/PKU.WHXB19970714
6026
Abstract/Metrics
2541
PDF(521KB)
Vacuum-ultraviolet Photoion Spectrum of Vinyl Chloride Near Ionization Threshlod
Sheng Liu-Si,Qi Fei,Gao Hui,Zhang Yun-Wu,Yu Shu-Qin
The photoionization efficiency curve (PIE) of C2H3Cl+ formation from C2H3Cl has been measured in wavelength region 105.0...
1997, 13 (07): 647-649.
DOI: 10.3866/PKU.WHXB19970715
5289
Abstract/Metrics
2715
PDF(487KB)
Study on Inhibition of Xanthine Oxidase by Umbelliferone
Kan Jin-Qing,Mu Shao-Lin
The investigation on inhibition of xanthine oxidase by umbelliferone was carried out using a polyaniline-xanthine oxidas...
1997, 13 (07): 650-654.
DOI: 10.3866/PKU.WHXB19970716
5383
Abstract/Metrics
2677
PDF(901KB)
Electrochemical Study of the Self-exchange between Viologen-thiol Self-assembled Monolayers and Alkanethiol on Gold Electrodes
Li Jing-Hong,Cheng Guang-Jin,Dong Shao-Jun
The preparation and cyclic voltammetric behaviors of self assembled monolayers (SAMs) containing electroactive viologen ...
1997, 13 (07): 655-658.
DOI: 10.3866/PKU.WHXB19970717
6533
Abstract/Metrics
2511
PDF(661KB)
Coordinating Properties of Nickel(II) tetra(4-
N
-benzylpyridyl) porphyrin in Aqueous Solution
Liu Zhi-Xian,Shi Shuang-Qun,Zhang Jian-Jun,Song Xin-Fang,Meng Min-Quan
Beer's law experiment, variable-temperature spectral experiment of UV-Vis absorption, 1H NMR, and measurement of magneti...
1997, 13 (07): 659-662.
DOI: 10.3866/PKU.WHXB19970718
5526
Abstract/Metrics
2525
PDF(747KB)
The Studies on Fluorescence Kinetics and Possible Structure of Binary Complex——Ti-3,5-dibromosalicylfluorone System
Zhu Bi-Xue,Shi Hong-Xin,Lin Zhi-Xin,Cai Ru-Xiu
The fluorescence kinetic characteristics of binary complex Ti-3,5-dibromosalicylfluorone (Ti-3,5-DBSAF) was studied by s...
1997, 13 (07): 664-668.
DOI: 10.3866/PKU.WHXB19970719
6389
Abstract/Metrics
2372
PDF(678KB)
Observation of Nanometer-sized Structures Using a Scanning Near-field Optical Microscope(SNOM)
Tang Ming,OuYang-Min,Cai Sheng-Min,Xue Zeng-Quan,Liu Zhong-Fan
A polydiacetylene nanocrystalline film has been fabricated using surface evaporation method and observed by using Aurora...
1997, 13 (07): 669-672.
DOI: 10.3866/PKU.WHXB19970720
5532
Abstract/Metrics
2544
PDF(691KB)