Acta Physico-Chimica Sinica
Acta Physico-Chimica Sinica
1994 Vol. 10,No. 04
Published:15 April 1994
Date of publication: 15 April 1994
Preparation of Alumina-pillared Layered Titanoniobates with Different Interlayer Distances
Hou Wen-Hua, Yan Qi-Jie, Peng Bing-Cheng, Fu Xian-Cai
A series of alumina-pillared layered titanoniobates with different interlayer distances were first prepared by using a s...
1994, 10 (04): 289-292
Chemiluminescence of the Reaction of He
Hu Yi-Hua, Chu Yan-Nan, Ni Jin-Zhi, Li Ying-Chun, LI Shu-Chao, Cao De-Zhao, Guo Jing-Zhong, Liu Chuan-Pu, Gu Yue-Shu
The reaction of He~*(2~3S)/CO_2 with CS_2 has been studied in discharge fiowing-afterglow apparatus. The emission spectr...
1994, 10 (04): 293-296
Kinetics and Mechanism of Oxidation of
-alanine by Dihydroxydiperiodatonickelate (IV) Complex Ion
Yang Li-Ting, Chang Qing, Wang Feng-Li, Wang An-Zhou
The kinetics of oxidation of α-alanine by dihydroxydiperiodatonickelate (Ⅳ) ion was studied by spectrophotometry i...
1994, 10 (04): 297-302
A Study of the Heterogenization of Heteropoly Acid(II)
Wang Xin-Ping, Ye Xing-Kai, Wu Yue
The surface chemincal species of surface-modified activated carbons and ad sorption of 12-silicotungstic acid (SiW_(12))...
1994, 10 (04): 303-307
Studies of Carbon Cluster Anions with a Heteroatom of IIIA or VA Group
Huang Rong-Bin, Liu Zhao-Yang, Zhao Jian-Hong, Lin Feng-Chen, Zheng Lan-Sun
A series of carbon cluster anions with a heteroatom have been generated on a home-made apparatus by laser abalation of a...
1994, 10 (04): 308-311
Kinetic Study on Porphinatoiron(III) Catalyzing Decomposition of
Ruan Wen-Juan, Zhu Zhi-Ang, Huang Xiao-Qun, Chen Rong-Ti, Jiang Dong-Qing
A spectrophotometric study of the kinetics of β-carotene oxidative decom-position to vitamin A is reported in this ...
1994, 10 (04): 312-318
Spectra Studies of Titanium and Vanadium-Pentadienyl-Carbonyl Compounds
Wang Yue, Liu Ju-Zheng, Jiang Shi-Mei, Liang Ying-Qiu
The characterization of a series of carbonyl adducts of open titanocenes, open vanadocenes and half-open vanadocene was ...
1994, 10 (04): 319-323
Study of Methane Oxidative Coupling over Ti-La-Li Mixed Oxides
Zhao Zhen, Yuan Song-Yue, Yu Zuo-Long
The composition and structures of Li-Ti-La minxed oxides as well as their catalytic activity for methane oxidative coupl...
1994, 10 (04): 324-329
The Study of Energy Transfer from Vibrational State to Electronic State in C
Li Quan-Xin, Yu Shu-Qin, Chen Cong-Xiang, Ma Xing-Xiao
Ethylene molecules were excited to high vibrational states by a TEA CO_2 laser, and then coilided with ground electronic...
1994, 10 (04): 330-335
Complexation Thermodynamics of Rare Earch(III) Nitrates with Stibeno-15-Crown-5 in Anhydrous Acetonitrile
Liu Yu, Lu Tong-Bu, Tan Min-Yu, Inoue Yoshihisa, Hakushi Tadao
Calorimetric titrations have been performed in anthydrous acetonitrile at 298.15 K in order to obtain the complex stabil...
1994, 10 (04): 336-341
Phase Diagram of Binary Systems YbCl
(M=Li, Mg, Ca, Pb; n=1 or 2)
Zheng Chao-Gui, Huang Shou-Lin, Wang Si-Qiang
The Phase diagrams of binary systems YbCl_3-MCl_n(M=Li, Mg, Ca, Pb; n=1 or 2) were investigated by means of DTA and X-ra...
1994, 10 (04): 342-347
Effect of VA Elements on the Semiconducting Properties of the Anodic Plumbous Oxide Flim(II)
Pu Zong, Zhou Wei-Fang
The semiconducting properties of t-PbO (also known as tet-PbO or α-PbO) in the anodic plumbous oxide films formed ...
1994, 10 (04): 348-353
The Determination of the Second Order Rate Coefficient of Enzymatic Reaction for the Mediator Enzyme Electrode
Lv Ming-Xiang, Dai Hong-Li, Zhang Guo-Heng
In this paper, the second order rate coefficient for homogeneous catalytic re action of ferrocene and its derivative hav...
1994, 10 (04): 354-359
Study on Bonding Behavior of the element Clusters Li
Zhang Hua-Bei, Liang Guo-Ming, Tian An-Min, Yan Guo-Sen
The Localized molecular orbitals of element clusters Li~e_n(n=1-6, 8; e=+1) have been calculated. The results show besid...
1994, 10 (04): 360-362
Collisional Quenching of Electronically Excited CH Radicals by Ar, NO and CHBr
Chen Cong-Xiang, Ran Qin, Yu Shu-Qin, Ma Xing-Xiao
The collisional quenching rate constants of CH(A, V'=0) by Ar and CHBr_3 and CH(A, B, V'=0) by NO molecule were measured...
1994, 10 (04): 363-366
LMO Study on the Reaction: H
Yang Jie, Liang Guo-Ming, Tian An-Min, Yan Guo-Sen
The localized molecular orbital (LMO) theory is used to study the reaction mechanism of the isomerization reaction: H_3P...
1994, 10 (04): 367-370
Approach to the Mechanism of the Electrochemiluminescence of Luminol in Aqueous Alkaline Solution
Fu Zhi-Dong, Lin Zhong-Hua, Huang Shao-Hua, Liu Min
The electrochemiluminescence (ECL) of the luminol in aqueous alkaline solu tion has been studied using cyclic voltammetr...
1994, 10 (04): 371-375
Photoelectrochemical Properties of Iron Oxide Ultrafine Particles
Yang Mai-Zhi, Li Hui-Ming, Cai Sheng-Min, Ji Yong-Jun
From the FeCl_3 solutions of different concentrations, the polycrystalline iron oxide ultrthee particles of different si...
1994, 10 (04): 376-380
The Effect of Additives on the Premicell Formation in Different Surfactant Solutions
Jiang Yong-Cai, Wu Shi-Kang
The mechanism of premicellar formation in aqueous solution of six kinds of ionic surfactant has been studied. By the int...
1994, 10 (04): 381-384