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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1985 Vol. 1,No. 05
Published: 15 October 1985
Current column
ARTICLE
Note
INVITED COMMENT
ARTICLE
ALUMINUM-27 AND PROTON NMR SPECTROSCOPY OF THE ALUMINUM ETHER COMPLEX
Guo Guolin; Xie Youchang
The chemical shifts and linewidths for aluminum chloride in ethyl ether have been studied by O'Reilly~[1], Haragushi~[2]...
1985, 1 (05): 397-403.
DOI: 10.3866/PKU.WHXB19850501
4543
Abstract/Metrics
1944
PDF(2457KB)
INVESTIGATION OF ULTRAVIOLET SPECTRA ON N-(SUBSTITUTED-PHENYL)-ETHYLGLYCINATES
Chen Rongti; Zhu Zhiang; Zhang Yibao; Wu Li
The ultraviolet spectra of N-(substituted phenyl)-ethylglycinates (RPhGEt, R=p-OCH_3, p-CH_3, m-CH_3, -H, m-OCH_3, m-Cl,...
1985, 1 (05): 404-411.
DOI: 10.3866/PKU.WHXB19850502
5543
Abstract/Metrics
1871
PDF(2426KB)
STUDY ON THE REDUCIBILITY AND SURFACE STATE OF MoO
3
SUPPORTED ON THE SURFACE OF γ-AI
2
O
3
, TiO
2
AND SiO
2
BY XPS
Gui Linlin; Zhong Bianxiao; Tang Youqi
MoO_3/γ-Al_2O_3, MoO_3╱TiO_2, and MoO_3╱SiO_2 samples prepared by impregnation method were reduced at 480 ℃ by H_2 flow(...
1985, 1 (05): 412-419.
DOI: 10.3866/PKU.WHXB19850503
4689
Abstract/Metrics
1766
PDF(2650KB)
STUDY ON ELECTRONIC STRUCTURE AND COMPLEX ACTIVATION OF NEODYMIUM CHLORIDE COMPLEX WITH ISOPROPANOL
Li Zhenxiang; Wang Shenlong; Wang Fosong
The molecular orbital energy, charge distribution, and Mulliken's bond order in neodymium chloride complex with isopropa...
1985, 1 (05): 420-423.
DOI: 10.3866/PKU.WHXB19850504
4484
Abstract/Metrics
2308
PDF(1525KB)
REDOX MECHANISM OF PROPYLENE OXIDATION OVER Bi
2
Mo
3
O
12
-Bi
2
O
3
CATALYST
Hong Cunmao; Ding Shuji; Sun Chenge
The kinetics of propylene oxidation over Bi_2Mo_3O_(12)-Bi_2O_3 catalyst in a differ ential flow reactor has been invest...
1985, 1 (05): 424-430.
DOI: 10.3866/PKU.WHXB19850505
8021
Abstract/Metrics
2225
PDF(2265KB)
“IN-SITU” IR SPECTROSCOPIC STUDIES ON METHANOL SYNTHESIS OVER Cu—ZnO—Al
2
O
3
CATALYST
Tong Yudong; Zhu Qiming; Pan Weixiong; Liu Dianqiu; Yang Guanghua
"In-situ" infrared spectraphotometer cell designed and constructed by ourselves has been used to identify the surface sp...
1985, 1 (05): 431-441.
DOI: 10.3866/PKU.WHXB19850506
4806
Abstract/Metrics
2395
PDF(3417KB)
CHEMILUMINESCENT REACTION DYNAMICS OF Sn+N
2
O IN BEAM-GAS
Wang Xiuyan; Ning Baogang; Li Jian; Peng Lianshun; Lou Nanquan
The chemiluminescence reaction of tin with N_2O and O_2 have been investigated in a beam-gas apparatus under the pressur...
1985, 1 (05): 442-447.
DOI: 10.3866/PKU.WHXB19850507
4220
Abstract/Metrics
1851
PDF(2163KB)
CF
3
I MULTIPHOTON DISSOCIATION UNDER THE INTENSE IR FIELD
Xie Kuangji; Li Changlin
Using TEA CO_2 laser 9.6R (14) line as excitation source, Fourier transforma tion IR spectrometer as measuring instrumen...
1985, 1 (05): 448-454.
DOI: 10.3866/PKU.WHXB19850508
4526
Abstract/Metrics
1842
PDF(2307KB)
A NEW EXPLANATION TO THE CATHODIC PROCESS OF SILVER(Ⅱ) OXIDE WITH THE CONCEPT OF SEMICONDUCTOR HIGH-LOW JUNCTION
Li Cheng; Li Guozheng; Wang Shixun; Xu Guoxian
The concept of semiconductor solid junction was first introduced into the tra ditional electrochemistry. The cathodic pr...
1985, 1 (05): 455-459.
DOI: 10.3866/PKU.WHXB19850509
5363
Abstract/Metrics
2012
PDF(1805KB)
Note
STUDIES ON TRANSITION-METAL PERHALOPHENYL COMPOUNDS
Ⅸ. KINETICS AND MECHANISM OF SUBSTITUTION REACTIONS OF CHLORO-BIS (DIPHENYLMETHYLPHOSPHINE) (PENTACHLOROPHENYL)-NICKEL(Ⅱ) WITH PYRIDINE AND SUBSTITUTED PYRIDINE
Zhang Qiyan; Li Yuejin; Chen Jinchang; Chen Rongti; Zhang Zhengzhi; Wang Xukun
The kinetics of nucleophilic substitution reactions between trans-(Ph_2PMe)_2 Ni(C_6Cl_5)Cl and pyridine and various sub...
1985, 1 (05): 460-463.
DOI: 10.3866/PKU.WHXB19850510
5120
Abstract/Metrics
1938
PDF(1388KB)
A STUDY ON SOME PECULARITIES OF Pt/Al
2
O
3
CATALYSTS
Yang Yongnian; Huang Xidong; Zeng Yiding; Zhang Jiayu
The dissolved Al~(3+) amounts of various alumina (Ketjen CK 300, Degussa Alu minium Oxid C, Tonerdo γ-Al_2O_3 and Changl...
1985, 1 (05): 464-470.
DOI: 10.3866/PKU.WHXB19850511
3720
Abstract/Metrics
1883
PDF(2186KB)
STUDIES ON THERMOCHEMISTRY OF PORPHYRINS
Ⅱ. THE STANDARD ENERGIES OF COMBUSTION AND STANDARD ENTHALPIES OF FORMATION OF TETRAPHENYLPORPHYRIN AND ITS DERIVATIVES
Xue Rongshu; Wu Dingquan; Qu Songsheng
Using precision static oxygen bomb combustion calorimeter, the standard energies of combustion of tetraphenylpophyrin, t...
1985, 1 (05): 471-475.
DOI: 10.3866/PKU.WHXB19850512
3718
Abstract/Metrics
2196
PDF(1630KB)
STUDIES OF ACTIVITY COEFFICIENTS OF MIXED ELECTROLYTES IN MIXED SOLVENTS System of HCI+NaCI+PrOH+H
2
O, at 298.15 K
Chu Mingchen; Yang Jiazhen; Liang Chunyu; Zheng Xijuan; Zhu Ruoyao
This paper reports our studies on HCl+NaCl+PrOH+H_2O system by mesns of emf measurements of the cell without liquid junc...
1985, 1 (05): 476-481.
DOI: 10.3866/PKU.WHXB19850513
4071
Abstract/Metrics
1983
PDF(2007KB)
THE EFFECT OF POLYHYDRIC ALCOHOLS ON O/W TYPE MICROEMULSION
Hua Xiyuan*; Song Hongyan; Hu Guanjian
The effect of α-propylene glycol, glycol, and glycerin on the phase behavior of water-hexane-dodecylsulfonate-hexanol(as...
1985, 1 (05): 482-486.
DOI: 10.3866/PKU.WHXB19850514
4262
Abstract/Metrics
1777
PDF(1558KB)