Current Issue
- 2011 Vol. 27,No. 03Published:03 March 2011 Date of publication: 03 March 2011
- Current column
- Table of Contents
- Invited Aticle
- REVIEW
- THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
- THEORETICAL AND COMPUTATIONAL CHEMISTRY
- ELECTROCHEMISTRY AND NEW ENERGY
- SOFT MATTER
- CATALYSIS AND SURFACE SCIENCE
- PHOTOCHEMISTRY AND RADIATION CHEMISTRY
- PHYSICAL CHEMISTRY OF MATERIALS
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Table of Contents
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- Cover and Table of Contents for Vol.27 No. 3
- 2011, 27 (03): 0
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Invited Aticle
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- Doping 25-Atom and 38-Atom Gold Nanoclusters with Palladium
- QIAN Huifeng, BARRY Ellen, ZHU Yan, JIN Rongchao
- In this work, we describe two synthetic procedures for preparing palladium doped 25-atom nanoclusters (referred to as Pd...
- 2011, 27 (03): 513 -519 DOI: 10.3866/PKU.WHXB20110304
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REVIEW
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- Mesoscopic Simulations on the Aggregation Behavior of Polymeric Surfactants in Aqueous Solutions
- PANG Jin-Yu, Lü Xin, ZHANG Jian, YUAN Shi-Ling, XU Gui-Ying
- Polymeric surfactants are widely used in many fields. Their aggregation behavior is different from that of small molecul...
- 2011, 27 (03): 520 -529 DOI: 10.3866/PKU.WHXB20110328
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THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
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- Reduced Chemical Kinetic Model of Toluene Reference Fuels for HCCI Combustion
- ZHANG Qing-Feng, ZHENG Zhao-Lei, HE Zu-Wei, WANG Ying
- We developed a reduced kinetic model for toluene reference fuel (TRF) including 70 species and 196 reactions for homogen...
- 2011, 27 (03): 530 -538 DOI: 10.3866/PKU.WHXB20110334
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- Design, Synthesis and Mimic Catalytic Activity of a Vanadium Haloperoxidase Conformation Model Molecule
- CAO Yun-Zhu, WEI Dong-Ming, REN Dong-Xue, CHEN Chen, XING Yong-Heng, SHI Zhan
- Based on mimicing the N, O coordination environment of the active center of vanadium haloperoxidase (V-HPOs) and the hyd...
- 2011, 27 (03): 539 -546 DOI: 10.3866/PKU.WHXB20110326
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- Formation Thermodynamics of Adefovir Dipivoxil-Saccharin Co-Crystals
- ZHANG Jian-Jun, ZU Hui, GAO Yuan
- The solubilities of adefovir dipivoxil (AD) in saccharin (SAC) ethanolic solutions at different temperatures and in SAC ...
- 2011, 27 (03): 547 -552 DOI: 10.3866/PKU.WHXB20110330
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THEORETICAL AND COMPUTATIONAL CHEMISTRY
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- Stepped Behavior of Carbon Dioxide Adsorption in Metal-Organic Frameworks
- AN Xiao-Hui, LIU Da-Huan, ZHONG Chong-Li
- Grand canonical Monte Carlo (GCMC) simulations were performed to study the stepped behaviors of carbon dioxide adsorptio...
- 2011, 27 (03): 553 -558 DOI: 10.3866/PKU.WHXB20110319
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- Electronic Transport in Z-Shaped Graphene-Nanoribbons: Shape and Size Effects
- XU Ning, KONG Fan-Jie, WANG Yan-Zong
- Based on the Green′s function method and the Landauer-Büttiker formula, we studied the electronic transport p...
- 2011, 27 (03): 559 -563 DOI: 10.3866/PKU.WHXB20110305
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- Mechanisms and Kinetics of the HOSO+NO Reaction
- LI Xiao-Yan, LIU Qun, ZHENG Shi-Jun, MENG Ling-Peng
- The mechanism of the reaction between HOSO and NO was investigated at the B3LYP/6-311++G(d,p) level of theory. The geome...
- 2011, 27 (03): 564 -570 DOI: 10.3866/PKU.WHXB20110308
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- Reaction Mechanisms between (Cl-nacnac)Pt(H) and a Terminal Alkyne
- WANG Jia-Yong, BI Si-Wei, ZHAO Jun-Feng
- On the basis of Templeton′s experiment (West, N. M.; et al. Organometallics 2008, 27, 5252), the mechanisms of the...
- 2011, 27 (03): 571 -576 DOI: 10.3866/PKU.WHXB20110312
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- Mechanism of AuCl3-Catalyzed Synthesis of Highly Substituted Furans Based on 2-(1-Alkynyl)-2-alken-1-ones
- AN Xiao-Ying, HE Rong-Xing, HUANG Cheng, LI Ming
- We investigated the mechanism of the AuCl3-catalyzed synthesis of highly substituted furans from 2-(1-alkynyl)-2-alken-1...
- 2011, 27 (03): 577 -583 DOI: 10.3866/PKU.WHXB20110338
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- Second-Order Nonlinear Optical Properties of Organic Heteroaromatic Molecules with Carbazole Chromophores
- ZHAO Min, ZHANG Yuan, WANG Lu
- Density functional theory (DFT) B3LYP/6-31G* method was used to optimize the geometrical structures of a series of heter...
- 2011, 27 (03): 584 -588 DOI: 10.3866/PKU.WHXB20110316
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- Effect of Substituents on the Optical Properties of 3(5)-(9-Anthryl) Pyrazole
- WANG Kun-Peng, WANG Chang-Sheng
- The ground state (S0) structures of 3(5)-(9-anthryl) pyrazole and its derivatives were obtained using the density functi...
- 2011, 27 (03): 589 -594 DOI: 10.3866/PKU.WHXB20110303
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- A First-Principles Method for Predicting Redox Potentials of Nucleobases and the Metabolites in Aqueous Solution
- LI Min-Jie, LIU Wei-Xia, PENG Chun-Rong, LU Wen-Cong
- Redox potentials are of importance in understanding the charge/electron transfer processes involved in nucleic acids. In...
- 2011, 27 (03): 595 -603 DOI: 10.3866/PKU.WHXB20110333
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ELECTROCHEMISTRY AND NEW ENERGY
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- Electrocatalytic Performance of Pd Catalyst Supported on Macropore Carbon for Oxidation of Formic Acid
- LIU Chun-Yan, XU Bin, TANG Ya-Wen, CAO Gao-Ping, YANG Yu-Sheng, LU Tian-Hong
- The electrocatalytic performances of a Vulcan XC-72 carbon black supported Pd (Pd/XC) catalyst and a macroporous carbon ...
- 2011, 27 (03): 604 -608 DOI: 10.3866/PKU.WHXB20110301
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- Synthesis and Properties of Spindle-Shaped LiFePO4 for the Cathode Material of Lithium Ion Battery
- SU Chang, LU Guo-Qiang, XU Li-Huan, ZHANG Cheng, MA Chun-An
- We synthesized LiFePO4 directly by a solvothermal method at low temperature and then a heat treatment was carried out to...
- 2011, 27 (03): 609 -614 DOI: 10.3866/PKU.WHXB20110241
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- Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam
- YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling CAO Dian-Xue
- We prepared an electrode consisting of NiCo2O4 nanowire arrays that stand freely on nickel foam by a template-free growt...
- 2011, 27 (03): 615 -619 DOI: 10.3866/PKU.WHXB20110317
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- Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance
- LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min
- Several microporous carbons were prepared by polyfurfuryl alcohol-impregnation and impregnation-acetonitrile chemical va...
- 2011, 27 (03): 620 -626 DOI: 10.3866/PKU.WHXB20110331
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- Catalytic Oxidation of Sulfide Ion over a Spherular-Co3O4 Electrode
- LAO Guo-Hong, SHAO Hai-Bo, FAN Yu-Qian, WANG Jian-Ming, ZHANG Jian-Qing, CAO Chu-Nan
- Spherular-Co3O4 particles were synthesized on graphite electrode surface by ammonia-evaporation-induction. Its electroox...
- 2011, 27 (03): 627 -632 DOI: 10.3866/PKU.WHXB20110240
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- Electrochemical Study on Electroless Nickel Plating Using Sodium Borohydride as the Reductant
- JIA Fei, WANG Zhou-Cheng
- We studied electroless Ni-B plating with sodium borohydride as the reductant by linear sweep voltammetry. The effects of...
- 2011, 27 (03): 633 -640 DOI: 10.3866/PKU.WHXB20110302
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- Mechanism of Au Electrodeposition onto Indium Tin Oxide
- TANG Jing, TIAN Xiao-Chun, ZHOU Fu-Qing, LIU Yue-Qiang, LIN Jian-Hang
- Cyclic voltammetric and chronoamperometric methods were used to study the initial stage of Au electrodeposition on an in...
- 2011, 27 (03): 641 -646 DOI: 10.3866/PKU.WHXB20110322
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- Corrosion Inhibition by Sorbitol/Diethylenetriamine Condensation Product for Carbon Steel in 3.5% NaCl Saturated Ca(OH)2 Solution
- ZHOU Xin, YANG Huai-Yu, WANG Fu-Hui
- The inhibitive action of a sorbitol/diethylenetriamine condensation (SDC) product toward carbon steel corrosion in satur...
- 2011, 27 (03): 647 -654 DOI: 10.3866/PKU.WHXB20110315
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- Effect of Alkylimidazolium Ionic Liquids on the Corrosion Inhibition of Copper in Sulfuric Acid Solution
- ZHANG Qi-Bo, HUA Yi-Xin
- The effects of three newly synthesized alkylimidazolium based ionic liquids: 1-butyl-3- methylimidazolium hydrogen sulfa...
- 2011, 27 (03): 655 -663 DOI: 10.3866/PKU.WHXB20110339
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SOFT MATTER
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- Synthesis and Solution Properties of the Photo-Sensitive Telechelic Polymer——Coumarin-Containing Poly(4-vinylpyridine)
- JIANG Jin-Qiang, QIANG Jing, NI Zhong-Bin, SONG Xiao-Qing, ZHANG Hong-Wu, LIU Xiao-Ya, CHEN Ming-Qing
- A novel photo-sensitive telechelic polymer——coumarin-containing poly(4-vinylpyridine) (C- P4VP) was prepared...
- 2011, 27 (03): 664 -670 DOI: 10.3866/PKU.WHXB20110238
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- Interaction of Hydrophobically Associating Polyacrylamide with Gemini Surfactant
- CHEN Hong, LI Er-Xiao, YE Zhong-Bin, HAN Li-Juan, LUO Ping-Ya
- A fatty acid disulfonate anionic gemini surfactant was prepared and the structure of the surfactant was characterized by...
- 2011, 27 (03): 671 -676 DOI: 10.3866/PKU.WHXB20110306
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CATALYSIS AND SURFACE SCIENCE
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- Acid Dye Adsorption Properties of Ethylenediamine-Modified Magnetic Chitosan Nanoparticles
- ZHOU Li-Min, SHANG Chao, LIU Zhi-Rong
- Ethylenediamine-modified magnetic chitosan nanoparticles (EMCN) were prepared and used for the adsorption of Acid Orange...
- 2011, 27 (03): 677 -682 DOI: 10.3866/PKU.WHXB20110314
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- Preparation of Sulfonated Carbon Nanotubes/Activated Carbon Composite Beads and Their Adsorption Capacity for Low Density Lipoprotein
- LU Yue-Mei, GONG Qian-Ming, LU Fang-Ping, LIANG Ji, NIE Qing-Dong, ZHANG Xiu-Mei
- Sulfonated carbon nanotubes (CNTs)/activated carbon composite beads were obtained by suspension polymerization, carboniz...
- 2011, 27 (03): 683 -688 DOI: 10.3866/PKU.WHXB20110307
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- Synthesis of Micro/Mesoporous Composites and Their Application as CO2 Adsorbents
- MA Yan-Hui, ZHAO Hui-Ling, TANG Sheng-Jie, HU Jun, LIU Hong-Lai
- We synthesized a series of micro/mesoporous composites of S-β-MCM41(c), P-β-MCM41(c), P-ZSM-MCM41(c), P-ZSM-C ...
- 2011, 27 (03): 689 -696 DOI: 10.3866/PKU.WHXB20110335
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- Mechanism of Biogas Reforming for Hydrogen Production over Ni-Co Bimetallic Catalyst
- XU Jun-Ke, SHEN Li-Hong, ZHOU Wei, MA Jian-Xin
- Ni-Co bimetallic catalysts supported on commercial γ-Al2O3 modified with La2O3 were prepared by conventional incip...
- 2011, 27 (03): 697 -704 DOI: 10.3866/PKU.WHXB20110309
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- Effect of Supports on the Catalytic Performance of Pd-Cu/Activated Carbon Catalyst for Eliminating CO in Cigarette Smoke
- ZHAN Wang-Cheng, ZHOU Guo-Jun, CHU Guo-Hai, SHEN Kai, YU Jun, WANG Ai-Yong, SU Na, LU Guan-Zhong, GUO Yang-Long
- Pd-Cu/activated carbon catalysts were prepared by wetness impregnation and their performance in the room-temperature cat...
- 2011, 27 (03): 705 -710 DOI: 10.3866/PKU.WHXB20110311
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- Pt-Ni Catalyst Supported on CMK-5 for the Electrochemical Oxidation of Methanol
- DING Xiao-Chun, CHEN Xiu, ZHOU Jian-Hua, WANG Tao, SUN Dun, HE Jian-Ping
- Pt-Ni alloy catalysts with different atomic ratios were deposited on CMK-5 (carbon replicated from SBA-15 silica) by NaB...
- 2011, 27 (03): 711 -716 DOI: 10.3866/PKU.WHXB20110327
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PHOTOCHEMISTRY AND RADIATION CHEMISTRY
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- Third Order Nonlinear Optical Properties of Benzyltriethylamine Bis(2-thioxo-1,3-dithiole-4,5-dithiolato) Aurate(III)
- CHEN Jing-Wei, WANG Xin-Qiang, REN Quan, LI Ting-Bin, YANG Hong-Liang, ZHANG Jing-Nan, LI Guo-Chao
- We prepared a new crystalline nonlinear optical coordination compound, benzyltriethylamine bis (2-thioxo-1,3-dithiole-4,...
- 2011, 27 (03): 717 -721 DOI: 10.3866/PKU.WHXB20110340
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PHYSICAL CHEMISTRY OF MATERIALS
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- Preparation and Antibacterial Properties of Water-Soluble Ag Nanoparticles
- SUN Lei, LIU Ai-Xin, HUANG Hong-Ying, TAO Xiao-Jun, ZHAO Yan-Bao, ZHANG Zhi-Jun
- Water-soluble surface modified silver nanoparticles were synthesized by liquid phase reduction with tannic acid as the r...
- 2011, 27 (03): 722 -728 DOI: 10.3866/PKU.WHXB20110235
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- Delicately Controlled Synthesis of Mesoporous Carbon Materials with Thin Pore Walls
- WANG Yu, YU Gang, CAI Bin, ZHU Yue-Xiang, XIE You-Chang
- Mesoporous carbon materials with a range of pore sizes were synthesized by a delicately controlled procedure using disor...
- 2011, 27 (03): 729 -735 DOI: 10.3866/PKU.WHXB20110321
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- Synthesis and Structural Characterization of Graphene-Based Membranes
- YANG Yong-Hui, SUN Hong-Juan, PENG Tong-Jiang, HUANG Qiao
- A stable hydrosol of graphene was synthesized by oxidation reduction and then a flow assembly of this graphene was used ...
- 2011, 27 (03): 736 -742 DOI: 10.3866/PKU.WHXB20110320
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- Controlled Synthesis of Mesoporous MnO2 Nanospindles
- HAN Ling, NI Ji-Peng, ZHANG Liang-Miao, YUE Bao-Hua, SHEN Shan-Shan, ZHANG Hao, LU Wen-Cong
- We synthesized mesoporous MnO2 nanospindles by a one-step hydrothermal process in an aqueous solution of KMnO4 and gluco...
- 2011, 27 (03): 743 -748 DOI: 10.3866/PKU.WHXB20110318
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- Fabrication of Large Area of Anodic Aluminum Oxide Ultrathin Film Directly onto an ITO Electrode with a Ti Buffer Layer
- XIAO Lixin, DUAN Laiqiang, CHAI Junyi, WANG Yun, CHEN Zhijian, QU Bo, GONG Qihuang
- An anodic aluminum oxide (AAO) ultrathin film (~140 nm, about half the thickness of the original Al film) was successful...
- 2011, 27 (03): 749 -753 DOI: 10.3866/PKU.WHXB20110310
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- Electrostatically Self-Assembled Films Prepared Using Bipolar Thiophene Hemicyanine and Prussian Blue
- WANG Zhi-Ping, LUO Hong, GAO Li-Hua, WANG Ke-Zhi
- We successfully prepared a novel inorganic-organic hybrid electrostatically self-assembled multilayer film by alternatel...
- 2011, 27 (03): 754 -758 DOI: 10.3866/PKU.WHXB20110313
