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Acta Phys. -Chim. Sin.
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中文
Current Issue
2010 Vol. 26,No. 10
Published: 27 September 2010
Current column
Table of Contents
Review
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
CHEMICAL KINETICS AND MOLECULE DYNAMICS
ELECTROCHEMISTRY
COLLOID AND INTERFACE CHEMISTRY
CATALYSIS AND SURFACE STRUCTURE
PHOTOCHEMISTRY AND SPECTROSCOPY
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
BIOPHYSICAL CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.26 No. 10
2010, 26 (10): 0.
1826
Abstract/Metrics
2016
PDF(4933KB)
Review
Conductivity for the Investigation of Ionic Surfactants in an AqueousSolution and Some Characteristic Parameters
ZHAO Jian-Xi
Conductivity is important in the investigation of the micellization behavior of ionic surfactants in an aqueous solution...
2010, 26 (10): 2589-2596.
DOI: 10.3866/PKU.WHXB20101019
6331
Abstract/Metrics
4431
PDF(571KB)
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
Cryogenic Magnetic Transition of D- and L-Alanine: Magnetic Field Dependence of Specific Heat and DC Magnetic Susceptibility
WANG Wen-Qing, SHEN Xin-Chun, GONG Yan
To understand the intrinsic asymmetries of D- and L-alanine crystal lattices, the magnetic field dependence of zero-fiel...
2010, 26 (10): 2597-2603.
DOI: 10.3866/PKU.WHXB20100912
4733
Abstract/Metrics
2152
PDF(657KB)
Non-Covalent Complexes of the Antidepressant Compound SIPI5358 with Cyclodextrins
HE Xiao-Dan, JIANG Dan, CHEN Chen, CHU Yan-Qiu, DING Chuan-Fan, WENG Zhi-Jie, LI Jian-Qi
Non-covalent complexes of α-, β-, and γ-cyclodextrin (CD) with the antidepressant compound SIPI5358 wer...
2010, 26 (10): 2604-2612.
DOI: 10.3866/PKU.WHXB20100911
5817
Abstract/Metrics
2085
PDF(999KB)
Morphology Control and Its Influence on the DecompositionBehavior and Sensitivity of KDNBF
FENG Jin-Ling, ZHANG Jian-Guo, ZHANG Tong-Lai, LI Zhi-Min, YANG Li, WANG Shao-Zong
The potassium salt of 7-hydroxy-4,6-dinitro-5,7-dihydrobenzofuroxanide (KDNBF) was prepared by a reaction of the sodium ...
2010, 26 (10): 2613-2618.
DOI: 10.3866/PKU.WHXB20100950
5466
Abstract/Metrics
2099
PDF(542KB)
CHEMICAL KINETICS AND MOLECULE DYNAMICS
Temperature Dependence of Reactions of C
2
(
a
3
Π
u
) Radical with Several Unsaturated Hydrocarbons
HU Ren-Zhi, ZHANG Qun, CHEN Yang
We studied the temperature dependence on the gas phase reactions of theC2(a3Πu) radical with several unsaturated hydr...
2010, 26 (10): 2619-2624.
DOI: 10.3866/PKU.WHXB20100938
4498
Abstract/Metrics
1525
PDF(223KB)
ELECTROCHEMISTRY
Electrodeposition of Copper in a Citrate Bath and Its Application to a Micro-Electro-Mechanical System
WU Wei-Gang, YANG Fang-Zu, LUO Ming-Hui, TIAN Zhong-Qun, ZHOU Shao-Min
We investigated the effect of plating parameters on the coating morphology and grain size of copper using a novel citrat...
2010, 26 (10): 2625-2632.
DOI: 10.3866/PKU.WHXB20101002
6171
Abstract/Metrics
Supporting Info
2318
PDF(6471KB)
Effect of Hydrazine on the Performance of LiNi
0.5
Mn
1.5
O
4
Cathode Materials
CHANG Zhao-Rong, DAI Dong-Mei, LI Bao, TANG Hong-Wei
Reduction pretreatment of the precursor of LiNi0.5Mn1.5O4 was carried out by adding hydrazine to a solution of NaOH duri...
2010, 26 (10): 2633-2637.
DOI: 10.3866/PKU.WHXB20101015
5080
Abstract/Metrics
2028
PDF(1069KB)
Characteristics of theMicrobiologically Influenced Corrosion of 304 Stainless Steel in Reclaimed Water Enviroment
LI Jin, XU Zhao-Yi, LI Jiu-Yi, JIAO Di
The growth characteristics of sulfate reducing bacteria (SRB) in real reclaimed water were studied. Characteristics of t...
2010, 26 (10): 2638-2646.
DOI: 10.3866/PKU.WHXB20100927
5803
Abstract/Metrics
2624
PDF(2742KB)
Electropolymerization of Nickel Complexes with Schiff Bases: Effect of Sweep Rate on Anodic Polymerization
LI Jian-Ling, GAO Fei, ZHANG Ya-Kun, HE Li-Zhi, HAN Gui-Mei, WANG Xin-Dong
Anodic electrochemical polymerization of N,N'-ethylenbis (salicylideneaminato) nickel(II) ([Ni(salen)]) in tetrabutylamm...
2010, 26 (10): 2647-2652.
DOI: 10.3866/PKU.WHXB20100940
5225
Abstract/Metrics
2161
PDF(1536KB)
Preparation and Properties of Poly(vinyl alcohol)/Poly(vinyl pyrrolidone) Composites for Solid Alkaline Electrolyte Membranes
FU Jing, LIN Rui, LüHong, WANG Xiao-Lei, MA Jian-Xin, QIAO Jin-Li
Solid alkaline electrolyte membranes were prepared using poly(vinyl alcohol)/poly(vinyl pyrrolidone) (PVA/PVP) by KOH do...
2010, 26 (10): 2653-2658.
DOI: 10.3866/PKU.WHXB20100918
6552
Abstract/Metrics
2817
PDF(1090KB)
Electroosmotic Drag of Water in Hydrated Potassium Perfluorosulfonated Polymer Membrane in External Electric Fields
ZHU Su-Hua, YAN Liu-Ming, JI Xiao-Bo, SHAO Chang-Le, LU Wen-Cong
The electroosmotic drag and the corresponding mechanism of water molecules in hydrated potassiumperfluorosulfonate elect...
2010, 26 (10): 2659-2665.
DOI: 10.3866/PKU.WHXB20100934
5829
Abstract/Metrics
2249
PDF(1544KB)
COLLOID AND INTERFACE CHEMISTRY
Effect of Catalysts on the Morphologies of Carbon Materials Synthesized by an Emulsion Templating Method
GAN Li-Hua, LIU Ming-Xian, CHEN Long-Wu, HU Jun, LIU Hong-Lai
An oil in water (O/W) emulsion with a resorcinol and formaldehyde (R+F) water solution as the external phase and liquid ...
2010, 26 (10): 2666-2671.
DOI: 10.3866/PKU.WHXB20100933
7283
Abstract/Metrics
2656
PDF(3340KB)
CATALYSIS AND SURFACE STRUCTURE
Study of Competitive Adsorption Behavior of Protein andMethylene Blue by Optical Waveguide Spectroscopy
DENG Lin, QI Zhi-Mei
We used time-resolved optical waveguide spectroscopy (OWGS) to in-situ measure visible absorption spectrum for methylene...
2010, 26 (10): 2672-2678.
DOI: 10.3866/PKU.WHXB20101003
5175
Abstract/Metrics
1990
PDF(1695KB)
NO
x
Molecule Adsorption in [Ag]-MAPO-5 (M=Si, Ti)Molecular Sieves
LIU Jie-Xiang, ZHANG Xiao-Guang, DUAN Zhong-Yu, LIU Xiao-Li
NOx adsorption in silver-exchanged aluminophosphate molecular sieves ([Ag]-SAPO-5 and [Ag]-TAPO-5) was investigated usin...
2010, 26 (10): 2679-2685.
DOI: 10.3866/PKU.WHXB20101013
6893
Abstract/Metrics
1809
PDF(632KB)
Electric Field Assisted Hopping of Tert-Butylamine on Cu(111) Surface
XU Yu-Qun, ZHANG Jun, YUAN Bing-Kai, DENG Ke, YANG Rong, QIU Xiao-Hui
The lateral hopping of tert-butylamine (t-BA) molecules ona Cu(111) surface was studied by scanning tunneling microscopy...
2010, 26 (10): 2686-2690.
DOI: 10.3866/PKU.WHXB20101012
5413
Abstract/Metrics
1625
PDF(1913KB)
Naphthalene Hydrogenation Activity over Pd, Pt and Pd-Pt Catalysts and Their Sulfur Tolerance
ZHANG Xiao-Fei, SHAO Zheng-Feng, MAO Guo-Qiang, HE De-Min,ZHANG Qiu-Min, LIANG Chang-Hai
Monometallic Pd and Pt as well as bimetallic Pd:Pt catalysts (Pd1Pt1, Pd1Pt4, and Pd4Pt1) with Pd/Pt molar ratios of 1:1...
2010, 26 (10): 2691-2698.
DOI: 10.3866/PKU.WHXB20101006
5882
Abstract/Metrics
2518
PDF(2968KB)
Activation Factors for the Carboxyl Group in the Hydrogenation of Carboxylic Esters
ZHENG Xiao-Juan, ZHOU Ya-Fen, FU Hai-Yan, CHEN Hua, LI Xian-Jun, LI Rui-Xiang
We prepared a 4%Ru-9%La/γ-Al2O3 catalyst by impregnation method and characterized it using X-ray diffraction(XRD) ...
2010, 26 (10): 2699-2704.
DOI: 10.3866/PKU.WHXB20100920
5941
Abstract/Metrics
2006
PDF(812KB)
Selective Oxidation of Ethylbenzene with Hydrogen Peroxide Catalyzed by 5,7-Dibromo-8-quinolinolato Manganese Complexes
LU Chun-Li, FU Zai-Hui, LIU Ya-Chun, LIU Feng-Lan, QIN Jin-Wei, HE Xiang-Ling, YIN Du-Lin
Two 5,7-dibromo-8-quinolinolato manganese complexes in tetradentate (Q2MnII) and hexadentate (Q3MnIII) modes were prepar...
2010, 26 (10): 2705-2710.
DOI: 10.3866/PKU.WHXB20100936
4887
Abstract/Metrics
1884
PDF(1126KB)
Asymmetric Hydrogenation of Acetophenone Catalyzed by RuCl
2
(TPP)
3
Supported on Hydroxyapatite Modified with Chiral Amine
ZHANG Ding-Lin, YANG Chao-Fen, SUN Ya-Ping, FU Hai-Yan, LI Rui-Xiang, CHEN Hua, LI Xian-Jun
Chiral amine (L-proline,D-proline, (1R,2R)-1,2 -diphenyl -1,2 -ethylene diamine sulfonate disodium ((1R, 2R)-DPENDS) and...
2010, 26 (10): 2711-2718.
DOI: 10.3866/PKU.WHXB20101017
5189
Abstract/Metrics
1814
PDF(1494KB)
1-Octene Hydroformylation Using Supported Amorphous Co-B Catalysts
LONG Jun-Ying, MA Lan, HE De-Hua
Co-B catalysts supported on ZrO2 (prepared by alcogel nitrogen thermo-treatment method), carbon nanotubes (CNTs), and me...
2010, 26 (10): 2719-2725.
DOI: 10.3866/PKU.WHXB20101022
4436
Abstract/Metrics
1667
PDF(1673KB)
Preparation, Characterization and Photocatalytic Property of
p
-CoO/
n
-CdS Compound Semiconductor Photocatalyst
DU Huan, WANG Sheng, LIU Lian-Lian, LIU Zhong-Xiang, LI Zhen, LU Nan, LIU Fu-Sheng
The photocatalysts CdS and p-n coupled semiconductor photocatalysts CoO/CdS(p-CoO/n-CdS) were prepared using cadmium ace...
2010, 26 (10): 2726-2732.
DOI: 10.3866/PKU.WHXB20101023
6005
Abstract/Metrics
2993
PDF(2630KB)
Photoinduced Charge Carrier Properties and Photocatalytic Activity of N-Doped TiO
2
Nanocatalysts
ZHANG Xiao-Ru, LIN Yan-Hong, ZHANG Jian-Fu, HE Dong-Qing, WANG De-Jun
Nitrogen-doped TiO2 (N-TiO2) photocatalysts with different amounts of N doping were successfully synthesized by the hydr...
2010, 26 (10): 2733-2738.
DOI: 10.3866/PKU.WHXB20101007
6677
Abstract/Metrics
3795
PDF(1321KB)
Decomposition of N
2
O on ACo
2
O
4
/HZSM-5 Catalysts
WANG Hong,WANG Jun-Li, LI Cui-Qing, SONG Yong-Ji, CHI Yao-Ling, WANG Tao
ACo2O4(A=Mg, Ni, Zn)andACo2O4/HZSM-5 (A=Mg, Fe, Ni, Cu, Zn, Zr, La) catalysts were synthesized by the citric acid -ligat...
2010, 26 (10): 2739-2744.
DOI: 10.3866/PKU.WHXB20100928
5065
Abstract/Metrics
1897
PDF(1372KB)
PHOTOCHEMISTRY AND SPECTROSCOPY
Enhancing the Photovoltaic Performance of Dye Sensitized Solar Cells with the TiO
2
Sol Infiltrated Nanocrystalline Electrode
QIAN Di-Feng, ZHANG Qing-Hong, WAN Jun, LI Yao-Gang, WANG Hong-Zhi
Transparent anatase titanium dioxide sol was prepared by the hydrothermal treatment of the home-made water soluble perox...
2010, 26 (10): 2745-2751.
DOI: 10.3866/PKU.WHXB20100948
6451
Abstract/Metrics
2395
PDF(2962KB)
Efficient Polymer White-Light-Emitting Devices Based on Two Complementary Phosphorescent Colors
LI Yan-Hu, FANG Yuan, ZOU Jian-Hua, WANG Biao, WU Hong-Bin, PENG Jun-Biao
White polymer light -emitting diodes (WPLEDs) were fabricated by spin coating method using two complementary colors. The...
2010, 26 (10): 2752-2756.
DOI: 10.3866/PKU.WHXB20100949
5520
Abstract/Metrics
1903
PDF(456KB)
Effects of NaCl on the Separation of Single-Walled Carbon Nanotubes by Agarose Gel Electrophoresis
WEN Xiao-Nan, ZHANG Jing, GU Wen-Xiu, JIN He-Hua, LI Hong-Bo, LI Qing-Wen
Plenty of attention has been paid to obtaining single-walled carbon nanotubes (SWCNT) with single conductive properties ...
2010, 26 (10): 2757-2762.
DOI: 10.3866/PKU.WHXB20100932
5661
Abstract/Metrics
2314
PDF(705KB)
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
Structure, Spectroscopy and Reactivity Properties of Helically Chiral Metal(II)-Bisdipyrrin Complexes
ZHONG Ai-Guo, HUANG Ling, LI Bai-Lin, JIANG Hua-Jiang, LIU Shu-Bin
The tetradentate coordination of bisdipyrrin ligands from cyclooctapyrroles with single and double metal cation metalati...
2010, 26 (10): 2763-2771.
DOI: 10.3866/PKU.WHXB20101005
6174
Abstract/Metrics
2356
PDF(2879KB)
Characteristics of One Electron Redox Behavior of Hydrophobic AminoAcids in Gas Phase
LI Wei-Wei, HOU Ruo-Bing, SUN Yan-Li
Characteristics of the one electron redox behavior of hydrophobic amino acids in gas phase were calculated with density ...
2010, 26 (10): 2772-2778.
DOI: 10.3866/PKU.WHXB20101004
5632
Abstract/Metrics
1946
PDF(1224KB)
Theoretical Investigation of the Key Reaction for the Chemiluminescence of Cypridina Luciferin Analogues
SUN Ying, REN Ai-Min, MIN Chun-Gang, ZOU Lu-Yi, REN Xue-Feng
A series of 6-aryl-2-methylimidazo[1,2-α]pyrazin-3-(7H)-ketone based derivatives MIPa-MIPd (cypridina luciferin an...
2010, 26 (10): 2779-2786.
DOI: 10.3866/PKU.WHXB20101018
5786
Abstract/Metrics
1972
PDF(2162KB)
Photodissociation Mechanism of Cyanogen Azide
CI Cheng-Gang, DUAN Xue-Mei, LIU Jing-Yao, SUN Chia-Chung
We investigated the photodissociation mechanism of cyanogen azide (N3CN) at the MRCI+Q//CAS(10,9)/6-311+G(2df) level of ...
2010, 26 (10): 2787-2792.
DOI: 10.3866/PKU.WHXB20100914
6170
Abstract/Metrics
1864
PDF(992KB)
Atomic Partial Charges for Periodic Systems from First -Principles Calculations
LI Ya-Na, Lü Yang, ZHOU Li-Chuan, CHEN Li, LI Shen-Min
We calculated the electrostatic potential (ESP) and electric field (EF) of periodic liquid water systems using the quant...
2010, 26 (10): 2793-2800.
DOI: 10.3866/PKU.WHXB20101009
5905
Abstract/Metrics
2102
PDF(1818KB)
Half-Metallic Properties of Mn-AlN and Cr-AlN Based on First-Principles
FAN Yu-Qin, HE A-Ling
The band structures, density of states (DOS), and magnetic properties of wurtzite Mn-AlN and Cr-AlN were studied using d...
2010, 26 (10): 2801-2806.
DOI: 10.3866/PKU.WHXB20101021
5458
Abstract/Metrics
1733
PDF(1005KB)
Effect of the Hydrodynamic Radius of Colloid Microspheres on theEstimation of the Coagulation Rate Constant
DU Xuan, XU Sheng-Hua, SUN Zhi-Wei, A Yan
Experimental values of the coagulation rate constant for colloidal particles are known to be much lower than the theoret...
2010, 26 (10): 2807-2812.
DOI: 10.3866/PKU.WHXB20100941
7311
Abstract/Metrics
2278
PDF(923KB)
BIOPHYSICAL CHEMISTRY
Effects ofMolecular Volume and Fractional Polar Surface Area of Osmolytes on the Thermal Stability of Chymotrypsin Inhibitor 2
LIU Fu-Feng, JI Luo, DONG Xiao-Yan
We correlated the protective ability of osmolytes on proteins with their fractional polar surface area (fpSA) and molecu...
2010, 26 (10): 2813-2820.
DOI: 10.3866/PKU.WHXB20101011
5866
Abstract/Metrics
1946
PDF(1360KB)
Effect of Surface Chemical Properties of a Silicon Chip on Antibody Immobilization
ZHOU Wen-Wen, LIAN Jie, HU Ke-Jia, GAO Yun-Hua, XU Bai
The key to constructing a protein microarray is the stable immobilization of proteins and the retention of their biologi...
2010, 26 (10): 2821-2827.
DOI: 10.3866/PKU.WHXB20101016
5893
Abstract/Metrics
2999
PDF(782KB)
Specificity of Cation-
π
Interactions in Typical Protein Folds
QIAO Hui, LI Xiao-Qin, XU Hai-Song, KONG Ling-Qiang, PENG Yu
In proteins, cation-π interactions are formed between positively charged amino acids (Lys, Arg) and aromatic amino ac...
2010, 26 (10): 2828-2832.
DOI: 10.3866/PKU.WHXB20100939
4797
Abstract/Metrics
1742
PDF(1487KB)
Homology Modeling and Structure Validation of the Adenosine A
1
Receptor
KE Yan-Rong, JIN Hong-Wei, LIU Zhen-Ming, ZHANG Liang-Ren
A three dimensional structure model of the adenosine A1 receptor was built using homology modeling. The antagonist DPCPX...
2010, 26 (10): 2833-2839.
DOI: 10.3866/PKU.WHXB20100916
5688
Abstract/Metrics
1958
PDF(1951KB)
PHYSICAL CHEMISTRY OF MATERIALS
Structure and Formation Mechanism of Sn-Doped ZnO Nanoneedles
WANG Jie, ZHUANG Hui-Zhao, XUE Cheng-Shan, LI Jun-Lin, XU Peng
We synthesized Sn -doped ZnO nanoneedles on Si(111) substrates in two steps: sputtering and thermal oxidation. First, a ...
2010, 26 (10): 2840-2844.
DOI: 10.3866/PKU.WHXB20101024
5621
Abstract/Metrics
1996
PDF(839KB)
Synthesis and Properties of Amphiphilic Photosensitive Telechelic Polymer C-PNIPAAm
SHU Qiao-Zhen, CHEN Xin, CHEN Kai-Hua, JIANG Jin-Qiang, NI Zhong-Bin, ZHANG Hong-Wu, LIU Xiao-Ya, CHEN Ming-Qing
Coumarin-containing disulfide (C-S-S-C) was designed and synthesized, which could be used as chain transfer agent with t...
2010, 26 (10): 2845-2850.
DOI: 10.3866/PKU.WHXB20100929
6442
Abstract/Metrics
2190
PDF(1193KB)
Effect of Natural Impurities on the Electronic Structures and Semiconducting Properties of Sphalerite
CHEN Ye, CHEN Jian-Hua, GUO Jin
A systematic study of the electronic structures of sphalerite containing fourteen kinds of natural impurities was perfor...
2010, 26 (10): 2851-2856.
DOI: 10.3866/PKU.WHXB20101001
5945
Abstract/Metrics
2226
PDF(1212KB)