Acta Physico-Chimica Sinica
Acta Physico-Chimica Sinica
1996 Vol. 12,No. 01
Published:15 January 1996
Date of publication: 15 January 1996
Nonlinear Phenomena in Uncatalyzed Reaction of Some Sulfur Compounds with H
Gao Qing-Yu,Wang Yue-Min,Zang Ya-Ru,Ma Ke-qin,Zhao Xue-Zhuang
In absence of catalysts, Oscillations in the oxidation of KSCN、Na2S2O3 and SC(NH2)2 by H2O2 are observed in CSTR experim...
1996, 12 (01): 1-3
Temperature-dependent Solubilities of C
in Some Solvents
Zhou Xi-Huang,Liu Jian-Ben,Jin Zhao-Xia,Gu Zhen-Nan,Wu Yong-Qing,Sun Yi-Liang
The solubilities of C60 and C70 in toluene, o-xylene and CS2 between melting point and boiling point have been measured....
1996, 12 (01): 4-6
The Comparative Study on TiO
Luo Sheng-Cheng,Gui Lin-Lin,Tang You-Qi
TiO2-Al2O3 composites (TiO2 content is 0.08gTiO2/gAl2O3) were prepared by two methods: mixing gel and coprecipitation, a...
1996, 12 (01): 7-11
Study on the Intramolecular Electron Transfer of TTP-(CH
CHEN Jian-Xin, TIAN Hong-Jian, ZHANG Hong-Hao, ZHOU Qiang-Fu, HU Hui-Jun, XU Guang-Zhi
The intramolecular electron transfer of TTP-(CH2)n-Pc was studied by means of time correlated single-photon counting met...
1996, 12 (01): 12-17
The CIDEP Spectra of Photolized
-benzosemiquinone and 2-hydroxy-2-propyl Radicals
Zhang Wen-Min,He Guang-Long,Lu Tong-Xing
The CIDEP of photolized р-benzosemiquinone and 2-hydroxy-2-propyl radicals was measured with time-resolved ESR spe...
1996, 12 (01): 18-21
Hydrogen Evolution Reaction on Composite-Coated Electrodes of Ball Milling-Formed Nanocrystalline Ni-Co Alloy
Ma Jie,Jiang Xiong,Jiang Lin-Cai,Lv Man-Qi
The electrochemical behaviours of the hydrogen evolution reaction (HER) on electrodes prepared by composite coating of n...
1996, 12 (01): 22-28
Quantum Chemical Study of Hydrogen Abstraction from a Diamond (100) Surface
Rong Chui-Qing,Li Yan-Xin,Song Qing-Feng
Abstraction of terminal hydrogens on a diamond (100) surface by atomic hydrogen has been considered as a possible ...
1996, 12 (01): 29-32
The Adsoption of Thiourea and tis Derivatives on Iron Electrode in Acidic Solution
Dong Jun-Hua,Song Guang-Ling,Lin Hai-Chao,Cao Chu-Nan
The cathodic adsorption beheaviors of thiourea and 4 of its derivatives on iron in hydrochloric acid and sulphuric acid ...
1996, 12 (01): 34-38
Strcuture of Oriented Non-crystalline PET Studied with Two-dimensional WAXS Intensity by Symmetrical Transmission
Han Fu-Tian,Chen Ji-Zhou,Wang Jun-Qiao,Wu Xuan-Chi,Bin Ren-Mao
The two dimensional Wide Angle X-ray Scattering (WAXS) coherent intensity of oriented non-crystalline polyethylene tetre...
1996, 12 (01): 39-43
The Studies of the Supramolecular System of Porphyrin-Phthalocyanine Formed by Molecular Self-assembly and Its Photoinduced Electron Transfer Processes
Tian Hong-Jian,Zhou Qing-Fu,Shen Shu-Yin,Xu Hui-Jun
The supramolecular assemblies consisting of metal-free tetra(N-trimethylaminobenoxy) phthalocyanate (H2TAPc) and its zin...
1996, 12 (01): 44-48
Solubilization of Aqueous Solution of Electrolytes by Dodecylammonium Propionate in Carbon Tetrachloride
Huang Wen,Gu Ti-Ren
The limiting solubilization amount of aqueous solution of electrolytes, including NaCl, KCl, NaBr, NaI, CaCl2 and Na2SO4...
1996, 12 (01): 49-53
Laser Flash Photolysis of Tri(4-tert-butoxycarbonyloxyphenyl) Sulphonium Salts
Dai Guang-Song,Wu Shi-Kang,Schnabel W
The photochemical and photophysical behaviors of tri(4-tert-butoxycarbonyl oxyphenyl) sulphonium salts have been investi...
1996, 12 (01): 54-58
Bonding of Alkali-mercury and Alkanli-lead Clusters
Relativistic density-functional calculations on free Hg2, Hg4, Hg8, Pb2 and Pb4 clusters, and those clusters embedded in...
1996, 12 (01): 59-62
Highly Oriented Bi
(100) Thin Films Prepared by Sol-Gel Technique
Gu Hao-Shuang,Wang Shi-Min,Wu Xin-Min,Kuang An-Xiang,Ma Shi-An,Wang Lian-Shan,Zh
Highly oriented Bi4Ti3O12 thin films were prepared by Sol-Gel technique on SrTiO3(100) single crystal, using Bi(NO3)3.5H...
1996, 12 (01): 63-66
Regularity and Prediction of Molten Salt Phase Diagrams of Monovalent and Quadrivalent Metal Halide Binary Systems
Wang Xue-Ye,Kang De-Shan,Li Chong-He,Qin Pei,Chen Nian-Yi
Rules of molten salt phase diagrams of binary system MeX-Me’X4 (Me is monovalent metal, Me’ quadrivalent met...
1996, 12 (01): 67-70
H NMR Study of Active Species of Hydroformylation Catalyst
Li Da-Gang,Xia Chun-Gu,Sun Yan-Wen,Yang Wei-Man
The rhodium-phosphine complex catalyst Rh(CO)(acac)(PPh3)(Ⅰ) for 1-hexene hydroformylation was studied under the followi...
1996, 12 (01): 71-74
Molar Conductances of NaCl and KCl in Aqueous Methanol Mixtures at 298.15K
Zhang Suo-Jiang,Han Shi-Jun,Jin Yin-Dong
Molar conductances of NaCl and KCl in 0~100%(ω/ω) CH3OH-H2O have been measured by using the alternating cond...
1996, 12 (01): 75-80
The Relationship of Permeability Coefficient and Acid Concentration of Stripping Solution in the System of Supported Liquid Membrane
Mao Jian-Xin,Wang Qi,Chen Geng-Hua,Han Shi-Jun
A new permeability coefficient equation was theoretically derived. It contains both the acid concentration of feed solut...
1996, 12 (01): 81-84
The Preparation and Characterization of Alumina Membranes Supported by Porous Titanium Plate
Wang Wen-Tao,Zhong Bang-Ke
γ-alumine membranes supported by porous titanium plate were prepared by sol-gel techniqe with alumina isopropoxide...
1996, 12 (01): 85-90
Study on the Conformation of Three Cyclic Peptides and Their Correspondent Linear Peptides with CD Spectroscopy
Jiang Yun,Miao Zhen-Wei,Xu Xiao-Jie,Tang You-Qi
We used CD spectroscopy to study the conformations of three cyclic peptides (CP10E: cyclo[Glu(OBz1)-Pro-Gly-Glu(OBzl)-Gl...
1996, 12 (01): 91-95