Current Issue
- 2010 Vol. 26,No. 04 Published: 02 April 2010
- Current column
- Table of Contents
- Preface
- Communication
- THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
- CHEMICAL KINETICS AND MOLECULE DYNAMICS
- ELECTROCHEMISTRY
- COLLOID AND INTERFACE CHEMISTRY
- CATALYSIS AND SURFACE STRUCTURE
- PHOTOCHEMISTRY AND SPECTROSCOPY
- QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
- BIOPHYSICAL CHEMISTRY
- PHYSICAL CHEMISTRY OF MATERIALS
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Table of Contents
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- Table of Contents for Vol.26 No. 04
- 2010, 26 (04): 0.
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Preface
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- Preface
- GAO Song, WU Kai, MA Yu-Guo
- 2010, 26 (04): 799-800. DOI: 10.3866/PKU.WHXB100ZKPreface
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Communication
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- Raman Characterization of a Highly Folded Individual Serpentine (7,5) Single-Walled Carbon Nanotube
- XIE Li-Ming, YU Xue-Chun, FENG Chao-Qun, ZHANG Jin, LIU Zhong-Fan
- We carried out Raman characterization of a highly folded individual serpentine (7,5) single-walled carbon nanotube (SWNT...
- 2010, 26 (04): 801-804. DOI: 10.3866/PKU.WHXB20100411
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THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
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- Controllable Radiolytic Reduction of Cu2+ in Aqueous Solution by β-Cyclodextrin
- YANG Shi-Guo, CHEN Qing-De, SHI Jian-Feng, SHEN Xing-Hai
- We used β-cyclodextrin (β-CD) to control the radiolytic reduction of Cu2+ in aqueous solution at a safe absorb...
- 2010, 26 (04): 805-810. DOI: 10.3866/PKU.WHXB20100407
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- Solubility Analysis of Americiumin Yuci Groundwater
- CHEN Tao, WANG Xiang-Yun, TIAN Wen-Yu, SUN Mao, LI Chun, LIU Xiao-Yu, WANG Lu-Hua, LIU Chun-Li
- The solubility of americiumin Yuci groundwater was analyzed using a newly developed geochemical code CHEMSPEC and the in...
- 2010, 26 (04): 811-816. DOI: 10.3866/PKU.WHXB20100114
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- Phase Transitions and Structures of 5-{[(4’-Pentyloxy-4-biphenylyl)carbonyl]oxy}-1-pentyne
- YU Zhen-Qiang, ZHU Cai-Zhen, TIAN Sai, LIU Jian-Hong, LAM Jacky Wing Yip, TANG Ben-Zhong
- Phase transitions and structures of the monomer of side-chain liquid crystalline polyacetylene containing biphenyl mesog...
- 2010, 26 (04): 817-821. DOI: 10.3866/PKU.WHXB20100405
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CHEMICAL KINETICS AND MOLECULE DYNAMICS
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- Photolysis Kinetics of 4-(2-(4’-Pyridinyl)ethynyl)benzenic Diazonium Salt and Characterization of Its Self-Assembled Monolayer Film
- ZHAO Wei, TONG Bin, ZHI Jun-Ge, PAN Yue-Xiu, SHEN Jin-Bo, SHI Jian-Bing, DONG Yu-Ping
- In this paper, the photolysis kinetics of conjugate 4-(2-(4'-pyridinyl)ethynyl)benzene diazonium salt in acetonitrile an...
- 2010, 26 (04): 822-826. DOI: 10.3866/PKU.WHXB201004001
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ELECTROCHEMISTRY
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- Preparation of Single-Chamber Solid Oxide Fuel Cell by Co-Pressing and Direct Forming Process
- ZONG Wei-Zheng, ZHU Yong-Fa
- Co-pressing and direct forming process has been developed for the preparation of a single-chamber solid oxide fuel cell ...
- 2010, 26 (04): 827-832. DOI: 10.3866/PKU.WHXB20100443
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- Synergistic Effect of a Nonmetal and a Metal on the Electrochemical Properties of a Mg-Based Hydrogen Storage Alloy
- YANG Gui-Ling, WANG Chun, YANG Xiao-Min, ZHAO Na, JIAO Xiao-Yan
- The surface of an amorphous Mg45Ti3V2Ni50 alloy was modified with Ti, B, and a specific composite TiB by high energy bal...
- 2010, 26 (04): 833-839. DOI: 10.3866/PKU.WHXB20100438
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COLLOID AND INTERFACE CHEMISTRY
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- Application of Fluorescent Probe Technology in Self-Assembly Systems of Amphiphile Aqueous Solutions
- ZHAO Li, YAN Yun, HUANG Jian-Bin
- In this paper, we review the application of fluorescent probe technology in self-assembly systems of amphiphile aqueous ...
- 2010, 26 (04): 840-849. DOI: 10.3866/PKU.WHXB20100429
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- Study on the Fine Structure of Polypeptides at Solid-Liquid Interfaces by Scanning Tunneling Microscopy
- MAO Xiao-Bo, WANG Chen-Xuan, LIU Lei, MA Xiao-Jing, NIU Lin, YANG Yan-Lian, WANG Chen
- In this review, a summary of recent research progress on the assembly structures of amyloid peptides related to protein ...
- 2010, 26 (04): 850-861. DOI: 10.3866/PKU.WHXB20100440
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- Online Monitoring of the Aggregation and Fusion of DPPC/PAby Static and Dynamic Light Scattering
- DENG Lin, LIANG De-Hai
- Static and dynamic light scattering were employed to monitor the temperature-induced aggregation and fusion processes of...
- 2010, 26 (04): 862-868. DOI: 10.3866/PKU.WHXB20100422
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CATALYSIS AND SURFACE STRUCTURE
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- Rational Design of Low-Temperature Hydrogenation Catalysts: Theoretical Predictions and Experimental Verification
- CHEN Jingguang G, QI Sui-Tao, HUMBERT Michael P, MENNING Carl A, ZHU Yue-Xiang
- In this review, we will provide a brief review of our recent theoretical and experimental studies of bimetallic surfaces...
- 2010, 26 (04): 869-876. DOI: 10.3866/PKU.WHXB20100441
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- Wide Bandgap p-Block Metal Oxides/Hydroxides for Photocatalytic Benzene Degradation
- LI Zhao-Hui, LIU Ping, FU Xian-Zhi
- Benzene has severe health and environmental consequences because of its high toxicity and carcinogenicity. Although TiO2...
- 2010, 26 (04): 877-884. DOI: 10.3866/PKU.WHXB20100404
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- Recent Progress in the Removal of Volatile Organic Compounds by Catalytic Combustion
- LI Wei-Bin, GONG Hao
- Catalytic combustion is one of the most effective techniques for the removal of volatile organic compounds (VOCs). In th...
- 2010, 26 (04): 885-894. DOI: 10.3866/PKU.WHXB20100436
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- Relationship between the Structures of Metal Oxide Catalysts and Their Properties in Selective Oxidation of Light Alkanes
- ZHANG Sheng-Hong, LIU Hai-Chao
- It is of great importance to study the selective oxidation of light alkanes on metal oxide catalysts from a fundamental ...
- 2010, 26 (04): 895-907. DOI: 10.3866/PKU.WHXB20100444
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- Ionic Liquid and Water: Making Nanoparticle Catalysis More Efficient and Greener
- YUAN Xiao, LOU Shu-Jie, KOU Yuan
- Transition metal nanoparticles (MNP) stabilized in green solvents, i.e., ionic liquids (ILs) and water, have great poten...
- 2010, 26 (04): 908-914. DOI: 10.3866/PKU.WHXB20100433
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- Hydrothermal Preparation and Photocatalytic Activity of Chlorine Doped Titanium Dioxide Supported on SiO2
- DEDG Pei-Chang, HU Jie-Zhen, WANG Hai-Zeng, SUN Bao-Wei
- A chlorine doped titaniumdioxide photocatalyst was synthesized by a hydrothermal process using silica gel as a carrier, ...
- 2010, 26 (04): 915-920. DOI: 10.3866/PKU.WHXB20100428
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- Surface Modification of Mg-Al Hydrotalcite Mixed Oxides with Potassium
- ZHANG Ye-Xin, SU Qing-Yun, WANG Zhong-Peng, GAO Xi-Yan, ZHANG Zhao-Liang
- The surface modification of Mg-Al hydrotalcite mixed oxides (MgAlO) with K was investigated using X-ray powder diffracti...
- 2010, 26 (04): 921-926. DOI: 10.3866/PKU.WHXB20100446
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- Phase Transfer Catalytic Activity of Immobilized Dibenzo-18-Crown-6 for Butyl Benzoate Synthesis
- WANG Shi-Wei, GAO Bao-Jiao, GAO Xue-Chao, WANG Ling
- Dibenzo-18-crown-6 (DBC) was immobilized on cross-linked polyvinyl alcohol (CPVA) microspheres to prepare the triphase-t...
- 2010, 26 (04): 927-932. DOI: 10.3866/PKU.WHXB20100430
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- Self-Assemblies of Oxovanadium Phthalocyanine Molecules and Nanoclusters on Highly Oriented Pyrolytic Graphite
- WANG Yong-Feng, ZHANG Xin-Ran, YE Ying-Chun, LIANG De-Jian, WANG Yuan, WU Kai
- Self-assembled monolayer (SAM) of oxovanadium phthalocyanine (VOPc), an organic semiconductor compound, was prepared at ...
- 2010, 26 (04): 933-938. DOI: 10.3866/PKU.WHXB20100419
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- Synthesis of Asymmetrical Organic Carbonates Catalyzed by Metal Organic Frameworks
- ZHOU Yin-Xi, LIANG Shu-Guang, SONG Jin-Liang, WU Tian-Bin, HU Su-Qin, LIU Hui-Zhen, JIANG Tao, HAN Bu-Xing
- Metal organic frameworks (MOFs) are a new class of materials that are formed by the copolymerization of organic ligands ...
- 2010, 26 (04): 939-945. DOI: 10.3866/PKU.WHXB20100406
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PHOTOCHEMISTRY AND SPECTROSCOPY
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- Spectral Stability of Polyfluorene-Based Semiconductors
- LIANG Jing, QIAN Yan, XIE Ling-Hai, SHI Nai-En, CHEN Shu-Fen, DENG Xian-Yu, HUANG Wei
- The physical and chemical properties of organic semiconductors play key roles in the performance of optoelectronic devic...
- 2010, 26 (04): 946-963. DOI: 10.3866/PKU.WHXB20100415
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- Low Frequency Spectrumof Ionic Liquid [bmim][PF6] Studied by Femtosecond Optically Heterodyne-Detected Optical Kerr Effect Spectroscopy and Low Frequency Raman Spectroscopy
- WANG Wei, LV Rong, YU An-Chi
- The low frequency vibrational spectrum that reflects the intermolecular interaction of an imidazolium cation ionic liqui...
- 2010, 26 (04): 964-970. DOI: 10.3866/PKU.WHXB20100418
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- Synthesis and Helical Conformation of New Optically Active Liquid Crystalline Polythiophene Containing Cyanoterphenyl Mesogen Pendant
- CHEN Lie, CHEN Yi-Wang, YAO Kai, ZHOU Wei-Hua, LI Fan, NIE Hua-Rong
- A novel liquid crystalline (LC) polythiophene bearing cyanoterphenyl mesogenic pendants with a long flexible spacer {&md...
- 2010, 26 (04): 971-980. DOI: 10.3866/PKU.WHXB20100409
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- Radiation-Induced Changes of Phase Behavior and Fluorescence Properties of the Ionic Liquids [C4mim][PF6] and [C4mim][NTf2]
- YUAN Li-Yong, PENG Jing, LI Jiu-Qiang, ZHAI Mao-Lin
- The application of room-temperature ionic liquids (RTILs) to the separation of high level radioactive nuclides from wast...
- 2010, 26 (04): 981-987. DOI: 10.3866/PKU.WHXB20100423
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- Radiation Stability and Analysis of Radiolysis Product of 1-Octanol
- YU Chu-Hong, ZHANG Jia-Wei, DAI Jing, PENG Jing, LI Jiu-Qiang, ZHAI Mao-Lin
- 1-Octanol is a promising solvent for the extraction of high-level radioactive waste from nuclear fuel reprocessing and a...
- 2010, 26 (04): 988-992. DOI: 10.3866/PKU.WHXB20100434
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- Synthesis and Luminescence Properties of Soluble Spirobifluorene-Based Conjugated Polymers
- ZHANG Cheng, XU Yu, XU Yi, OUYANG Mi, MA Chun-An
- Spirobifluorene (SPF)-based soluble copolymers containing different chain lengths of alkoxy-benzene units in the main ch...
- 2010, 26 (04): 993-998. DOI: 10.3866/PKU.WHXB20100403
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QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
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- Understanding and Predicting Thiolated Gold Nanoclusters from First Principles
- JIANG De-En
- This is an exciting time for studying thiolated gold nanoclusters. Single crystal structures of Au102(SR)44 and Au25(SR)...
- 2010, 26 (04): 999-1016. DOI: 10.3866/PKU.WHXB20100414
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- The GW Method: Basic Principles, Latest Developments and Its Applications for d-and f-Electron Systems
- JIANG Hong
- The many-body perturbation theory based on the Green's function provides a rigorous conceptual framework to describe gro...
- 2010, 26 (04): 1017-1033. DOI: 10.3866/PKU.WHXB20100413
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- Coorperativity between Metals, Ligands and Solvent: a DFT Study on the Mechanism of a Dizinc Complex-Mediated Phosphodiester Cleavage
- FAN Yu-Bo, GAO Yi-Qin
- Density functional theory (DFT)-Tao-Perdew-Staroverov-Scuseria (TPSS) functional calculations on dizinc complex-mediated...
- 2010, 26 (04): 1034-1042. DOI: 10.3866/PKU.WHXB20100447
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- Comparative Study of Two Integration Methods for Solvation Effect Calculation
- DONG Bo, CHEN Fei-Wu, WEI Mei-Ju
- The parallelism and convergence of the approximate and analytical integration methods on solvation effect calculation we...
- 2010, 26 (04): 1043-1050. DOI: 10.3866/PKU.WHXB20100432
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- Electronic Structures and Spectroscopic Properties of Group-14 Metalloles MPh6 (M=Si, Ge, Sn)
- DENG Chun-Mei, NIU Ying-Li, PENG Qian, SHUAI Zhi-Gang
- Group-14 metalloles possess interesting optical properties and are promising molecules for light-emitting materials. We ...
- 2010, 26 (04): 1051-1058. DOI: 10.3866/PKU.WHXB20100420
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- Semiconductor Properties of Perylene Diimide Derivatives
- CAI Xue, QI Dong-Dong, ZHANG Yue-Xing, BIAN Yong-Zhong, JIANG Jian-Zhuang
- Density functional theory (DFT) calculations were carried out to study the charge transfer properties of N,N'-bisperylen...
- 2010, 26 (04): 1059-1064. DOI: 10.3866/PKU.WHXB20100421
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- QSAR of Macrolactone Derivatives with Herbicidal Activity
- DUAN Hong-Xia, WANG Rui-Gang, ZHANG Jian-Jun, DONG Yan-Hong, LIANG Xiao-Mei, WU Jing-Ping, WANG Dao-Quan
- We studied the quantitative structure-activity relationships (QSAR) of macrolactone derivatives. Statistical results fro...
- 2010, 26 (04): 1065-1074. DOI: 10.3866/PKU.WHXB20100435
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- Photoelectric Properties of 9,9’-Spirobifluorene
- ZHANG Cheng, YAN Yan, CHEN Li-Tao, MA Chun-An
- 9,9'-Spirobifluorene oligomers ((SBF)n(n=1-4)) were fully optimized using density functional theory (DFT) at the B3LYP/6...
- 2010, 26 (04): 1075-1081. DOI: 10.3866/PKU.WHXB20100402
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BIOPHYSICAL CHEMISTRY
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- Investigation of Interaction of Small Natural Product Molecules and Human Telomeric G-Quadruplex and Thermal Stabilities of the Complexes by Electrospray Ionization Mass Spectrometry
- HE Xiang-Wei, LONG Hai-Tao, YUAN Gu, Xu Xiao-Jie, ZHOU Ya-Wei
- Electrospray ionization mass spectrometry (ESI-MS) was used to investigate the non-covalent interaction of human telomer...
- 2010, 26 (04): 1082-1086. DOI: 10.3866/PKU.WHXB20100416
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- Maximum Entropy Method for Analyses of Fluorescence Correlation Spectra of Oligonucleotide Intra-Chain Collision
- YIN Yan-Dong, ZHOU Xiao-Xue, ZHAO Xin-Sheng
- It has been a challenge to accurately extract dynamic information from experimental fluorescence correlation spectroscop...
- 2010, 26 (04): 1087-1092. DOI: 10.3866/PKU.WHXB20100408
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- Substrate Binding and Homo-Dimerization of SARS 3CL Proteinase are Mutual Allosteric Effectors
- WEI Ping, LI Chun-Mei, ZHOU Lu, LIU Ying, LAI Lu-Hua
- The 3C-like proteinase (3CLpro) of severe acute respiratory syndrome (SARS) coronavirus has been proposed to be a key ta...
- 2010, 26 (04): 1093-1098. DOI: 10.3866/PKU.WHXB20100449
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- Single Molecule Fluorescence Resonance Energy Transfer and Ensemble Biophysical Characterization of a G-quadruplex Formed in the Promoter of Human Myocyte Enhancer Factor 2D
- ZHOU Wen-Hua, YING Li-Ming
- DNA G-quadruplexes (G4s) are believed to be involved in many biological processes, including the gene expression regulat...
- 2010, 26 (04): 1099-1106. DOI: 10.3866/PKU.WHXB20100439
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- Interaction of Nickel(II) with Yeast Alcohol Dehydrogenase
- YIN Guo-Wei, WEI Wei, XU Jia, LI Zhi-Fen, WANG Bao-Huai, DU Wei-Hong
- The binding mode of metal ions with proteins is usually different in different systems. Yeast alcohol dehydrogenase (YAD...
- 2010, 26 (04): 1107-1112. DOI: 10.3866/PKU.WHXB20100410
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- Adsorptive Immobilization of Four Proteases on Different Molecular Sieves
- LIU Ping, XING Guo-Wen, LI Xuan-Wen, YE Yun-Hua
- The immobilization of four different proteases on a series of molecular sieves, including microporous HY, NaY, NH4Y, MCM...
- 2010, 26 (04): 1113-1118. DOI: 10.3866/PKU.WHXB20100448
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- Electrochemical DNA Biosensor with a Polyamide Probe
- CAO Rui-Guo, ZHU Bin, LIU Wei, LI Jing-Jian, XU Dong-Sheng
- The base pair stack within a DNA duplex can transport charge over long distances. The π-stacked base pairs provide an...
- 2010, 26 (04): 1119-1123. DOI: 10.3866/PKU.WHXB20100427
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PHYSICAL CHEMISTRY OF MATERIALS
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- Progress in Discotic Liquid Crystalline Materials
- CHEN Shu-Sen, LI Tian, ZHAO Da-Hui
- Discotic liquid crystal (LC) molecules readily form columnar supramolecular structures. Because of molecular mobility in...
- 2010, 26 (04): 1124-1134. DOI: 10.3866/PKU.WHXB20100412
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- A Novel Path to Patterning Based on the Static Breath Figure Technique
- LI Lei, ZHONG Ya-Wen, CHEN Cai-Kang, LI Jian
- The breath figure technique is one of the most promising strategies for the fabrication of large-sized patterns containi...
- 2010, 26 (04): 1135-1142. DOI: 10.3866/PKU.WHXB20100424
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- Preparations and Catalytic Applications of High Surface Area Silicon Carbide
- GUO Xiang-Yun, JIN Guo-Qiang, WANG Ying-Yong
- We discuss recent developments in the preparation methods of high surface area silicon carbide, such as templated synthe...
- 2010, 26 (04): 1143-1150. DOI: 10.3866/PKU.WHXB20100426
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- Facile Fabrication of the Crossed Nanotube-Graphene Junctions
- GAN Lin, LIU Song, LI Dan-Na, GU Hang, CAO Yang, SHEN Qian, WANG Zhen-Xing, WANG Qing, GUO Xue-Feng
- In this study, a nondestructive method to mass produce crossed nanotube-graphene junctions through twice polymer-mediate...
- 2010, 26 (04): 1151-1156. DOI: 10.3866/PKU.WHXB20100417
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- Effect ofMolecular Structure on the Surface Morphology of Ultrathin Films by Competing Crystallization and Dewetting Processes
- YUAN Wei-Zhong, ZHANG Feng-Bo, YUAN Jin-Ying, XIE Xu-Ming, HONG Xiao-Yin
- Star-branched poly(ε-caprolactone) (PCL) including hexa-armed star-shaped PCL (HPCL), dendritic PCL (DPCL), and ...
- 2010, 26 (04): 1157-1163. DOI: 10.3866/PKU.WHXB20100431
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- Synthesis and Characterization of a Polyquinoline Derivative Thin Film with a Low Dielectric Constant
- ZHAO Xiong-Yan
- We prepared a novel plasma polyquinoline derivative thin film, plasma-polymerized 3-cyanoquinoline (PP3QCN). Fourier tra...
- 2010, 26 (04): 1164-1170. DOI: 10.3866/PKU.WHXB20100425
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- Preparation of High Specific Surface Area Nano-Alumina by Vacuum Freeze Drying
- LIU Xiang-Zhi, PIAO Ling-Yu, MAO Li-Juan, HAO Shi-Jie, YANG Lei, JU Si-Ting
- Nano-alumina powders were prepared by vacuum freeze drying combined with reverse microemulsion method. The reverse micro...
- 2010, 26 (04): 1171-1176. DOI: 10.3866/PKU.WHXB20100445
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- Preparation and Optical Properties of Triangular Silver Nanoplates by a Dual-Reduction Method
- LAI Wen-Zhong, ZHAO Wei, YANG Rong, LI Xing-Guo
- Triangular silver nanoplates were successfully prepared by a water-bath heating method. NaBH4 and sodium citrate were bo...
- 2010, 26 (04): 1177-1183. DOI: 10.3866/PKU.WHXB20100437
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- Synthesis and Photoluminescence of Iridium(III) Diazine Complex Modified with a Carbazyl Group
- YU Xiao-Hang, GE Guo-Ping, ZHANG Guo-Lin, GUO Hai-Qing
- We designed and synthesized a new pyrazine derivative containing the carbazyl moiety, 2,3-di(4-(9-carbazylmethyl)phenyl)...
- 2010, 26 (04): 1184-1190. DOI: 10.3866/PKU.WHXB20100442
