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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
2010 Vol. 26,No. 11
Published: 29 October 2010
Current column
Table of Contents
Invited Aticle
Review
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
ELECTROCHEMISTRY
COLLOID AND INTERFACE CHEMISTRY
CATALYSIS AND SURFACE STRUCTURE
PHOTOCHEMISTRY AND SPECTROSCOPY
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.26 No. 11
2010, 26 (11): 0.
1668
Abstract/Metrics
2101
PDF(4420KB)
Invited Aticle
Simple Chemical Model for Facilitated Transport with an Application to Wyman-Murray Facilitated Diffusion
COLE Christine Lind, QIAN Hong
A simple chemical kinetic model is developed which describes the behavior of small ligands that can bind reversibly with...
2010, 26 (11): 2857-2864.
DOI: 10.3866/PKU.WHXB20101129
4750
Abstract/Metrics
Supporting Info
1783
PDF(795KB)
Review
Solution Synthesis Strategies for Hierarchical Nanostructures
ZHANG Dong-Feng, NIU Li-Ya, GUO Lin
The coupling and synergistic effects of the unique structure of multi-level, multi-dimension, and multi- components allo...
2010, 26 (11): 2865-2876.
DOI: 10.3866/PKU.WHXB20101104
7074
Abstract/Metrics
3804
PDF(4476KB)
Progress of Investigations on Structures and Interactions of Ionic Liquids by Infrared Spectroscopy and Raman Spectroscopy
ZHANG Li-Qun, LI Hao-Ran
Experimental methods, theoretical calculations as well as computer simulations are the three most often used approaches ...
2010, 26 (11): 2877-2889.
DOI: 10.3866/PKU.WHXB20101123
11692
Abstract/Metrics
3643
PDF(1343KB)
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
Thermodynamics and Kinetics of Adsorption of Diclofenac on Magnetic Multiwalled Carbon Nanotubes in an Aqueous Solution
XIONG Zhen-Hu, WANG Lu, ZHOU Jian-Guo, LIU Jian-Ming
We investigated the adsorption of diclofenac (an anti-inflammatory drug) in aqueous solutions by magnetic multiwalled ca...
2010, 26 (11): 2890-2898.
DOI: 10.3866/PKU.WHXB20101130
7812
Abstract/Metrics
5932
PDF(1697KB)
Thermodynamic Analysis of Low Temperature Methane Wet-Air Reforming in a Microcombustor
RAN Jing-Yu, ZHAO Liu-Jie
We studied the effects of reaction pressure, molar ratios of air to methane and steam to methane on the reforming proces...
2010, 26 (11): 2899-2906.
DOI: 10.3866/PKU.WHXB20101121
5199
Abstract/Metrics
1609
PDF(1021KB)
Molecular Simulation of Dilute Polyacrylamide Solutions
LIU Yan-Yan, CHEN Pan-Ke, LUO Jian-Hui, ZHOU Ge, JIANG Bo
Polyacrylamide (PAM) applied to various fields is an important class of linear water-soluble polymers. Therefore, it is ...
2010, 26 (11): 2907-2914.
DOI: 10.3866/PKU.WHXB20101110
6811
Abstract/Metrics
2658
PDF(1281KB)
Thermal Decomposition Kinetics of Poly(propylene carbonate maleate)
WU Wei-Kang, WANG Jia-Li, LIU Su-Qin, HUANG Ke-Long, LIU Yan-Fei
The thermal decomposition kinetics of the novel terpolymer, poly(propylene carbonate maleate) (PPCMA), was investigated ...
2010, 26 (11): 2915-2919.
DOI: 10.3866/PKU.WHXB20101028
6176
Abstract/Metrics
1879
PDF(257KB)
ELECTROCHEMISTRY
Mathematical Model and Circuit Realization to Improve Chronoamperometry
CHEN Xu-Hai, CHEN Jing-Hua, PAN Hai-Bo, LI Yu-Rong, DU Min, LIN Xin-Hua
To overcome the disadvantages of chronoamperometry we report a novel electrochemical method where a peak current is quic...
2010, 26 (11): 2920-2926.
DOI: 10.3866/PKU.WHXB20101117
4694
Abstract/Metrics
2820
PDF(2237KB)
Preparation and Photoeletrochemical Performance of CdS Quantum Dot Sensitized ZnO Nanorod Array Electrodes
ZHANG Qiao-Bao, FENG Zeng-Fang, HAN Nan-Nan, LIN Ling-Ling, ZHOU Jian-Zhang, LIN Zhong-Hua
We sensitized CdS quantum dots on a ZnO nanorod array electrode by the successive ionic layer adsorption and reaction me...
2010, 26 (11): 2927-2934.
DOI: 10.3866/PKU.WHXB20101113
7264
Abstract/Metrics
2943
PDF(2014KB)
Kinetics and Electrochemical Impedance Properties of TiO
2
Nanotube Array Photoelectrode
ZHANG Zhi-Yu, SANG Li-Xia, SUN Biao, ZHANG Xiao-Min, MA Chong-Fang
The 2μm and 650 nm TiO2 nanotube (TNT) arrays were fabricated by sonoelectrochemical anodic oxidation in ethylene gly...
2010, 26 (11): 2935-2940.
DOI: 10.3866/PKU.WHXB20101131
5094
Abstract/Metrics
2011
PDF(1346KB)
Evaluation of Metal Corrosion under Defective Coatings by WBE and EIS Technique
ZHANG Wei, WANG Jia, LI Yu-Nan, WANG Wei
We investigated the corrosion of steel under defective coatings in 3.5% (mass fraction) NaCl solution by the wire beamel...
2010, 26 (11): 2941-2950.
DOI: 10.3866/PKU.WHXB20101102
5175
Abstract/Metrics
2170
PDF(2976KB)
Improved Capacitive Performance of Polypyrrole Doped with 9,10-Anthraquinone-2-sulfonic Acid Sodium Salt
WAN Qun-Yi, FAN Shuan-Shi, YUE Xian-Jun, LANG Xue-Mei, XU Wen-Dong, LI Jing, FENG Chun-Hua
A polypyrrole(PPy)/9,10-anthraquinone-2-sulfonic acid sodium salt (AQS) composite electrode was prepared by constant-pot...
2010, 26 (11): 2951-2956.
DOI: 10.3866/PKU.WHXB20101107
5074
Abstract/Metrics
2104
PDF(2003KB)
Pt/FTO Counter Electrode for Dye-Sensitized Solar Cells Prepared by Sputtering-Displacement
WANG Yao-Qiong, WEI Zi-Dong, CAI Hong-Ying, ZHANG Qian, ZHAO Qiao-Ling
APt/FTOelectrode for dye-sensitized solar cells (DSSC) was prepared by the sputtering (Cu) -displacement (Pt) (SD) metho...
2010, 26 (11): 2957-2961.
DOI: 10.3866/PKU.WHXB20101026
6066
Abstract/Metrics
2283
PDF(3362KB)
Preparation and Electrochemical Performance of H
2
Ti
2
O
5
·H
2
O/Cr
2
O
3
Nanotubes as AnodeMaterials for Lithium-Ion Batteries
HE Yong, TANG Zi-Long, ZHANG Zhong-Tai
One problem that limits the rate capabilities of lithium-ion batteries is that despite the small size of the nanocrystal...
2010, 26 (11): 2962-2966.
DOI: 10.3866/PKU.WHXB20101101
4602
Abstract/Metrics
2054
PDF(865KB)
Properties of SPES/PWA/SiO
2
Composite Proton Exchange Membranes
GONG Chun-Li, ZHOU Yi, YAN Li-Cheng, WEN Sheng, ZHENG Gen-Wen
Novel sulfonated poly(ether sulfone) (SPES)/phosphotungstic acid (PWA)/silica organic-inorganic composite membranes for ...
2010, 26 (11): 2967-2974.
DOI: 10.3866/PKU.WHXB20101124
5440
Abstract/Metrics
2607
PDF(1169KB)
Highly Stable Solid Alkaline ElectrolyteMembranes fromPoly(vinyl alcohol)/Poly(vinyl pyrrolidone) Based on Chemical Cross-Linking
FU Jing, QIAO Jin-Li, MA Jian-Xin
The stability of alkaline electrolyte membranes is recognized as a key factor that affects their electrochemical applica...
2010, 26 (11): 2975-2981.
DOI: 10.3866/PKU.WHXB20101014
5817
Abstract/Metrics
2088
PDF(1535KB)
COLLOID AND INTERFACE CHEMISTRY
Effect of Hydrophobically Modified Polyacrylamide on Interfacial Dilational Rheological Properties of Crude Oil Components
ZONG Hua, WANG Lei, FANG Hong-Bo, MAO Lei-Ting, WANG Yu-Hui, ZHANG Lu, ZHAO Sui, YU Jia-Yong
The effect of hydrophobically modified polyacrylamide (HMPAM) on the dilational rheological properties of interfacial fi...
2010, 26 (11): 2982-2988.
DOI: 10.3866/PKU.WHXB20101105
5495
Abstract/Metrics
1999
PDF(312KB)
Effect of Hierarchical Architecture of Super-Hydrophobic Surface on the Condensed Drop's Final State
LIU Tian-Qing, SUN Wei, SUN Xiang-Yu, AI Hong-Ru
The interface free energy of a local condensate from the growth and combination of numerous initial condensation nuclei ...
2010, 26 (11): 2989-2996.
DOI: 10.3866/PKU.WHXB20101025
6853
Abstract/Metrics
1933
PDF(3342KB)
Interactions between
N
-Alkyl-
N
,
N
-di(2-hydroxyethyl)-
N
-methylammonium Bromide and Bovine Serum Albumin
SHAO Shuang, HU Xiao-Huan, YOU Jin-Zong, LEI Qun-Fang
Interactions between a series of N-alkyl-N,N-di(2-hydroxyethyl)-N-methylammonium bromides with alkyl chain from dodecyl ...
2010, 26 (11): 2997-3001.
DOI: 10.3866/PKU.WHXB20101008
5307
Abstract/Metrics
1957
PDF(743KB)
CATALYSIS AND SURFACE STRUCTURE
Cataluminescence Performance on Catalysts of Graphene Supported Platinum
WU Xiao-Qin, ZONG Rui-Long, MU Hao-Jie, ZHU Yong-Fa
Platinum nanoparticles supported by graphene were prepared by the colloid deposition process. The effects of particle si...
2010, 26 (11): 3002-3008.
DOI: 10.3866/PKU.WHXB20101010
6036
Abstract/Metrics
3426
PDF(1991KB)
Deactivation of MnO
x
-CeO
x
/ACF Catalysts for Low-Temperature NH
3
-SCR in the Presence of SO
2
SHEN Bo-Xiong, LIU Ting
The low-temperature selective catalytic reduction of NO with NH3 (NH3-SCR) over MnOx-CeOx/ACF (activated carbon fiber) m...
2010, 26 (11): 3009-3016.
DOI: 10.3866/PKU.WHXB20101120
4543
Abstract/Metrics
2239
PDF(1038KB)
Carbon Deposition on a Toluene Disproportionation and Transalkylation Catalyst
MENG Gen, KONG De-Jin, QI Xiao-Lan, XU Zhong-Qiang
The nature of carbon deposition on a toluene disproportionation and transalkylation catalyst was characterized using the...
2010, 26 (11): 3017-3022.
DOI: 10.3866/PKU.WHXB20101118
6034
Abstract/Metrics
1823
PDF(1056KB)
Dynamic Performance of CO
2
Adsorption with Amine-Modified SBA-16
SHI Jing-Jin, LIU Ya-Min, CHEN Jie, ZHANG Yu, SHI Yao
Novel CO2 adsorbents for CO2 removal were prepared by introducing tetraethylenepentamine (TEPA) into SBA-16 type mesopor...
2010, 26 (11): 3023-3029.
DOI: 10.3866/PKU.WHXB20101109
5406
Abstract/Metrics
2001
PDF(1349KB)
PHOTOCHEMISTRY AND SPECTROSCOPY
XPS Study of the Thickness Nanosize Effect for Ultrathin SiO
2
on Si Substrate
ZHAO Zhi-Juan, LIU Fen, ZHAO Liang-Zhong
X-ray photoelectron spectroscopy (XPS) was used to record the Si 2p and valence band spectra for a series of ultrathin S...
2010, 26 (11): 3030-3034.
DOI: 10.3866/PKU.WHXB20101111
5805
Abstract/Metrics
1786
PDF(201KB)
Effect ofWater Ligation on the Redox Potential and Infrared Spectra of Chlorophyll-
a
HU Qiong, WANG Guo-Ying, OU Jia-Ming, WANG Rui-Li
In the reaction center of photosystem I the accessory electron transfer cofactors are two monomeric chlorophyll-a molecu...
2010, 26 (11): 3035-3040.
DOI: 10.3866/PKU.WHXB20101116
6141
Abstract/Metrics
1902
PDF(704KB)
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
Molecular Dynamics Simulation of Corrosive Medium Diffusion in Corrosion Inhibitor Membrane
QIAO Gui-Min, REN Zhen-Jia, ZHANG Jun, HU Song-Qing, YAN You-Guo, TI Yang
The corrosion inhibition mechanism of four 1-R1-2-undecyl-imidazoline inhibitors (R1: CH2COOH (A), CH2CH2OH (B), CH2CH2N...
2010, 26 (11): 3041-3046.
DOI: 10.3866/PKU.WHXB20101020
5441
Abstract/Metrics
2212
PDF(1573KB)
Adsorption Behavior of NO on Cu
3
Pt(111) Surface
XIE Xiu-Juan, CHEN Wen-Kai, SUN Bao-Zhen, GUO Xin, ZHANG Yong-Fan
The adsorption behavior of NOonto a Cu3Pt (111) surface was studied using a periodic slab model and the PW91 generalized...
2010, 26 (11): 3047-3051.
DOI: 10.3866/PKU.WHXB20101122
6418
Abstract/Metrics
1945
PDF(1308KB)
Electronic Structure and Optical Properties of the Novel Nonlinear LiAsSe
2
Crystal
NI Bi-Lian, ZHOU He-Gen, JIANG Jun-Quan, LI Yi, ZHANG Yong-Fan
We used density functional theory based on the pseudo-potential plane wave basis set to investigate the electronic struc...
2010, 26 (11): 3052-3060.
DOI: 10.3866/PKU.WHXB20101115
5445
Abstract/Metrics
2173
PDF(2296KB)
Geometric and Electronic Structures of Hexanuclear Binary Ta/Rh Mixed Clusters
CAO Fei, TAN Kai, LIN Meng-Hai
Density functional theory (DFT) was employed to investigate the geometric and electronic properties of a series of hexan...
2010, 26 (11): 3061-3066.
DOI: 10.3866/PKU.WHXB20101112
5124
Abstract/Metrics
1808
PDF(3987KB)
Effects of CH
3
OH and NH
3
on the Hydrolytic Deamination Mechanismof Adenine
LIU Hai-Ying, MENG Fan-Cui, LI Ping, DING Shi-Liang
The effects of CH3OH and NH3 on the hydrolytic deamination mechanism of adenine were studied by density functional theor...
2010, 26 (11): 3067-3072.
DOI: 10.3866/PKU.WHXB20101106
4615
Abstract/Metrics
1587
PDF(1146KB)
PHYSICAL CHEMISTRY OF MATERIALS
Synthesis and Nonlinear Optical Properties of Fluorinated Polyimides Containing Benzothiazole
HE Man, ZHOU Yu-Ming, MIAO Jun-Liang, LIU Cheng, FANG Cheng, CUI Yi-Ping, ZHANG Tong
Hetarylazo chromophores were incorporated into fluorinated polyimide matrices to prepare novel nonlinear optical (NLO) s...
2010, 26 (11): 3073-3079.
DOI: 10.3866/PKU.WHXB20101127
4435
Abstract/Metrics
1705
PDF(1024KB)
Purification of Multiwalled Carbon Nanotubes and Characterization of Their Oxygen-Containing Surface Groups
ZHOU Jin-Mei, LI Hai-Yan, LIN Guo-Dong, ZHANG Hong-Bin
We conveniently removed the Ni-MgO catalyst components from an as-grown multiwalled carbon nanotube (CNT) using an aqueo...
2010, 26 (11): 3080-3086.
DOI: 10.3866/PKU.WHXB20101108
5704
Abstract/Metrics
2509
PDF(961KB)
Preparation and Characterization of One-Dimensional TiO
2
Nanowire Films on a Flexible Stainless Steel Substrate
WU Tao, TAO Jie, DENG Jie, TANG Yu-Xin, ZHU Hong, GAO Peng
We synthesized a one dimensional (1D) TiO2 nanowire with a large aspect ratio on non-Ti substrate in NaOH aqueous soluti...
2010, 26 (11): 3087-3094.
DOI: 10.3866/PKU.WHXB20101103
5337
Abstract/Metrics
2728
PDF(5380KB)
Synthesis, Formation Mechanism and Surface-Enhanced Raman Scattering Properties of Silver Tangled Nanowires and Dendritic Structures
WU Xin-Zhou, PEI Mei-Shan, WANG Lu-Yan, LI Xiao-Nan, TAO Xu-Tang
Silver tangled nanowires and dendritic structures were readily synthesized in high yield by reducing silver nitrate with...
2010, 26 (11): 3095-3100.
DOI: 10.3866/PKU.WHXB20101132
5651
Abstract/Metrics
2542
PDF(5769KB)
Preparation and Triethylamine Sensing Properties of Ce-Doped In
2
O
3
Nanofibers
WANG Jin-Xing, YU Lian-Xiang, WANG Hao-Ming, RUAN Sheng-Ping, LI Jia-Jing, WU Feng-Qing
Ce-doped In2O3 nanofibers were synthesized by a simple and effective electrospinning method. The morphology and crystal ...
2010, 26 (11): 3101-3105.
DOI: 10.3866/PKU.WHXB20101126
5241
Abstract/Metrics
2104
PDF(1230KB)
Fabrication of Al
2
O
3
Nanoparticles by Cathodic Plasma Electrolysis
LI Zhao-Hu, ZHANG Zhi-Kun, GUO Deng-Zhu
We used aluminum as the cathodic material and an aqueous solution of 3 mol·L-1 NH4NO3 as the electrolyte in our w...
2010, 26 (11): 3106-3112.
DOI: 10.3866/PKU.WHXB20101114
4553
Abstract/Metrics
2148
PDF(1133KB)
Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe
2
O
3
Nanocrystals
ZHAN Yong-Gong, CHEN Qi-Yuan, YIN Zhou-Lan, LI Li-Li, CAI Bing-Xin
We synthesized novel α-Fe2O3 nanocrystals (NFO-1) with single crystalline structure. In our synthetic strategy, th...
2010, 26 (11): 3113-3119.
DOI: 10.3866/PKU.WHXB20101119
4843
Abstract/Metrics
Supporting Info
1891
PDF(1756KB)
Magnetite Sub-Microspheres with Controlled Diameter and Magnetic Properties Synthesized by the Citrate-Assisted Polyol Process
YAN Gong-Qin, WANG Wei, SUN Zhi-Gang, GUAN Jian-Guo
Monodispersed superparamagnetic magnetite (Fe3O4) sub-microspheres with controlled grain sizes and diameters were obtain...
2010, 26 (11): 3120-3126.
DOI: 10.3866/PKU.WHXB20101027
4528
Abstract/Metrics
2371
PDF(2661KB)