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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1994 Vol. 10,No. 09
Published: 15 September 1994
Current column
Communication
ARTICLE
Note
Review
Communication
He I Photoelectron Spectroscopy(UPS) of Isotopic
18
O
2
Molecules
Wang Dian-Xun, Li Ying, Li Sheng, Chen Ben-Ming
HeⅠ photoelectron spectrum of isotopic 18O2 molecules has been firstly recorded on a double-chambers UPS machine Ⅱ which...
1994, 10 (09): 771-773.
DOI: 10.3866/PKU.WHXB19940901
5462
Abstract/Metrics
2582
PDF(366KB)
ARTICLE
Thermal Decompositon Process and the Fragmentation Regularity of FAB-Mass Spectra of the Complex [Na
3
Fe(C
2
O
4
)
3
]
·
5H
2
O
Zheng Yu, Xie Wei-Wen, Zhang Lin-Na, Fu Gui-Xiang, Yu Lu, Zhu Zi-Ying
The thermal decomposition process of iron trisoxalato complex has been investigated by InSitu IR spectroscopy. The Produ...
1994, 10 (09): 774-778.
DOI: 10.3866/PKU.WHXB19940902
6036
Abstract/Metrics
2743
PDF(662KB)
Study of the Thermolysis of RC(X)OC(O)CH
3
Using MIVDO/3
Hong San-Guo, Wang Shen
MINDO/3 MO method has been used to study the thermolysis of RC(X)OC(O)CH3 (X=O or S). The results obtained show that ace...
1994, 10 (09): 779-784.
DOI: 10.3866/PKU.WHXB19940903
5410
Abstract/Metrics
2604
PDF(806KB)
Ligand Exchange Reactions of Lanthanide Complexes with Nitrilotriacetate Ln(NTA)
2
by
13
C and
1
H NMR
Ren Ji-Min, Jing Feng-Ying, Pei Feng-Kui, Wang Wen-Yun, Ni Jia-Zuan
Ligand exchange reactions were studied by VT 13C and 1H NMR for lanthanide complexes with nitrilotriacetate Ln(NTA...
1994, 10 (09): 785-789.
DOI: 10.3866/PKU.WHXB19940904
5747
Abstract/Metrics
2794
PDF(797KB)
Composite Sulfide Photocatalyst of Cu
χ
S
·
CdS Interface-Modified with Cobalt Phthalocyanine
Lv Gong-Xun, Li Shu-Ben, Savinov , E N, Parmon V N
A new kind of modification photocatalyst has been synthesized by coating CoPc on the interface CuxS and CdS. The p...
1994, 10 (09): 790-795.
DOI: 10.3866/PKU.WHXB19940905
5703
Abstract/Metrics
3083
PDF(1010KB)
The Structure and Labile Oxygen of Impurity-doped Perovskite-type Oxide
Qu Zhao-Jun, Yu Chun-Ying, Li Wen-Zhao, Chen Yi-Xuan
Perovskite type oxide has a stable cubic structure. XRD pattern showed that the fundamental structure of SrTiO3 is uncha...
1994, 10 (09): 796-801.
DOI: 10.3866/PKU.WHXB19940906
5600
Abstract/Metrics
2874
PDF(911KB)
Studies of PBN Spin Adducts by the Combined Technique of Quartz Capillary Column GC/MS/ESR
Chen De-Wen, Zhou Jian-Cheng, Ma Ren-Lan, Xu Gaung-Zhi, Long Yao-Ting, Sun Xiang-Yu, Zhao Yao-Xing
A new technique, high resolution quartz capillary column GC/MS/ESR combined with the silanization approach of free radic...
1994, 10 (09): 802-808.
DOI: 10.3866/PKU.WHXB19940907
5507
Abstract/Metrics
2737
PDF(980KB)
An Empirical Criterion for Superconductivity of Oxides
Zhao Liang-Zhong
In this article it is suggested that the Sanderson's equalized electronegativity, Seq, can be used as a new empiri...
1994, 10 (09): 809-812.
DOI: 10.3866/PKU.WHXB19940908
5238
Abstract/Metrics
2814
PDF(682KB)
Interaction between Palladium Microparticles and Polyaniline in Electrocatalytic Process for Oxidation of Formic Acid
Zhong Qi-Ling, Wu Wen, Li Wu-Hu, Tian Zhong-Qun
Electrochemical oxidation of formic acid at polyaniline films modified by palladium microparticles (PAN(Pd)) has been st...
1994, 10 (09): 813-817.
DOI: 10.3866/PKU.WHXB19940909
6452
Abstract/Metrics
2818
PDF(754KB)
Quantum Dynamics Calculations in Reaction of Cl with H
2
on SPK Potential Energy Surface
Zhao Mei-Shan
Accurate three-dimensional quantum dynamics calculations of state-to-state reactive probabilities for reaction Cl+H2&rar...
1994, 10 (09): 818-824.
DOI: 10.3866/PKU.WHXB19940910
5225
Abstract/Metrics
2682
PDF(1012KB)
A Theoretical Study on the Substituent Effect of Polythiophene
Zhou Chuan-Hua, Li Qi, Huang Yuan-He, Liu Ruo-Zhuang
We present a theoretical investigation of the electronic structure of some derivatives of poly-thiophene (PT), mainly po...
1994, 10 (09): 825-829.
DOI: 10.3866/PKU.WHXB19940911
6222
Abstract/Metrics
2587
PDF(977KB)
Studies on the Production and Dissociation of Coenzyme B
12
Models by Electrochemistry and Spectroelectrochemistry(II)
Zheng Guo-Dong, Yan Yan, Wang Ying, Huang Chu-Bao, Gao De, An Qing-Da
The reaction of CoTPP (cobalt tetrophenylporphyrin) with various alkyl bromides [CH3CH2Br; CH3(CH2)3Br; CH3(CH2)7Br; CH3...
1994, 10 (09): 831-837.
DOI: 10.3866/PKU.WHXB19940912
5988
Abstract/Metrics
2615
PDF(960KB)
Note
High Resolution Multiphoton Ionization Photoelectron Spectra of OCS
Yang Da-Lin, Ding Chuan-Fan, Zhou You, Cai Hui, Zhu Qi-He
Using a Nd:YAG pumped pulsed dye laser-wavelength extender as UV light source, the multiphoton ionization of o CS was st...
1994, 10 (09): 838-840.
DOI: 10.3866/PKU.WHXB19940913
5155
Abstract/Metrics
2456
PDF(514KB)
Linear Free Energy Relationships of Complexes(XIX)
Xian Jing-Chun, Zhu Shou-Rong, Lin Hua-Kuan, Chen Rong-Ti
The stability constants of 5-substituted phenanthroline-12-(2'-hydroxy 1-5substituted benzy1)-1,4,7,10-tetraazacyclotr a...
1994, 10 (09): 841-846.
DOI: 10.3866/PKU.WHXB19940914
6130
Abstract/Metrics
3001
PDF(845KB)
Synthesis and Crystal Structure of Rh
2
(
μ
-SC
6
H
5
)
2
(CO)
4
Wu Bing-Fang, Su Hai-Quan, Yan Xiu-Ying, Hu Xiang, Liu Shu-Tang, Liu Qi-Wang, Shi Jian-Qiu
The title compound was obtained by the reaction of Rh4 (CO)12 with P(SC6H5)3. The crystal structure of the compoun...
1994, 10 (09): 847-851.
DOI: 10.3866/PKU.WHXB19940915
5035
Abstract/Metrics
2504
PDF(774KB)
Observation of the Aggregation Morphology of CdS Nanoparticles in Stearate Labgmuir-Blodgett Films by Atomic Force Microscope
Yang Xiao-Min, Gu Zhong-Ze, Lu Zu-Hong, Wei Yu
Nanoparticles of CdS in Langmuir-Blodgett (LB) films were synthesized by exposing LB films of cadrium stearate (CdSt2) t...
1994, 10 (09): 852-855.
DOI: 10.3866/PKU.WHXB19940916
5520
Abstract/Metrics
2724
PDF(863KB)
Effect of Aliphatic Alcohol on the Twisted Intramolecular Charge Transfer in Charged Micelle Studied by Dual Fluorescence
Jiang Yun-Bao, Wang Xiu-Juan
The effects of aliphatic alcohol on the twisted intramolecular charge transfer (TICT) of p-N, N-dimethylaminobenzoic aci...
1994, 10 (09): 856-859.
DOI: 10.3866/PKU.WHXB19940917
6553
Abstract/Metrics
2707
PDF(665KB)