Loading...
Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
Home
About Journal
About Journal
Editorial Board
Database Included
Impact Factor
Reader Center
Online First
Special Issue
Most Cited
Most Read
Most Downloaded
Volumn Content
Subject Content
Archive
Elsevier
Email Alert
Author Center
Online Submission
Submission Information
Review Online
Contact Us
中文
Current Issue
2010 Vol. 26,No. 09
Published: 02 September 2010
Current column
Table of Contents
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
CHEMICAL KINETICS AND MOLECULE DYNAMICS
ELECTROCHEMISTRY
STRUCTURE CHEMISTRY
CATALYSIS AND SURFACE STRUCTURE
PHOTOCHEMISTRY AND SPECTROSCOPY
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
BIOPHYSICAL CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.26 No. 09
2010, 26 (09): 0.
1718
Abstract/Metrics
1817
PDF(6801KB)
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
Structure of Supersaturated Aqueous SodiumPentaborate Solution
ZHOU Yong-Quan, FANG Chun-Hui, FANG Yan
We determined the time-averaged and space-averaged structures of supersaturated aqueous sodiumpentaborate solutions by r...
2010, 26 (09): 2323-2330.
DOI: 10.3866/PKU.WHXB20100903
7279
Abstract/Metrics
2349
PDF(1215KB)
CHEMICAL KINETICS AND MOLECULE DYNAMICS
Ab initioMolecular Dynamics Investigation on the Production Channels for the Reaction of O
-
with CH
3
F
WU Li-Xia, YU Feng, LIU Jing, DAI Jing-Hua, ZHOU Xiao-Guo, LIU Shi-Lin
H-atom abstraction and H2O production channels for the reaction of O- with CH3F were reinvestigated using the ab initio ...
2010, 26 (09): 2331-2336.
DOI: 10.3866/PKU.WHXB20100907
5930
Abstract/Metrics
1783
PDF(545KB)
ELECTROCHEMISTRY
Electrocatalytic Oxidation of Formic Acid on Pt-Se HollowNanosphere Modified Glassy Carbon Electrodes
YAN Liang-Liang, JIANG Qing-Ning, LIU De-Yu, ZHONG Yan, WEN Fei-Peng, DENG Xiao-Cong, ZHONG Qi-Ling, REN Bin, TIAN Zhong-Qun
Platinum-selenium and platinum hollow nanospheres (denoted as (Pt-Se)HN and PtHN, respectively) with different coverages...
2010, 26 (09): 2337-2342.
DOI: 10.3866/PKU.WHXB20100835
8201
Abstract/Metrics
2253
PDF(1274KB)
Photoelectrochemical Properties of Cubic Tungsten Trioxide Films Obtained by the Polymeric Precursor Method
LI Wen-Zhang, LI Jie, WANG Xuan, ZHANG Shu-Juan, CHEN Qi-Yuan
WO3 films were prepared using ammonium metatungstate as the precursor and polyethylene glycol 1000 as the structure-dire...
2010, 26 (09): 2343-2348.
DOI: 10.3866/PKU.WHXB20100904
5724
Abstract/Metrics
2411
PDF(1490KB)
Photogenerated Cathodic Protection Properties of a TiO
2
Nanowire FilmPrepared by a Hydrothermal Method
ZHU Yan-Feng, DU Rong-Gui, LI Jing, QI Hai-Qing, LIN Chang-Jian
A TiO2 film was synthesized on the surface of a Ti substrate by a hydrothermal method, followed by acid treatment and ca...
2010, 26 (09): 2349-2353.
DOI: 10.3866/PKU.WHXB20100913
5312
Abstract/Metrics
2028
PDF(1028KB)
Influence of Organic Inhibitors on the Corrosion Behavior of Steel Rebar insideMortar Specimens Immersed in Saturated NaCl Solution
ZHENG Lei-Gang, YANG Huai-Yu
The long-term effects of four kinds of amine-alcohol based inhibitors on the corrosion behavior of steel rebar inside mo...
2010, 26 (09): 2354-2360.
DOI: 10.3866/PKU.WHXB20100905
5822
Abstract/Metrics
1996
PDF(1613KB)
Electrochemical Corrosion Behaviors of Rusted Carbon Steel
ZOU Yan, WANG Jia, ZHENG Ying-Ying
Electrochemical methods including polarization curves, linear polarization resistance (LPR), and electrochemical impedan...
2010, 26 (09): 2361-2368.
DOI: 10.3866/PKU.WHXB20100825
5135
Abstract/Metrics
2436
PDF(2251KB)
Effect of Current Densities on the Electrochemical Behavior of a Flat Plate Pb-Ag Anode for Zinc Electrowinning
JIANG Liang-Xing, ZHONG Shui-Ping, LAI Yan-Qing, LüXiao-Jun, HONG Bo, PENG Hong-Jian, ZHOU Xiang-Yang, LI Jie, LIU Ye-Xiang
We studied the anodic potential, corrosion rate, and anodic passive layer of a flat plate Pb-Ag (0.8% (mass fraction, w)...
2010, 26 (09): 2369-2374.
DOI: 10.3866/PKU.WHXB20100935
5833
Abstract/Metrics
2480
PDF(2278KB)
Electrodeposition of Nanocrystalline Nickel Alloys and Their Hydrogen Evolution in Seawater
SONG Li-Jun, MENG Hui-Min
Ni, Ni-Fe, and Ni-Fe-C alloy electrodes were prepared by electrodeposition. Polarization curves showed that the Ni-Fe-C ...
2010, 26 (09): 2375-2380.
DOI: 10.3866/PKU.WHXB20100847
5515
Abstract/Metrics
2152
PDF(2417KB)
Synthesis of Ferrocenoyl-Labeled Tripeptide Fc-Gly-Pro-Arg(NO
2
)-OMe and Its Interaction with Cu(II)
LIU Xiao-Fang, LI Xue-Qiang, YE Wu-Long, ZHOU Bin-Bin, LIU You-Nian
N-ferrocenoyl-labeled tripeptide Fc-Gly-Pro-Arg(NO2)-OMe(Fc-GPR) was synthesized from ferrocene-carboxylic acid, glycine...
2010, 26 (09): 2381-2386.
DOI: 10.3866/PKU.WHXB20100827
5507
Abstract/Metrics
1658
PDF(399KB)
Nanosized Flame Retarded HydroxideMagnesium/Poly(ethylene-oxide) Composite Polymer Electrolyte
LI Ya-Juan, ZHAN Hui, LIU Su-Qin, HUANG Ke-Long, ZHOU Yun-Hong
We prepared nanosized hydroxide magnesium (Mg(OH)2) as a plasticizer and a flame-retarding additive for a poly(ethylene-...
2010, 26 (09): 2387-2391.
DOI: 10.3866/PKU.WHXB20100818
5833
Abstract/Metrics
1928
PDF(1005KB)
In situ Ellipsometric Study on the Initial Stages of Porous Anodization of Aluminum
LEI Jing-Lei, ZHANG Li-Na, LI Ling-Jie, ZHENG Sha, WANG Chao, XIE Zhao-Ming, ZHANG Sheng-Tao
The initial stages of the anodization of aluminum are influential during the preparation of anodic aluminum oxide nanote...
2010, 26 (09): 2392-2396.
DOI: 10.3866/PKU.WHXB20100846
5159
Abstract/Metrics
1698
PDF(258KB)
Influence of Ball-Milling on Hydrogen Storage and Electrochemical Properties of (Ti Cr)
0.497
V
0.42
Fe
0.083
/30%(w) (LaRMg)(NiCoAl)
3.5
Alloy Electrodes
LUO Yong-Chun, ZHANG Tie-Jun, WANG Duo, KANG Long
Changes in phase structure, hydrogen storage and electrochemical properties of the (Ti Cr)0.497V0.42Fe0.083+ 30% (w) (La...
2010, 26 (09): 2397-2404.
DOI: 10.3866/PKU.WHXB20100845
5476
Abstract/Metrics
2230
PDF(1752KB)
Comparative Study of Electrochemical Performances of Three Carbon-Based ElectrodeMaterials
ZHOU Yan-Li, ZHI Jin-Fang, ZHANG Xiang-Fei, XU Mao-Tian
The electrochemical properties of three carbon-based electrodes including boron-doped nanocrystalline diamond (BDND), bo...
2010, 26 (09): 2405-2409.
DOI: 10.3866/PKU.WHXB20100841
6673
Abstract/Metrics
2015
PDF(509KB)
STRUCTURE CHEMISTRY
Synthesis, Crystal Structure, Thermal Behavior and Sensitivity of [Mn(AZT)
2
(H
2
O)
4
] (HTNR)
2
·4H
2
O
FENG Jin-Ling, ZHANG Jian-Guo, ZHANG Tong-Lai, CUI Yan
A novel energetic coordination complex of [Mn(AZT)2(H2O)4] (HTNR)2·4H2O (AZT=3-azido-1,2,4- triazole, HTNR=2,4,6-...
2010, 26 (09): 2410-2416.
DOI: 10.3866/PKU.WHXB20100919
7587
Abstract/Metrics
2203
PDF(861KB)
CATALYSIS AND SURFACE STRUCTURE
Raman Spectroscopic Study on the Solid-State Reaction of V
2
O
5
/CeO
2
Catalyst
WU Yan-Ni, GUO Ming, CHEN Fang, LUO Meng-Fei
We prepared V2O5 /CeO2 catalysts with different V2O5 loadings (5% and 15%) by incipient wetness impregnation. Raman spec...
2010, 26 (09): 2417-2421.
DOI: 10.3866/PKU.WHXB20100915
4600
Abstract/Metrics
1756
PDF(1336KB)
Catalytic Performance of Porous SiO
2
·
x
H
2
O Supported RuB Nanoparticles for the Hydrogenation of Quinoline
ZHANG Lei, HU Bo, CHEN Hua, LI Xian-Jun, LI Rui-Xiang
A porous and hydroxyl group-rich catalyst RuB/SiO2·xH2O was prepared by hydrolyzing ethyl silicate, protecting Si...
2010, 26 (09): 2422-2428.
DOI: 10.3866/PKU.WHXB20100901
4529
Abstract/Metrics
1799
PDF(1719KB)
Effect of Sepiolite on the Combustion and Thermal Decomposition of Intumescent Flame Retardant Polypropylene
WU Na, DING Chao, YANG Rong-Jie, HAO Jian-Wei
We added modified sepiolite to a polypropylene (PP)/ammoniumpolyphosphate (APP)/di-pentaerythritol (DPER) composite to s...
2010, 26 (09): 2429-2436.
DOI: 10.3866/PKU.WHXB20100908
5519
Abstract/Metrics
2259
PDF(1560KB)
Optimizational Preparation and Mesoporous Material Characteristics of a Novel Biomimetic Photocatalyst and Its Application to the Photocatalytic Degradation of Phenol
GAO Guan-Dao, LI Jing, ZHANG Ai-Yong, AN Xiao-Hong, ZHOU Lei
Hexagonal mesoporous silica (HMS) was synthesized using dodecylamine (DDA) or octadecylamine (ODA) as templates which we...
2010, 26 (09): 2437-2442.
DOI: 10.3866/PKU.WHXB20100910
5775
Abstract/Metrics
2205
PDF(1022KB)
Preparation, Characterization and Catalytic Activity for ortho- Dichlorobenzene Ozonation of Fe-, Mn-Doped Xerogels
HUANG Yan, ZHANG Xing-Wang, LEI Le-Cheng
Metal-doped xerogels were synthesized by the sol-gel method and their catalytic performance was evaluated for the cataly...
2010, 26 (09): 2443-2448.
DOI: 10.3866/PKU.WHXB20100840
5508
Abstract/Metrics
1551
PDF(1649KB)
Influence of Tungsten Oxide on Selective Catalytic Reduction of NO
x
with NH
3
over MnO
x
-CeO
2
/ZrO
2
-TiO
2
Monolith Catalyst
XU Hai-Di, QIU Chun-Tian, ZHANG Qiu-Lin, LIN Tao,GONG Mao-Chu, CHEN Yao-Qiang
MnOx-CeO2/WO3/ZrO2-TiO2monolithic catalyst was prepared by ZrO2-TiO2 as support, MnOx-CeO2 as active components and WO3 ...
2010, 26 (09): 2449-2454.
DOI: 10.3866/PKU.WHXB20100838
5634
Abstract/Metrics
1891
PDF(261KB)
Preparation of Au@TiO
2
Catalyst Using Escherichia Coil as the Template and Its Oxidation Reaction Activity toward CO
LIU Yu-Liang, YOU Cui-Rong, LI Yang, HE Tao, ZHANG Xiang-Qin, SUO Zhang-Huai
Many microorganisms can adsorb metal ions strongly and even reduce them to their metal states. We studied the adsorption...
2010, 26 (09): 2455-2460.
DOI: 10.3866/PKU.WHXB20100909
6054
Abstract/Metrics
1723
PDF(975KB)
Preparation, Hydrodesulfurization and Hydrodenitrogenation Performance of a Ni
2
P/TiO
2
-Al
2
O
3
Catalyst
SONG Hua,GUO Yun-Tao, LI Feng ,YU Hong-Kun
We prepared a TiO2-Al2O3 complex support by the sol-gel method. A nickel phosphide catalyst, Ni2P/ TiO2-Al2O3, was prepa...
2010, 26 (09): 2461-2467.
DOI: 10.3866/PKU.WHXB20100937
5122
Abstract/Metrics
2145
PDF(509KB)
PHOTOCHEMISTRY AND SPECTROSCOPY
Au Nanoparticles Based Colorimetric Detection of Conformational Changes in Cytochrome c
LI Na, ZHOU Jian-Zhang, LIN Ling-Ling, HAN Nan-Nan, LIN Zhong-Hua
The colors of Au nanoparticles (Au NPs) change along with conformational changes in cytochrome c (Cyt c). We exploited t...
2010, 26 (09): 2468-2472.
DOI: 10.3866/PKU.WHXB20100923
5713
Abstract/Metrics
2124
PDF(1410KB)
Effects of Salts on theMicrostructure ofMethanol
YU Xiao-Chun, LIN Ke, HU Nai-Yin, ZHOU Xiao-Guo, LIU Shi-Lin
We studied the effects of salts on the microstructure of liquid methanol using the Raman spectra. We compared the excess...
2010, 26 (09): 2473-2480.
DOI: 10.3866/PKU.WHXB20100922
5642
Abstract/Metrics
1738
PDF(2622KB)
Photoinduced Electron and Hydrogen Transfer Reactions of Thioxanthone with Amines, Phenols and Alcohols
SUN Qian, WANG Jin-Ting, ZHANG Li-Min, YANG Mao-Ping
The quenching reactions of triplet thioxanthone (TX) by a series of amines, phenols, and alcohols were investigated by l...
2010, 26 (09): 2481-2488.
DOI: 10.3866/PKU.WHXB20100925
5591
Abstract/Metrics
1952
PDF(371KB)
Role of Pyrite inMaintaining the Reductive Environment of the Near Field for a High-Level RadioactiveWaste Repository
CHEN Tao, TIAN Wen-Yu, LI Chun, LIU Xiao-Yu, WANG Lu-Hua, SUN Mao, ZHENG Zhong, ZHU Jian-Bo, LIU Chun-Li
The influence of pyrite irradiated by γradiation from 60Co on the reductive environment of groundwater was investi...
2010, 26 (09): 2489-2493.
DOI: 10.3866/PKU.WHXB20100917
4984
Abstract/Metrics
1554
PDF(938KB)
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
QSPRModel Analysis on the Solubility of Organic Compounds in Ionic Liquids
PAN Shan-Fei, HU Gui-Xiang, LV Yang, ZOU Jian-Wei, YU Qing-Sen
A quantitative structure-property relationship (QSPR) study on the solubility of 84 organic compounds in 4 different ion...
2010, 26 (09): 2494-2502.
DOI: 10.3866/PKU.WHXB20100902
6307
Abstract/Metrics
2059
PDF(819KB)
Adsorption of Linear C
2
-C
5
Olefins on HYand H-ZSM-5 Zeolites
GUO Yu-Hua, PU Min, CHEN Biao-Hua
The adsorption properties of linear C2-C5 olefins on HY and H-ZSM-5 zeolites were studied by the ONIOM(B3LYP/6-311++G(d,...
2010, 26 (09): 2503-2509.
DOI: 10.3866/PKU.WHXB20100839
5646
Abstract/Metrics
2236
PDF(1157KB)
Structural, Electronic andMagnetic Properties of the Ge
n
Eu (n=1-13) Clusters
JING Qun, GE Gui-Xian, CAO Hai-Bin, HUANG Xu-Chu, LIU Xiao-Yong, YAN Hong-Xia
The growth pattern and magnetic properties of the GenEu (n=1-13) clusters have been investigated using the density funct...
2010, 26 (09): 2510-2514.
DOI: 10.3866/PKU.WHXB20100926
4867
Abstract/Metrics
2413
PDF(579KB)
Electronic Structures and Spectral Properties of 3-Pyrrolidinobenzanthrone
CHEN Ben, HE Rong, XING LI Ming
Benzanthrone derivatives show great potential for use as new luminescent, nonlinear optical, and liquid crystalline mate...
2010, 26 (09): 2515-2522.
DOI: 10.3866/PKU.WHXB20100843
5736
Abstract/Metrics
2031
PDF(728KB)
ElectronMomentumSpectroscopy for Saturated Alkanes C
n
H
2
n
+2
(
n
=4-6)
YANG Ze-Jin, GUO Yun-Dong, ZHU Zheng-He, YANG Xiang-Dong
Orbital electron momentum spectroscopies for saturated alkanes CnH2n+2(n=4-6) were systematically studied using the B3LY...
2010, 26 (09): 2523-2528.
DOI: 10.3866/PKU.WHXB20100924
4793
Abstract/Metrics
1720
PDF(2293KB)
Carrier Injection Property of Fluorene-Aromatic Nitrogen Heterocycle Copolymers
SUN Guan-Nan, XU Hai, LIU Xiao-Dong, LIU Dan-Dan,YANG Bing, TIAN Lei-Lei, MA Yu-Guang
To improve the carrier-injection of polyfluorene, oligomers of polyfluorene, fluorene-bipyridine, and fluorene-phenanthr...
2010, 26 (09): 2529-2534.
DOI: 10.3866/PKU.WHXB20100831
5524
Abstract/Metrics
1664
PDF(1026KB)
Density Functional Theory Study on N—O Bond Dissociation Enthalpies
ZHENG Wen-Rui, XU Jing-Li, XIONG Rui
A number of density functional theory (DFT) methods were compared for the calculation of N—O bond dissociation ent...
2010, 26 (09): 2535-2542.
DOI: 10.3866/PKU.WHXB20100931
6617
Abstract/Metrics
2057
PDF(939KB)
Structures of the Triplet Silylenoid HB=SiLiF and Its Insertion Reactions with R—H(R=F, OH, NH
2
)
LI Wen-Zuo,ZHU Hong-Jie, CHENG Jian-Bo, LI Qing-Zhong, GONG Bao-An
Density functional theory (DFT) and quadratic configuration interaction with single and double excitations (QCISD) metho...
2010, 26 (09): 2543-2548.
DOI: 10.3866/PKU.WHXB20100830
4685
Abstract/Metrics
1396
PDF(233KB)
BIOPHYSICAL CHEMISTRY
Molecular Simulations of the Inhibition of Active Components in Traditional ChineseMedicine on the Thromboxane A2 Receptor
LIU Hai-Bo, CUI Wei, XU Jun, PENG Yong, ZHOU Jia-Ju, XIAO Pei-Gen
Some natural products from traditional Chinese medicine (TCM) such as flavones and resveratrol have been reported to hav...
2010, 26 (09): 2549-2556.
DOI: 10.3866/PKU.WHXB20100844
6013
Abstract/Metrics
2584
PDF(3017KB)
PHYSICAL CHEMISTRY OF MATERIALS
Biomolecule-Assisted Hydrothermal Synthesis and Optical Properties of Cu
7
S
4
Nanotubes
GUO Pei-Zhi, HAN Guang-Ting, WANG Bao-Yan, ZHAO Xiu-Song
Cu7S4 nanotubes were synthesized using a biomolecule DL-methionine-assisted hydrothermal method. The morphology and phas...
2010, 26 (09): 2557-2562.
DOI: 10.3866/PKU.WHXB20100834
4654
Abstract/Metrics
1958
PDF(2084KB)
Field Emission Properties of Aligned ZnO Nanowire Arrays Prepared by Simple Solution-PhaseMethod
ZHANG Huan, LI Meng-Ke, ZHANG Jing, YU Li-Yuan, LIU Ling-Ling, YANG Zhi
One-dimensional (1D) aligned ZnO nanowire arrays with different morphologies were synthesized by a solution-phase method...
2010, 26 (09): 2563-2568.
DOI: 10.3866/PKU.WHXB20100921
5098
Abstract/Metrics
2252
PDF(2983KB)
Ultrasonic-Assisted Preparation of Bimodal Mesoporous HollowGlobal Tungsten Carbide and Its Electrocatalytic Performance
CHEN Zhao-Yang, ZHAO Feng-Ming, MA Chun-An, QIAO Yun
Hollowspherical ammoniummetatungstate (AMT), as a precursor, was prepared by an ultrasonic method. Tungsten carbide (WC)...
2010, 26 (09): 2569-2574.
DOI: 10.3866/PKU.WHXB20100906
4591
Abstract/Metrics
1859
PDF(2174KB)
Solution Based Synthesis of ZnO/CdS Composite Nanorod Array Film and Its Photoelectric Properties
FU Dong-Wei, CHENG Ke, PANG Shan, DU Zu-Liang
Well-aligned ZnO/CdS composite nanorod array film was grown on an indium tin oxide (ITO) substrate by two-step chemical ...
2010, 26 (09): 2575-2580.
DOI: 10.3866/PKU.WHXB20100930
5580
Abstract/Metrics
1856
PDF(1811KB)
Preparation and Release Behavior in vitro of Aspirin/Chitosan Nanospheres by Nucleation and Ionic Crosslinking in Emulsion
JIN Shu-Ping, FENG Lei, HE Wen-Yan, HAN Yu-Qi, WEI Yu-Juan
Chitosan (CS) nanosphere loaded aspirin (aspirin/CS) was prepared by nucleation and ionic crosslinking in an emulsion us...
2010, 26 (09): 2581-2588.
DOI: 10.3866/PKU.WHXB20100842
5858
Abstract/Metrics
2010
PDF(1279KB)