Table of Contents

• Table of Contents for Vol.26 No. 05
• 2010, 26 (05): 0-0

• 1272Abstract/Metrics
• 2034 PDF(4265KB)

COMMUNICATION

• Fueling Solid Oxide Fuel Cells with Activated Carbon
• TANG Yu-Bao, LIU Jiang
• A tubular electrolyte-supporting solid oxide fuel cell (SOFC) was fabricated by a slip casting technique. Yttrium stabil...
• 2010, 26 (05): 1191-1194 DOI: 10.3866/PKU.WHXB20100502

• 3814Abstract/Metrics
• 1724 PDF(484KB)

THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY

• Synthesis and Characterization of Novel Salen-Type Complexes and Their Axial Coordination Thermodynamics
• GUO Li-Qin, SHI Xiu-Li, RUAN Wen-Juan, ZHANG Xiao-Hong, ZHU Zhi-Ang
• Four novel Salen-type mono-and bi-nuclear complexes were synthesized by a metal template method, and were characterized ...
• 2010, 26 (05): 1195-1201 DOI: 10.3866/PKU.WHXB20100336

• 2991Abstract/Metrics
• 1527 PDF(299KB)

ELECTROCHEMISTRY

• Structure and Electrical Properties of MgO-Doped Ce_0.9Sm_0.1O_2-δ Based Solid Electrolytes
• NING De-Zheng, ZHOU De-Feng, XIA Yan-Jie, ZHAO Gui-Chun, MENG Jian
• The precursor powder of Ce0.9Sm0.1O2-δ(SDC) containing 5.0×10-4 (w) SiO2 as an impurity (SDCSi) was prepared...
• 2010, 26 (05): 1202-1206 DOI: 10.3866/PKU.WHXB20100509

• 2437Abstract/Metrics
• 1973 PDF(1433KB)

• Rare Earth Eu Doped PtRu/C Catalysts and Their Properties for Methanol Electrooxidation
• AN Xiao-Sha, CHEN De-Jun, ZHOU Zhi-You, WANG Qiang, FAN You-Jun, SUN Shi-Gang
• Commercially available PtRu/C catalyst was doped with Eu by chemical reduction and sintering, resulting in PtRuEux/C cat...
• 2010, 26 (05): 1207-1213 DOI: 10.3866/PKU.WHXB20100522

• 2676Abstract/Metrics
• 1701 PDF(986KB)

• Preparation of Carbon Nanotube Chemically Modified Electrode via Growing In situ Method by the Direct Current Electrochemical Deposition Nickel Catalyst
• HE Zheng-Wen, JIANG Qi, YANG Rong, QI Peng, ZHAO Fei, YUAN Hua, ZHAO Yong
• Grown in situ carbon nanotube chemically modified electrode (GSCNT-CME) was prepared by the in situ growth of carbon nan...
• 2010, 26 (05): 1214-1218 DOI: 10.3866/PKU.WHXB20100335

• 2983Abstract/Metrics
• 2048 PDF(2151KB)

• Galvanic Replacement Strategy for a Core-Shell Like Ni-Pt Electrocatalyst with High Pt Utilization
• SUN Dun, HE Jian-Ping, ZHOU Jian-Hua, WANG Tao, DI Zhi-Yong, DING Xiao-Chun
• A highly active and well-dispersed nanoscale Ptshell-Nicore/XC-72 electrocatalyst was synthesized. The Ni-core was reduc...
• 2010, 26 (05): 1219-1224 DOI: 10.3866/PKU.WHXB20100507

• 3049Abstract/Metrics
• 1770 PDF(1059KB)

• Corrosion Inhibition and Antifog Properties of an Environmentally Friendly Polyaspartate Inhibitor on A3 Carbon Steel
• XU Yi-Chun, TANG Bing, FU Feng-Lian, WANG Qiao-Yun, LIN Shao-Qiong, FENG Chun
• The synergetic adsorption, antifogging and corrosion inhibition properties of polyaspartate (PASP) and dodecane phenol p...
• 2010, 26 (05): 1225-1232 DOI: 10.3866/PKU.WHXB20100516

• 2393Abstract/Metrics
• 1677 PDF(1612KB)

• Preparation of an Ionic Liquid Gel Polymer Electrolyte and Its Compatibility with a LiFePO₄ Cathode
• CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia
• An ionic liquid gel polymer electrolyte (ILGPE) based on 1-ethyl-3-methyl-imidazoliumhexafluorophosphate (EMIPF6), poly(...
• 2010, 26 (05): 1233-1238 DOI: 10.3866/PKU.WHXB20100530

• 3691Abstract/Metrics
• 1797 PDF(1548KB)

• Capacitance at the Electrode/Ionic Liquid Interface
• ZHAO Di, HUANG Qing, JIN Xian-Bo, WEI Xian-Jun, CHEN George Z.
• The interfacial structure and capacitance of a Pt foil electrode were investigated by electrochemical impedance spectros...
• 2010, 26 (05): 1239-1248 DOI: 10.3866/PKU.WHXB20100506

• 4032Abstract/Metrics
• 2628 PDF(1217KB)

• Electrochemical Impedance Spectroscopy Analysis of an Electrophoretic Titania Nanotube/Nanoparticle Composite Film
• WANG Wen-Li, LIN Hong, ZHANG Luo-Zheng, LI Xin, CUI Bai, LI Jian-Bao
• As one-dimensional (1D) TiO2 nanostructures can benefit charge transport and improve the performance of dye-sensitized s...
• 2010, 26 (05): 1249-1253 DOI: 10.3866/PKU.WHXB20100505

• 3200Abstract/Metrics
• 2007 PDF(238KB)

• Preparation of Chitosan-Based Porous Carbons and Their Application as Electrode Materials for Supercapacitors
• JI Qian-Qian, GUO Pei-Zhi, ZHAO Xiu-Song
• Four porous carbon samples C-600, C-700, C-800, and C-900 were prepared by the carbonization of chitosan at 600, 700, 80...
• 2010, 26 (05): 1254-1258 DOI: 10.3866/PKU.WHXB20100330

• 5412Abstract/Metrics
• 2629 PDF(170KB)

• Preparation and Electrochemical Properties of SnO2/Onion-Like Hollow Carbon Nanoparticle Composites as Anode Materials for Lithium-Ion Batteries
• ZHANG Hui-Juan, SONG Huai-He, ZHOU Ji-Sheng, ZHANG Hong-Kun, CHEN Xiao-Hong
• New kinds of onion-like hollowcarbon nanoparticles (OC) with amean diameter of 40 nmwere synthesized by the pyrolysis of...
• 2010, 26 (05): 1259-1263 DOI: 10.3866/PKU.WHXB20100334

• 4095Abstract/Metrics
• 2299 PDF(1345KB)

STRUCTURE CHEMISTRY

• Synthesis, Structure and Chromic Properties of 4,4’-Bipyridine Polyoxomolybdate
• SUN De-Hui, ZHANG Ji-Lin, REN Hui-Juan, CUI Zhen-Feng, SUN De-Xin
• We synthesized a 4,4'-bipyridine polyoxomolybdate ((4,4'-bipyridine)Mo7O22·H2O) single crystal supramolecular com...
• 2010, 26 (05): 1264-1270 DOI: 10.3866/PKU.WHXB20100512

• 2848Abstract/Metrics
• 1809 PDF(1065KB)

COLLOID AND INTERFACE CHEMISTRY

• Determination of Surfactant cmc Based on the Fiber Refractive Index Sensor Principle
• HUANG Zhen-Jian, TAN Chun-Hua, HUANG Xu-Guang
• Anovelmethod for the determination of surfactant criticalmicelle concentration (cmc), based on the fiber refractive inde...
• 2010, 26 (05): 1271-1276 DOI: 10.3866/PKU.WHXB20100535

• 3540Abstract/Metrics
• 1980 PDF(764KB)

• Dilational Properties of Gemini Surfactants with Different Charge at the Interface
• LIU Xue-Peng, FENG Jie, ZHANG Lu, ZHAO Sui, YU Jia-Yong
• The dilational properties of the zwitterionic Gemini surfactant C8E4NC12, cationic Gemini surfactant C12NE3NC12, and ani...
• 2010, 26 (05): 1277-1283 DOI: 10.3866/PKU.WHXB20100510

• 3983Abstract/Metrics
• 1528 PDF(1048KB)

• Size Controlled Synthesis of CeO₂ Nanoparticles by a Microemulsion Method
• ZHU Wen-Qing, XU Lei, MA Jin, REN Jian-Mei, CHEN Ya-Shao
• Precursors of CeO2 were synthesized in a reverse microemulsion composed of cetyltrimethylammonium bromide (CTAB), 1-buta...
• 2010, 26 (05): 1284-1290 DOI: 10.3866/PKU.WHXB20100333

• 3138Abstract/Metrics
• 2352 PDF(1272KB)

CATALYSIS AND SURFACE STRUCTURE

• Growth of Manganese Silicide Thin Films on Si(111)-7×7 Surfaces by a Solid Phase Reaction
• WANG Dan, ZOU Zhi-Qiang, SUN Jing-Jing, ZHAO Ming-Hai
• Ultrathin manganese films were deposited onto Si(111)-7×7 surfaces by electron-beam evaporation. The solid phase r...
• 2010, 26 (05): 1291-1295 DOI: 10.3866/PKU.WHXB20100504

• 2520Abstract/Metrics
• 1669 PDF(2729KB)

• Dimethyl Ether Steam Reforming for Hydrogen Production over Cu-Ni/γ-A_l2O₃ Bi-Functional Catalyst
• WANG Xiao-Lei, PAN Xiang-Min, LIN Rui, KOU Su-Yuan, ZOU Wei-Bing, MA Jian-Xin
• Cu/γ-Al2O3, Ni/γ-Al2O3, and Cu-Ni/γ-Al2O3 catalysts were prepared using the deposition-precipitation m...
• 2010, 26 (05): 1296-1304 DOI: 10.3866/PKU.WHXB20100322

• 3658Abstract/Metrics
• 1690 PDF(799KB)

• Synthesis and Catalytic Properties of MeAPO-5 Molecular Sieves for Selective Oxidation of Cinnamyl Alcohol
• HE Yue, DONG Mei, LI Jun-Fen, WANG Jian-Guo, FAN Wei-Bin
• A series of metal ion-substituted aluminophosphate molecular sieves of MeAPO-5 (Me=Co, Fe, Cu, Zn, Mn) were hydrothermal...
• 2010, 26 (05): 1305-1310 DOI: 10.3866/PKU.WHXB20100517

• 2616Abstract/Metrics
• 1442 PDF(279KB)

• Effect of Carbon Modification on Electrocatalytic Performance of Carbon Supported Pd Catalysts
• DING Liang-Xin, WANG Shi-Rui, ZHENG Xiao-Long, CHEN Yu, LU Tian-Hong, CAO Dian-Xue, TANG Ya-Wen
• The effect of carbon modification on electrocatalytic performance of carbon supported Pd catalysts was investigated. Fou...
• 2010, 26 (05): 1311-1316 DOI: 10.3866/PKU.WHXB20100521

• 2767Abstract/Metrics
• 1991 PDF(1461KB)

• Preparation and Electrocatalytic Activity of Tungsten Carbide and Zeolite Nanocomposite
• YAO Guo-Xin, SHI Bin-Bin, LI Guo-Hua, ZHENG Yi-Fan
• WC zeolite nanocomposite was synthesized by combining a mechano-chemical approach with the reduction-carbonization techn...
• 2010, 26 (05): 1317-1322 DOI: 10.3866/PKU.WHXB20100337

• 2900Abstract/Metrics
• 1773 PDF(1625KB)

• Preparation of Nanocomposite Ag/TiO₂-ZrO₂ and the Microwave Enhanced Photocatalytic Degradation of Methyl Orange
• LI Li, LU Dan, JI Yuan, ZHAO Yue-Hong
• The nanocomposite Ag/TiO2-ZrO2 possessing high photocatalytic activity was prepared by the sol-gel method combined with ...
• 2010, 26 (05): 1323-1329 DOI: 10.3866/PKU.WHXB20100511

• 3219Abstract/Metrics
• 2530 PDF(1112KB)

• Synthesis and Photocatalytic Activity of Highly Dispersed TiO₂/SBA-15
• ZHANG Shu-Cui, JIANG Dong, TANG Tao, LI Jun-Hua, XU Yao
• Highly dispersed TiO2/SBA-15 photocatalysts were successfully synthesized by solvothermal treatment using titanium n-but...
• 2010, 26 (05): 1330-1336 DOI: 10.3866/PKU.WHXB20100520

• 3188Abstract/Metrics
• 1993 PDF(1267KB)

• Syntheses and Activities of Visible-Light-Driven Cu/BiVO₄ Composite Photocatalysts
• ZHANG Ai-Ping, ZHANG Jin-Zhi
• Cu-doped BiVO4 photocatalysts were hydrothermally synthesized and characterized by X-ray diffraction (XRD), X-ray photoe...
• 2010, 26 (05): 1337-1342 DOI: 10.3866/PKU.WHXB20100533

• 2970Abstract/Metrics
• 1913 PDF(1413KB)

PHOTOCHEMISTRY AND SPECTROSCOPY

• Synthesis and Photoluminescence of Zn₂SnO₄ Nanomaterials
• ZHAO Chuan-Xi, WU Ping, ZHANG Dan-Li, CHEN Rong, CHI Ling-Fei, XIAO Tan
• We synthesized Zn2SnO4 nanomaterials by the carbon-thermal evaporation method with Zn, SnO2 and C powder mixture, withou...
• 2010, 26 (05): 1343-1348 DOI: 10.3866/PKU.WHXB20100524

• 3241Abstract/Metrics
• 2042 PDF(781KB)

• Spectrum Analysis on Phase Transformations in TiO₂ Thin Films
• YANG Chang-Hu, MA Zhong-Quan, LI Feng, HE Bo, YUAN Jian-Hui, ZHANG Zhen-Hua
• 2010, 26 (05): 1349-1354 DOI: 10.3866/PKU.WHXB20100519

• 4051Abstract/Metrics
• Supporting Info
• 1727 PDF(1098KB)

• Design and Fabrication of a Miniature FAIMS Sensor Chip
• LI Hua, WANG Xiao-Hao, TANG Fei, ZHANG Liang, YANG Ji, LIN Tao, DING Li
• Based on micro-electro-mechanical system (MEMS) technology, a miniature high-field asymmetric waveformion mobility spect...
• 2010, 26 (05): 1355-1363 DOI: 10.3866/PKU.WHXB20100508

• 2595Abstract/Metrics
• 2844 PDF(3164KB)

QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY

• Quantum Chemical Calculation of Hydroxyalkyl Ammonium Functionalized Ionic Liquids for Absorbing SO₂
• LI Xue-Liang, CHEN Jie-Jie, LUO Mei, CHEN Xiang-Ying, LI Pei-Pei
• Interactions between hydroxyalkyl ammonium ionic liquids (HyAA ILs) and sulfur dioxide (SO2) were investigated by quantu...
• 2010, 26 (05): 1364-1372 DOI: 10.3866/PKU.WHXB20100529

• 3627Abstract/Metrics
• Supporting Info
• 1986 PDF(1842KB)

• Adsorption of Urea onto a ZnO(10-10) Surface
• TANG Wen-Dong, GAO Yang-Yan, WEI Wei, SUN Yu-Han
• First-principles calculations based on density functional theory (DFT) were used to investigate the adsorption of urea o...
• 2010, 26 (05): 1373-1377 DOI: 10.3866/PKU.WHXB20100503

• 3550Abstract/Metrics
• 2056 PDF(1701KB)

• CO Adsorption on α-U(001) Surface
• LI Gan, LUO Wen-Hua, CHEN Hu-Chi
• The adsorption, dissociation, and diffusion of CO on the α-U(001) surface were studied using density functional th...
• 2010, 26 (05): 1378-1384 DOI: 10.3866/PKU.WHXB20100523

• 4265Abstract/Metrics
• 1636 PDF(1454KB)

• Molecular Dynamics Simulation of the Adsorption Behavior of Imidazoline Corrosion Inhibitors on a Fe(001) Surface
• ZHANG Jun, YU Wei-Zhao, YAN You-Guo, YU Li-Jun, REN Zhen-Jia
• The adsorption behaviors of five imidazoline corrosion inhibitors with different alkyl chain lengths on a Fe(001) surfac...
• 2010, 26 (05): 1385-1390 DOI: 10.3866/PKU.WHXB20100501

• 3060Abstract/Metrics
• 2198 PDF(2825KB)

• Structures andMagnetic Properties of Fe_6-xAl_x Clusters
• YU Shuai-Qin, JIA Xiang-Feng, DONG Li-Hua, YIN Yan-Sheng
• All possible geometrical structures of Fe6-xAlx clusters were optimized at the BPW91 level in density functional theory ...
• 2010, 26 (05): 1391-1395 DOI: 10.3866/PKU.WHXB20100537

• 4017Abstract/Metrics
• 1631 PDF(922KB)

• Structural Characteristics and Stability of C_nAl⁺ Small-Size Clusters
• MA Wen-Jin, SONG Xiang, ZHANG Xian-Ming, WU Hai-Shun
• The geometric and electronic properties of CnAl+ (n=2-12) clusters were investigated using the B3LYP method of density f...
• 2010, 26 (05): 1396-1400 DOI: 10.3866/PKU.WHXB20100513

• 3317Abstract/Metrics
• 1372 PDF(499KB)

• Light Absorption Properties of V-Doped Anatase TiO₂
• XU Ling, TANG Chao-Qun, HUANG Zong-Bin
• Vanadium-doped anatase TiO2 was prepared by a sol-gel method while V2O5 and ethanol were used as vanadium precursors. UV...
• 2010, 26 (05): 1401-1407 DOI: 10.3866/PKU.WHXB20100526

• 3100Abstract/Metrics
• 1653 PDF(1165KB)

• Molecular Design of D5 Analogues for Dye-Sensitized Solar Cells
• ZHAN Wei-Shen, PAN Shi, LI Yuan-Zuo, CHEN Mao-Du
• Using density functional theory, time-dependent density functional theory and natural bond orbital analysis, we designed...
• 2010, 26 (05): 1408-1416 DOI: 10.3866/PKU.WHXB20100518

• 3043Abstract/Metrics
• 2233 PDF(2165KB)

• Probable Configurations and Spectroscopic Properties of the Inclusion Compound of Cucurbit[7]uril and Riboflavin
• WANG Su-Fan, ZHOU Yun-You, YE Shi-Yong, ZHOU Tao, HUANG Yu-Cheng
• Possible configurations and optical properties of a cucurbit[7]uril (CB7) and riboflavin (VB2) inclusion compound were i...
• 2010, 26 (05): 1417-1422 DOI: 10.3866/PKU.WHXb20100527

• 2563Abstract/Metrics
• 1494 PDF(1896KB)

• Charge Transfer Properties of Fluorine-Functionalized Thieno-Tetrathiafulvalene as Organic Field-Effect Materials
• KAN Yu-He, WU Kai, ZHU Yu-Lan, HOU Li-Mei, SU Zhong-Min
• Thieno-tetrathiafulvalene derivatives show great potential for use as organic field effect materials. We investigated th...
• 2010, 26 (05): 1423-1428 DOI: 10.3866/PKU.WHXB20100528

• 3710Abstract/Metrics
• 1793 PDF(928KB)

• Insertion Reactions of Heterocyclic Stable Silylenes into HF, H₂O and NH₃
• SUN Long, XIE Ju
• Divalent silicon species (silylenes) corresponding to carbenes in organic chemistry are key intermediates in numerous th...
• 2010, 26 (05): 1429-1434 DOI: 10.3866/PKU.WHXB20100325

• 2164Abstract/Metrics
• 1547 PDF(1284KB)

• Electronic Structures and Flotation Behavior of Pyrite Containing Vacancy Defects
• LI Yu-Qiong, CHEN Jian-Hua, CHEN Ye
• Electronic structures of pyrites containing vacancies were calculated using a first-principles plane-wave pseudopotentia...
• 2010, 26 (05): 1435-1441 DOI: 10.3866/PKU.WHXB20100332

• 2914Abstract/Metrics
• 1950 PDF(1068KB)

BIOPHYSICAL CHEMISTRY

• Microcalorimetric Investigation of Four Bioactive Extracts from Cornu Cervi Pantotrichumon Intestinal Diagnostic Flora Growth
• TANG Hui-Ying, YAN Dan, ZHANG Qing-Zhe, ZHANG Shao-Feng, XIAO Xiao-He, LIU Rong-Hua
• The facilitative effects of four bioactive extracts from Cornu Cervi Pantotrichum, a valuable traditional Chinese medici...
• 2010, 26 (05): 1442-1447 DOI: 10.3866/PKU.WHXB20100525

• 2301Abstract/Metrics
• 1598 PDF(1004KB)

PHYSICAL CHEMISTRY OF MATERIALS

• Adsorption and Diffusion of H on Mg₂Ni(100) Surface
• LI Guang-Xu, CHEN Xiao-Wei, BAI Jia-Dong, LAN Zhi-Qiang, GUO Jin
• First-principles were used to investigate hydrogen adsorption and diffusion on clean and Al doped Mg2Ni(100) surfaces. T...
• 2010, 26 (05): 1448-1456 DOI: 10.3866/PKU.WHXB20100540

• 3366Abstract/Metrics
• 1705 PDF(2794KB)

• Fabrication and Anti-Icing Performance of a Superhydrophobic Copper Surface with Low Adhesion
• ZHANG You-Fa, YU Xin-Quan, ZHOU Quan-Hui, LI Kang-Ning
• Microscale V-shaped impact pits are formed on copper surfaces after sandblasting. After surface oxidation, the whole cop...
• 2010, 26 (05): 1457-1462 DOI: 10.3866/PKU.WHXB20100532

• 3192Abstract/Metrics
• 1738 PDF(2683KB)