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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1985 Vol. 1,No. 06
Published: 15 December 1985
Current column
ARTICLE
Note
ARTICLE
THE VIBRATIONAL SPECTRA OF LANTHANIDE THENOYLTRIFLUOROACETONATE COMPOUNDS
Liang Yingqiu; Zhao Wenyun; Zhang Yuanfu; Zhao Yongnian; Sun Jiabin
The FT-IR and Raman spectra for (TTA)_4LnQH(Q=quinoline) series were measured and discussed as following:1. Structure an...
1985, 1 (06): 493-503.
DOI: 10.3866/PKU.WHXB19850601
4351
Abstract/Metrics
1948
PDF(3296KB)
A THEORETICAL STUDY ON THE REACTION BETWEEN HYDROGEN AND IODINE
Fu Xiaoyuan; Jin Suqian
The termolecular reaction H_2+2I→2HI has been studied by quantum chemi- cal pseudopotential ab initio method. The transi...
1985, 1 (06): 504-510.
DOI: 10.3866/PKU.WHXB19850602
4265
Abstract/Metrics
2032
PDF(2282KB)
STUDY OF THE INTERFACIAL TENSION OF WATER/KEROSENE WITH ADDED AP TYPE DEMULSIFIERS
Dai Lerong; Li Wailang; Zhu Demin; Liang Guohong
The interracial tension of water/kerosene with added AP type polyoxyethyle- ne-polyoxypropylene block copolymers has bee...
1985, 1 (06): 511-516.
DOI: 10.3866/PKU.WHXB19850603
6827
Abstract/Metrics
2458
PDF(1904KB)
STRUCTURE OF THE ELECTRONIC ENERGY BANDS OF THE CHARGE TRANSFER COMPLEX MOLECULAR CRYSTAL TMPD·(TCNQ)
2
AND THE COMPARISON WITH THOSE OF NMP·TCNQ AND TTF·TCNQ
Zhang Qiyuan; Yan Jimin
The electronic energy bands of the charge transfer complex molecular crystal TMPD·(TCNQ)_2 have been calculated. In the ...
1985, 1 (06): 517-527.
DOI: 10.3866/PKU.WHXB19850604
4854
Abstract/Metrics
1855
PDF(3391KB)
DONOR PROPERTIES OF METALLOPORPHINS
Yang Yanheng; Wang Wenyun*
The visible absorption and fluorescence spectra of metallo derivatives of tetrakis- (ortho-chlorophenyl) porphin (OCITPP...
1985, 1 (06): 528-532.
DOI: 10.3866/PKU.WHXB19850605
4149
Abstract/Metrics
1710
PDF(1506KB)
AN INFRARED SPECTROSCOPY METHOD FOR MEASURING THE BRÖNSTED ACID OF ZSM-5 AND THE STUDY OF SURFACE ACIDITY OF MODIFIED ZSM-5 ZEOLITES
Liu Xingyun; She Liqin; Li Xuanwen
Based on the studies of IR Spectra of various ZSM-5 zeolites it was found that there are two strong bands at ca. 1875 an...
1985, 1 (06): 533-542.
DOI: 10.3866/PKU.WHXB19850606
4438
Abstract/Metrics
1981
PDF(3179KB)
SUBLIMATION CALORIMETER AND THE MEASUREMENT OF ENTHALPIES OF VAPORIZATION AND SUBLIMATION OF TRICHLOROBENZENES
Yan Haike; Gu Jiangou; Hu Rihen
A sublimation calorimeter has been constructed in our laboratory for solid compounds in pressure range≥0.1 mmHg at 298.1...
1985, 1 (06): 543-546.
DOI: 10.3866/PKU.WHXB19850607
4108
Abstract/Metrics
1888
PDF(1424KB)
CONTRIBUTION OF THE REPULSIVE INTERACTION BETWEEN FRAGMENTS TO ROTATIONAL DISTRIBUTION OF THE FRAGMENTS IN PHOTOLYSIS
Lü Richang
any studies on rotational distribution of photofragments have been done both in experimental and in theoretical aspects ...
1985, 1 (06): 547-555.
DOI: 10.3866/PKU.WHXB19850608
4108
Abstract/Metrics
1973
PDF(2877KB)
THE EIGENVALUE PROBLEM OF HÜCKEL MATRIX INCLUDING NEXT NEAREST INTERACTION
Lü Tianxiong; Jiang Yuansheng; Tang Aoqing
The eigenvalue problem of Hückel matrix including next nearest interaction has been dealt with using graphic method as w...
1985, 1 (06): 556-565.
DOI: 10.3866/PKU.WHXB19850609
4229
Abstract/Metrics
1728
PDF(2805KB)
THERMOCHEMICAL STUDY FOR WATER/SILICA ADSORPTION SYSTEM
Zhou Lixing; Chen Shuxia; Zheng Lubin
By the use of a precision automatic adiabatic calorimeter we have measured the heat capacities for water/silica adsorpti...
1985, 1 (06): 566-570.
DOI: 10.3866/PKU.WHXB19850610
4092
Abstract/Metrics
1723
PDF(1847KB)
Note
THE SDUDY OF THE INTERMEDIATES REACTIONS AND THE REACTION MECHANISM IN THEE THERMOLYSIS OF TETRALINE
Yang Xiaolin; Yang Huixing; Han Degang
In order to understand more clearly the reaction mechanism in the thermolysis of tertraline, thermal decomposition of so...
1985, 1 (06): 571-574.
DOI: 10.3866/PKU.WHXB19850611
4280
Abstract/Metrics
1886
PDF(1323KB)
THE CRYSTAL STRUCTURE AND MOLECULAR ABSOLUTE CONFIGURATIONS OF BIS [N-(5-CHLORO-OXID-BENZYLIDENE)-α-PHENYLETHYLAMINE] PALLADIUM(Ⅱ)
Xu Xiaojie; Guan Yedi; Shang Zhenhai; Guan Yue; Tang Youqi
The title compound crystallizes in orthorhombic crystal system with space group P 2_12_12_1, α=0.8983(4) nm, b=1.7538(9)...
1985, 1 (06): 575-578.
DOI: 10.3866/PKU.WHXB19850612
3617
Abstract/Metrics
1830
PDF(1283KB)
DETERMINATION OF IONIC HYDRATION NUMBERS BY THE MEMBRANE ELECTROLYSIS METHOD
Cheng Pengli
This paper suggests a method for the determination of the ionic hydration num- bers, The method is based on the selectiv...
1985, 1 (06): 579-585.
DOI: 10.3866/PKU.WHXB19850613
4013
Abstract/Metrics
1858
PDF(2294KB)