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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1993 Vol. 9,No. 02
Published: 15 April 1993
Current column
Communication
ARTICLE
Note
Review
Communication
The Establishment of the SET-UP ion-Neutral Reaction and Application
Peng Yue-Xiang; Chen Xin-Guo; Song Fen-Hong; Qiu Lian-Xiong
This paper reports the establishment of the set-up of ion-neutral reaction and the measurement of the rate constant of t...
1993, 9 (02): 145-147.
DOI: 10.3866/PKU.WHXB19930201
5000
Abstract/Metrics
2465
PDF(588KB)
Studies on Langmuir-Blodgett Films of Luminescent Rare-Earth Chelates (I)
Qian Dong-Jin; Yang Kong-Zhang
Two series of luminescent rare-earth chelates have been studied spectroscopically, one is(TOPO)_2Eu(β-dik)_3(TOPO=tri-n-...
1993, 9 (02): 148-154.
DOI: 10.3866/PKU.WHXB19930202
5184
Abstract/Metrics
2797
PDF(1629KB)
Theoretical Study on the Dynamic Properties and State-Selected rate Constants of the Reaction CH(
4
Σ
-
)+H
2
→CH
2
(
3
B
1
)+H
Liu Ruo-Zhuang; Ma Si-Yu; Li Zong-He
Tbe reaction path (IRC or MEP) of the reaction CH(~4∑~-)+H_2→CH_2(~3B_1)+H has been traced by Fukui's theory and ab init...
1993, 9 (02): 155-160.
DOI: 10.3866/PKU.WHXB19930203
5201
Abstract/Metrics
2589
PDF(1163KB)
Non-Linear Elemental Exciton and Electronic Level of C
60
Molecule
Yan Li-Gen; Wang De-Min; Li Ming; Jia Rong-Yi
The electronic states of a C_(60) molecule have been calculated by using the SSH model. The electronic energy spectrum a...
1993, 9 (02): 161-164.
DOI: 10.3866/PKU.WHXB19930204
4416
Abstract/Metrics
2415
PDF(741KB)
Electronic Structures and Conductivities of Halogen-Containing Carbon-Sixty C
60
X
Lu Chong-Xian; Kong Jing; Yan Ji-Min
1993, 9 (02): 165-169.
DOI: 10.3866/PKU.WHXB19930205
5142
Abstract/Metrics
2878
PDF(870KB)
ARTICLE
Determination of O
1
s
Binding Energies of the Alkaline Earth Oxides and Peroxide
Zhao Liang-Zhong
The O_(1s) binding energy of MgO, CaO, SrO and BaO were determined by means of XPS. Prior to the determination,the sampl...
1993, 9 (02): 170-174.
DOI: 10.3866/PKU.WHXB19930206
6650
Abstract/Metrics
2919
PDF(1190KB)
Study on the Polarographic Behaviors of Morin
Li Nan-Qiang; Xu You-Xuan
The electrochemical properties of morin(MOR)over the entire pH range were studied. Four reduction waves were obtained. P...
1993, 9 (02): 175-180.
DOI: 10.3866/PKU.WHXB19930207
5405
Abstract/Metrics
2839
PDF(1315KB)
Application of SPE(Solid Polymer Electrolyte) in Electrooxidation of Cinnamyl Alcohol(I)
Chen Zhen
SPE (Solid Polymer Electrolyte) composite electrodes were utilized for the selective oxidation of allyl alcohol to aldeh...
1993, 9 (02): 181-186.
DOI: 10.3866/PKU.WHXB19930208
4967
Abstract/Metrics
2815
PDF(1270KB)
Study on Dispersion of V
2
O
5
on Surface of SiO
2
and the Effect of Promoter K
2
SO
4
Zhao Bi-Ying; Wang Qiu-Xia; Tang You-Qi
It has been shown by in situ XRD that V_2O_5 can disperse spontaneously onto the surface of silica gel, but the dispersi...
1993, 9 (02): 187-192.
DOI: 10.3866/PKU.WHXB19930209
5273
Abstract/Metrics
2771
PDF(1461KB)
Preparation,Pillarinc Structure and Thermal Stability of Hydroxy-Fe-Al Pillared Clays Containing Mixed-Metal Complexes(I)
Zhao Dong-Yuan; Yang Ya-Shu; Guo Xie-Xian; Wang Guo-Jia
A series of Hydroxy-Fe-Al Pillared Clays (FeAl-PILC) containing mixed-metal complexes with various Fe/Al ratios were pre...
1993, 9 (02): 193-199.
DOI: 10.3866/PKU.WHXB19930210
6277
Abstract/Metrics
2588
PDF(1530KB)
Study on the Property of Orientation Distribution Function for Uniaxially two-Dimensional Condensed Phases
Zhang Yun-Hong; Tian Yong-Chi; Liang Ying-Qiu
In this paper, the property of orientation distribution function composed of second and fourth legendre polynomials was ...
1993, 9 (02): 200-205.
DOI: 10.3866/PKU.WHXB19930211
4978
Abstract/Metrics
2896
PDF(1184KB)
The Catalytic Oxidation of Co Over Ba
2-
x
Sr
x
YCu
3
O
7-
a
Deng Jing-Fa; Peng Ying; Jiang An-Ren; Wang Zhi-Hong
High temperature oxide superconducters Ba_(2-x)Sr_xYCu_3O_(7-a) (x=0, 0.25, 0.50, 0.75, 1.0, 1.25) was prepared using hi...
1993, 9 (02): 206-210.
DOI: 10.3866/PKU.WHXB19930212
5707
Abstract/Metrics
2606
PDF(967KB)
AES Chemical Shift and Application on Surface Chemistry
Zhu Yong-Fa
The relationship of AES chemical shift with clement valence and electronegativity is discussed. It has also offered Auge...
1993, 9 (02): 211-217.
DOI: 10.3866/PKU.WHXB19930213
5650
Abstract/Metrics
4052
PDF(1768KB)
Studies on the Oscillation of
m
-C
6
H
4
(OH)
2
-KBrO
3
-H
2
SO
4
System
Gao Zhi-Di; Liu Jun-Li; Han De-Gang; Shen Shi-Gang; Wang An-Zhou
The oscillations of m-C_6H_4(OH)_2-KBrO_3-H_2SO_4 (system A) as well as m-C_6H_4(OH)_2-KBrO_3-H_2SO_4-MnSO_4(system B) h...
1993, 9 (02): 218-223.
DOI: 10.3866/PKU.WHXB19930214
5699
Abstract/Metrics
2866
PDF(1171KB)
The Viscosity Behaviour of SEP Block Copolymer Solution During its Micellization
Zhou Wei-Ping; He Zhi-Duan; Zhang Hao; Zhang Hai-Bo
The viscosities of polystyrene-b-poly (ethylene/propylene) diblock copolymer in mixed solvent of n-octane and benzene we...
1993, 9 (02): 224-228.
DOI: 10.3866/PKU.WHXB19930215
5568
Abstract/Metrics
2706
PDF(989KB)
Note
Effect of the Length of Alkane Skeleton on the Thermodynamic Function of Microemulsion with Nonionic Surfactant
Hao Ce; Sun Zhi-Gang; Chen Zong-Qi; Shi Cai-Yun
This paper reported the studies on the microemulsion of TritonX-100, hexanol, Water and alkane system. △G_(s→i)~0, the v...
1993, 9 (02): 229-232.
DOI: 10.3866/PKU.WHXB19930216
5906
Abstract/Metrics
2632
PDF(718KB)
Studying on Stability of Emulsion Liquid Membrane with Moving Single Drop Method
Zhang He-Zhe; Bai Guang-Yue; Wang Yue-Jie; Yang Zhong
We detailed the stability of ELM with glutamic acid dialkyl esters as surfactants by moving single drop method. It is a ...
1993, 9 (02): 233-237.
DOI: 10.3866/PKU.WHXB19930217
5358
Abstract/Metrics
2691
PDF(944KB)
A Study on UV and Visible Fluorescence Produced by Irmpd of Trimethyl Phosphite
Lu Qing-Zheng; Tao Li; Yu Shu-Qin; Kong Fan-Ao
IR multi-photon dissociation (IRMPD) of trimethyl phosphite has been carried out by a TEA CO_2 laser. The fluorescence s...
1993, 9 (02): 238-241.
DOI: 10.3866/PKU.WHXB19930218
4743
Abstract/Metrics
2646
PDF(824KB)
Application of Pervaporation Membrane to Catalytic Esterification Reaction
Gao Zi; Yue Ying-Hong; Li Wen-Jun
Studies on pervaporation separation of alcohol/water mixture and pervaporation-aided catalytic esterification reaction h...
1993, 9 (02): 242-246.
DOI: 10.3866/PKU.WHXB19930219
6406
Abstract/Metrics
2993
PDF(1005KB)
Quenching Rate Constants for Metastable Molecule CS(
α
3
П
)
Wang Hai-Qing; Gu Yue-Shu; Guo Jing-Zhong; Liu Chuan-Pu; Yin Yong-Jia; Cao De-Zhao
The metastable molecule CS(a~3Π) has been obtained, by the energy transfer reaction of He(2~3S) with CS_2 in a discharge...
1993, 9 (02): 247-251.
DOI: 10.3866/PKU.WHXB19930220
4866
Abstract/Metrics
2594
PDF(1020KB)
Electronic Structure and Chemical Bond of Complex La(NO
3
)
3
·
bipy
·
2H
2
O
·
(B-15-C-5)
Dong Nan; Zhu Long-Guan; Wu Nian-Ci
The electronic structure and chemical bonds in La(NO_3)_3·bipy·2H_2O·(B-15-C-5) has been studied by INDO method. The res...
1993, 9 (02): 252-255.
DOI: 10.3866/PKU.WHXB19930221
5395
Abstract/Metrics
2460
PDF(785KB)
Investigation on the Structure of Electronic Energy Bands of Polydiacetylenes
Zhang Qi-Yuan; Yan Ji-Min; Zhang Da-Ren
The influences of the side phenyls (PHs) on the electronic energy band-structure of polydiaeetylenes have been studied b...
1993, 9 (02): 256-262.
DOI: 10.3866/PKU.WHXB19930222
5143
Abstract/Metrics
3147
PDF(1455KB)
Determination of the Activity Coefficients of TBP in
n
-Cetane by Cryoscopic Method
Chen Jin-Bang
The activity coefficients of TBP in n-cetane have been determined by cryoscopic method. This method is simpler, more rap...
1993, 9 (02): 263-267.
DOI: 10.3866/PKU.WHXB19930223
5204
Abstract/Metrics
2817
PDF(929KB)
Study on the Ferrocene-Containing Ploynuculi Metal Complexes Quenching Luminescence of
*
[Cr(bpy)
3
]
3+
Xia Xu-Bing; Duan Chun-Ying; Zhu Long-Gen; Cao Hong; You Jing-Jing
Ferrocene-containing ploynuclear metal complexes M(Fe-C(CH_3)=N N=CSSR)_2 (M=Ni~(2+), Cu~(2+), Zn~(2+), Pd~(2+), Co~(2+)...
1993, 9 (02): 268-272.
DOI: 10.3866/PKU.WHXB19930224
4812
Abstract/Metrics
2980
PDF(1049KB)
Spontaneous Oscillation of Electrical Potential Across Liquid Membrane
Wang Shou-Xiang; Qiu Zhi-Xin; Chen Sen; Gong Jian-Ping
An artificial membrane consisting of pricramic acid in nitrobenzene was used as an oil phase imposed between two aqueous...
1993, 9 (02): 273-276.
DOI: 10.3866/PKU.WHXB19930225
4368
Abstract/Metrics
2640
PDF(755KB)
Photoelectrochemical Polymerization of Conducting Polymer Monomers
Chen Yan-Zhen; Gu Zhi-Jun; Tian Zhong-Qun
The photoelectrochemical polymerization process: monomer first polymerizes into low polymer and then the low polymer may...
1993, 9 (02): 277-280.
DOI: 10.3866/PKU.WHXB19930226
5395
Abstract/Metrics
2785
PDF(800KB)