Table of Contents

• Cover and Table of Contents for Vol.26 No. 11
• 2010, 26 (11): 0

• 1422Abstract/Metrics
• 2066 PDF(4420KB)

Invited Aticle

• Simple Chemical Model for Facilitated Transport with an Application to Wyman-Murray Facilitated Diffusion
• COLE Christine Lind, QIAN Hong
• A simple chemical kinetic model is developed which describes the behavior of small ligands that can bind reversibly with...
• 2010, 26 (11): 2857 -2864 DOI: 10.3866/PKU.WHXB20101129

• 2594Abstract/Metrics
• Supporting Info
• 1640 PDF(795KB)

Review

• Solution Synthesis Strategies for Hierarchical Nanostructures
• ZHANG Dong-Feng, NIU Li-Ya, GUO Lin
• The coupling and synergistic effects of the unique structure of multi-level, multi-dimension, and multi- components allo...
• 2010, 26 (11): 2865 -2876 DOI: 10.3866/PKU.WHXB20101104

• 5181Abstract/Metrics
• 3453 PDF(4476KB)

• Progress of Investigations on Structures and Interactions of Ionic Liquids by Infrared Spectroscopy and Raman Spectroscopy
• ZHANG Li-Qun, LI Hao-Ran
• Experimental methods, theoretical calculations as well as computer simulations are the three most often used approaches ...
• 2010, 26 (11): 2877 -2889 DOI: 10.3866/PKU.WHXB20101123

• 7107Abstract/Metrics
• 2988 PDF(1343KB)

THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY

• Thermodynamics and Kinetics of Adsorption of Diclofenac on Magnetic Multiwalled Carbon Nanotubes in an Aqueous Solution
• XIONG Zhen-Hu, WANG Lu, ZHOU Jian-Guo, LIU Jian-Ming
• We investigated the adsorption of diclofenac (an anti-inflammatory drug) in aqueous solutions by magnetic multiwalled ca...
• 2010, 26 (11): 2890 -2898 DOI: 10.3866/PKU.WHXB20101130

• 5936Abstract/Metrics
• 4684 PDF(1697KB)

• Thermodynamic Analysis of Low Temperature Methane Wet-Air Reforming in a Microcombustor
• RAN Jing-Yu, ZHAO Liu-Jie
• We studied the effects of reaction pressure, molar ratios of air to methane and steam to methane on the reforming proces...
• 2010, 26 (11): 2899 -2906 DOI: 10.3866/PKU.WHXB20101121

• 3440Abstract/Metrics
• 1310 PDF(1021KB)

• Molecular Simulation of Dilute Polyacrylamide Solutions
• LIU Yan-Yan, CHEN Pan-Ke, LUO Jian-Hui, ZHOU Ge, JIANG Bo
• Polyacrylamide (PAM) applied to various fields is an important class of linear water-soluble polymers. Therefore, it is ...
• 2010, 26 (11): 2907 -2914 DOI: 10.3866/PKU.WHXB20101110

• 4495Abstract/Metrics
• 2355 PDF(1281KB)

• Thermal Decomposition Kinetics of Poly(propylene carbonate maleate)
• WU Wei-Kang, WANG Jia-Li, LIU Su-Qin, HUANG Ke-Long, LIU Yan-Fei
• The thermal decomposition kinetics of the novel terpolymer, poly(propylene carbonate maleate) (PPCMA), was investigated ...
• 2010, 26 (11): 2915 -2919 DOI: 10.3866/PKU.WHXB20101028

• 4274Abstract/Metrics
• 1675 PDF(257KB)

ELECTROCHEMISTRY

• Mathematical Model and Circuit Realization to Improve Chronoamperometry
• CHEN Xu-Hai, CHEN Jing-Hua, PAN Hai-Bo, LI Yu-Rong, DU Min, LIN Xin-Hua
• To overcome the disadvantages of chronoamperometry we report a novel electrochemical method where a peak current is quic...
• 2010, 26 (11): 2920 -2926 DOI: 10.3866/PKU.WHXB20101117

• 3070Abstract/Metrics
• 2405 PDF(2237KB)

• Preparation and Photoeletrochemical Performance of CdS Quantum Dot Sensitized ZnO Nanorod Array Electrodes
• ZHANG Qiao-Bao, FENG Zeng-Fang, HAN Nan-Nan, LIN Ling-Ling, ZHOU Jian-Zhang, LIN Zhong-Hua
• We sensitized CdS quantum dots on a ZnO nanorod array electrode by the successive ionic layer adsorption and reaction me...
• 2010, 26 (11): 2927 -2934 DOI: 10.3866/PKU.WHXB20101113

• 5077Abstract/Metrics
• 2672 PDF(2014KB)

• Kinetics and Electrochemical Impedance Properties of TiO₂ Nanotube Array Photoelectrode
• ZHANG Zhi-Yu, SANG Li-Xia, SUN Biao, ZHANG Xiao-Min, MA Chong-Fang
• The 2μm and 650 nm TiO2 nanotube (TNT) arrays were fabricated by sonoelectrochemical anodic oxidation in ethylene gly...
• 2010, 26 (11): 2935 -2940 DOI: 10.3866/PKU.WHXB20101131

• 3028Abstract/Metrics
• 1727 PDF(1346KB)

• Evaluation of Metal Corrosion under Defective Coatings by WBE and EIS Technique
• ZHANG Wei, WANG Jia, LI Yu-Nan, WANG Wei
• We investigated the corrosion of steel under defective coatings in 3.5% (mass fraction) NaCl solution by the wire beamel...
• 2010, 26 (11): 2941 -2950 DOI: 10.3866/PKU.WHXB20101102

• 3353Abstract/Metrics
• 1927 PDF(2976KB)

• Improved Capacitive Performance of Polypyrrole Doped with 9,10-Anthraquinone-2-sulfonic Acid Sodium Salt
• WAN Qun-Yi, FAN Shuan-Shi, YUE Xian-Jun, LANG Xue-Mei, XU Wen-Dong, LI Jing, FENG Chun-Hua
• A polypyrrole(PPy)/9,10-anthraquinone-2-sulfonic acid sodium salt (AQS) composite electrode was prepared by constant-pot...
• 2010, 26 (11): 2951 -2956 DOI: 10.3866/PKU.WHXB20101107

• 3448Abstract/Metrics
• 1898 PDF(2003KB)

• Pt/FTO Counter Electrode for Dye-Sensitized Solar Cells Prepared by Sputtering-Displacement
• WANG Yao-Qiong, WEI Zi-Dong, CAI Hong-Ying, ZHANG Qian, ZHAO Qiao-Ling
• APt/FTOelectrode for dye-sensitized solar cells (DSSC) was prepared by the sputtering (Cu) -displacement (Pt) (SD) metho...
• 2010, 26 (11): 2957 -2961 DOI: 10.3866/PKU.WHXB20101026

• 4333Abstract/Metrics
• 2092 PDF(3362KB)

• Preparation and Electrochemical Performance of H₂Ti₂O₅·H₂O/Cr₂O₃ Nanotubes as AnodeMaterials for Lithium-Ion Batteries
• HE Yong, TANG Zi-Long, ZHANG Zhong-Tai
• One problem that limits the rate capabilities of lithium-ion batteries is that despite the small size of the nanocrystal...
• 2010, 26 (11): 2962 -2966 DOI: 10.3866/PKU.WHXB20101101

• 2901Abstract/Metrics
• 1899 PDF(865KB)

• Properties of SPES/PWA/SiO₂ Composite Proton Exchange Membranes
• GONG Chun-Li, ZHOU Yi, YAN Li-Cheng, WEN Sheng, ZHENG Gen-Wen
• Novel sulfonated poly(ether sulfone) (SPES)/phosphotungstic acid (PWA)/silica organic-inorganic composite membranes for ...
• 2010, 26 (11): 2967 -2974 DOI: 10.3866/PKU.WHXB20101124

• 3545Abstract/Metrics
• 2275 PDF(1169KB)

• Highly Stable Solid Alkaline ElectrolyteMembranes fromPoly(vinyl alcohol)/Poly(vinyl pyrrolidone) Based on Chemical Cross-Linking
• FU Jing, QIAO Jin-Li, MA Jian-Xin
• The stability of alkaline electrolyte membranes is recognized as a key factor that affects their electrochemical applica...
• 2010, 26 (11): 2975 -2981 DOI: 10.3866/PKU.WHXB20101014

• 3868Abstract/Metrics
• 1852 PDF(1535KB)

COLLOID AND INTERFACE CHEMISTRY

• Effect of Hydrophobically Modified Polyacrylamide on Interfacial Dilational Rheological Properties of Crude Oil Components
• ZONG Hua, WANG Lei, FANG Hong-Bo, MAO Lei-Ting, WANG Yu-Hui, ZHANG Lu, ZHAO Sui, YU Jia-Yong
• The effect of hydrophobically modified polyacrylamide (HMPAM) on the dilational rheological properties of interfacial fi...
• 2010, 26 (11): 2982 -2988 DOI: 10.3866/PKU.WHXB20101105

• 3583Abstract/Metrics
• 1794 PDF(312KB)

• Effect of Hierarchical Architecture of Super-Hydrophobic Surface on the Condensed Drop's Final State
• LIU Tian-Qing, SUN Wei, SUN Xiang-Yu, AI Hong-Ru
• The interface free energy of a local condensate from the growth and combination of numerous initial condensation nuclei ...
• 2010, 26 (11): 2989 -2996 DOI: 10.3866/PKU.WHXB20101025

• 4832Abstract/Metrics
• 1708 PDF(3342KB)

• Interactions between N-Alkyl-N,N-di(2-hydroxyethyl)-N-methylammonium Bromide and Bovine Serum Albumin
• SHAO Shuang, HU Xiao-Huan, YOU Jin-Zong, LEI Qun-Fang
• Interactions between a series of N-alkyl-N,N-di(2-hydroxyethyl)-N-methylammonium bromides with alkyl chain from dodecyl ...
• 2010, 26 (11): 2997 -3001 DOI: 10.3866/PKU.WHXB20101008

• 3048Abstract/Metrics
• 1740 PDF(743KB)

CATALYSIS AND SURFACE STRUCTURE

• Cataluminescence Performance on Catalysts of Graphene Supported Platinum
• WU Xiao-Qin, ZONG Rui-Long, MU Hao-Jie, ZHU Yong-Fa
• Platinum nanoparticles supported by graphene were prepared by the colloid deposition process. The effects of particle si...
• 2010, 26 (11): 3002 -3008 DOI: 10.3866/PKU.WHXB20101010

• 3894Abstract/Metrics
• 3176 PDF(1991KB)

• Deactivation of MnO_x-CeO_x/ACF Catalysts for Low-Temperature NH₃-SCR in the Presence of SO₂
• SHEN Bo-Xiong, LIU Ting
• The low-temperature selective catalytic reduction of NO with NH3 (NH3-SCR) over MnOx-CeOx/ACF (activated carbon fiber) m...
• 2010, 26 (11): 3009 -3016 DOI: 10.3866/PKU.WHXB20101120

• 3399Abstract/Metrics
• 1983 PDF(1038KB)

• Carbon Deposition on a Toluene Disproportionation and Transalkylation Catalyst
• MENG Gen, KONG De-Jin, QI Xiao-Lan, XU Zhong-Qiang
• The nature of carbon deposition on a toluene disproportionation and transalkylation catalyst was characterized using the...
• 2010, 26 (11): 3017 -3022 DOI: 10.3866/PKU.WHXB20101118

• 3693Abstract/Metrics
• 1613 PDF(1056KB)

• Dynamic Performance of CO₂ Adsorption with Amine-Modified SBA-16
• SHI Jing-Jin, LIU Ya-Min, CHEN Jie, ZHANG Yu, SHI Yao
• Novel CO2 adsorbents for CO2 removal were prepared by introducing tetraethylenepentamine (TEPA) into SBA-16 type mesopor...
• 2010, 26 (11): 3023 -3029 DOI: 10.3866/PKU.WHXB20101109

• 3504Abstract/Metrics
• 1750 PDF(1349KB)

PHOTOCHEMISTRY AND SPECTROSCOPY

• XPS Study of the Thickness Nanosize Effect for Ultrathin SiO₂ on Si Substrate
• ZHAO Zhi-Juan, LIU Fen, ZHAO Liang-Zhong
• X-ray photoelectron spectroscopy (XPS) was used to record the Si 2p and valence band spectra for a series of ultrathin S...
• 2010, 26 (11): 3030 -3034 DOI: 10.3866/PKU.WHXB20101111

• 3492Abstract/Metrics
• 1566 PDF(201KB)

• Effect ofWater Ligation on the Redox Potential and Infrared Spectra of Chlorophyll-a
• HU Qiong, WANG Guo-Ying, OU Jia-Ming, WANG Rui-Li
• In the reaction center of photosystem I the accessory electron transfer cofactors are two monomeric chlorophyll-a molecu...
• 2010, 26 (11): 3035 -3040 DOI: 10.3866/PKU.WHXB20101116

• 4436Abstract/Metrics
• 1711 PDF(704KB)

QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY

• Molecular Dynamics Simulation of Corrosive Medium Diffusion in Corrosion Inhibitor Membrane
• QIAO Gui-Min, REN Zhen-Jia, ZHANG Jun, HU Song-Qing, YAN You-Guo, TI Yang
• The corrosion inhibition mechanism of four 1-R1-2-undecyl-imidazoline inhibitors (R1: CH2COOH (A), CH2CH2OH (B), CH2CH2N...
• 2010, 26 (11): 3041 -3046 DOI: 10.3866/PKU.WHXB20101020

• 3595Abstract/Metrics
• 1965 PDF(1573KB)

• Adsorption Behavior of NO on Cu₃Pt(111) Surface
• XIE Xiu-Juan, CHEN Wen-Kai, SUN Bao-Zhen, GUO Xin, ZHANG Yong-Fan
• The adsorption behavior of NOonto a Cu3Pt (111) surface was studied using a periodic slab model and the PW91 generalized...
• 2010, 26 (11): 3047 -3051 DOI: 10.3866/PKU.WHXB20101122

• 4895Abstract/Metrics
• 1691 PDF(1308KB)

• Electronic Structure and Optical Properties of the Novel Nonlinear LiAsSe₂ Crystal
• NI Bi-Lian, ZHOU He-Gen, JIANG Jun-Quan, LI Yi, ZHANG Yong-Fan
• We used density functional theory based on the pseudo-potential plane wave basis set to investigate the electronic struc...
• 2010, 26 (11): 3052 -3060 DOI: 10.3866/PKU.WHXB20101115

• 3686Abstract/Metrics
• 1944 PDF(2296KB)

• Geometric and Electronic Structures of Hexanuclear Binary Ta/Rh Mixed Clusters
• CAO Fei, TAN Kai, LIN Meng-Hai
• Density functional theory (DFT) was employed to investigate the geometric and electronic properties of a series of hexan...
• 2010, 26 (11): 3061 -3066 DOI: 10.3866/PKU.WHXB20101112

• 3236Abstract/Metrics
• 1634 PDF(3987KB)

• Effects of CH₃OH and NH₃ on the Hydrolytic Deamination Mechanismof Adenine
• LIU Hai-Ying, MENG Fan-Cui, LI Ping, DING Shi-Liang
• The effects of CH3OH and NH3 on the hydrolytic deamination mechanism of adenine were studied by density functional theor...
• 2010, 26 (11): 3067 -3072 DOI: 10.3866/PKU.WHXB20101106

• 3031Abstract/Metrics
• 1452 PDF(1146KB)

PHYSICAL CHEMISTRY OF MATERIALS

• Synthesis and Nonlinear Optical Properties of Fluorinated Polyimides Containing Benzothiazole
• HE Man, ZHOU Yu-Ming, MIAO Jun-Liang, LIU Cheng, FANG Cheng, CUI Yi-Ping, ZHANG Tong
• Hetarylazo chromophores were incorporated into fluorinated polyimide matrices to prepare novel nonlinear optical (NLO) s...
• 2010, 26 (11): 3073 -3079 DOI: 10.3866/PKU.WHXB20101127

• 3019Abstract/Metrics
• 1484 PDF(1024KB)

• Purification of Multiwalled Carbon Nanotubes and Characterization of Their Oxygen-Containing Surface Groups
• ZHOU Jin-Mei, LI Hai-Yan, LIN Guo-Dong, ZHANG Hong-Bin
• We conveniently removed the Ni-MgO catalyst components from an as-grown multiwalled carbon nanotube (CNT) using an aqueo...
• 2010, 26 (11): 3080 -3086 DOI: 10.3866/PKU.WHXB20101108

• 3426Abstract/Metrics
• 2197 PDF(961KB)

• Preparation and Characterization of One-Dimensional TiO₂ Nanowire Films on a Flexible Stainless Steel Substrate
• WU Tao, TAO Jie, DENG Jie, TANG Yu-Xin, ZHU Hong, GAO Peng
• We synthesized a one dimensional (1D) TiO2 nanowire with a large aspect ratio on non-Ti substrate in NaOH aqueous soluti...
• 2010, 26 (11): 3087 -3094 DOI: 10.3866/PKU.WHXB20101103

• 3579Abstract/Metrics
• 2526 PDF(5380KB)

• Synthesis, Formation Mechanism and Surface-Enhanced Raman Scattering Properties of Silver Tangled Nanowires and Dendritic Structures
• WU Xin-Zhou, PEI Mei-Shan, WANG Lu-Yan, LI Xiao-Nan, TAO Xu-Tang
• Silver tangled nanowires and dendritic structures were readily synthesized in high yield by reducing silver nitrate with...
• 2010, 26 (11): 3095 -3100 DOI: 10.3866/PKU.WHXB20101132

• 3636Abstract/Metrics
• 2299 PDF(5769KB)

• Preparation and Triethylamine Sensing Properties of Ce-Doped In₂O₃ Nanofibers
• WANG Jin-Xing, YU Lian-Xiang, WANG Hao-Ming, RUAN Sheng-Ping, LI Jia-Jing, WU Feng-Qing
• Ce-doped In2O3 nanofibers were synthesized by a simple and effective electrospinning method. The morphology and crystal ...
• 2010, 26 (11): 3101 -3105 DOI: 10.3866/PKU.WHXB20101126

• 3260Abstract/Metrics
• 1811 PDF(1230KB)

• Fabrication of Al₂O₃ Nanoparticles by Cathodic Plasma Electrolysis
• LI Zhao-Hu, ZHANG Zhi-Kun, GUO Deng-Zhu
• We used aluminum as the cathodic material and an aqueous solution of 3 mol·L-1 NH4NO3 as the electrolyte in our w...
• 2010, 26 (11): 3106 -3112 DOI: 10.3866/PKU.WHXB20101114

• 2989Abstract/Metrics
• 1822 PDF(1133KB)

• Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe₂O₃ Nanocrystals
• ZHAN Yong-Gong, CHEN Qi-Yuan, YIN Zhou-Lan, LI Li-Li, CAI Bing-Xin
• We synthesized novel α-Fe2O3 nanocrystals (NFO-1) with single crystalline structure. In our synthetic strategy, th...
• 2010, 26 (11): 3113 -3119 DOI: 10.3866/PKU.WHXB20101119

• 2990Abstract/Metrics
• Supporting Info
• 1672 PDF(1756KB)

• Magnetite Sub-Microspheres with Controlled Diameter and Magnetic Properties Synthesized by the Citrate-Assisted Polyol Process
• YAN Gong-Qin, WANG Wei, SUN Zhi-Gang, GUAN Jian-Guo
• Monodispersed superparamagnetic magnetite (Fe3O4) sub-microspheres with controlled grain sizes and diameters were obtain...
• 2010, 26 (11): 3120 -3126 DOI: 10.3866/PKU.WHXB20101027

• 2949Abstract/Metrics
• 2137 PDF(2661KB)