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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1992 Vol. 8,No. 05
Published: 15 October 1992
Current column
Communication
ARTICLE
Note
Review
Communication
The Influence of Aggregation of Bilayer Membrane Containing Schiff Base Moiety Upon the Fluorescence Efficiency
Wu Li-Xin; Tian Yong-Chi; Liang Ying-Qiu
Single chain amphiphiles containing Schiff base chromophore can organize into bilayer membrane as vesicles in aqueous so...
1992, 8 (05): 577-579.
DOI: 10.3866/PKU.WHXB19920501
4654
Abstract/Metrics
2627
PDF(519KB)
The Steady State Properties of Electrochemical Reduction of C
60
Yang Han-Xi; Xiao Yi-Jin; Zhu Ling; Sheng Rong-Sheng; Chen Su-Nian; Li Gui-Hua
The electroreduction of C_(60) was investigated by microelectrode voltammetry and in-situ optically transparent thin lay...
1992, 8 (05): 580-582.
DOI: 10.3866/PKU.WHXB19920502
5004
Abstract/Metrics
2623
PDF(539KB)
Vesicle Formation in Aqueous Solution of Surfactant Mixture
Zhao Guo-Xi; Huang Jian-Bin
1992, 8 (05): 583-585.
DOI: 10.3866/PKU.WHXB19920503
5535
Abstract/Metrics
3397
PDF(1048KB)
ARTICLE
Hydrogen Absorption Kinetics of LaNi
5
Alloy
Hong Cun-Mao; Lin Qiu-Zhu; Han De-Gang
Hydrogen absorption kinetics of LaNi_5-H system in α and α+β phases has been investigated. Taking the reversibility of h...
1992, 8 (05): 586-594.
DOI: 10.3866/PKU.WHXB19920504
6507
Abstract/Metrics
2521
PDF(1617KB)
Pore Structure and Catalytic Behavior of Modified Y Zeolites
Tang Yi; Hua Wei-Ming; Gao Zi
The N_2 adsorption and desorption isotherms of Y zeolites modified by hydrothermal treatment (HUSY), H_4EDTA dealuminati...
1992, 8 (05): 595-601.
DOI: 10.3866/PKU.WHXB19920505
4632
Abstract/Metrics
3018
PDF(1225KB)
Solvatochromic Behavior and Photophysical Properties of Pyrazoline Derivatives in Solvents
Yang Guo-Qiang; Wu Shi-Kang
In this work, after the synthesis of a series of substituted diphenyl pyrazoline compounds, their solvatochromic behavio...
1992, 8 (05): 602-608.
DOI: 10.3866/PKU.WHXB19920506
7015
Abstract/Metrics
3032
PDF(1183KB)
In-Situ
Electroluminescence Study of Copper Electrode Surface
Cai Sheng-Min; Kan Jin-Qing; Tian Wei-Fu; Mu Shao-Lin
The surface structure and other related properties of copper electrodes in 0.25 mol·L~(-1) Na_2S_2O_8+1.25 mol·L~(-1) Na...
1992, 8 (05): 609-612.
DOI: 10.3866/PKU.WHXB19920507
5068
Abstract/Metrics
2750
PDF(726KB)
The Studies of Pore Structures of High-Silica Y Zeolites by N
2
Adsorption
Pei Zhan-Fen; Liu Xing-Yun; Li Xuan-Wen
The properties of pore structure of high-silica Y zeolites prepared by combined hydrothermal-chemical treatments have be...
1992, 8 (05): 613-618.
DOI: 10.3866/PKU.WHXB19920508
5415
Abstract/Metrics
2768
PDF(1067KB)
Determination of Apo-Metallothionein's Protonation Constants and Complexing Constants With Cadmium Ion
Duan Zhen-Wen; Wang Wen-Qing; Chen Xiang-Yang; Wang Xiang-Yun; Ru Bing-Gen; Chu De-Ying; Lin Yu
Metallothionein (MT) is a protein of molecular weight about 6000 Dalton obtained from liver of rat, rabbit and silver ca...
1992, 8 (05): 619-624.
DOI: 10.3866/PKU.WHXB19920509
5465
Abstract/Metrics
2923
PDF(1078KB)
Rovibrationally Excited States of Diatomic Molecules
Fang Jian-Yun
The present paper developes a simple method for calculating the rovibrationally excited states of diatomic molecules. In...
1992, 8 (05): 625-629.
DOI: 10.3866/PKU.WHXB19920510
4237
Abstract/Metrics
2462
PDF(754KB)
Correlation of Composition、Crystal Structure、Reducibility and Catalytic Oxidation Activity on La-Mn-Ni-O System
Du Shao-Bin; Wang Jin; Ma Fu-Tai; Zheng Hong-Yuan; Lou Hui; Jing Cheng-Heng
The correlation of the composition, structure, IR, TPR and catalytic activity for CO and CH_3OH oxidation on LaMn_(1-x)N...
1992, 8 (05): 630-635.
DOI: 10.3866/PKU.WHXB19920511
5404
Abstract/Metrics
2390
PDF(1065KB)
Vapor-Liquid Equilibrium for Some Polar Aprotic Solvents with Methanol or 1,2-Dichloroethane
Wang Yi-Xuan; Zhao Jian-Ping; Dai Ming
Isobaric vapor-liquid equilibrium data have been measured at 99.3 kPa for the binary mixtures of acetone(AON), ethyl ace...
1992, 8 (05): 636-641.
DOI: 10.3866/PKU.WHXB19920512
7564
Abstract/Metrics
2892
PDF(1002KB)
Crystal Structure and Thermal Analysis of Erbium Complex with Benzene Acetic Acid
Wang Zeng-Lin; Hu Ning-Hai; Niu Chun-Ji; Ni Jia-Zuan; Cui Ai-Li
The crystal structure of erbium (Ⅲ) complex of benzene acetic acid is reported. The complex crystallizes in the monoclin...
1992, 8 (05): 642-646.
DOI: 10.3866/PKU.WHXB19920513
5726
Abstract/Metrics
2423
PDF(833KB)
The Solution Structure Studies of L-Lysine by Means of NMR Lanthanide Shift Reagent
Wang Jian-Jun; Wang Xiao-Chun; Ouyang Yi-Shan; You Yu-Jian; Dai An-Bang
~(13)C NMR spectral studies have been performed on the structure of the adducts of lanthanide ions and L-lysine using aq...
1992, 8 (05): 647-653.
DOI: 10.3866/PKU.WHXB19920514
6055
Abstract/Metrics
2602
PDF(1217KB)
Note
Theoretical Study on the Tautomeric Reaction of Acetaldehyde Into Vinyl Alcohol and Ketene Into Ethynol
Ma Si-Yu; Feng Wen-Lin
The tautomeric mechanism of acetaldehyde into vinyl alcohol and ketene into ethynol have been investigated theoretically...
1992, 8 (05): 654-658.
DOI: 10.3866/PKU.WHXB19920515
6353
Abstract/Metrics
2922
PDF(845KB)
Solvent Effect on Conformations of
α
,
ω
-Bis(4-Nitrophenoxy)-Alkanes
Sun Xiang-Yu; Zhao Yao-Xing; Liang Xiao-Tian
Solvent effect on the conformations of α,ω-bis(4-nitrophenoxy)-alkanes with different chain lengths(N_n) was studied by ...
1992, 8 (05): 659-663.
DOI: 10.3866/PKU.WHXB19920516
5232
Abstract/Metrics
2555
PDF(835KB)
The Liquid Crystal Structure Between System SDS/Decanol/Glycerol and SDS/Decanol/Formamide
Guo Rong; Zhu Xia-Shi; Yan Peng-Quan
The interlayer spacing of lamellar liquid crystal decreased with increase of the weight ratio of decanol/SDS at constant...
1992, 8 (05): 664-667.
DOI: 10.3866/PKU.WHXB19920517
5951
Abstract/Metrics
2707
PDF(1605KB)
The Electrode Kinetics of Cathodic Reduction of Pd(II)-Complex and Zinc Chloride in DMF
Zhang Ping-Ping; Zhang Wu-Chang; Zhang Ting-Fang; Zhou Wen-Juan; Wang Zhi-Qin
In this paper the electrode kinetics of cathodic reduction of dichloro-bis(triphenyl-phosphine) palladium complex and zi...
1992, 8 (05): 668-672.
DOI: 10.3866/PKU.WHXB19920518
5207
Abstract/Metrics
2909
PDF(778KB)
A Calculation of Ion Solvation Enthalpy in Aqueous and Nonaqueous Solutions
Wang Feng-Yun; Ye Jing-Xian; Chen Min-Sheng
In the light of the interactions between particles, this paper is a calculation of the standard solvation enthalpies for...
1992, 8 (05): 673-676.
DOI: 10.3866/PKU.WHXB19920519
6803
Abstract/Metrics
3031
PDF(677KB)
Raman Spectra of Triallylthiourea Cadmium Bromide Crystal
Li Li-Xia; Wang Ji-Yang; Yuan Duo-Rong; Qin Shi-Ying; Yu Hui; Zheng Ying
In this paper, we reported the Raman Scattering characteristics of a new Organo-metallic complex crystal-Triallylthioure...
1992, 8 (05): 677-680.
DOI: 10.3866/PKU.WHXB19920520
4872
Abstract/Metrics
2668
PDF(640KB)
An EPR Study of DL-
α
-Tocopherol Neutral Radical
Feng Liang-Bo; Wang Han-Qing
The DL-α-tocopherol neutral radical (α-T) produced by the hydrogen abstraction of DL-α-tocopheral (α-TH) with di-tert-bu...
1992, 8 (05): 681-684.
DOI: 10.3866/PKU.WHXB19920521
5072
Abstract/Metrics
2525
PDF(638KB)
A Preliminary Approach to the Chemical Kinetics of CuCl Oxidization
Fan Chong-Zheng; Wang Chang-Sui; Zhao Hua-Zhang; Wang Sheng-Jun
XRD and SPM techniques were used to identify the products and reaction rates for CuCl oxidization. The results showed tb...
1992, 8 (05): 685-689.
DOI: 10.3866/PKU.WHXB19920522
5537
Abstract/Metrics
2712
PDF(790KB)
Microemulsion and Lamellar Liquid Crystal of CTMAB-C
5
H
11
OH-H
2
O System and Their Solubilization
Yan Peng-Quan; Guo Rong; Zhu Xia-Shi; Shen Ming
When C_7H_(16) was solubilized, both the molecular number ratio of CTMAB and C_5H_(11)OH in the interfacial layer of O/W...
1992, 8 (05): 690-693.
DOI: 10.3866/PKU.WHXB19920523
5246
Abstract/Metrics
2726
PDF(704KB)
Surface Tension and Density of NaCl-NaF-RE
2
O
3
Melts
Lu Hua-Yi; Guo Chun-Tai; Zhao Lian-Shan; Tang Ding-Xiang; Wang Fen
Surface tension and density of NaCl-NaF-RE_2O_3 melts have been measured by means of maximum buble pressure and Archimed...
1992, 8 (05): 694-696.
DOI: 10.3866/PKU.WHXB19920524
5811
Abstract/Metrics
2731
PDF(451KB)
Behavior of Quenching of Pyrene Fluorescence by Alkylbenzylammonium in Aqueous Solution
Jiang Yun-Bao; Xu Jin-Gou
The quenchings of pyrene fluorescence were studied with tetradecylbenzyldime- thylammonium chloride (Zeph) and benzyltri...
1992, 8 (05): 697-701.
DOI: 10.3866/PKU.WHXB19920525
5567
Abstract/Metrics
2685
PDF(888KB)
A Study on the Structure and Luminescent Properties of (Sr
1-x
,Eu
x
)B
4
O
7
Liu De-Wen; Mo Shu-Cheng; Chen Zhao-Zong
A sample was produced by heating the mixture of boric acid, strontium carbonate added europium oxide at 800—1000 ℃ in re...
1992, 8 (05): 702-706.
DOI: 10.3866/PKU.WHXB19920526
4504
Abstract/Metrics
2847
PDF(793KB)
Effect of Supporting Electrolyte on the Electrochemical Oxidation Pathways of Anhydrous Methanol at Gold Electrode
Zhou Zhi-Hua; Hu Wei-Dong; Lu Wen-Qing; Zhou Yi-Ming; Xue Kuan-Hong
The electroxidation mechanism of methanol at gold electrode with different supporting electrolytes in anhydrous methanol...
1992, 8 (05): 707-711.
DOI: 10.3866/PKU.WHXB19920527
6268
Abstract/Metrics
2845
PDF(755KB)