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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1992 Vol. 8,No. 04
Published: 15 August 1992
Current column
Communication
ARTICLE
Note
Communication
Electrochemical Formation of Porous Silicon
Qian Bi-Dong; Cai Sheng-Min; Hou Yong-Tian; He Guo-Shan; Zhang Shu-Lin
1992, 8 (04): 433-435.
DOI: 10.3866/PKU.WHXB19920401
5980
Abstract/Metrics
2837
PDF(455KB)
Mass Spectrometry of Laser Generated Negative Carbon Cluster Ions(II)
Huang Rong-Bin; Zheng Lan-Sun
Mass spectrum of negative cluster carbon ions with cluster size up to 100 was recorded on a self-built laser plasma sour...
1992, 8 (04): 436-437.
DOI: 10.3866/PKU.WHXB19920402
4804
Abstract/Metrics
2564
PDF(430KB)
Generation of a New Type of Borane Anions with Laser Ablation
Huang Rong-Bin; Zheng Lan-Sun; Zhu Yong-Bao; Zhang Qian-Er
By laser ablation of NaBH_4 on a home-made instrument, four series of borane anions B_nH_m~- with formular of n=3k+1, m=...
1992, 8 (04): 438-440.
DOI: 10.3866/PKU.WHXB19920403
4911
Abstract/Metrics
2879
PDF(452KB)
ARTICLE
The Absorption Peaks of Sodium Aluminate Solutions
Liu Hong-Lin; Cao Yi-Lin; Chen Nian-Yi
MNDO and X_a methods have been used for the quantum chemical calculation of [Al_2O(OH)_6]~(2-) and Al(OH)_4~- ions exist...
1992, 8 (04): 441-444.
DOI: 10.3866/PKU.WHXB19920404
6556
Abstract/Metrics
2678
PDF(614KB)
Energy Band Structures of Duble Tl-O Layer Tl-Ba-Ca-Cu Oxide Superconductors
Cao Yang; Liu Jian
We calculated the energy band structures of the double TI-O layer TI-Ba-Ca-CuO oxide superconductors by performing the t...
1992, 8 (04): 445-451.
DOI: 10.3866/PKU.WHXB19920405
5389
Abstract/Metrics
2663
PDF(1163KB)
The Characteristic Behavior of H
2
and O
2
Over CeO
2
and Pt/CeO
2
Catalysts
Chen Yan-Xin; Li Can; Li Wen-Zhao; Chen Yi-Xuan
The characteristic behavior of H_2 and O_2 over CeO_2 and Pt/CeO_2 was studied by means of TPR, TPD, FT-IR and TPEC. The...
1992, 8 (04): 452-458.
DOI: 10.3866/PKU.WHXB19920406
6135
Abstract/Metrics
2856
PDF(1314KB)
The Inhibition Effects of Tributylphosphate on the Raoiolysis of Cyclohexane
Zhang Nan; Wu Ji-Lan
The inhibition effects of tributylphosphate on the radiolysis of cyclohexane have been reported. Combintion of the inhib...
1992, 8 (04): 459-463.
DOI: 10.3866/PKU.WHXB19920407
5007
Abstract/Metrics
2766
PDF(766KB)
Mechanism of Uptake of Amino Acid on ion Exchange Resin in Dilute Solutions
Tao Zu-Yi; Zhang Bao-Lin; Sheng Fen-Ling
The uptake of glycine by 001×7, a strong acid cation exchange resin and 201×7, a strong base anion exchange resin at low...
1992, 8 (04): 464-469.
DOI: 10.3866/PKU.WHXB19920408
6713
Abstract/Metrics
3194
PDF(1212KB)
Effect of Sulfur Species on H
2
Adsorption on Supported Palladium Catalyst
Xiao Tian-Cun; An Li-Dun; Zhang bing; Jiang Zhi-Cheng
A series of supported palladium catalysts were prepared with impregnating method. SO_4~(2-) was introduced by dipping Al...
1992, 8 (04): 470-475.
DOI: 10.3866/PKU.WHXB19920409
6031
Abstract/Metrics
2933
PDF(1163KB)
Spectroelectrochemical Investigation on Indigo Carmine II. Heterogeneous Electron Transfer Kinetics of Indigo Carmine
Shen Bao-En; Wang Gui-Liang; Tang Yin-Xuan
The heterogeneous electron transfer kinetic parameters of Indigo Carmine at tin dioxide optically transparent electrode ...
1992, 8 (04): 476-480.
DOI: 10.3866/PKU.WHXB19920410
5754
Abstract/Metrics
3267
PDF(942KB)
A Study on Association of Amine With Several Solutes by Infrared Spectrometry
Wang Jin-Ben; Wang Yi-Xuan; Zhang Fu-Qiang; Zhao Jian-Ping; Dai Ming
Infrared spectra of binary mixtures of aniline or N-methylaniline with n-heptane, carbon tetrachloride, benzene or tolue...
1992, 8 (04): 481-486.
DOI: 10.3866/PKU.WHXB19920411
6019
Abstract/Metrics
2765
PDF(1033KB)
Study on the Form and Size Distribution of La(OH)
3
-Aggregation
Deng Zhao-Jing; Li Sheng-Ze; Zeng Xiang-Ji
In the form-space,the form-distribution for the ensemble of La(OH)_3-aggregation has been described. On the basis of thi...
1992, 8 (04): 487-492.
DOI: 10.3866/PKU.WHXB19920412
5072
Abstract/Metrics
2537
PDF(1317KB)
Studies on the Dilute Solution Behavior of Polysaccharide of Pleuratu Ostretus
Zheng Chang-Ren; Zhu Zhi-Min; Gu Yun-Le; Hu Lei; Fu Ting-Zhi; Ou Hui-Chun
The polysaccharide of pleuratu ostreatus was fractionated by repeated precipitation method. Modified Elias cloud-point t...
1992, 8 (04): 493-499.
DOI: 10.3866/PKU.WHXB19920413
4629
Abstract/Metrics
2511
PDF(1197KB)
Note
Kinetics of Oxidation of Sodium Tartrate by Ni(IV) Periodate Complex in Aqueous Alkaline Medium
Xie En-Hai; Meng Qing-Shui; Wang Zhi-Pu
The kinetics and mechanism of electron transfer from sodium tartrate to Ni(Ⅳ) periodate complex have been studied in aqu...
1992, 8 (04): 500-504.
DOI: 10.3866/PKU.WHXB19920414
5854
Abstract/Metrics
2891
PDF(764KB)
Spectroscopic Study on Sodium Fluorescein in Ethanol Solution
Zhang Gui-Lan; Yu Bao-Long; Chen Wen-Ju
In this paper, the spectra of absorption, fluorescence excitation and fluorescence emission for the ethanol solutions of...
1992, 8 (04): 505-509.
DOI: 10.3866/PKU.WHXB19920415
5736
Abstract/Metrics
3815
PDF(880KB)
The Effects of Pre-Exsisting Particles on the Formation of Uniform Colloidal Particles
Zhang Yu-Ting; Lv Tong
The presence of pre-exsisting foreign particles will strongly affect the formation, morphology and even the crystal type...
1992, 8 (04): 510-514.
DOI: 10.3866/PKU.WHXB19920416
4999
Abstract/Metrics
2706
PDF(1899KB)
Impendance Analysis for the Interface of Polyaniline and PEO-LiClO
4
Complex
Zhang Sheng-Shui; Chou Wei-Hua; Liu Qing-Guo; Yang Lei-Ling
Poly(aniline) (PAn) was synthesized by chemical oxidation with (NH_4)_2S_2O_8 as oxidant, and the interface between PAn ...
1992, 8 (04): 515-518.
DOI: 10.3866/PKU.WHXB19920417
6541
Abstract/Metrics
3164
PDF(740KB)
Electrochemistry and XPS of Palladium Oxides
Wu Hui-Huang; Wu Bao-Zhang; Zhou Shao-Min
Palladium oxide electrodes were prepared by decomposition of Pd(NO_3)_2 or thermal oxidation of Pd, their voltammetric c...
1992, 8 (04): 519-522.
DOI: 10.3866/PKU.WHXB19920418
5167
Abstract/Metrics
2624
PDF(649KB)
The Transmembrane Potential of HCG Antibody-Binding Membrane
Lv Ming-Xiang; Fang Dao-Bin; Zhang Jie; Chen Kun-Ming
In this paper the antibody of HCG was immobilzed on the cellulose acetate membrane. The membrane potentials varied with ...
1992, 8 (04): 523-526.
DOI: 10.3866/PKU.WHXB19920419
4827
Abstract/Metrics
2785
PDF(730KB)
Effect of Added Elements on Solidification Process of Al-Si Alloys
Wang Zi-Chen; Wang Xiao-Hui; Zhang Li-Hua; Zhao Mu-Yu
The influence of added elements on the solidification process of Al-Si alloys was systematially investigated by DTA and ...
1992, 8 (04): 527-529.
DOI: 10.3866/PKU.WHXB19920420
4795
Abstract/Metrics
2809
PDF(590KB)
Vibrational Spectrum and Normal Coordinate Analysis on Rh(acac)(CO)
2
Liu Sheng-Ming; Lin Zheng-Yan; Yin Yuan-Qi
The Raman and infrared spectra of dicarbonyl (acetylacetonato) rhodium have been measured form 4000 to 80 cm~(-1). A nor...
1992, 8 (04): 530-535.
DOI: 10.3866/PKU.WHXB19920421
6299
Abstract/Metrics
3002
PDF(789KB)
Multiphoton Ionization Spectrum and Mass Measurement of Tetramethylsilane
Lu Qing-Zheng; Shi De-Heng; Yu Zhi-Guang; Ma Xing-Xiao; Kong Fan-Ao
MPI spectrum of Si(CH_3)_4 has been measured in the wavelength range of 410—370 nm. Most of the peaks with strong backgr...
1992, 8 (04): 536-539.
DOI: 10.3866/PKU.WHXB19920422
4399
Abstract/Metrics
2703
PDF(843KB)
Studies on the Structures and Electrical Propertis of Iodine-Doped 3-Ethyl-5-(2-(3-Ethyl-2-Benzothiazolinylidene)-Ethylidene)-Rhodanine
Chang You-Ming; Deng Xiao-Dong
The merocyanine dye 3-ethyl-5-(2-(3-ethyl-2-benzothiazolinylidene)-ethylidene)-rhodanine (BTER) known as Agfa-10 has bee...
1992, 8 (04): 540-544.
DOI: 10.3866/PKU.WHXB19920423
5914
Abstract/Metrics
2675
PDF(1810KB)
Crystal Structures of 1,2-Dimethyl-3-Indolmethyl-Idene Succinic Fulgide Anhydride and 1,2-Dimethyl-3-Indolylethylidene Succinic Fulgide Anhydride
Fan Guang-Yu; Wang Huan-Zhong; Cui Xiu-Shan; Li Yun-Zheng; Zhu He-Sun
The crystal structures of 1,2-dimethyl-3-indolylmethylidene succinic fulgide anhydride (1) and 1,2-dimethyl-3-indolyleth...
1992, 8 (04): 545-549.
DOI: 10.3866/PKU.WHXB19920424
4827
Abstract/Metrics
2883
PDF(836KB)
DV
-X
α
Cluster Calculations of Local Electronic Structure for Amorphous Co-B Alloy
Ni Min; He Li-Ming; Jin Qian-Yuan; Liu Hong-Lin
In the research on metallic glass, there are arguments against the "rigid band charge transfer", model which assumes a c...
1992, 8 (04): 550-554.
DOI: 10.3866/PKU.WHXB19920425
4963
Abstract/Metrics
3011
PDF(861KB)
Photoelectrochemical Studies of Intercalation Reaction
Dong Qing-Hua; Kong Wei-He; Wu Bing-Liang
The electrochemical intercalation reaction of lithium cell was investigated by photoelectrochemical technique. The exper...
1992, 8 (04): 555-557.
DOI: 10.3866/PKU.WHXB19920426
4883
Abstract/Metrics
2451
PDF(566KB)
The Determination of Thermodynamic Characteristics of Several Rare Earth Hydrogen-Storage Alloys by Electrochemical Method
Zhou Zuo-Xiang; He Chun-Hong; Wang Zheng-Ping; Wang Chun-Ming
The p—C—T curves of three kinds of hydrogen-storage alloys were examined by solid-gas phase hydrogen absorbing-desorbing...
1992, 8 (04): 558-562.
DOI: 10.3866/PKU.WHXB19920427
4879
Abstract/Metrics
2922
PDF(862KB)
Measurement of Surface Area of Solid With Microadsorption Flow Calorimetry
Gao Lan; Yan Hai-Ke
Specific surface area of solid is an important physico-chemical parameter. This kind of information is frequently requir...
1992, 8 (04): 563-566.
DOI: 10.3866/PKU.WHXB19920428
4805
Abstract/Metrics
2554
PDF(578KB)
Alternating Current Conductivity of
α
-Zirconium Phosphate Mixed with Fumed Silica in Hydrogen Form
Hao Jin-Ku; Zhao Wei-Jun; Fang Yan-Quan; Zhang Shu-Ji
α-layered zirconium phosphate was obtained by direct precipitation method. Composites formed by α-zirconium phosphate an...
1992, 8 (04): 567-570.
DOI: 10.3866/PKU.WHXB19920429
4841
Abstract/Metrics
2719
PDF(696KB)
The Mechanism of Chromium Electrodeposition From Chromic Acid Solution
Tan Qi-Xian; Liu Shu-Lan; Cheng Dan-Hong; Guo He-Tong
Electrodeposition process of metallic Cr from chromic acid solution was investigated with techniques of AC impedance, po...
1992, 8 (04): 571-574.
DOI: 10.3866/PKU.WHXB19920430
5423
Abstract/Metrics
2967
PDF(766KB)