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Acta Physico-Chimica Sinca
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中文
Current Issue
2010 Vol. 26,No. 11
Published:29 October 2010
Date of publication: 29 October 2010
Current column
Table of Contents
REVIEW
Invited Aticle
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
ELECTROCHEMISTRY
COLLOID AND INTERFACE CHEMISTRY
CATALYSIS AND SURFACE STRUCTURE
PHOTOCHEMISTRY AND SPECTROSCOPY
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.26 No. 11
2010, 26 (11): 0-0
1216
Abstract/Metrics
1910
PDF(4420KB)
Invited Aticle
Simple Chemical Model for Facilitated Transport with an Application to Wyman-Murray Facilitated Diffusion
COLE Christine Lind, QIAN Hong
A simple chemical kinetic model is developed which describes the behavior of sma...
2010, 26 (11): 2857-2864
DOI: 10.3866/PKU.WHXB20101129
2180
Abstract/Metrics
Supporting Info
1540
PDF(795KB)
Review
Solution Synthesis Strategies for Hierarchical Nanostructures
ZHANG Dong-Feng, NIU Li-Ya, GUO Lin
The coupling and synergistic effects of the unique structure of multi-level, mul...
2010, 26 (11): 2865-2876
DOI: 10.3866/PKU.WHXB20101104
4465
Abstract/Metrics
3148
PDF(4476KB)
Progress of Investigations on Structures and Interactions of Ionic Liquids by Infrared Spectroscopy and Raman Spectroscopy
ZHANG Li-Qun, LI Hao-Ran
Experimental methods, theoretical calculations as well as computer simulations a...
2010, 26 (11): 2877-2889
DOI: 10.3866/PKU.WHXB20101123
6514
Abstract/Metrics
2637
PDF(1343KB)
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
Thermodynamics and Kinetics of Adsorption of Diclofenac on Magnetic Multiwalled Carbon Nanotubes in an Aqueous Solution
XIONG Zhen-Hu, WANG Lu, ZHOU Jian-Guo, LIU Jian-Ming
We investigated the adsorption of diclofenac (an anti-inflammatory drug) in aque...
2010, 26 (11): 2890-2898
DOI: 10.3866/PKU.WHXB20101130
5321
Abstract/Metrics
3997
PDF(1697KB)
Thermodynamic Analysis of Low Temperature Methane Wet-Air Reforming in a Microcombustor
RAN Jing-Yu, ZHAO Liu-Jie
We studied the effects of reaction pressure, molar ratios of air to methane and ...
2010, 26 (11): 2899-2906
DOI: 10.3866/PKU.WHXB20101121
3033
Abstract/Metrics
1160
PDF(1021KB)
Molecular Simulation of Dilute Polyacrylamide Solutions
LIU Yan-Yan, CHEN Pan-Ke, LUO Jian-Hui, ZHOU Ge, JIANG Bo
Polyacrylamide (PAM) applied to various fields is an important class of linear w...
2010, 26 (11): 2907-2914
DOI: 10.3866/PKU.WHXB20101110
3984
Abstract/Metrics
2091
PDF(1281KB)
Thermal Decomposition Kinetics of Poly(propylene carbonate maleate)
WU Wei-Kang, WANG Jia-Li, LIU Su-Qin, HUANG Ke-Long, LIU Yan-Fei
The thermal decomposition kinetics of the novel terpolymer, poly(propylene carbo...
2010, 26 (11): 2915-2919
DOI: 10.3866/PKU.WHXB20101028
3711
Abstract/Metrics
1583
PDF(257KB)
ELECTROCHEMISTRY
Mathematical Model and Circuit Realization to Improve Chronoamperometry
CHEN Xu-Hai, CHEN Jing-Hua, PAN Hai-Bo, LI Yu-Rong, DU Min, LIN Xin-Hua
To overcome the disadvantages of chronoamperometry we report a novel electrochem...
2010, 26 (11): 2920-2926
DOI: 10.3866/PKU.WHXB20101117
2611
Abstract/Metrics
1941
PDF(2237KB)
Preparation and Photoeletrochemical Performance of CdS Quantum Dot Sensitized ZnO Nanorod Array Electrodes
ZHANG Qiao-Bao, FENG Zeng-Fang, HAN Nan-Nan, LIN Ling-Ling, ZHOU Jian-Zhang, LIN Zhong-Hua
We sensitized CdS quantum dots on a ZnO nanorod array electrode by the successiv...
2010, 26 (11): 2927-2934
DOI: 10.3866/PKU.WHXB20101113
4484
Abstract/Metrics
2391
PDF(2014KB)
Kinetics and Electrochemical Impedance Properties of TiO
2
Nanotube Array Photoelectrode
ZHANG Zhi-Yu, SANG Li-Xia, SUN Biao, ZHANG Xiao-Min, MA Chong-Fang
The 2μm and 650 nm TiO
2
nanotube (TNT) arrays were fabricated by s...
2010, 26 (11): 2935-2940
DOI: 10.3866/PKU.WHXB20101131
2565
Abstract/Metrics
1486
PDF(1346KB)
Evaluation of Metal Corrosion under Defective Coatings by WBE and EIS Technique
ZHANG Wei, WANG Jia, LI Yu-Nan, WANG Wei
We investigated the corrosion of steel under defective coatings in 3.5% (mass fr...
2010, 26 (11): 2941-2950
DOI: 10.3866/PKU.WHXB20101102
2843
Abstract/Metrics
1677
PDF(2976KB)
Improved Capacitive Performance of Polypyrrole Doped with 9,10-Anthraquinone-2-sulfonic Acid Sodium Salt
WAN Qun-Yi, FAN Shuan-Shi, YUE Xian-Jun, LANG Xue-Mei, XU Wen-Dong, LI Jing, FENG Chun-Hua
A polypyrrole(PPy)/9,10-anthraquinone-2-sulfonic acid sodium salt (AQS) composit...
2010, 26 (11): 2951-2956
DOI: 10.3866/PKU.WHXB20101107
2973
Abstract/Metrics
1707
PDF(2003KB)
Pt/FTO Counter Electrode for Dye-Sensitized Solar Cells Prepared by Sputtering-Displacement
WANG Yao-Qiong, WEI Zi-Dong, CAI Hong-Ying, ZHANG Qian, ZHAO Qiao-Ling
APt/FTOelectrode for dye-sensitized solar cells (DSSC) was prepared by the sputt...
2010, 26 (11): 2957-2961
DOI: 10.3866/PKU.WHXB20101026
3858
Abstract/Metrics
1873
PDF(3362KB)
Preparation and Electrochemical Performance of H
2
Ti
2
O
5
·H
2
O/Cr
2
O
3
Nanotubes as AnodeMaterials for Lithium-Ion Batteries
HE Yong, TANG Zi-Long, ZHANG Zhong-Tai
One problem that limits the rate capabilities of lithium-ion batteries is that d...
2010, 26 (11): 2962-2966
DOI: 10.3866/PKU.WHXB20101101
2446
Abstract/Metrics
1770
PDF(865KB)
Properties of SPES/PWA/SiO
2
Composite Proton Exchange Membranes
GONG Chun-Li, ZHOU Yi, YAN Li-Cheng, WEN Sheng, ZHENG Gen-Wen
Novel sulfonated poly(ether sulfone) (SPES)/phosphotungstic acid (PWA)/silica or...
2010, 26 (11): 2967-2974
DOI: 10.3866/PKU.WHXB20101124
3041
Abstract/Metrics
1856
PDF(1169KB)
Highly Stable Solid Alkaline ElectrolyteMembranes fromPoly(vinyl alcohol)/Poly(vinyl pyrrolidone) Based on Chemical Cross-Linking
FU Jing, QIAO Jin-Li, MA Jian-Xin
The stability of alkaline electrolyte membranes is recognized as a key factor th...
2010, 26 (11): 2975-2981
DOI: 10.3866/PKU.WHXB20101014
3270
Abstract/Metrics
1605
PDF(1535KB)
COLLOID AND INTERFACE CHEMISTRY
Effect of Hydrophobically Modified Polyacrylamide on Interfacial Dilational Rheological Properties of Crude Oil Components
ZONG Hua, WANG Lei, FANG Hong-Bo, MAO Lei-Ting, WANG Yu-Hui, ZHANG Lu, ZHAO Sui, YU Jia-Yong
The effect of hydrophobically modified polyacrylamide (HMPAM) on the dilational ...
2010, 26 (11): 2982-2988
DOI: 10.3866/PKU.WHXB20101105
3146
Abstract/Metrics
1676
PDF(312KB)
Effect of Hierarchical Architecture of Super-Hydrophobic Surface on the Condensed Drop's Final State
LIU Tian-Qing, SUN Wei, SUN Xiang-Yu, AI Hong-Ru
The interface free energy of a local condensate from the growth and combination ...
2010, 26 (11): 2989-2996
DOI: 10.3866/PKU.WHXB20101025
4211
Abstract/Metrics
1484
PDF(3342KB)
Interactions between
N
-Alkyl-
N
,
N
-di(2-hydroxyethyl)-
N
-methylammonium Bromide and Bovine Serum Albumin
SHAO Shuang, HU Xiao-Huan, YOU Jin-Zong, LEI Qun-Fang
Interactions between a series of
N
-alkyl-
N
,
N
-di(2-hyd...
2010, 26 (11): 2997-3001
DOI: 10.3866/PKU.WHXB20101008
2661
Abstract/Metrics
1624
PDF(743KB)
CATALYSIS AND SURFACE STRUCTURE
Cataluminescence Performance on Catalysts of Graphene Supported Platinum
WU Xiao-Qin, ZONG Rui-Long, MU Hao-Jie, ZHU Yong-Fa
Platinum nanoparticles supported by graphene were prepared by the colloid deposi...
2010, 26 (11): 3002-3008
DOI: 10.3866/PKU.WHXB20101010
3418
Abstract/Metrics
2922
PDF(1991KB)
Deactivation of MnO
x
-CeO
x
/ACF Catalysts for Low-Temperature NH
3
-SCR in the Presence of SO
2
SHEN Bo-Xiong, LIU Ting
The low-temperature selective catalytic reduction of NO with NH
3
(NH<...
2010, 26 (11): 3009-3016
DOI: 10.3866/PKU.WHXB20101120
2955
Abstract/Metrics
1717
PDF(1038KB)
Carbon Deposition on a Toluene Disproportionation and Transalkylation Catalyst
MENG Gen, KONG De-Jin, QI Xiao-Lan, XU Zhong-Qiang
The nature of carbon deposition on a toluene disproportionation and transalkylat...
2010, 26 (11): 3017-3022
DOI: 10.3866/PKU.WHXB20101118
3021
Abstract/Metrics
1378
PDF(1056KB)
Dynamic Performance of CO
2
Adsorption with Amine-Modified SBA-16
SHI Jing-Jin, LIU Ya-Min, CHEN Jie, ZHANG Yu, SHI Yao
Novel CO
2
adsorbents for CO
2
removal were prepared by intr...
2010, 26 (11): 3023-3029
DOI: 10.3866/PKU.WHXB20101109
3054
Abstract/Metrics
1540
PDF(1349KB)
PHOTOCHEMISTRY AND SPECTROSCOPY
XPS Study of the Thickness Nanosize Effect for Ultrathin SiO
2
on Si Substrate
ZHAO Zhi-Juan, LIU Fen, ZHAO Liang-Zhong
X-ray photoelectron spectroscopy (XPS) was used to record the Si 2
p
and...
2010, 26 (11): 3030-3034
DOI: 10.3866/PKU.WHXB20101111
2767
Abstract/Metrics
1401
PDF(201KB)
Effect ofWater Ligation on the Redox Potential and Infrared Spectra of Chlorophyll-
a
HU Qiong, WANG Guo-Ying, OU Jia-Ming, WANG Rui-Li
In the reaction center of photosystem I the accessory electron transfer cofactor...
2010, 26 (11): 3035-3040
DOI: 10.3866/PKU.WHXB20101116
3894
Abstract/Metrics
1544
PDF(704KB)
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
Molecular Dynamics Simulation of Corrosive Medium Diffusion in Corrosion Inhibitor Membrane
QIAO Gui-Min, REN Zhen-Jia, ZHANG Jun, HU Song-Qing, YAN You-Guo, TI Yang
The corrosion inhibition mechanism of four 1-R1-2-undecyl-imidazoline inhibitors...
2010, 26 (11): 3041-3046
DOI: 10.3866/PKU.WHXB20101020
3134
Abstract/Metrics
1734
PDF(1573KB)
Adsorption Behavior of NO on Cu
3
Pt(111) Surface
XIE Xiu-Juan, CHEN Wen-Kai, SUN Bao-Zhen, GUO Xin, ZHANG Yong-Fan
The adsorption behavior of NOonto a Cu
3
Pt (111) surface was studied u...
2010, 26 (11): 3047-3051
DOI: 10.3866/PKU.WHXB20101122
4443
Abstract/Metrics
1531
PDF(1308KB)
Electronic Structure and Optical Properties of the Novel Nonlinear LiAsSe
2
Crystal
NI Bi-Lian, ZHOU He-Gen, JIANG Jun-Quan, LI Yi, ZHANG Yong-Fan
We used density functional theory based on the pseudo-potential plane wave basis...
2010, 26 (11): 3052-3060
DOI: 10.3866/PKU.WHXB20101115
3245
Abstract/Metrics
1643
PDF(2296KB)
Geometric and Electronic Structures of Hexanuclear Binary Ta/Rh Mixed Clusters
CAO Fei, TAN Kai, LIN Meng-Hai
Density functional theory (DFT) was employed to investigate the geometric and el...
2010, 26 (11): 3061-3066
DOI: 10.3866/PKU.WHXB20101112
2880
Abstract/Metrics
1489
PDF(3987KB)
Effects of CH
3
OH and NH
3
on the Hydrolytic Deamination Mechanismof Adenine
LIU Hai-Ying, MENG Fan-Cui, LI Ping, DING Shi-Liang
The effects of CH
3
OH and NH
3
on the hydrolytic deamination...
2010, 26 (11): 3067-3072
DOI: 10.3866/PKU.WHXB20101106
2603
Abstract/Metrics
1278
PDF(1146KB)
PHYSICAL CHEMISTRY OF MATERIALS
Synthesis and Nonlinear Optical Properties of Fluorinated Polyimides Containing Benzothiazole
HE Man, ZHOU Yu-Ming, MIAO Jun-Liang, LIU Cheng, FANG Cheng, CUI Yi-Ping, ZHANG Tong
Hetarylazo chromophores were incorporated into fluorinated polyimide matrices to...
2010, 26 (11): 3073-3079
DOI: 10.3866/PKU.WHXB20101127
2579
Abstract/Metrics
1296
PDF(1024KB)
Purification of Multiwalled Carbon Nanotubes and Characterization of Their Oxygen-Containing Surface Groups
ZHOU Jin-Mei, LI Hai-Yan, LIN Guo-Dong, ZHANG Hong-Bin
We conveniently removed the Ni-MgO catalyst components from an as-grown multiwal...
2010, 26 (11): 3080-3086
DOI: 10.3866/PKU.WHXB20101108
2891
Abstract/Metrics
1958
PDF(961KB)
Preparation and Characterization of One-Dimensional TiO
2
Nanowire Films on a Flexible Stainless Steel Substrate
WU Tao, TAO Jie, DENG Jie, TANG Yu-Xin, ZHU Hong, GAO Peng
We synthesized a one dimensional (1D) TiO
2
nanowire with a large aspe...
2010, 26 (11): 3087-3094
DOI: 10.3866/PKU.WHXB20101103
3176
Abstract/Metrics
2298
PDF(5380KB)
Synthesis, Formation Mechanism and Surface-Enhanced Raman Scattering Properties of Silver Tangled Nanowires and Dendritic Structures
WU Xin-Zhou, PEI Mei-Shan, WANG Lu-Yan, LI Xiao-Nan, TAO Xu-Tang
Silver tangled nanowires and dendritic structures were readily synthesized in hi...
2010, 26 (11): 3095-3100
DOI: 10.3866/PKU.WHXB20101132
3247
Abstract/Metrics
2031
PDF(5769KB)
Preparation and Triethylamine Sensing Properties of Ce-Doped In
2
O
3
Nanofibers
WANG Jin-Xing, YU Lian-Xiang, WANG Hao-Ming, RUAN Sheng-Ping, LI Jia-Jing, WU Feng-Qing
Ce-doped In
2
O
3
nanofibers were synthesized by a simple and...
2010, 26 (11): 3101-3105
DOI: 10.3866/PKU.WHXB20101126
2861
Abstract/Metrics
1592
PDF(1230KB)
Fabrication of Al
2
O
3
Nanoparticles by Cathodic Plasma Electrolysis
LI Zhao-Hu, ZHANG Zhi-Kun, GUO Deng-Zhu
We used aluminum as the cathodic material and an aqueous solution of 3 mol&middo...
2010, 26 (11): 3106-3112
DOI: 10.3866/PKU.WHXB20101114
2592
Abstract/Metrics
1607
PDF(1133KB)
Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe
2
O
3
Nanocrystals
ZHAN Yong-Gong, CHEN Qi-Yuan, YIN Zhou-Lan, LI Li-Li, CAI Bing-Xin
We synthesized novel α-Fe
2
O
3
nanocrystals (NFO-1) wi...
2010, 26 (11): 3113-3119
DOI: 10.3866/PKU.WHXB20101119
2591
Abstract/Metrics
Supporting Info
1523
PDF(1756KB)
Magnetite Sub-Microspheres with Controlled Diameter and Magnetic Properties Synthesized by the Citrate-Assisted Polyol Process
YAN Gong-Qin, WANG Wei, SUN Zhi-Gang, GUAN Jian-Guo
Monodispersed superparamagnetic magnetite (Fe
3
O
4
) sub-micr...
2010, 26 (11): 3120-3126
DOI: 10.3866/PKU.WHXB20101027
2479
Abstract/Metrics
1946
PDF(2661KB)