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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1987 Vol. 3,No. 05
Published: 15 October 1987
Current column
Communication
ARTICLE
Note
Communication
THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS,
I. DYNAMIC STEREOCHEMISTRY OF FIVECOORDINATE MOLYBDENUM COMPOUNDS Mo(L)
5
Liao Daiqing; Fu Heng; Tang Yougi
The principle of structure correlation is applied to 28 crystal structures which contain 44 different five-coordinate mo...
1987, 3 (05): 449-452.
DOI: 10.3866/PKU.WHXB19870501
3920
Abstract/Metrics
2002
PDF(1149KB)
THERMAL DECOMPOSITON OF BIS (TRINITROETHYL-N-NITRO) ETHANE
(1) NONISOTHERMAL KINETICS OF THERMAL DECOMPOSITION
Song Quancai; Wang Wendi
Bis(trinitroethyl-N-nitro) ethane (BTNE) is a compound that decomposes thermally in solid state. We have reported the fi...
1987, 3 (05): 453-455.
DOI: 10.3866/PKU.WHXB19870502
3516
Abstract/Metrics
2022
PDF(1136KB)
THERMAL DECOMPOSITION OF BIS (TRINITRO-ETHYL-N-NITRO) ETHANE
(2) CRYSTAL PROPERTIES AND PARAMETERS OF THERMAL DECOMPOSITION KINETICS
Song Quancai; Wang Wendi
It has been found that the rate constant of thermal decomposition for various crystals of bis(trinitroethyl-N-nitro) eth...
1987, 3 (05): 456-459.
DOI: 10.3866/PKU.WHXB19870503
3559
Abstract/Metrics
1980
PDF(1350KB)
APPLICATION OF ISS TO INVESTIGATING THE INTERACTION BETWEEN ACTIVE COMPONENT AND CARRIER IN SUPPORTED CATALYSTS
Huang Huizhong; Guo Qinlin; Gui Linlin; Zhou Yu; Liu Yingjun; Tang Youqi
Low energy (1.5 KeV) ISS is a surface sensitive technique for identification of element on the top layer of material. Th...
1987, 3 (05): 460-464.
DOI: 10.3866/PKU.WHXB19870504
4150
Abstract/Metrics
1905
PDF(1787KB)
THERMOCHEMICAL STUDIES ON CELL'S METABOLISM——A NEW METHOD FOR IDENTIFICATION OF RESTING CELL
Sun Dayung; Tang Houkuan; Xie Changli; Song Zhaohua; Qu Songsheng; Liao Yaoting; Liu Haishui
A new microcalorimetric method has been developed for identifying the en- dgenous cells and resting cells with good accu...
1987, 3 (05): 465-467.
DOI: 10.3866/PKU.WHXB19870505
3661
Abstract/Metrics
1954
PDF(1174KB)
ARTICLE
UV LASER PHOTOLYSIS AND MULTIPHOTON IONIZATION OF SbH
3
Ni Tuqian; Ma Xinxiao; Yu Shuqian; Kong Fanao
The 403-700 nm emission spectrum observed in ArF laser photolysis of stibine was recorded for the first time and was ass...
1987, 3 (05): 468-473.
DOI: 10.3866/PKU.WHXB19870506
3641
Abstract/Metrics
2133
PDF(1799KB)
RELAXATION STUDIES OF IODINE MOLECULES IN SUPERSONIC JETS Ⅱ. VIBRATIONAL RELAXATION
Ma Zhiliu; Huang Ruiping
Using LIF technique, the distribution of vibrational temperature of I_2 along a supersonic jet axis has been measured, H...
1987, 3 (05): 474-478.
DOI: 10.3866/PKU.WHXB19870507
4043
Abstract/Metrics
1913
PDF(1936KB)
INVESTIGATION OF THE PITTING CORROSION OF 18-8 STAINLESS STEEL IN EARLY STAGE I. BY USING THE SMRE TECHNIQUE
Lin Changjan; Tian Zhaowu
An improved scanning micro reference electrode (SMRE) technique controlled by micro-computer was used to study the pitti...
1987, 3 (05): 479-484.
DOI: 10.3866/PKU.WHXB19870508
4510
Abstract/Metrics
2190
PDF(2070KB)
CRYSTAL AND MOLECULE STRUCTURE OF GUANIDINIUM HEXAMOLYBDO-BIS(
n
-PROPYLARSONATE), (CN
3
H
6
)
4
(
n
-C
3
H
7
As)
2
Mo
6
O
24
Wang Ming; Zheng Peiju; Liu Benyao; Gu Yidong
The crystal structure of the title compound was determined by single crystal X-ray diffraction analysis. The intensity d...
1987, 3 (05): 485-490.
DOI: 10.3866/PKU.WHXB19870509
4856
Abstract/Metrics
1864
PDF(1984KB)
STUDIES ON NEUTRAL PHOSPHINE EXTRACTED COMPLEXES OF RARE EARTHS Ⅲ. SYNTHESIS AND CRYSTAL STRUCTURE OF TRINITRATOTRI (TRIPHENYL-PHOSPHINE OXIDE) LANTHANUM
Huang Chunhui, Xu Rongfang, Zhou Yongfeng, Xu Guangxian, Guo Fang, Zhu Naijue
The Synthesis, character and crystal structure of La(NO_3)_3·3Ph_3PO·C_2H_5OH· CHCl_3 has been pres...
1987, 3 (05): 491-500.
DOI: 10.3866/PKU.WHXB19870510
5003
Abstract/Metrics
1845
PDF(2852KB)
THE STANDARD GIBBS ENERGIES OF TRANSFER AND THE ACTIVITY COEFFICIENTS OF NaF AND NaCl FROM WATER TO DIOXAN+WATER MIXTURES——USING IONSELECTIVE ELECTRODES TO STUDY THE THERMODYNAMICS OF SOLUTIONS
Chu Deying; Liu Li; Liu Ruilin
The reversible cell without liquid junction consists of the sodium ion glass- electrode and fluoride or chloride selecti...
1987, 3 (05): 501-507.
DOI: 10.3866/PKU.WHXB19870511
4833
Abstract/Metrics
2321
PDF(2022KB)
INVESTIGATION OF TERNARY SYSTEM BaO-B
2
O
3
-GeO
2
(BaO≤50 mol%)
Liang Jingkui; Chai Zhang; Zhang Jinping
The ternary system BaO-B_2O_3-GeO_2 (BaO≤50 mol%) has been investigated by means of X-ray diffraction and DTA techniques...
1987, 3 (05): 508-513.
DOI: 10.3866/PKU.WHXB19870512
4196
Abstract/Metrics
2002
PDF(2021KB)
INTERACTION OF OXYGEN WITH Ag AND Ag-Pd ALLOY BY WORK FUNCTION MEASUREMENT
Deng Jingfa; Bao Xinhe
The adsorption and desoption of oxygen on Ag and Ag-Pd alloy surfaces have been investigated by AES, TDS and by the cont...
1987, 3 (05): 514-519.
DOI: 10.3866/PKU.WHXB19870513
5059
Abstract/Metrics
2366
PDF(2210KB)
THE STUDIES ON SALT EFFECT OF THE ISOTHERMAL VAPOUR-LIQUID EQUILIBRIUM——ORGANIC SOLVENT-WATER-INORGANIC SALT SYSTEM
Wei Dongqing; Lu Jinsuo; Zhu Jianjun; Zhou Xishun
Nomatter for its industrial usefulness or theoretical importance as a very con- vient way to study thermodynamic behavio...
1987, 3 (05): 520-524.
DOI: 10.3866/PKU.WHXB19870514
4543
Abstract/Metrics
2073
PDF(1702KB)
Note
THE ELECTRODE PROCESSES OF COPPER ELECTRODEPOSITION FOR PYROPHOSPHATE SOLUTION II. THE STUDY BY ROTATING ELECTRODE METHOD
Qin Erhua; Gu Linying
Cathodic polarization curves has been measured by means of rotating disc and ring-disc electrodes in cupric pyrophosphat...
1987, 3 (05): 525-528.
DOI: 10.3866/PKU.WHXB19870515
4004
Abstract/Metrics
1958
PDF(1414KB)
THERMODYNAMIC STUDIES OF THE FORMATION FOR ADENOSINE TRIPHOSPHATE COMPLEXES WITH MAGNESIUM ION AND CALCIUM ION
Liu Yunna
The formation constant (K) and thermodynamic parameters (ΔC.ΔH.ΔS) in reactions in which complexes of adenosine triphosp...
1987, 3 (05): 529-533.
DOI: 10.3866/PKU.WHXB19870516
3625
Abstract/Metrics
1995
PDF(1540KB)
A TEFLON ISOTHERMAL DILUTION CALORIMETER
Bao Jingdan; You Yu; Xie Youzhen; Hu Ying
A new teflon isothermal dilution calorimeter for measuring excess enthalpies of liquid mixtures is described. The calori...
1987, 3 (05): 534-538.
DOI: 10.3866/PKU.WHXB19870517
3873
Abstract/Metrics
1876
PDF(1619KB)
CONNECTION AND COMPARISON OF DIFFERENT FORMULAS OF HOMOLOGOUS RULE OF ORGANIC COMPOUNDS
Sun Yukun
In this paper, the author deduced the Gradation Rule of the Conjugated Homo- logs E=a+b/N from the Linear Rule of the Ho...
1987, 3 (05): 539-543.
DOI: 10.3866/PKU.WHXB19870518
3750
Abstract/Metrics
1886
PDF(1566KB)
THERMOCHEMICAL STUDY OF THE SIGMA-PHASE OF Fe-Cr BINARY ALLOYS
Cheng Shuwu; Fan Min; Lin Hai; Zu Lin
In this paper the properties of the sigma-phase of Fe-Cr alloy have been stu- died at 109 K and 718 K by calorimetry. At...
1987, 3 (05): 544-546.
DOI: 10.3866/PKU.WHXB19870519
4298
Abstract/Metrics
2294
PDF(1196KB)
APPLICATION OF NMR TO PHASE DIAGRAM STUDY——ISOTHERMAL PHASE DIAGRAM OF Na
2
SO
4
-Al2(SO4)3-H
2
O SYSTEM BY
23
Na,
27
Al NMR QUANTITATIVE METHOD
Mao Xian; Xu Guangzhi; Tang Youqi; Qiu Jianqin; Yuan Hanzhen
In the present paper, Na_2SO_4-Al_2(SO_4)_3-H_2O system has been studied by ~(23)Na and ~(27)Al NMR quantitative method....
1987, 3 (05): 547-550.
DOI: 10.3866/PKU.WHXB19870520
4001
Abstract/Metrics
1880
PDF(1296KB)
THE CHARGE-TRANSFER COMPLEXES OF POLY (
N
-VINYL-CARBAZOLE) AND NITROFLUORENONES IN DIFFERENT SOLVENTS
Li Guifang; Zhao Yang; Liu Changyan
The charge-transfer complexes of poly(N-vinylcarbazole) (Mn=7200) and nitro- fluorenones were studied with VPO in differ...
1987, 3 (05): 551-554.
DOI: 10.3866/PKU.WHXB19870521
3964
Abstract/Metrics
1941
PDF(1369KB)
USING THE DIELECTRIC POLARIZATION MEASUREMENT IN STUDYING OF MOLECULAR INTERACTION IN SOLUTION I. WATER-TBP-BENZENE SYSTEM
Shi Xiukun; Peng Qixiu; Gao Hongcheng
Tri-n-butyl-phosphate (TBP) is one of the important extractants and widely used in solvent extraction of chemical indust...
1987, 3 (05): 555-559.
DOI: 10.3866/PKU.WHXB19870522
3882
Abstract/Metrics
2007
PDF(1422KB)