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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1991 Vol. 7,No. 04
Published: 15 August 1991
Current column
Communication
ARTICLE
Note
Review
Communication
FREE Energy of Symmetric Catanionic Surfactants in Micellization and Surface Adsorption
Zhu Bu-Yao; Zhao Guo-Xi
1991, 7 (04): 385-389.
DOI: 10.3866/PKU.WHXB19910401
5974
Abstract/Metrics
2988
PDF(3245KB)
Ca
2+
Sublattice and F
-
Sublattice in Superionic Conductor CaF
2
Cheng Zhao-Nian; Zhang Jing; Jia Zheng-Ming; Chen Nian-Yi
In the molecular dynamics study of the superionic conductor CaF_2, the structures of Ca~(2+) sublattice and F~- sublatti...
1991, 7 (04): 390-393.
DOI: 10.3866/PKU.WHXB19910402
6137
Abstract/Metrics
2658
PDF(3215KB)
Mass Spectrometry of Laser Generated Negative InP Cluster Ions
Zhang Peng; Huang Rong-Bin; Li Wen-Ying; Su Jian-Rui; Zheng Lan-Sun
Both positive and negative InP cluster ions were generated on a self-built laser probe time-of-flight mass spectrometer....
1991, 7 (04): 394-395.
DOI: 10.3866/PKU.WHXB19910403
5301
Abstract/Metrics
2466
PDF(2123KB)
Effect of Structural Mudulation on Electronic Structure of Bi
2
Sr
2
CuO
6
Chen Xue-An; Fu Heng; Tang You-Qi; Zhu Min-Hui; Xu Jiang
Tight-binding band calculations of the Extended Huckel type were performed on the modulated Bi_2Sr_2CuO_6 sublattice in ...
1991, 7 (04): 396-399.
DOI: 10.3866/PKU.WHXB19910404
5329
Abstract/Metrics
2754
PDF(3373KB)
31
P-NMR Studies on Complexation of Fe
4
S
4
*
with ATP
Wu Ye-Fan; Li Chun-Fang; Zeng Ding; Hong Liang; Lin Guo-Dong; Cai Qi-Rui
Chemical modeling studies of ATP driven electron-transfer in Nitrogenase reaction show that adenylate compounds can comp...
1991, 7 (04): 400-403.
DOI: 10.3866/PKU.WHXB19910405
4717
Abstract/Metrics
2649
PDF(3040KB)
ARTICLE
Theoretical Stury of Electronic Structures of Some Octahedral Transition Metal Complexes
Shen Yi-Min; Li Bo-Fu; Sun Jia-Zhong
An irreducible tensor method based on restricted Hartree-Fock method for calculating many-electron states and energy lev...
1991, 7 (04): 404-408.
DOI: 10.3866/PKU.WHXB19910406
4988
Abstract/Metrics
2503
PDF(3435KB)
A Photoelectrochemical Study of Cyclic Voltammetry of MnO
2
Electrode
Yang Hua-Quan; Liu Xin; Cai Sheng-Min; Zhou Guo-Ding
Electrochemical and photoeletrochemical properties of electrodepositing γ-MnO_2 are studied when it is charged and disch...
1991, 7 (04): 409-412.
DOI: 10.3866/PKU.WHXB19910407
5609
Abstract/Metrics
2758
PDF(3201KB)
Interaction Between Cationic-Antonic and Zwitterionic Surfactant in Mixed Aqueous Solutions
Ding Hui-Jun; Tian Bin; Zhao Guo-Xi
Cationic-anionic surfactants have a high surface activity. But they are liable to precipitate as the concetration is sli...
1991, 7 (04): 413-419.
DOI: 10.3866/PKU.WHXB19910408
6386
Abstract/Metrics
2822
PDF(4764KB)
A Study on CH
5
O
+
Ions in Gas Phase CID Experiment and Quantum Chemistry Calculation
Guo Chun-Xiao; Hou Dong-Yan; Liu Shu-Ying
The structures of CH_5O~+ from two different reactions which are protonation of CH_3OH and association of CH_3~+ with wa...
1991, 7 (04): 420-424.
DOI: 10.3866/PKU.WHXB19910409
4319
Abstract/Metrics
2470
PDF(3521KB)
Positron Annihilation and Electrostatic Field in Zeolites
Gao Zi; Yang Xue-Min; Wang Yu
Positron annihilation measurements have been carried ont for Y zeolites with different types of cations, faujasites with...
1991, 7 (04): 425-429.
DOI: 10.3866/PKU.WHXB19910410
4925
Abstract/Metrics
2472
PDF(3953KB)
Comparsion Between the Ion Exchange Equilibria of Strong and Weak Base Anion Exchange Resins SO
2-
4
-Cl
-
-NO
-
3
System
Tao Zu-Yi; Wang Gang; Yu Chang-Ying
The ion exchange isotherms, the corrected selectivity coefficients and the rational thermodynamic equilibrium constants ...
1991, 7 (04): 430-435.
DOI: 10.3866/PKU.WHXB19910411
6165
Abstract/Metrics
2819
PDF(4686KB)
Biomimitics of Oxidase and Oxygenase The Electronic Spectra and the Oxygen Uptake Kintics for MPc and MTPP(M=Fe,Co,Cu,Pc and TPP-Are Dianions of Phthalocyanin and Tetraphenyl-Porphyrine, Respectively)
Zhao De-Chao; Ye Xing-Kai; Wu Yue
The kinetics of oxygen-uptake in DMF medium for MPc and MTPP catalytic systems has been investigated by means of measuri...
1991, 7 (04): 436-442.
DOI: 10.3866/PKU.WHXB19910412
8236
Abstract/Metrics
2691
PDF(4698KB)
Statistical Mechanical Treatment of Adsorbed Monolayer at Electrode/Solution Interface III. The Structure of Inner Layer Formed at the Interface of Hg/(H
2
O+CH
3
OH) Solution
Su Wen-Duan; Zhou Shao-Min; Zhou Xiao-Lin
The model proposed in previous paper was applied to metal/(mixed-solvents) solution system. According to this model, the...
1991, 7 (04): 443-448.
DOI: 10.3866/PKU.WHXB19910413
5812
Abstract/Metrics
2631
PDF(4661KB)
Studies of Trial and Error Methof for Crystal Structural Determinations(II)——Modifications of the Super-Solution Phase Eqation
Hou Yong-Geng; Ma Zhi-Mei; Fu Heng
In this paper, it is demonstrated that |E(k)E(h-k)| is a structure invari ant. On the basis of this knowledge, three mod...
1991, 7 (04): 449-455.
DOI: 10.3866/PKU.WHXB19910414
5517
Abstract/Metrics
2707
PDF(3848KB)
Kinetics of the Formation of (Para-Substituted Tetraphenylporphinato)-Copper(II) and the Catalytic Effect of Other Matal Ions
Zhu Zhi-Ang; Xia Xin; Chen Rong-Ti
The kinetics of formation reaction of Copper(Ⅱ) with para-substituted tetraphenylporphyrin H_2(p-X)TPP (X=NO_2,Cl,H, CH_...
1991, 7 (04): 456-461.
DOI: 10.3866/PKU.WHXB19910415
6025
Abstract/Metrics
2598
PDF(4496KB)
Note
A Constructuion Method of the Extended Basis Hybrid Orbital
Chang Guang-Jie; Li Jun
On the basis of the analysis of various construction methods of the hybrid orbitals, the conept of the extended basis hy...
1991, 7 (04): 462-466.
DOI: 10.3866/PKU.WHXB19910416
4719
Abstract/Metrics
2450
PDF(3582KB)
Calorimetric Determination of the Heat of Formation of Competitive Ternary Complex Compounds
Lin Hua-Kuan; Gu Zong-Xin; Zhou Zhi-Fen; Chen Rong-Ti
By utilizing the formation constants of Ni(Ⅱ)-Glycine binary complex compounds and the corresponding heats of formation ...
1991, 7 (04): 467-470.
DOI: 10.3866/PKU.WHXB19910417
5107
Abstract/Metrics
2442
PDF(2835KB)
Critical Growth Temperatures of Bacteria by Microcalorimetric Method
Xie Chang-Li; Tang Hou-Kuan; Song Zhao-Hua; Qu Song-Sheng; Liao Yao-Ting; Liu Hai-Shui
In this paper, we have determined the multiplication rate constanis (k) of Shigella flexneri and E. coli. at different t...
1991, 7 (04): 471-474.
DOI: 10.3866/PKU.WHXB19910418
5360
Abstract/Metrics
2735
PDF(2746KB)
Thermodynamics of Mixed Electroyte in Mixed Solutions of
d
-Glucose and Water II. System of HCl-NaCl-
d
-Glucose-H
2
O(from 5 to 45 ℃)
Lv Dian-Zhen; Wang Qin-Ping; Wang Jie; Li Jin-Wen
The thermodynamic properties of HCl-NaCl-d-Glueose-H_2O system was studied by emf measurement without liquid junction. P...
1991, 7 (04): 475-479.
DOI: 10.3866/PKU.WHXB19910419
5861
Abstract/Metrics
2717
PDF(3045KB)
Study on the Salt Effect in Nonaqueous Solutions by Gas Liquid Chromatography——For Nonelectrolyte Solute (Hydrocarbons,Aromatic Hydrocarbons,Chloro-Hydrocarbons,Ketones) in Salt (Nal, NaSCN, KSCN) and Propy-Lene Carbonate Solutions
Bai Tong-Chun; Wang Jian-Ji; Liu Wen-Bin; Lu Jin-Suo
The gas-liquid chromatographic method was used to measure the activity coefficients at infinite dilution (γ_1~∞) of some...
1991, 7 (04): 480-484.
DOI: 10.3866/PKU.WHXB19910420
6192
Abstract/Metrics
2478
PDF(3823KB)
Ion Exchange Kinetics of Regeneration for Weak Basic Anion Exchanger
Wang Gang; Tao Zu-Yi
The results of kinetic studies of regeneration for weak basic anion exchanger in NO_3~-, Cl~- and SO_4~(2-) forms are pr...
1991, 7 (04): 485-489.
DOI: 10.3866/PKU.WHXB19910421
5869
Abstract/Metrics
2844
PDF(3587KB)
Study on the Reaction of Laccase and Hydrogen Peroxide by Microcalorimetry
Wu Ding-Quan; Mei Fu-Ming; Qu Song-Sheng; Du Yu-Min; Zhan Dong-Feng
Study on thermokinetic properties of the reaction between laccase and hydrogen peroxide by microcalorimetry has been car...
1991, 7 (04): 490-494.
DOI: 10.3866/PKU.WHXB19910422
5264
Abstract/Metrics
2869
PDF(3376KB)
Study on the Properties of Cellulose Acetate Solution for the Casting of Reverse Osmosis Membrane
Yang Ke-Xuan; Mao Run-Sheng; Qi Qing-Hui; Huang Ji-Cai; Wu Feng-Lian
Infrared spectroscopy, viscosity measurement,HUGGINS equation and MCALLISTER equation characterization, and computer cur...
1991, 7 (04): 495-498.
DOI: 10.3866/PKU.WHXB19910423
4809
Abstract/Metrics
2767
PDF(3092KB)