Table of Contents

• Cover and Table of Contents for Vol.26 No. 08
• 2010, 26 (08): 0.

• 1420Abstract/Metrics
• 1935 PDF(6491KB)

COMMUNICATION

• Electrochemical Construction and Biological Performance of Micropatterned CaP Films
• HUANG Yong-Xia, LAI Yue-Kun, LIN, Long-Xiang, SUN Lan, LIN Chang-Jian
• Based on surface molecule self-assembly and photocatalytic lithography techniques, superhydrophilic/superhydrophobic mic...
• 2010, 26 (08): 2057-2060. DOI: 10.3866/PKU.WHXB20100837

• 3114Abstract/Metrics
• 1657 PDF(304KB)

REVIEW

• Intrinsically Disordered Proteins: the New
• HUANG Yong-Qi, LIU Zhi-Rong
• Intrinsically disordered proteins (IDPs) are a new class of proteins which lack a unique tertiary structure under native...
• 2010, 26 (08): 2061-2072. DOI: 10.3866/PKU.WHXB20100644

• 6117Abstract/Metrics
• 3220 PDF(447KB)

• Graphene: Synthesis, Functionalization and Applications in Chemistry
• HU Yao-Juan, JIN Juan, ZHANG Hui, WU Ping, CAI Chen-Xin
• Graphene, a recently discovered carbon nanomaterial with carbon atoms tightly packed into a two dimensional honeycomb la...
• 2010, 26 (08): 2073-2086. DOI: 10.3866/PKU.WHXB20100812

• 14374Abstract/Metrics
• 38414 PDF(2092KB)

• Crystallization of Calcium Carbonate Using Water-Soluble Macromolecules
• YANG Xiao-Deng, SHEN Qiang, XU Gui-Ying
• The influence of water-soluble macromolecules on the crystallization of calcium carbonate is reviewed combining with our...
• 2010, 26 (08): 2087-2095. DOI: 10.3866/PKU.WHXB20100639

• 4174Abstract/Metrics
• 2346 PDF(430KB)

THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY

• Low Temperature Heat Capacity and Thermal Analysis of Caffeine, Theophylline and Aminophylline
• XU Fen, QIU Shu-Jun, LIANG Jian-Guo, WU Rui-Hua, SUN Li-Xian, LI Fen
• Caffeine, theophylline, and aminophylline are important methyl-substituted xanthines and are widely used in clinics. In ...
• 2010, 26 (08): 2096-2102. DOI: 10.3866/PKU.WHXB20100836

• 5108Abstract/Metrics
• 2155 PDF(255KB)

• Heterotactic Enthalpy of the Interaction between Protein Model Compounds and Diols in Aqueous Solutions at 310.15 K
• ZHU Yan, PANG Xian-Hong, YU Li
• The enthalpies of mixing for model protein compounds (glycine, alanine, N,N-dimethyl formamide (DMF) and N,N-dimethyl ac...
• 2010, 26 (08): 2103-2108. DOI: 10.3866/PKU.WHXB20100821

• 3156Abstract/Metrics
• 1334 PDF(373KB)

• Determination of Acid-Base Equilibrium Constants on Aqueous Mesoporous Silica Surfaces
• ZHANG Wei-Min, YANG Zhen-Dong, LIU Jia, SUN Zhong-Xi
• We used the potentiometric titration technique to study the deprotonation reactions at aqueous mesoporous silica surface...
• 2010, 26 (08): 2109-2114. DOI: 10.3866/PKU.WHXB20100801

• 5181Abstract/Metrics
• 1952 PDF(232KB)

CHEMICAL KINETICS AND MOLECULE DYNAMICS

• Oxidation Reaction Kinetics of Abietic Acid and Rosin under Ultraviolet Light Irradiation
• LIU Xiong-Min, QIN Rong-Xiu, HUANG Pin-Xian, LIU Jia-Ling, MA Li, LI Wei-Guang
• We designed an oxidation reactor for abietic acid and rosin oxidation under ultraviolet light irradiation. The oxidation...
• 2010, 26 (08): 2115-2120. DOI: 10.3866/PKU.WHXB20100832

• 5498Abstract/Metrics
• 1815 PDF(271KB)

• Numerical Analysis of the Effect of Carbon Monoxide Addition on Soot Formation in an Acetylene/Air Premixed Flame
• JIANG Yong, QIU Rong
• The effect of carbon monoxide addition on soot formation in an acetylene/air premixed flame was investigated by detailed...
• 2010, 26 (08): 2121-2129. DOI: 10.3866/PKU.WHXB20100823

• 3449Abstract/Metrics
• 1481 PDF(317KB)

ELECTROCHEMISTRY

• High Rate Capability of 5 V LiNi_0.5Mn_1.5O₄ Cathode Materials Synthesized via a Gel-Combustion Method
• DAI Ke-Hua, MAO Jing, ZHAI Yu-Chun
• Sub-micron LiNi0.5Mn1.5O4 with excellent high rate performance was synthesized by a polyvinylpyrrolidone-assisted gel-co...
• 2010, 26 (08): 2130-2134. DOI: 10.3866/PKU.WHXB20100808

• 3665Abstract/Metrics
• 1930 PDF(722KB)

• Preparation and Electrochemical Properties of Ternary Catalyst PtRuCo/C for Direct Methanol Fuel Cell
• XU Qun-Jie, ZHOU Xiao-Jin, LI Qiao-Xia, LI Jin-Guang
• Using sodium citrate as a stabilizer, sodium borohydride as a reductant, 20%(w) Pt60Ru30Co10/C catalyst was prepared by ...
• 2010, 26 (08): 2135-2138. DOI: 10.3866/PKU.WHXB20100802

• 3367Abstract/Metrics
• 1770 PDF(269KB)

• Room Temperature Synthesis of Thorn-Like Pd Nanoparticles and Their Enhanced Electrocatalytic Property for Ethanol Oxidation
• XU Jia-Xin, JIANG Yan-Xia, LIAO Hong-Gang, CHEN Sheng-Pei, SUN Shi-Gang
• Thorn-like Pd nanoparticles (Pdnthorn000) were synthesized at room temperature by a reduction of PdCl2 with L-ascorbic a...
• 2010, 26 (08): 2139-2143. DOI: 10.3866/PKU.WHXB20100804

• 3177Abstract/Metrics
• 1900 PDF(874KB)

• Effect of Partial Substitution of Cu by Fe on the Phase Structure and Electrochemical Property of Low-Co AB₅ Type Hydrogen Storage Alloys
• YANG Su-Xia, LI Yuan, LIU Zhi-Ping, YANG Shu-Qin, HAN Shu-Min
• To obtain low-Co AB5 type hydrogen storage alloys with high discharge capacity and good cycling stability, the effects o...
• 2010, 26 (08): 2144-2150. DOI: 10.3866/PKU.WHXB20100647

• 3197Abstract/Metrics
• 2058 PDF(1412KB)

• Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes
• TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian
• Activated carbon/manganese oxide (MnOx) composites were prepared by the thermal decomposition of Mn(NO3)2 that was impre...
• 2010, 26 (08): 2151-2157. DOI: 10.3866/PKU.WHXB20100636

• 3319Abstract/Metrics
• 2195 PDF(3155KB)

• Optical and Electrochemical Properties of Ethynyl-Bridged Ferrocenes with Electron Donor Groups
• CAO Qian-Yong, LU Xin, KUANG Ren-Yun, LI Zhi-Hua, YANG Zhen-Yu
• We present the synthesis, optical and electrochemical properties of three ethynyl-bridged ferrocenes with electron donor...
• 2010, 26 (08): 2158-2162. DOI: 10.3866/PKU.WHXB20100822

• 4457Abstract/Metrics
• 1949 PDF(283KB)

• Corrosion Inhibition of Q235 Steel by a Novel Imidazoline Compound under H₂S and CO₂ Coexistence
• HU Song-Qing, HU Jian-Chun, FAN Cheng-Cheng, MI Si-Qi, ZHANG Jun, GUO Wen-Yue
• We synthesized a new imidazoline compound, 1-(2-amido-thioureaethyl)- 2-pentadecyl-imidazoline (IM-S). The corrosion inh...
• 2010, 26 (08): 2163-2170. DOI: 10.3866/PKU.WHXB20100809

• 3341Abstract/Metrics
• 1539 PDF(375KB)

• Inhibitory Effect of Kopsia Singapurensis Extract on the Corrosion Behavior ofMild Steel in AcidMedia
• RAJA Pandian Bothi, RAHIM Afidah Abdul, OSMAN Hasnah, AWANG Khalijah
• The influence of the alkaloid extract of Kopsia singapurensis on the corrosion behavior of mild steel (MS) in 1 mol&midd...
• 2010, 26 (08): 2171-2176. DOI: 10.3866/PKU.WHXB20100646

• 3120Abstract/Metrics
• 2237 PDF(2131KB)

COLLOID AND INTERFACE CHEMISTRY

• Novel Synthesis of Mesoporous Nanocrystalline Zirconia
• CHE Hong-Wei, HAN Shu-Hua, HOU Wan-Guo, LIU Ai-Feng
• A novel strategy involving the combination of soft-templating and the solid-liquid method (CSSL) is presented for the sy...
• 2010, 26 (08): 2177-2181. DOI: 10.3866/PKU.WHXB20100803

• 4286Abstract/Metrics
• 1839 PDF(617KB)

• Adsorption Mechanism of Nonylphenol Polyethoxylate onto Hypercrosslinked Resins
• YANG Wei-Ben, REN Li
• The aim of this study was to determine the behaviors and mechanism of three hypercrosslinked polymers during the adsorpt...
• 2010, 26 (08): 2182-2188. DOI: 10.3866/PKU.WHXB20100805

• 3114Abstract/Metrics
• 1526 PDF(733KB)

• Synthesis of P(DEAM-co-NAS) and the Environmental Effects of Its Temperature Sensitivity
• ZHANG Sa, LIU Shou-Xin, HAN Xiao-Yu, DANG Li, QI Xiao-Jun, YANG Xi
• Poly(N,N-diethylacrylamide-co-N-acryloxysuccinimide) (P(DEAM-co-NAS)) was synthesized by free radical solution polymeriz...
• 2010, 26 (08): 2189-2194. DOI: 10.3866/PKU.WHXB20100819

• 3626Abstract/Metrics
• 1907 PDF(786KB)

• Coexistence of Oligonucleotide/Single-Chained Cationic Surfactant Vesicles with Precipitates
• GUO Xia, LI Hua, GUO Rong
• It is well known that DNA (including oligonucleotide) and cationic surfactant can form insoluble complex. In this study,...
• 2010, 26 (08): 2195-2199. DOI: 10.3866/PKU.WHXB20100826

• 3241Abstract/Metrics
• 1441 PDF(498KB)

• Hydrophobic Synergism between the Alkyl Tails of Gemini Surfactants during Adsorption and Aggregation
• YOU Yi, DENG Yong-Shu, LI Er-Jun, PEI Xiao-Mei, ZHAO Jian-Xi
• The critical micelle concentration (cmc) and the concentration reducing 20 mN·m-1 of water surface tension (pC20)...
• 2010, 26 (08): 2200-2204. DOI: 10.3866/PKU.WHXB20100643

• 3532Abstract/Metrics
• 1505 PDF(182KB)

• Conductivity of AOT/Triton X-100 Mixed Reverse Micelles
• HU Jia-Qi, KUANG Ya-Fei, ZHOU Hai-Hui, SUN Lu, HAN Xue, ZHANG Ning-Shuang, CHEN Jin-Hua
• Surfactants p-octyl polyethylene glycol phenyl ether (Triton X-100) and bis(2-ethylhexyl)sulfosuccinate sodium salt (AOT...
• 2010, 26 (08): 2205-2210. DOI: 10.3866/PKU.WHXB20100632

• 4886Abstract/Metrics
• 1579 PDF(269KB)

• Variation of Surface Potential of Alkanethiol Self-Assembled Monolayers with Different Chain Lengths on a Gold Substrate
• GAO Yuan, XU Guo-Hua, AN Yue
• A theoretical study on the surface potential of alkanethiol self-assembled monolayers (SAMs) with different alkyl chain ...
• 2010, 26 (08): 2211-2216. DOI: 10.3866/PKU.WHXB20100817

• 3753Abstract/Metrics
• 2202 PDF(298KB)

CATALYSIS AND SURFACE STRUCTURE

• Small-Angle X-Ray Scattering Studies of Carboxyl Functionalized
• WU Bao-Hu, ZHANG Shu-Cui, TANG Tao, XU Yao, LIU Yi, WU Zhong-Hua
• Carboxyl functionalized SBA-15 type mesoporous molecular sieves synthesized via co-condensation process were characteriz...
• 2010, 26 (08): 2217-2223. DOI: 10.3866/PKU.WHXB20100824

• 3685Abstract/Metrics
• 2066 PDF(1352KB)

• One-Step Synthesis of Mesoporous Beta Zeolite Using Phosphate
• LIU Shu-Ping, YUE Ming-Bo, WANG Yi-Meng
• The addition of sodium phosphate monobasic (NaH2PO4) to a synthetic mixture allows a one-step synthesis of mesoporous Be...
• 2010, 26 (08): 2224-2228. DOI: 10.3866/PKU.WHXB20100806

• 3772Abstract/Metrics
• 1802 PDF(282KB)

• Effect of Al Content on the n-Pentane Isomerization of the Solid Superacid Pt-SO^2-₄ /ZrO₂-Al₂O₃
• SONG Hua, DONG Peng-Fei, ZHANG Xu
• Highly active and stable Pt-SO2-4 /ZrO2-Al2O3 solid superacid catalysts were prepared by simultaneously introducing appr...
• 2010, 26 (08): 2229-2234. DOI: 10.3866/PKU.WHXB20100640

• 4464Abstract/Metrics
• 1736 PDF(289KB)

• Influence of Calcination Temperature on the Performance of Cu-Al-Ba Catalyst for Hydrogenation of Esters to Alcohols
• YUAN Peng, LIU Zhong-Yi, SUN Hai-Jie, LIU Shou-Chang
• Novel chromium-free Cu-Al-Ba catalysts were prepared by co-precipitation and were calcined at different temperatures. Th...
• 2010, 26 (08): 2235-2241. DOI: 10.3866/PKU.WHXB20100642

• 4009Abstract/Metrics
• 1593 PDF(671KB)

• Effect of Magnesium Oxide Modification on the Catalytic Performance of Nanoscale HZSM-5 Zeolite for the Conversion of Methanol to Propylene
• MAO Dong-Sen, GUO Qiang-Sheng, MENG Tao
• A series of nanoscale HZSM-5 zeolites modified with different amounts (0-8%, w) of magnesium were prepared by an impregn...
• 2010, 26 (08): 2242-2248. DOI: 10.3866/PKU.WHXB20100814

• 7161Abstract/Metrics
• 1842 PDF(501KB)

• Complete Oxidation of Ethanol and Thermal Stability of Ceria-BasedMaterials Modified by Doping Cu
• WANG Jian-Qiang, SHEN Mei-Qing, WANG Jun, WANG Wu-Lin, JIA Li-Wei
• The complete oxidation of ethanol (COE) was studied over Cu0.1Ce0.9Ox and Cu0.1Ce0.6Zr0.3Ox catalysts prepared by the so...
• 2010, 26 (08): 2249-2254. DOI: 10.3866/PKU.WHXB20100641

• 2968Abstract/Metrics
• 1584 PDF(385KB)

• Electrocatalytic Oxidation of Methanol with Poly Functionalized Multiwalled Carbon Nanotubes Supported Pt Catalysts
• ZHAO Yan-Chun, LAN Huang-Xian, DENG Bin-Bin, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang
• A novel process to prepare well-dispersed Pt nanoparticles on poly(N-acetylaniline) functionalized multiwalled carbon na...
• 2010, 26 (08): 2255-2260. DOI: 10.3866/PKU.WHXB20100829

• 3533Abstract/Metrics
• 1909 PDF(369KB)

• Solvothermal Preparation of Ag/TiO₂ Nanoparticles and Their Photocatalytic Activity
• XU Ping-Chang, LIU Yang, WEI Jian-Hong, XIONG Rui, PAN Chun-Xu, SHI Jing
• Visible-light photoactive Ag/TiO2 catalysts were successfully prepared by a solvothermal method. The samples were charac...
• 2010, 26 (08): 2261-2266. DOI: 10.3866/PKU.WHXB20100815

• 5141Abstract/Metrics
• 2621 PDF(387KB)

• Density Functional Theory Study on Hydrogen Adsorption on Be(0001) Surface
• NING Hua, TAO Xiang-Ming, WANG Mang-Mang, CAI Jian-Qiu, TAN Ming-Qiu
• We report on density functional theory (DFT) total-energy calculations within the generalized gradient approximation for...
• 2010, 26 (08): 2267-2273. DOI: 10.3866/PKU.WHXB20100828

• 4108Abstract/Metrics
• 1640 PDF(334KB)

PHOTOCHEMISTRY AND SPECTROSCOPY

• Preparation and Spectroscopic Properties of Covalent Albumin Conjugates of Zinc Phthalocyanines Tetrasubstituted with Carboxyl Moieties
• XIAO Rong-Ping, KE Mei-Rong, HUANG Jian-Dong, ZHANG Han-Hui
• A series of covalently bound albumin (bovine serum albumin (BSA) and human serum albumin (HSA)) conjugates of phthalocya...
• 2010, 26 (08): 2274-2280. DOI: 10.3866/PKU.WHXB20100807

• 3580Abstract/Metrics
• 1885 PDF(410KB)

• Fluorescence Behavior of Biphenyl Containing Side-Chain Liquid Crystalline Polyacetylene with Various Lengths of Spacers
• YU Zhen-Qiang, ZHANG Xin, LI Zi-Chen, CHEN Er-Qiang, LAM Jacky W. Y., TANG Ben-Zhong
• Steady state fluorescence and fluorescence decay of a series of monosubstituted biphenyl containing side- chain liquid c...
• 2010, 26 (08): 2281-2285. DOI: 10.3866/PKU.WHXB20100848

• 3433Abstract/Metrics
• 1581 PDF(612KB)

QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY

• Inverse Hydrogen Bond between Silicane and AB-Type
• LIU Hong, CHEN Yan-Qin, YANG Yu-Qiong
• Intermolecular complexes of silicane with AB-type interhalogen compounds (ClF, BrF, IF, ICl, IBr, BrCl) were examined us...
• 2010, 26 (08): 2286-2291. DOI: 10.3866/PKU.WHXB20100811

• 3629Abstract/Metrics
• 1777 PDF(463KB)

• Charge Transport Properties of Anthracene Derivatives
• DUAN Gui-Hua, GAO Hong-Ze, WANG Li-Juan, ZHANG Hou-Yu, MA Yu-Guang
• The molecular geometries, electronic structures, reorganization energies, and charge transfer integrals of three anthrac...
• 2010, 26 (08): 2292-2297. DOI: 10.3866/PKU.WHXB20100813

• 4388Abstract/Metrics
• 1999 PDF(331KB)

• Electronic Structures and Optical Properties of BeO under High Pressure
• LIU Xiao-Liang, REN Yi, LIANG Liang-Wen, XU Hui
• Density functional theory within the generalized gradient approximation (GGA) was used to investigate the electronic str...
• 2010, 26 (08): 2298-2305. DOI: 10.3866/PKU.WHXB20100833

• 4180Abstract/Metrics
• 2139 PDF(838KB)

PHYSICAL CHEMISTRY OF MATERIALS

• Synthesis, Morphology and Optical Properties of Mn Doped SnO2 One-Dimensional Nanostructures
• CHI Jun-Hong, WANG Juan
• Mn doped SnO2 one-dimensional nanostructures (nanowires and nanobelts) were fabricated using catalyst assisted chemical ...
• 2010, 26 (08): 2306-2310. DOI: 10.3866/PKU.WHXB20100820

• 3437Abstract/Metrics
• 2113 PDF(882KB)

• Chemical Structure and Growth Mechanism of a-Si_xC_1-x:H Films Prepared by Plasma Enhanced Magnetron Sputtering
• SUN Wen-Li, XU Jun, LU Wen-Qi
• Hydrogenated amorphous silicon carbide (a-Si1-xCx:H) films were prepared by microwave electron cyclotron resonance (MW-E...
• 2010, 26 (08): 2311-2316. DOI: 10.3866/PKU.WHXB20100810

• 3184Abstract/Metrics
• 1849 PDF(770KB)

• Tribological Properties of Cu-Doped TiO₂ Films
• CHAO Wen-Liu, WAN Yong, WANG Yun-Xia, LIU Chang-Song
• Undoped TiO2 and Cu-doped TiO2 (Cu-TiO2) nano-structured thin films were prepared by a sol-gel process on glass substrat...
• 2010, 26 (08): 2317-2322. DOI: 10.3866/PKU.WHXB20100816

• 3182Abstract/Metrics
• 1739 PDF(450KB)