Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
1993 Vol. 9,No. 02
Published:15 April 1993
Date of publication: 15 April 1993
The Establishment of the SET-UP ion-Neutral Reaction and Application
Peng Yue-Xiang; Chen Xin-Guo; Song Fen-Hong; Qiu Lian-Xiong
This paper reports the establishment of the set-up of ion-neutral reaction and the measurement of the rate constant of t...
1993, 9 (02): 145-147.
Studies on Langmuir-Blodgett Films of Luminescent Rare-Earth Chelates (I)
Qian Dong-Jin; Yang Kong-Zhang
Two series of luminescent rare-earth chelates have been studied spectroscopically, one is(TOPO)_2Eu(β-dik)_3(TOPO=tri-n-...
1993, 9 (02): 148-154.
Theoretical Study on the Dynamic Properties and State-Selected rate Constants of the Reaction CH(
Liu Ruo-Zhuang; Ma Si-Yu; Li Zong-He
Tbe reaction path (IRC or MEP) of the reaction CH(~4∑~-)+H_2→CH_2(~3B_1)+H has been traced by Fukui's theory and ab init...
1993, 9 (02): 155-160.
Non-Linear Elemental Exciton and Electronic Level of C
Yan Li-Gen; Wang De-Min; Li Ming; Jia Rong-Yi
The electronic states of a C_(60) molecule have been calculated by using the SSH model. The electronic energy spectrum a...
1993, 9 (02): 161-164.
Electronic Structures and Conductivities of Halogen-Containing Carbon-Sixty C
Lu Chong-Xian; Kong Jing; Yan Ji-Min
1993, 9 (02): 165-169.
Determination of O
Binding Energies of the Alkaline Earth Oxides and Peroxide
The O_(1s) binding energy of MgO, CaO, SrO and BaO were determined by means of XPS. Prior to the determination,the sampl...
1993, 9 (02): 170-174.
Study on the Polarographic Behaviors of Morin
Li Nan-Qiang; Xu You-Xuan
The electrochemical properties of morin(MOR)over the entire pH range were studied. Four reduction waves were obtained. P...
1993, 9 (02): 175-180.
Application of SPE(Solid Polymer Electrolyte) in Electrooxidation of Cinnamyl Alcohol(I)
SPE (Solid Polymer Electrolyte) composite electrodes were utilized for the selective oxidation of allyl alcohol to aldeh...
1993, 9 (02): 181-186.
Study on Dispersion of V
on Surface of SiO
and the Effect of Promoter K
Zhao Bi-Ying; Wang Qiu-Xia; Tang You-Qi
It has been shown by in situ XRD that V_2O_5 can disperse spontaneously onto the surface of silica gel, but the dispersi...
1993, 9 (02): 187-192.
Preparation,Pillarinc Structure and Thermal Stability of Hydroxy-Fe-Al Pillared Clays Containing Mixed-Metal Complexes(I)
Zhao Dong-Yuan; Yang Ya-Shu; Guo Xie-Xian; Wang Guo-Jia
A series of Hydroxy-Fe-Al Pillared Clays (FeAl-PILC) containing mixed-metal complexes with various Fe/Al ratios were pre...
1993, 9 (02): 193-199.
Study on the Property of Orientation Distribution Function for Uniaxially two-Dimensional Condensed Phases
Zhang Yun-Hong; Tian Yong-Chi; Liang Ying-Qiu
In this paper, the property of orientation distribution function composed of second and fourth legendre polynomials was ...
1993, 9 (02): 200-205.
The Catalytic Oxidation of Co Over Ba
Deng Jing-Fa; Peng Ying; Jiang An-Ren; Wang Zhi-Hong
High temperature oxide superconducters Ba_(2-x)Sr_xYCu_3O_(7-a) (x=0, 0.25, 0.50, 0.75, 1.0, 1.25) was prepared using hi...
1993, 9 (02): 206-210.
AES Chemical Shift and Application on Surface Chemistry
The relationship of AES chemical shift with clement valence and electronegativity is discussed. It has also offered Auge...
1993, 9 (02): 211-217.
Studies on the Oscillation of
Gao Zhi-Di; Liu Jun-Li; Han De-Gang; Shen Shi-Gang; Wang An-Zhou
The oscillations of m-C_6H_4(OH)_2-KBrO_3-H_2SO_4 (system A) as well as m-C_6H_4(OH)_2-KBrO_3-H_2SO_4-MnSO_4(system B) h...
1993, 9 (02): 218-223.
The Viscosity Behaviour of SEP Block Copolymer Solution During its Micellization
Zhou Wei-Ping; He Zhi-Duan; Zhang Hao; Zhang Hai-Bo
The viscosities of polystyrene-b-poly (ethylene/propylene) diblock copolymer in mixed solvent of n-octane and benzene we...
1993, 9 (02): 224-228.
Effect of the Length of Alkane Skeleton on the Thermodynamic Function of Microemulsion with Nonionic Surfactant
Hao Ce; Sun Zhi-Gang; Chen Zong-Qi; Shi Cai-Yun
This paper reported the studies on the microemulsion of TritonX-100, hexanol, Water and alkane system. △G_(s→i)~0, the v...
1993, 9 (02): 229-232.
Studying on Stability of Emulsion Liquid Membrane with Moving Single Drop Method
Zhang He-Zhe; Bai Guang-Yue; Wang Yue-Jie; Yang Zhong
We detailed the stability of ELM with glutamic acid dialkyl esters as surfactants by moving single drop method. It is a ...
1993, 9 (02): 233-237.
A Study on UV and Visible Fluorescence Produced by Irmpd of Trimethyl Phosphite
Lu Qing-Zheng; Tao Li; Yu Shu-Qin; Kong Fan-Ao
IR multi-photon dissociation (IRMPD) of trimethyl phosphite has been carried out by a TEA CO_2 laser. The fluorescence s...
1993, 9 (02): 238-241.
Application of Pervaporation Membrane to Catalytic Esterification Reaction
Gao Zi; Yue Ying-Hong; Li Wen-Jun
Studies on pervaporation separation of alcohol/water mixture and pervaporation-aided catalytic esterification reaction h...
1993, 9 (02): 242-246.
Quenching Rate Constants for Metastable Molecule CS(
Wang Hai-Qing; Gu Yue-Shu; Guo Jing-Zhong; Liu Chuan-Pu; Yin Yong-Jia; Cao De-Zhao
The metastable molecule CS(a~3Π) has been obtained, by the energy transfer reaction of He(2~3S) with CS_2 in a discharge...
1993, 9 (02): 247-251.
Electronic Structure and Chemical Bond of Complex La(NO
Dong Nan; Zhu Long-Guan; Wu Nian-Ci
The electronic structure and chemical bonds in La(NO_3)_3·bipy·2H_2O·(B-15-C-5) has been studied by INDO method. The res...
1993, 9 (02): 252-255.
Investigation on the Structure of Electronic Energy Bands of Polydiacetylenes
Zhang Qi-Yuan; Yan Ji-Min; Zhang Da-Ren
The influences of the side phenyls (PHs) on the electronic energy band-structure of polydiaeetylenes have been studied b...
1993, 9 (02): 256-262.
Determination of the Activity Coefficients of TBP in
-Cetane by Cryoscopic Method
The activity coefficients of TBP in n-cetane have been determined by cryoscopic method. This method is simpler, more rap...
1993, 9 (02): 263-267.
Study on the Ferrocene-Containing Ploynuculi Metal Complexes Quenching Luminescence of
Xia Xu-Bing; Duan Chun-Ying; Zhu Long-Gen; Cao Hong; You Jing-Jing
Ferrocene-containing ploynuclear metal complexes M(Fe-C(CH_3)=N N=CSSR)_2 (M=Ni~(2+), Cu~(2+), Zn~(2+), Pd~(2+), Co~(2+)...
1993, 9 (02): 268-272.
Spontaneous Oscillation of Electrical Potential Across Liquid Membrane
Wang Shou-Xiang; Qiu Zhi-Xin; Chen Sen; Gong Jian-Ping
An artificial membrane consisting of pricramic acid in nitrobenzene was used as an oil phase imposed between two aqueous...
1993, 9 (02): 273-276.
Photoelectrochemical Polymerization of Conducting Polymer Monomers
Chen Yan-Zhen; Gu Zhi-Jun; Tian Zhong-Qun
The photoelectrochemical polymerization process: monomer first polymerizes into low polymer and then the low polymer may...
1993, 9 (02): 277-280.