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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1996 Vol. 12,No. 01
Published: 15 January 1996
Current column
Communication
ARTICLE
Note
Communication
Nonlinear Phenomena in Uncatalyzed Reaction of Some Sulfur Compounds with H
2
O
2
Gao Qing-Yu,Wang Yue-Min,Zang Ya-Ru,Ma Ke-qin,Zhao Xue-Zhuang
In absence of catalysts, Oscillations in the oxidation of KSCN、Na2S2O3 and SC(NH2)2 by H2O2 are observed in CSTR experim...
1996, 12 (01): 1-3.
DOI: 10.3866/PKU.WHXB19960101
4708
Abstract/Metrics
2467
PDF(482KB)
Temperature-dependent Solubilities of C
60
and C
70
in Some Solvents
Zhou Xi-Huang,Liu Jian-Ben,Jin Zhao-Xia,Gu Zhen-Nan,Wu Yong-Qing,Sun Yi-Liang
The solubilities of C60 and C70 in toluene, o-xylene and CS2 between melting point and boiling point have been measured....
1996, 12 (01): 4-6.
DOI: 10.3866/PKU.WHXB19960102
5950
Abstract/Metrics
2699
PDF(480KB)
ARTICLE
The Comparative Study on TiO
2
-Al
2
O
3
Composites
Luo Sheng-Cheng,Gui Lin-Lin,Tang You-Qi
TiO2-Al2O3 composites (TiO2 content is 0.08gTiO2/gAl2O3) were prepared by two methods: mixing gel and coprecipitation, a...
1996, 12 (01): 7-11.
DOI: 10.3866/PKU.WHXB19960103
5280
Abstract/Metrics
2487
PDF(838KB)
Study on the Intramolecular Electron Transfer of TTP-(CH
2
)
n
-Pc
CHEN Jian-Xin, TIAN Hong-Jian, ZHANG Hong-Hao, ZHOU Qiang-Fu, HU Hui-Jun, XU Guang-Zhi
The intramolecular electron transfer of TTP-(CH2)n-Pc was studied by means of time correlated single-photon counting met...
1996, 12 (01): 12-17.
DOI: 10.3866/PKU.WHXB19960104
5604
Abstract/Metrics
2729
PDF(814KB)
The CIDEP Spectra of Photolized
p
-benzosemiquinone and 2-hydroxy-2-propyl Radicals
Zhang Wen-Min,He Guang-Long,Lu Tong-Xing
The CIDEP of photolized р-benzosemiquinone and 2-hydroxy-2-propyl radicals was measured with time-resolved ESR spe...
1996, 12 (01): 18-21.
DOI: 10.3866/PKU.WHXB19960105
5242
Abstract/Metrics
2416
PDF(633KB)
Hydrogen Evolution Reaction on Composite-Coated Electrodes of Ball Milling-Formed Nanocrystalline Ni-Co Alloy
Ma Jie,Jiang Xiong,Jiang Lin-Cai,Lv Man-Qi
The electrochemical behaviours of the hydrogen evolution reaction (HER) on electrodes prepared by composite coating of n...
1996, 12 (01): 22-28.
DOI: 10.3866/PKU.WHXB19960106
5821
Abstract/Metrics
3012
PDF(1408KB)
Quantum Chemical Study of Hydrogen Abstraction from a Diamond (100) Surface
Rong Chui-Qing,Li Yan-Xin,Song Qing-Feng
Abstraction of terminal hydrogens on a diamond (100) surface by atomic hydrogen has been considered as a possible ...
1996, 12 (01): 29-32.
DOI: 10.3866/PKU.WHXB19960107
6046
Abstract/Metrics
2542
PDF(867KB)
The Adsoption of Thiourea and tis Derivatives on Iron Electrode in Acidic Solution
Dong Jun-Hua,Song Guang-Ling,Lin Hai-Chao,Cao Chu-Nan
The cathodic adsorption beheaviors of thiourea and 4 of its derivatives on iron in hydrochloric acid and sulphuric acid ...
1996, 12 (01): 34-38.
DOI: 10.3866/PKU.WHXB19960108
6429
Abstract/Metrics
2863
PDF(852KB)
Strcuture of Oriented Non-crystalline PET Studied with Two-dimensional WAXS Intensity by Symmetrical Transmission
Han Fu-Tian,Chen Ji-Zhou,Wang Jun-Qiao,Wu Xuan-Chi,Bin Ren-Mao
The two dimensional Wide Angle X-ray Scattering (WAXS) coherent intensity of oriented non-crystalline polyethylene tetre...
1996, 12 (01): 39-43.
DOI: 10.3866/PKU.WHXB19960109
6203
Abstract/Metrics
2742
PDF(845KB)
The Studies of the Supramolecular System of Porphyrin-Phthalocyanine Formed by Molecular Self-assembly and Its Photoinduced Electron Transfer Processes
Tian Hong-Jian,Zhou Qing-Fu,Shen Shu-Yin,Xu Hui-Jun
The supramolecular assemblies consisting of metal-free tetra(N-trimethylaminobenoxy) phthalocyanate (H2TAPc) and its zin...
1996, 12 (01): 44-48.
DOI: 10.3866/PKU.WHXB19960110
6501
Abstract/Metrics
2868
PDF(882KB)
Note
Solubilization of Aqueous Solution of Electrolytes by Dodecylammonium Propionate in Carbon Tetrachloride
Huang Wen,Gu Ti-Ren
The limiting solubilization amount of aqueous solution of electrolytes, including NaCl, KCl, NaBr, NaI, CaCl2 and Na2SO4...
1996, 12 (01): 49-53.
DOI: 10.3866/PKU.WHXB19960111
5603
Abstract/Metrics
2770
PDF(805KB)
Laser Flash Photolysis of Tri(4-tert-butoxycarbonyloxyphenyl) Sulphonium Salts
Dai Guang-Song,Wu Shi-Kang,Schnabel W
The photochemical and photophysical behaviors of tri(4-tert-butoxycarbonyl oxyphenyl) sulphonium salts have been investi...
1996, 12 (01): 54-58.
DOI: 10.3866/PKU.WHXB19960112
5121
Abstract/Metrics
2488
PDF(776KB)
Communication
Bonding of Alkali-mercury and Alkanli-lead Clusters
Liao Meng-Sheng
Relativistic density-functional calculations on free Hg2, Hg4, Hg8, Pb2 and Pb4 clusters, and those clusters embedded in...
1996, 12 (01): 59-62.
DOI: 10.3866/PKU.WHXB19960113
5235
Abstract/Metrics
2420
PDF(568KB)
Note
Highly Oriented Bi
4
Ti
3
O
12
/SrTiO
3
(100) Thin Films Prepared by Sol-Gel Technique
Gu Hao-Shuang,Wang Shi-Min,Wu Xin-Min,Kuang An-Xiang,Ma Shi-An,Wang Lian-Shan,Zh
Highly oriented Bi4Ti3O12 thin films were prepared by Sol-Gel technique on SrTiO3(100) single crystal, using Bi(NO3)3.5H...
1996, 12 (01): 63-66.
DOI: 10.3866/PKU.WHXB19960114
5483
Abstract/Metrics
2557
PDF(560KB)
Regularity and Prediction of Molten Salt Phase Diagrams of Monovalent and Quadrivalent Metal Halide Binary Systems
Wang Xue-Ye,Kang De-Shan,Li Chong-He,Qin Pei,Chen Nian-Yi
Rules of molten salt phase diagrams of binary system MeX-Me’X4 (Me is monovalent metal, Me’ quadrivalent met...
1996, 12 (01): 67-70.
DOI: 10.3866/PKU.WHXB19960115
5347
Abstract/Metrics
2972
PDF(640KB)
in situ
1
H NMR Study of Active Species of Hydroformylation Catalyst
Li Da-Gang,Xia Chun-Gu,Sun Yan-Wen,Yang Wei-Man
The rhodium-phosphine complex catalyst Rh(CO)(acac)(PPh3)(Ⅰ) for 1-hexene hydroformylation was studied under the followi...
1996, 12 (01): 71-74.
DOI: 10.3866/PKU.WHXB19960116
5619
Abstract/Metrics
2684
PDF(589KB)
Molar Conductances of NaCl and KCl in Aqueous Methanol Mixtures at 298.15K
Zhang Suo-Jiang,Han Shi-Jun,Jin Yin-Dong
Molar conductances of NaCl and KCl in 0~100%(ω/ω) CH3OH-H2O have been measured by using the alternating cond...
1996, 12 (01): 75-80.
DOI: 10.3866/PKU.WHXB19960117
6747
Abstract/Metrics
2831
PDF(882KB)
The Relationship of Permeability Coefficient and Acid Concentration of Stripping Solution in the System of Supported Liquid Membrane
Mao Jian-Xin,Wang Qi,Chen Geng-Hua,Han Shi-Jun
A new permeability coefficient equation was theoretically derived. It contains both the acid concentration of feed solut...
1996, 12 (01): 81-84.
DOI: 10.3866/PKU.WHXB19960118
4646
Abstract/Metrics
2556
PDF(580KB)
The Preparation and Characterization of Alumina Membranes Supported by Porous Titanium Plate
Wang Wen-Tao,Zhong Bang-Ke
γ-alumine membranes supported by porous titanium plate were prepared by sol-gel techniqe with alumina isopropoxide...
1996, 12 (01): 85-90.
DOI: 10.3866/PKU.WHXB19960119
6098
Abstract/Metrics
3272
PDF(1286KB)
Study on the Conformation of Three Cyclic Peptides and Their Correspondent Linear Peptides with CD Spectroscopy
Jiang Yun,Miao Zhen-Wei,Xu Xiao-Jie,Tang You-Qi
We used CD spectroscopy to study the conformations of three cyclic peptides (CP10E: cyclo[Glu(OBz1)-Pro-Gly-Glu(OBzl)-Gl...
1996, 12 (01): 91-95.
DOI: 10.3866/PKU.WHXB19960120
5341
Abstract/Metrics
2827
PDF(712KB)