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Acta Phys. -Chim. Sin.
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中文
Current Issue
2010 Vol. 26,No. 05
Published: 29 April 2010
Current column
Table of Contents
COMMUNICATION
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
ELECTROCHEMISTRY
STRUCTURE CHEMISTRY
COLLOID AND INTERFACE CHEMISTRY
CATALYSIS AND SURFACE STRUCTURE
PHOTOCHEMISTRY AND SPECTROSCOPY
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
BIOPHYSICAL CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Table of Contents for Vol.26 No. 05
2010, 26 (05): 0.
1478
Abstract/Metrics
2138
PDF(4265KB)
COMMUNICATION
Fueling Solid Oxide Fuel Cells with Activated Carbon
TANG Yu-Bao, LIU Jiang
A tubular electrolyte-supporting solid oxide fuel cell (SOFC) was fabricated by a slip casting technique. Yttrium stabil...
2010, 26 (05): 1191-1194.
DOI: 10.3866/PKU.WHXB20100502
4871
Abstract/Metrics
1880
PDF(484KB)
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
Synthesis and Characterization of Novel Salen-Type Complexes and Their Axial Coordination Thermodynamics
GUO Li-Qin, SHI Xiu-Li, RUAN Wen-Juan, ZHANG Xiao-Hong, ZHU Zhi-Ang
Four novel Salen-type mono-and bi-nuclear complexes were synthesized by a metal template method, and were characterized ...
2010, 26 (05): 1195-1201.
DOI: 10.3866/PKU.WHXB20100336
4024
Abstract/Metrics
1672
PDF(299KB)
ELECTROCHEMISTRY
Structure and Electrical Properties of MgO-Doped Ce
0.9
Sm
0.1
O
2-
δ
Based Solid Electrolytes
NING De-Zheng, ZHOU De-Feng, XIA Yan-Jie, ZHAO Gui-Chun, MENG Jian
The precursor powder of Ce0.9Sm0.1O2-δ(SDC) containing 5.0×10-4 (w) SiO2 as an impurity (SDCSi) was prepared...
2010, 26 (05): 1202-1206.
DOI: 10.3866/PKU.WHXB20100509
3354
Abstract/Metrics
2156
PDF(1433KB)
Rare Earth Eu Doped PtRu/C Catalysts and Their Properties for Methanol Electrooxidation
AN Xiao-Sha, CHEN De-Jun, ZHOU Zhi-You, WANG Qiang, FAN You-Jun, SUN Shi-Gang
Commercially available PtRu/C catalyst was doped with Eu by chemical reduction and sintering, resulting in PtRuEux/C cat...
2010, 26 (05): 1207-1213.
DOI: 10.3866/PKU.WHXB20100522
3507
Abstract/Metrics
2051
PDF(986KB)
Preparation of Carbon Nanotube Chemically Modified Electrode via Growing In situ Method by the Direct Current Electrochemical Deposition Nickel Catalyst
HE Zheng-Wen, JIANG Qi, YANG Rong, QI Peng, ZHAO Fei, YUAN Hua, ZHAO Yong
Grown in situ carbon nanotube chemically modified electrode (GSCNT-CME) was prepared by the in situ growth of carbon nan...
2010, 26 (05): 1214-1218.
DOI: 10.3866/PKU.WHXB20100335
3997
Abstract/Metrics
2258
PDF(2151KB)
Galvanic Replacement Strategy for a Core-Shell Like Ni-Pt Electrocatalyst with High Pt Utilization
SUN Dun, HE Jian-Ping, ZHOU Jian-Hua, WANG Tao, DI Zhi-Yong, DING Xiao-Chun
A highly active and well-dispersed nanoscale Ptshell-Nicore/XC-72 electrocatalyst was synthesized. The Ni-core was reduc...
2010, 26 (05): 1219-1224.
DOI: 10.3866/PKU.WHXB20100507
4133
Abstract/Metrics
1971
PDF(1059KB)
Corrosion Inhibition and Antifog Properties of an Environmentally Friendly Polyaspartate Inhibitor on A3 Carbon Steel
XU Yi-Chun, TANG Bing, FU Feng-Lian, WANG Qiao-Yun, LIN Shao-Qiong, FENG Chun
The synergetic adsorption, antifogging and corrosion inhibition properties of polyaspartate (PASP) and dodecane phenol p...
2010, 26 (05): 1225-1232.
DOI: 10.3866/PKU.WHXB20100516
3222
Abstract/Metrics
1864
PDF(1612KB)
Preparation of an Ionic Liquid Gel Polymer Electrolyte and Its Compatibility with a LiFePO
4
Cathode
CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia
An ionic liquid gel polymer electrolyte (ILGPE) based on 1-ethyl-3-methyl-imidazoliumhexafluorophosphate (EMIPF6), poly(...
2010, 26 (05): 1233-1238.
DOI: 10.3866/PKU.WHXB20100530
4637
Abstract/Metrics
2294
PDF(1548KB)
Capacitance at the Electrode/Ionic Liquid Interface
ZHAO Di, HUANG Qing, JIN Xian-Bo, WEI Xian-Jun, CHEN George Z.
The interfacial structure and capacitance of a Pt foil electrode were investigated by electrochemical impedance spectros...
2010, 26 (05): 1239-1248.
DOI: 10.3866/PKU.WHXB20100506
5236
Abstract/Metrics
2910
PDF(1217KB)
Electrochemical Impedance Spectroscopy Analysis of an Electrophoretic Titania Nanotube/Nanoparticle Composite Film
WANG Wen-Li, LIN Hong, ZHANG Luo-Zheng, LI Xin, CUI Bai, LI Jian-Bao
As one-dimensional (1D) TiO2 nanostructures can benefit charge transport and improve the performance of dye-sensitized s...
2010, 26 (05): 1249-1253.
DOI: 10.3866/PKU.WHXB20100505
4105
Abstract/Metrics
2113
PDF(238KB)
Preparation of Chitosan-Based Porous Carbons and Their Application as Electrode Materials for Supercapacitors
JI Qian-Qian, GUO Pei-Zhi, ZHAO Xiu-Song
Four porous carbon samples C-600, C-700, C-800, and C-900 were prepared by the carbonization of chitosan at 600, 700, 80...
2010, 26 (05): 1254-1258.
DOI: 10.3866/PKU.WHXB20100330
6423
Abstract/Metrics
2782
PDF(170KB)
Preparation and Electrochemical Properties of SnO2/Onion-Like Hollow Carbon Nanoparticle Composites as Anode Materials for Lithium-Ion Batteries
ZHANG Hui-Juan, SONG Huai-He, ZHOU Ji-Sheng, ZHANG Hong-Kun, CHEN Xiao-Hong
New kinds of onion-like hollowcarbon nanoparticles (OC) with amean diameter of 40 nmwere synthesized by the pyrolysis of...
2010, 26 (05): 1259-1263.
DOI: 10.3866/PKU.WHXB20100334
4900
Abstract/Metrics
2579
PDF(1345KB)
STRUCTURE CHEMISTRY
Synthesis, Structure and Chromic Properties of 4,4’-Bipyridine Polyoxomolybdate
SUN De-Hui, ZHANG Ji-Lin, REN Hui-Juan, CUI Zhen-Feng, SUN De-Xin
We synthesized a 4,4'-bipyridine polyoxomolybdate ((4,4'-bipyridine)Mo7O22·H2O) single crystal supramolecular com...
2010, 26 (05): 1264-1270.
DOI: 10.3866/PKU.WHXB20100512
3793
Abstract/Metrics
2011
PDF(1065KB)
COLLOID AND INTERFACE CHEMISTRY
Determination of Surfactant cmc Based on the Fiber Refractive Index Sensor Principle
HUANG Zhen-Jian, TAN Chun-Hua, HUANG Xu-Guang
Anovelmethod for the determination of surfactant criticalmicelle concentration (cmc), based on the fiber refractive inde...
2010, 26 (05): 1271-1276.
DOI: 10.3866/PKU.WHXB20100535
4553
Abstract/Metrics
2151
PDF(764KB)
Dilational Properties of Gemini Surfactants with Different Charge at the Interface
LIU Xue-Peng, FENG Jie, ZHANG Lu, ZHAO Sui, YU Jia-Yong
The dilational properties of the zwitterionic Gemini surfactant C8E4NC12, cationic Gemini surfactant C12NE3NC12, and ani...
2010, 26 (05): 1277-1283.
DOI: 10.3866/PKU.WHXB20100510
4884
Abstract/Metrics
1645
PDF(1048KB)
Size Controlled Synthesis of CeO
2
Nanoparticles by a Microemulsion Method
ZHU Wen-Qing, XU Lei, MA Jin, REN Jian-Mei, CHEN Ya-Shao
Precursors of CeO2 were synthesized in a reverse microemulsion composed of cetyltrimethylammonium bromide (CTAB), 1-buta...
2010, 26 (05): 1284-1290.
DOI: 10.3866/PKU.WHXB20100333
4133
Abstract/Metrics
2618
PDF(1272KB)
CATALYSIS AND SURFACE STRUCTURE
Growth of Manganese Silicide Thin Films on Si(111)-7×7 Surfaces by a Solid Phase Reaction
WANG Dan, ZOU Zhi-Qiang, SUN Jing-Jing, ZHAO Ming-Hai
Ultrathin manganese films were deposited onto Si(111)-7×7 surfaces by electron-beam evaporation. The solid phase r...
2010, 26 (05): 1291-1295.
DOI: 10.3866/PKU.WHXB20100504
3396
Abstract/Metrics
1837
PDF(2729KB)
Dimethyl Ether Steam Reforming for Hydrogen Production over Cu-Ni/
γ
-A
l2
O
3
Bi-Functional Catalyst
WANG Xiao-Lei, PAN Xiang-Min, LIN Rui, KOU Su-Yuan, ZOU Wei-Bing, MA Jian-Xin
Cu/γ-Al2O3, Ni/γ-Al2O3, and Cu-Ni/γ-Al2O3 catalysts were prepared using the deposition-precipitation m...
2010, 26 (05): 1296-1304.
DOI: 10.3866/PKU.WHXB20100322
4577
Abstract/Metrics
1835
PDF(799KB)
Synthesis and Catalytic Properties of MeAPO-5 Molecular Sieves for Selective Oxidation of Cinnamyl Alcohol
HE Yue, DONG Mei, LI Jun-Fen, WANG Jian-Guo, FAN Wei-Bin
A series of metal ion-substituted aluminophosphate molecular sieves of MeAPO-5 (Me=Co, Fe, Cu, Zn, Mn) were hydrothermal...
2010, 26 (05): 1305-1310.
DOI: 10.3866/PKU.WHXB20100517
3503
Abstract/Metrics
1589
PDF(279KB)
Effect of Carbon Modification on Electrocatalytic Performance of Carbon Supported Pd Catalysts
DING Liang-Xin, WANG Shi-Rui, ZHENG Xiao-Long, CHEN Yu, LU Tian-Hong, CAO Dian-Xue, TANG Ya-Wen
The effect of carbon modification on electrocatalytic performance of carbon supported Pd catalysts was investigated. Fou...
2010, 26 (05): 1311-1316.
DOI: 10.3866/PKU.WHXB20100521
3711
Abstract/Metrics
2202
PDF(1461KB)
Preparation and Electrocatalytic Activity of Tungsten Carbide and Zeolite Nanocomposite
YAO Guo-Xin, SHI Bin-Bin, LI Guo-Hua, ZHENG Yi-Fan
WC zeolite nanocomposite was synthesized by combining a mechano-chemical approach with the reduction-carbonization techn...
2010, 26 (05): 1317-1322.
DOI: 10.3866/PKU.WHXB20100337
3701
Abstract/Metrics
1924
PDF(1625KB)
Preparation of Nanocomposite Ag/TiO
2
-ZrO
2
and the Microwave Enhanced Photocatalytic Degradation of Methyl Orange
LI Li, LU Dan, JI Yuan, ZHAO Yue-Hong
The nanocomposite Ag/TiO2-ZrO2 possessing high photocatalytic activity was prepared by the sol-gel method combined with ...
2010, 26 (05): 1323-1329.
DOI: 10.3866/PKU.WHXB20100511
3861
Abstract/Metrics
2687
PDF(1112KB)
Synthesis and Photocatalytic Activity of Highly Dispersed TiO
2
/SBA-15
ZHANG Shu-Cui, JIANG Dong, TANG Tao, LI Jun-Hua, XU Yao
Highly dispersed TiO2/SBA-15 photocatalysts were successfully synthesized by solvothermal treatment using titanium n-but...
2010, 26 (05): 1330-1336.
DOI: 10.3866/PKU.WHXB20100520
3976
Abstract/Metrics
2165
PDF(1267KB)
Syntheses and Activities of Visible-Light-Driven Cu/BiVO
4
Composite Photocatalysts
ZHANG Ai-Ping, ZHANG Jin-Zhi
Cu-doped BiVO4 photocatalysts were hydrothermally synthesized and characterized by X-ray diffraction (XRD), X-ray photoe...
2010, 26 (05): 1337-1342.
DOI: 10.3866/PKU.WHXB20100533
3772
Abstract/Metrics
2080
PDF(1413KB)
PHOTOCHEMISTRY AND SPECTROSCOPY
Synthesis and Photoluminescence of Zn
2
SnO
4
Nanomaterials
ZHAO Chuan-Xi, WU Ping, ZHANG Dan-Li, CHEN Rong, CHI Ling-Fei, XIAO Tan
We synthesized Zn2SnO4 nanomaterials by the carbon-thermal evaporation method with Zn, SnO2 and C powder mixture, withou...
2010, 26 (05): 1343-1348.
DOI: 10.3866/PKU.WHXB20100524
4309
Abstract/Metrics
2268
PDF(781KB)
Spectrum Analysis on Phase Transformations in TiO
2
Thin Films
YANG Chang-Hu, MA Zhong-Quan, LI Feng, HE Bo, YUAN Jian-Hui, ZHANG Zhen-Hua
2010, 26 (05): 1349-1354.
DOI: 10.3866/PKU.WHXB20100519
4925
Abstract/Metrics
Supporting Info
1927
PDF(1098KB)
Design and Fabrication of a Miniature FAIMS Sensor Chip
LI Hua, WANG Xiao-Hao, TANG Fei, ZHANG Liang, YANG Ji, LIN Tao, DING Li
Based on micro-electro-mechanical system (MEMS) technology, a miniature high-field asymmetric waveformion mobility spect...
2010, 26 (05): 1355-1363.
DOI: 10.3866/PKU.WHXB20100508
3486
Abstract/Metrics
3169
PDF(3164KB)
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
Quantum Chemical Calculation of Hydroxyalkyl Ammonium Functionalized Ionic Liquids for Absorbing SO
2
LI Xue-Liang, CHEN Jie-Jie, LUO Mei, CHEN Xiang-Ying, LI Pei-Pei
Interactions between hydroxyalkyl ammonium ionic liquids (HyAA ILs) and sulfur dioxide (SO2) were investigated by quantu...
2010, 26 (05): 1364-1372.
DOI: 10.3866/PKU.WHXB20100529
4395
Abstract/Metrics
Supporting Info
2348
PDF(1842KB)
Adsorption of Urea onto a ZnO(10-10) Surface
TANG Wen-Dong, GAO Yang-Yan, WEI Wei, SUN Yu-Han
First-principles calculations based on density functional theory (DFT) were used to investigate the adsorption of urea o...
2010, 26 (05): 1373-1377.
DOI: 10.3866/PKU.WHXB20100503
4479
Abstract/Metrics
2247
PDF(1701KB)
CO Adsorption on
α
-U(001) Surface
LI Gan, LUO Wen-Hua, CHEN Hu-Chi
The adsorption, dissociation, and diffusion of CO on the α-U(001) surface were studied using density functional th...
2010, 26 (05): 1378-1384.
DOI: 10.3866/PKU.WHXB20100523
5051
Abstract/Metrics
1806
PDF(1454KB)
Molecular Dynamics Simulation of the Adsorption Behavior of Imidazoline Corrosion Inhibitors on a Fe(001) Surface
ZHANG Jun, YU Wei-Zhao, YAN You-Guo, YU Li-Jun, REN Zhen-Jia
The adsorption behaviors of five imidazoline corrosion inhibitors with different alkyl chain lengths on a Fe(001) surfac...
2010, 26 (05): 1385-1390.
DOI: 10.3866/PKU.WHXB20100501
3990
Abstract/Metrics
2439
PDF(2825KB)
Structures andMagnetic Properties of Fe
6-
x
Al
x
Clusters
YU Shuai-Qin, JIA Xiang-Feng, DONG Li-Hua, YIN Yan-Sheng
All possible geometrical structures of Fe6-xAlx clusters were optimized at the BPW91 level in density functional theory ...
2010, 26 (05): 1391-1395.
DOI: 10.3866/PKU.WHXB20100537
4612
Abstract/Metrics
1751
PDF(922KB)
Structural Characteristics and Stability of C
n
Al
+
Small-Size Clusters
MA Wen-Jin, SONG Xiang, ZHANG Xian-Ming, WU Hai-Shun
The geometric and electronic properties of CnAl+ (n=2-12) clusters were investigated using the B3LYP method of density f...
2010, 26 (05): 1396-1400.
DOI: 10.3866/PKU.WHXB20100513
4022
Abstract/Metrics
1477
PDF(499KB)
Light Absorption Properties of V-Doped Anatase TiO
2
XU Ling, TANG Chao-Qun, HUANG Zong-Bin
Vanadium-doped anatase TiO2 was prepared by a sol-gel method while V2O5 and ethanol were used as vanadium precursors. UV...
2010, 26 (05): 1401-1407.
DOI: 10.3866/PKU.WHXB20100526
3764
Abstract/Metrics
1815
PDF(1165KB)
Molecular Design of D5 Analogues for Dye-Sensitized Solar Cells
ZHAN Wei-Shen, PAN Shi, LI Yuan-Zuo, CHEN Mao-Du
Using density functional theory, time-dependent density functional theory and natural bond orbital analysis, we designed...
2010, 26 (05): 1408-1416.
DOI: 10.3866/PKU.WHXB20100518
3811
Abstract/Metrics
2350
PDF(2165KB)
Probable Configurations and Spectroscopic Properties of the Inclusion Compound of Cucurbit[7]uril and Riboflavin
WANG Su-Fan, ZHOU Yun-You, YE Shi-Yong, ZHOU Tao, HUANG Yu-Cheng
Possible configurations and optical properties of a cucurbit[7]uril (CB7) and riboflavin (VB2) inclusion compound were i...
2010, 26 (05): 1417-1422.
DOI: 10.3866/PKU.WHXb20100527
3432
Abstract/Metrics
1683
PDF(1896KB)
Charge Transfer Properties of Fluorine-Functionalized Thieno-Tetrathiafulvalene as Organic Field-Effect Materials
KAN Yu-He, WU Kai, ZHU Yu-Lan, HOU Li-Mei, SU Zhong-Min
Thieno-tetrathiafulvalene derivatives show great potential for use as organic field effect materials. We investigated th...
2010, 26 (05): 1423-1428.
DOI: 10.3866/PKU.WHXB20100528
4528
Abstract/Metrics
1934
PDF(928KB)
Insertion Reactions of Heterocyclic Stable Silylenes into HF, H
2
O and NH
3
SUN Long, XIE Ju
Divalent silicon species (silylenes) corresponding to carbenes in organic chemistry are key intermediates in numerous th...
2010, 26 (05): 1429-1434.
DOI: 10.3866/PKU.WHXB20100325
2912
Abstract/Metrics
1682
PDF(1284KB)
Electronic Structures and Flotation Behavior of Pyrite Containing Vacancy Defects
LI Yu-Qiong, CHEN Jian-Hua, CHEN Ye
Electronic structures of pyrites containing vacancies were calculated using a first-principles plane-wave pseudopotentia...
2010, 26 (05): 1435-1441.
DOI: 10.3866/PKU.WHXB20100332
3836
Abstract/Metrics
2146
PDF(1068KB)
BIOPHYSICAL CHEMISTRY
Microcalorimetric Investigation of Four Bioactive Extracts from Cornu Cervi Pantotrichumon Intestinal Diagnostic Flora Growth
TANG Hui-Ying, YAN Dan, ZHANG Qing-Zhe, ZHANG Shao-Feng, XIAO Xiao-He, LIU Rong-Hua
The facilitative effects of four bioactive extracts from Cornu Cervi Pantotrichum, a valuable traditional Chinese medici...
2010, 26 (05): 1442-1447.
DOI: 10.3866/PKU.WHXB20100525
3063
Abstract/Metrics
1722
PDF(1004KB)
PHYSICAL CHEMISTRY OF MATERIALS
Adsorption and Diffusion of H on Mg
2
Ni(100) Surface
LI Guang-Xu, CHEN Xiao-Wei, BAI Jia-Dong, LAN Zhi-Qiang, GUO Jin
First-principles were used to investigate hydrogen adsorption and diffusion on clean and Al doped Mg2Ni(100) surfaces. T...
2010, 26 (05): 1448-1456.
DOI: 10.3866/PKU.WHXB20100540
4423
Abstract/Metrics
1888
PDF(2794KB)
Fabrication and Anti-Icing Performance of a Superhydrophobic Copper Surface with Low Adhesion
ZHANG You-Fa, YU Xin-Quan, ZHOU Quan-Hui, LI Kang-Ning
Microscale V-shaped impact pits are formed on copper surfaces after sandblasting. After surface oxidation, the whole cop...
2010, 26 (05): 1457-1462.
DOI: 10.3866/PKU.WHXB20100532
4109
Abstract/Metrics
2101
PDF(2683KB)