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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1988 Vol. 4,No. 06
Published: 15 December 1988
Current column
Communication
ARTICLE
Note
Communication
INVESTIGATION OF INTERACTION BETWEEN SUBSTRATE AND YBa
2
Cu
3
O
7-δ
SUPERCONDUCTING THIN FILM BY AES
Zheng Yan; Zhang Chunsi; Ren Congxin; Chen Jianming; Chen Guoliang; Yang Jie; Jin Lina; Liu Xianghuai; Xie Leiming; Zou Shichang
The interaction between superconducting thin film of YBa_2Cu_3O_(7_δ) and substrate Of YSZ (Yttric stabilized zirconia) ...
1988, 4 (06): 561-565.
DOI: 10.3866/PKU.WHXB19880601
4298
Abstract/Metrics
1991
PDF(1818KB)
ARTICLE
THE UNITARY GROUP APPOACH (UGA) TO THE WEAK FIELD MODEL OF A LIGAND FIELD (
d
N
IONS)
Wen Zhenyi*; Wang Yubin; Dou Yusheng; Liu Zhaomeng
This paper deals with the weak ligand field of d-shell by use of the unitary group approach (UGA). It specially discusse...
1988, 4 (06): 566-571.
DOI: 10.3866/PKU.WHXB19880602
3950
Abstract/Metrics
2039
PDF(2130KB)
A STUDY OF PULSED LIGHT-INDUCED TRANSIENT BEHAVIORS AT
n
-InP ELECTRODE IN Fe
3+
/Fe
2+
Ⅲ. DETERMINATION OF COMPLEX COLLECTION EFFICIENCY FIGURE WITH FFT OPERATION
Qian Daosun*; Sun Lizhong; Sun Birou;
Guan Qi
In this paper the complex collection efficiency figures of n-InP in Fe~(8+)/Fe~(2+) solution are determined with light p...
1988, 4 (06): 572-577.
DOI: 10.3866/PKU.WHXB19880603
3857
Abstract/Metrics
2302
PDF(1869KB)
THE VIBRATIONAL SPECTRA OF ORGANOMETALLIC COMPOUNDS (Ⅱ) FT-INFRARED, LASER RAMAN SPECTRA AND NORMAL COORDINATE CALCULATION FOR 1,1'-DIMETHYLFERROCENE
Liu Juzheng*; Feng Yan; Jiang Shimei; Zhao Wenyun; Liang Yinqiu
FT-IR and Laser Raman spectra of (CH_3Cp)_2Fe have been measured. On the basis of qualitative assignment the force const...
1988, 4 (06): 578-586.
DOI: 10.3866/PKU.WHXB19880604
3730
Abstract/Metrics
2032
PDF(2433KB)
INTERACTION AND MODEL OF ANY SHAPE PARTICLES IN COLLOID DISPERSION SYSTEM Ⅰ. IDENTICAL SPHERICAL PARTICLES
Wang Haoping;
Jin Jun; Zhang Manxia
This paper present a new method which diseribes colloidal particles model and calculation of any shape colloidal particl...
1988, 4 (06): 587-592.
DOI: 10.3866/PKU.WHXB19880605
4030
Abstract/Metrics
2116
PDF(2036KB)
THERMODYNAMICS OF SOLVENT EXTRACTION OF METALS (Ⅶ) EHEHPA-CoSO
4
-CuSO
4
System
Li Jiding; Li Yigui; Lu Jiufang; Teng Teng
The system for metal solvent extraction is a complicated one, which deals with electrolyte solution, non-electrolyte sol...
1988, 4 (06): 593-599.
DOI: 10.3866/PKU.WHXB19880606
4305
Abstract/Metrics
2230
PDF(2526KB)
KINETIC RESEARCH OF THE REACTION OF SO
2
+OH+M(Ⅰ)
Chen Xinguo; Shi Shuhao; Qiu Lianxiong
By using the method of Discharge Flow-Resonance Fluorescence, the reaction of OH+SO_2+M was studied. The effect of wall ...
1988, 4 (06): 600-605.
DOI: 10.3866/PKU.WHXB19880607
3835
Abstract/Metrics
1968
PDF(1825KB)
THE MICROTACTICITY OF POLY (
n
-ALKYL METHACRYLATES)
Li Zhuomei; Feng Ke; Zhang Weibang
The microtacticity of seven poly (n-alkyl methacrylates)prepared from radical polymerization has been determined by ~(13...
1988, 4 (06): 606-610.
DOI: 10.3866/PKU.WHXB19880608
4300
Abstract/Metrics
1965
PDF(1661KB)
RESEARCH ON SUBSTITUTION REACTION OF LIGANDS IN Mo
3
S
4
(dtp)
4
(H
2
O)——SYNTHESIS AND CRYSTAL OF Mo
3
S
4
(μ-dtp)(η
2
-dtp)
2
(η
1
-dtp)(bpy)
Huang Mingdong*; Lu Shaofang; Huang Jianquan; Huang Jinling
From the reaction of Mo_2S_4(μ-dtp)(dtp)_3(H_2O) (I) (dtp = diethyldithiophosphanato) with 2,2'-bipyridine, the product ...
1988, 4 (06): 611-616.
DOI: 10.3866/PKU.WHXB19880609
4448
Abstract/Metrics
2443
PDF(2190KB)
STUDIES ON VIBRATION SPECTRA AND EHMO FOR CONJUGATION AND UNCONJUGATION UNSATURATED ESTER
Zhao Bing; Liu Juzheng*; Liang Yingqiu; Tang Aoqing
Tracing out dehydrated reaction of β-hydroxy ester by FT-IR, luster Raman spectroscopy and EHMO calculation,it is found ...
1988, 4 (06): 617-623.
DOI: 10.3866/PKU.WHXB19880610
3788
Abstract/Metrics
2026
PDF(1988KB)
THEORETICAL STUDY OF NH
3
CHEMISORBED ON Ni(111) SURFACE
Zheng Xiaoming; Wu Yue; Cao Peilin*
The chemisorption of NH_3 on Ni(111) surface has been studied by X_a-DV method. Total energies, ground states, charges t...
1988, 4 (06): 624-628.
DOI: 10.3866/PKU.WHXB19880611
3886
Abstract/Metrics
2159
PDF(1886KB)
INTERFACE CHEMICAL PROPERTIES OF THE MIXED AQUEOUS SOLUTION OF SODIUM PERFLUOROOCTANOATE AND ALKYLTRIMETHYLAMMONIUM BROMIDE
Ding Huijun; Chen Shaomo; Wang Lu; Zhao Guoxi
The interface adsorption and micelle formation of the mixed solution of fluorocarbon and hydrocarbon surfactants (7CFNa ...
1988, 4 (06): 629-635.
DOI: 10.3866/PKU.WHXB19880612
4512
Abstract/Metrics
1989
PDF(2450KB)
CONDUCTIVITY AND RELAXATION WITH SOLUTION OF LITHIUM PERCHLORATE IN DIMETHYL SILOXANE-ETHYLENE OXIDE COPOLYMER
Xue Rongjian
The conductivity and relaxation of the solutions of LiClO_4 in dimethyl siloxane-ethylene oxide copolymer (named DMS:EO:...
1988, 4 (06): 636-640.
DOI: 10.3866/PKU.WHXB19880613
4132
Abstract/Metrics
2111
PDF(1803KB)
Note
INTERACTION AND MODEL OF ANY SHAPE PARTICLES IN COLLOID DISPERSION SYSTEM Ⅱ. UNLIKE SPHERICAL PARTICLES
Jin Jun; Zhang Manxia;
Wang Haoping
We derived a simplified formula of electrostatic energy for the two unlike spheres at constant surface potential using t...
1988, 4 (06): 641-644.
DOI: 10.3866/PKU.WHXB19880614
3556
Abstract/Metrics
2175
PDF(1359KB)
EOM/PROPAGATOR CALCULATIONS OF VERTICAL IONIZATION POTENTIALS OF B
2
H
6
Huang Mingbao;
Pan Daokai
The vertical ionization potentials of B_2H_6 were calculated by means of the EOM/propagator method with a second-order a...
1988, 4 (06): 645-648.
DOI: 10.3866/PKU.WHXB19880615
4181
Abstract/Metrics
1930
PDF(1397KB)
THE CRYSTAL AND MOLECULAR STRUCTURE OF
β
-CYANOETHYL-
α
-FERROCENYLFLUOROBENZYL ETHER
Sun Xiaolin; Hu Yucai; Xin Min; Zhang Yuhong
This paper reports the crystal and molecular structure of β-cyanoethyl-α-ferro cenylfluorobenzyl ether (C_5H_5FeC_5H_4CH...
1988, 4 (06): 649-652.
DOI: 10.3866/PKU.WHXB19880616
4021
Abstract/Metrics
2137
PDF(1408KB)
CHEMILUMINESCENT POLARIZATION STUDIES OF Ba(
1
S
) +N
2
O REACTION
Wang Zhiyu; He Guozhong; Lou Nanquan
The variation of ehemiluminescent polarization for reaction Ba(~1S)+N_2O with respect to the Ba beam temperature or the ...
1988, 4 (06): 653-656.
DOI: 10.3866/PKU.WHXB19880617
3751
Abstract/Metrics
2081
PDF(1619KB)
AN AUTOCATALYTIC REACTION MODEL FOR BIRHYTHUM AND TRISTABILITY
Li Rusheng
An autocatalytic reaction model X+2Y→3Y, Y+Z→2Z, Y→P, in a CSTR is put forward to model the phenomena of birhythum and t...
1988, 4 (06): 657-659.
DOI: 10.3866/PKU.WHXB19880618
4437
Abstract/Metrics
2117
PDF(1289KB)
THE DYNAMICS STUDIES OF REACTIONS Ca(
1
S
0
)+CH
2
Cl
2
CHCl
3
AND Ca(
3
P
)+CH
2
Cl
2
、CHCl
3
Han Keli; He Guozhong; Lou Nanquan
The reactions Ca(~1S_0)+ CH_2Cl_2, CHCl_3 and Ca(~3P)+ CH_2Cl_2, CHCl_3 were studied by means of the laser induced fluor...
1988, 4 (06): 660-664.
DOI: 10.3866/PKU.WHXB19880619
4518
Abstract/Metrics
2199
PDF(1585KB)
THE LASER INDUCED FLUORESCENCE STUDIES OF THE REACTIONS Ca+C
2
H
6-n
Cl
n
(n=2,3,4,)
Han Keli; He Guozhong; Lou Nanquan
The internal state distributions of nascent CaCl formed in the reactions Ca + (1,1) and (1,2) C_2H_4Cl_2、(1,1,2) C_2H_2C...
1988, 4 (06): 665-668.
DOI: 10.3866/PKU.WHXB19880620
4158
Abstract/Metrics
2004
PDF(1401KB)
MULTIPHOTON DISSOCIATION-IONIZATION DYNAMICS OF Fe(CO)
5
Li Shutao; Han Jingcheng; Liu Houxiang; Li Zhaolin; Wu Cunkai;
Shi Jiliang; Li Fanglin
Multiphoton dissociation-ionization dynamics of Fe(CO)_5 were studied mass spectrometrically with a molecular beam and X...
1988, 4 (06): 669-672.
DOI: 10.3866/PKU.WHXB19880621
4087
Abstract/Metrics
2146
PDF(1705KB)