Acta Physico-Chimica Sinica
Acta Physico-Chimica Sinica
1994 Vol. 10,No. 11
Published:15 November 1994
Date of publication: 15 November 1994
A New Model for Calculating log
for Organic Compounds
Lai Lu-Hua, Wang Ren-Xiao, Tang You-Qi
logP is an important parameter for evaluating the hydrophobicity of organic compounds and other species. It is widely us...
1994, 10 (11): 963-965
Cyclic Voltammetric Study of the
-Aminoxime Complexes [M(Ⅱ)(PnAO)-H]
Lin Hua-Kuan, Zhang Yuan-Ming, Zhu Shou-Rong, Chen Rong-Ti
The redox reaction of the aliphatic complexes [M(Ⅱ)(PnAO) H]+(M=Ni, Co, Cu, Pd) were studied by cyclic voltammetry...
1994, 10 (11): 966-970
Synergetic Effect between NaCl and B
in Modified FeO
Xiong Guo-Xing, Xia Xin-Rui, Chen Heng-Rong, Guo Xie-Xian
A series of NaCl/B2O3/Fe2O3 catalysts having a B/Fe atomic ratio from 0 to 0.3 and 0.25 of Na/Fe atomic ratio were prepa...
1994, 10 (11): 971-977
Study on Electronic Structure and
Excited Energies of Cr
Liu Han-Xing, Li Bo-Fu, Sun Jia-Zhong
A new way is developed for calculating the d-d excited energies by resolving many-electron Schrodinger equation based on...
1994, 10 (11): 978-985
The Reduction of Siver Complex on Catalytic Nuclei
Kang Qing-He, Sheng Li-Qin, Sun Ren-De, Zheng De-Shui, Chen Ping
The reduction of silver complex on different catalytic nuclei (Ag, PdS, Pt, and CoS) by hydroquinone was studied. Experi...
1994, 10 (11): 986-991
Studies on the Dispersion States of Nickel Salt and Oxide on NaY Zeolites
Gao Zi, Cui Jun
The Ni(NO3)2/NaY and NiO/NaY dispersed systems were studied by XRD,EXAFS, and TPR methods. It has been found that Ni(NO3...
1994, 10 (11): 992-997
Head Group Effect on Molecular Dynamics Simulation of Labgmuir Monolayers
Zhang Hong-Yu, Wei Yu
The structure and thermodynamics of stearate Lamgmuir film were studied using Molecular Dynamics and the effect of head ...
1994, 10 (11): 998-1003
A Theoretical Study on the Thermo Decomposition of HNCO to HNCNH and CO
Zhang Shao-Wen, Fu Xiao-Yuan
Ab initio RHF/3-21G method has been employed to study the mechanism of the bimolecular thermolysis of HNCO. The re...
1994, 10 (11): 1004-1008
Characterization of CO and/or NO Adsorbed on Reduced Rh-V/SiO
Catalyst by Infraed Spectroscopy
Li Xin-Sheng, Xin Qin, Zhang Hui, Li Jun, Zhou Jian-Lue, Chen Yao-Qiang, Chen Yu
In situ infrared spectroscopy has been used to study CO and/or NO adsorbed on reduced as/SiO2 and Rh-V/SiO2 catalysts. O...
1994, 10 (11): 1009-1014
A New Method for Calculating Activities Involving Binary Simple Eutectic Phase Diagrams
Sun Chen-Ling, Cai Wei-Juan, Xie Fan-You
New formulae for calculating activities of components from a binary simple eutectic phase diagram are presented in this ...
1994, 10 (11): 1015-1019
A Study on the Photophysical Behavior of Cross-conjugate Enone Compounds
Wang Peng-Fei, Yue Zhi-Jun, Wu Shi-Kang
Several cross-conjugate enone compounds with different electron withdrawing substituents have been synthesized. The spec...
1994, 10 (11): 1020-1025
A Study on Binary Mixtures of Alcohols by
He Li-Ping, Li Zhi-Fen, Liu Rui-Lin
1994, 10 (11): 1026-1030
Studies on the Oscillation of
Tang Yu-Hong, Liu Quan-Liang, Hou Yin-Lan
The oscillations of P-H2NC6H4COOH-KBrO3- H2SO4 system are studied. The dual-frequency oscillations are found in this sys...
1994, 10 (11): 1031-1034
Ellectrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrins III.Effects of Axial Ligands on Catalytic Activity of CoTPP
Zheng Guo-Dong, Yan Yan, Gao Sai, Tong Shan-Ling, Gao De
The effects of peptides, amino acids and organic bases as axial ligands on reaction activities in the electrocarboxylati...
1994, 10 (11): 1035-1039
Cathodoluminescence Images of Met.(Cu,Ag)-TCNQ Anion Radical Salts Organic Thin Films
Gu Ning, Shen Hao-Ying, Lu Wu, Wei Yu
We present here the first observation of cathodoluminescence (CL) images of Met. (Cu, Ag)-TCNQ anion radical salts organ...
1994, 10 (11): 1040-1044
Molecular Dynamics Study of NaCl-NaBr Melt
Huang Shi-Ping, Ma Yan-Hui, Tang Bo, Xu Hua, Chen Nian-Yi
Molecular dynamics method has been used to study NaCl-NaBr molten salt mixture, as one of the simplest examples of commo...
1994, 10 (11): 1045-1048
Underpotential Deposition of Antimony(III) at a Platinum
Li Hong, Jiang Lin-Cai, Jiang Xiong
The behavior of the UPD of Sb(Ⅲ) at a platinum anode has been systematically studied using various electrochemical techn...
1994, 10 (11): 1049-1054
Study on the Catalytic Property of Ni-WC Composite Electrode for Hydrogen Evolution Reaction in Weak Acidic Medium
Zhu Long-Zhang, Liu Shu-Lan, Tan Qi-Xian, Guo He-Tong
Ni-WC composite coating was obtained by using composite electrodeposition technique. The behavior of Ni-WC composite coa...
1994, 10 (11): 1055-1058