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Acta Phys. -Chim. Sin.
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中文
Current Issue
2011 Vol. 27,No. 05
Published: 28 April 2011
Current column
Table of Contents
COMMUNICATION
REVIEW
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
THEORETICAL AND COMPUTATIONAL CHEMISTRY
ELECTROCHEMISTRY AND NEW ENERGY
SOFT MATTER
CATALYSIS AND SURFACE SCIENCE
PHOTOCHEMISTRY AND RADIATION CHEMISTRY
BIOPHYSICAL CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.27 No. 5
2011, 27 (05): 0.
1735
Abstract/Metrics
1883
PDF(4867KB)
COMMUNICATION
Catalytic Decomposition of Cellulose in Cooperative Ionic Liquids
LONG Jin-Xing, GUO Bin, LI Xue-Hui, WANG Fu-Rong, WANG Le-Fu
Cellulose, the abundant and cost-ineffective resource, is considered to be a perfect alternative for the alleviation of ...
2011, 27 (05): 995-999.
DOI: 10.3866/PKU.WHXB20110506
5333
Abstract/Metrics
2601
PDF(606KB)
Molecular Symmetry of Möbius Cyclacenes
XING Sheng-Kai, LI Yun, ZHAO Xue-Zhuang, CAI Zun-Sheng, SHANG Zhen-Feng, WANG Gui-Chang
Generally speaking, the highest symmetry of a Möbius cyclacene molecule is C2 group based on the point group theory...
2011, 27 (05): 1000-1004.
DOI: 10.3866/PKU.WHXB20110518
5157
Abstract/Metrics
2006
PDF(500KB)
REVIEW
Review of Sulfur-Based Cathodes for High Performance Lithium Rechargeable Batteries
YAO Zhen-Dong, WEI Wei, WANG Jiu-Lin, YANG Jun, NULI Yan-Na
The preparation, characteristics and electrochemical performances of the sulfur-based cathode materials in lithium/sulfu...
2011, 27 (05): 1005-1016.
DOI: 10.3866/PKU.WHXB20110345
7874
Abstract/Metrics
4863
PDF(1058KB)
Titanium Oxide Nanotubes Prepared by Anodic Oxidation and Their Application in Solar Cells
LI Huan-Huan, CHEN Run-Feng, MA Cong, ZHANG Sheng-Lan, AN Zhong-Fu, HUANG Wei
We review the history, fabrication procedures, and mechanisms of TiO2 nanotubes prepared by the anodic oxidation of tita...
2011, 27 (05): 1017-1025.
DOI: 10.3866/PKU.WHXB20110514
7789
Abstract/Metrics
4691
PDF(715KB)
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
The Second Virial Coefficient and Droplet Interaction of AOT/Water/Toluene Microemulsion
PENG Xu-Hong, ZHENG Pei-Zhu, MA Yuan-Ming, YIN Tian-Xiang, AN Xue-Qin, SHEN Wei-Guo
Static light scattering measurements on a microemulsion of sodium bis(2-ethylhexyl) sulfosuccinate (AOT)/water/toluene w...
2011, 27 (05): 1026-1030.
DOI: 10.3866/PKU.WHXB20110503
5414
Abstract/Metrics
2211
PDF(534KB)
Effect of Annealing Conditions on Enthalpy Relaxation Parameters of
D
-Sorbitol Glass
YE Bin, GAO Cai, LIU Xiang-Nong, YANG Suo, JIANG Bin
We studied the enthalpy relaxation dynamics of amorphous D-sorbitol by differential scanning calorimetry (DSC). A series...
2011, 27 (05): 1031-1038.
DOI: 10.3866/PKU.WHXB20110419
4541
Abstract/Metrics
2122
PDF(866KB)
Near Infrared Spectrum Analysis of Organic/Inorganic Composite Microcapsule Phase Change Materials
WU Xiao-Lin, SUN Rong, ZHU Peng-Li, DU Ru-Xu
Using Fourier transform near infrared (FT-NIR) spectroscopy, the characteristics and phase change mechanism of the phase...
2011, 27 (05): 1039-1044.
DOI: 10.3866/PKU.WHXB20110424
5224
Abstract/Metrics
2449
PDF(779KB)
Solvent Effects on the Photophysicochemical Properties of Tetra(tert-butylphenoxy)phthalocyaninato Zinc(II)
OGUNSIPE Abimbola, NYOKONG Tebello
The solvent viscosity dependence of the photophysical and photochemical properties of tetra(tert-butylphenoxy)phthalocya...
2011, 27 (05): 1045-1052.
DOI: 10.3866/PKU.WHXB20110508
4384
Abstract/Metrics
2162
PDF(667KB)
Statistical Model for Intensities in the Rotational Spectra of Linear and Non-Linear Molecules
SAIZ Andrés
In this study, we found regular behavior, from a statistical point of view, in the intensities of rotational spectra for...
2011, 27 (05): 1053-1060.
DOI: 10.3866/PKU.WHXB20110501
3555
Abstract/Metrics
1527
PDF(10259KB)
Experiment and Kinetics Simulation on the Pyrolysis of
n
-Decane
JIAO Yi, LI Jun, WANG Jing-Bo, WANG Jian-Li, ZHU Quan, CHEN Yao-Qiang, LI Xiang-Yuan
In this work, atmospheric cracking equipment was used to study the distribution of the main gas products of n-decane pyr...
2011, 27 (05): 1061-1067.
DOI: 10.3866/PKU.WHXB20110437
5707
Abstract/Metrics
2409
PDF(688KB)
THEORETICAL AND COMPUTATIONAL CHEMISTRY
Density Functional Theory Study of Atomic and Molecular Oxygen Adsorption on Au Clusters
GUO Xiao-Wei, TENG Bo-Tao, YUAN Jin-Huan, ZHAO Yun, ZHAO Yue, LIU Sha
The adsorption behaviors of O and O2 on charged and neutral Au19 and Au20 clusters were systematically investigated by d...
2011, 27 (05): 1068-1074.
DOI: 10.3866/PKU.WHXB20110438
7895
Abstract/Metrics
2796
PDF(2411KB)
Adsorption and Dissociation of Methanol on Perfect FeS
2
(100) Surface
DU Yu-Dong, ZHAO Wei-Na, GUO Xin, ZHANG Yong-Fan, CHEN Wen-Kai
First-principles calculations based on density functional theory (DFT) and the periodical slab model were used to study ...
2011, 27 (05): 1075-1080.
DOI: 10.3866/PKU.WHXB20110444
7721
Abstract/Metrics
2442
PDF(849KB)
Theoretical Study of the Double-Bond Isomerization of 1-Hexene to
cis
-2-Hexene over ZSM-5 Zeolite
LI Yan-Feng, ZHU Ji-Qin, LIU Hui, HE Peng, WANG Peng, TIAN Hui-Ping
We investigated the double-bond isomerization reaction of 1-hexene to cis-2-hexene on the surface of ZSM-5 zeolite using...
2011, 27 (05): 1081-1088.
DOI: 10.3866/PKU.WHXB20110516
5021
Abstract/Metrics
1933
PDF(1088KB)
Structures and Spectroscopic Properties of [Ru(iph)(L)
2
]
2+
(L=cpy, mpy, npy) Complexes Containing Tetradentate Ligands
ZHANG Jian-Po, JIN Li, ZHANG Hong-Xing
The geometries of ground and excited states of a series of ruthenium complexes [Ru(iph)(L)2]2+(L=cpy (1), mpy (2), npy (...
2011, 27 (05): 1089-1094.
DOI: 10.3866/PKU.WHXB20110505
5544
Abstract/Metrics
2211
PDF(634KB)
Structures and Stabilities of Small Zirconium Oxide Clusters
ZHAO Gao-Feng, XIANG Bing, SHEN Xue-Feng, SUN Jian-Min, BAI Yan-Zhi, WANG Yuan-Xu
The geometric structures and stabilities of small ZrmOn (1≤m≤5, 1≤n≤2m) clusters were studied using density ...
2011, 27 (05): 1095-1102.
DOI: 10.3866/PKU.WHXB20110440
4607
Abstract/Metrics
1982
PDF(833KB)
Electronic Transport Properties of Graphene Nanoribbons with Nanoholes
SUN Da-Li, PENG Sheng-Lin, OUYANG Jun, OUYANG Fang-Ping
Based on the density of the general theory, the structures of ziqzag graphene nanoribbons (ZGNRs) (N=17, N is the number...
2011, 27 (05): 1103-1107.
DOI: 10.3866/PKU.WHXB20110521
4988
Abstract/Metrics
2753
PDF(659KB)
ELECTROCHEMISTRY AND NEW ENERGY
Electrodeposition Behavior of Silicon from Na
3
AlF
6
-LiF Melts
JIA Ming, LAI Yan-Qing, TIAN Zhong-Liang, LIU Fang-Yang, LI Jie, XIN Peng-Fei, LIU Ye-Xiang
A fundamental electrochemical study of Si in Na3AlF6-LiF melts and electrowinning and electrorefining in a small-scale l...
2011, 27 (05): 1108-1115.
DOI: 10.3866/PKU.WHXB20110504
4596
Abstract/Metrics
2305
PDF(870KB)
Redox Stability of Polypyrrole in Aqueous Electrolyte Solutions by a Recurrent Potential Pulse Technique
TIAN Ying, WANG Jing-Ri, LIU Ming, SHI Kun, YANG Feng-Lin
The recurrent potential pulse (RPP) technique is an alternative and effective technique for redox stability measurement....
2011, 27 (05): 1116-1121.
DOI: 10.3866/PKU.WHXB20110515
4930
Abstract/Metrics
1624
PDF(665KB)
Anticorrosion Properties of Nano Anatase TiO
2
Films Derived from Sol-Gel and Hydrothermal Crystallization
YUN Hong, LIN Chang-Jian, DU Rong-Gui
Nano TiO2 films were applied to the surface of stainless steel (SS) by sol-gel and hydrothermal crystallization using Ti...
2011, 27 (05): 1122-1127.
DOI: 10.3866/PKU.WHXB20110433
4085
Abstract/Metrics
2165
PDF(716KB)
SOFT MATTER
Effects of Molecular Structure on Surfactin Micellization Activity
LI Yi, ZOU Ai-Hua, YE Ru-Qiang, MU Bo-Zhong
We produced a group of surfactin isoforms using Bacillus subtilis HSO121. The micellization activity properties such as ...
2011, 27 (05): 1128-1134.
DOI: 10.3866/PKU.WHXB20110436
5208
Abstract/Metrics
2594
PDF(744KB)
Disassembly of Polyelectrolyte/Surfactants Complex Induced by Macroions
LIU Zhen-Hai, SHANG Ya-Zhuo, HUANG Yong-Min, PENG Chang-Jun, LIU Hong-Lai
The effects of charge number, diameter, surface charge density as well as concentration of macroions on the structure of...
2011, 27 (05): 1135-1142.
DOI: 10.3866/PKU.WHXB20110406
5129
Abstract/Metrics
2127
PDF(815KB)
CATALYSIS AND SURFACE SCIENCE
Photocatalytic Reduction of Water to Hydrogen over Eosin Y/Pt/SiO
2
Catalysts
ZHANG Xiao-Jie, TANG Chang-Qing, JIN Zhi-Liang, LV Gong-Xuan, LI Shu-Ben
A novel efficient photoscatalytic system Eosin Y/Pt/SiO2 for photocatalytic reduction of water to hydrogen under visible...
2011, 27 (05): 1143-1148.
DOI: 10.3866/PKU.WHXB20110511
5225
Abstract/Metrics
2185
PDF(544KB)
Preparation of F-Modified Nanosized TiO
2
and Its Methyl Orange Photodegradation Mechanism
JIANG Jing-Jing, LONG Ming-Ce, WU De-Yong, CAI Wei-Min
Fluorine-modified nanosized TiO2 (F-TiO2) was prepared by a facile precipitation-fluorination- reflux method. Characteri...
2011, 27 (05): 1149-1156.
DOI: 10.3866/PKU.WHXB20110520
4783
Abstract/Metrics
2949
PDF(812KB)
Effects of Alkaline Earth Metal on Performance of ZrO
2
-Al
2
O
3
Support and Pd-Rh Close-Coupled Catalyst
HE Sheng-Nan, CUI Ya-Juan, YAO Yan-Ling, FANG Rui-Mei, SHI Zhong-Hua, GONG Mao-Chu, CHEN Yao-Qiang
A series of alumina supports stabilized by alkaline earth metals and zirconia were prepared by the peptizing method. Pd-...
2011, 27 (05): 1157-1162.
DOI: 10.3866/PKU.WHXB20110509
4305
Abstract/Metrics
1658
PDF(693KB)
Preparation of CuO-Ce
0.6
Zr
0.4
O
2
by Microwave Heating Decomposition and Its Catalytic Property for CO Oxidation
YANG Zhi-Qiang, MAO Dong-Sen, WU Ren-Chun, YU Jun, WANG Qian
A series of CuO-Ce0.6Zr0.4O2 catalysts with different contents (0-25%, w) of CuO were prepared by microwave heating deco...
2011, 27 (05): 1163-1168.
DOI: 10.3866/PKU.WHXB20110443
5276
Abstract/Metrics
1693
PDF(694KB)
Preparation and Catalytic Activities of La
2
CoAlO
6
for Methane Combustion
ZHANG Hui-Min, HU Rui-Sheng, HU Jia-Nan, ZHANG Yu-Long
A novel rare earth double perovskite-type catalyst (La2CoAlO6) was prepared by the sol-gel method using citric acid as c...
2011, 27 (05): 1169-1175.
DOI: 10.3866/PKU.WHXB20110502
4924
Abstract/Metrics
3660
PDF(785KB)
Effects of Surface Acidity on the Adsorption Desulfurization of Cu(I)Y Zeolites
WANG Wang-Yin, PAN Ming-Xue, QIN Yu-Cai, WANG Ling-Tao, SONG Li-Juan
Cu(I)Y zeolites with different degrees of ion exchange were prepared by solid state ion exchange (SSIE) and liquid phase...
2011, 27 (05): 1176-1180.
DOI: 10.3866/PKU.WHXB20110442
5909
Abstract/Metrics
2411
PDF(671KB)
Adsorption Performance of Hg(II) Ions on Amine-Modified Nanoporous Carbon Materials
YUAN Xiao-Ling, LU Chun-Mei, ZHU Wan-Chun, JIA Ming-Jun, LIU Gang, WANG Zhen-Lü, ZHANG Wen-Xiang
The adsorption performance of nanoporous carbon (NC) and ethylenediamine-modified nanoporous carbon (NC-EDA) toward Hg2+...
2011, 27 (05): 1181-1187.
DOI: 10.3866/PKU.WHXB20110519
5305
Abstract/Metrics
2642
PDF(792KB)
PHOTOCHEMISTRY AND RADIATION CHEMISTRY
Synthesis and Electroluminescent Properties of Phenyl-Substituted Poly(phenylenevinylene)
MO Yue-Qi, CHANG Xue-Yi, HU Su-Jun, HAN Shao-Hu, WU Hong-Bin, PENG Jun-Biao
Poly(phenylenevinylene) (PPV) is one of the most efficient electroluminescent conjugated polymers and has the potential ...
2011, 27 (05): 1188-1194.
DOI: 10.3866/PKU.WHXB20110527
5000
Abstract/Metrics
1857
PDF(473KB)
Photoluminescence and Electroluminescence of the Novel Soluble Zinc Phthalocyanine
BAI Qing-Long, ZHANG Chun-Hua, CHENG Chuan-Hui, LI Wan-Cheng, SHEN Ren-Sheng, DU Guo-Tong
α(β)-tetra-(methoxy-phenoxy)-zinc phthalocyanine are synthesized by employing 3(4)- nitrobenzene-1,2-dicarbon...
2011, 27 (05): 1195-1200.
DOI: 10.3866/PKU.WHXB20110425
5233
Abstract/Metrics
2807
PDF(740KB)
Effect of Europium Valence on the Luminescent Properties of Sr
2
MgSi
2
O
7
:Eu
WU Hao-Yi, HU Yi-Hua, CHEN Li, WANG Xiao-Juan
Sr1.99MgSi2O7:Eu0.01 samples were prepared in four steps under air, a reducing atmosphere, air again, and a reducing atm...
2011, 27 (05): 1201-1206.
DOI: 10.3866/PKU.WHXB20110523
5547
Abstract/Metrics
2016
PDF(690KB)
Polymer/ZnO Micro-Nano Array Composites for Light-Emitting Layer of Flexible Optoelectronic Devices
SONG Ji-Zhong, HE Ying, ZHU Di, CHEN Jie, PEI Chang-Long, WANG Jun-An
We prepared PAM/ZnO micro-nano arrays on indium tin oxide (ITO) conductive films based on poly(ethylene terephthalate) (...
2011, 27 (05): 1207-1213.
DOI: 10.3866/PKU.WHXB20110435
4509
Abstract/Metrics
2231
PDF(1040KB)
BIOPHYSICAL CHEMISTRY
Target Identification of Isomalabaricane Terpenes Extracted from Sponges
TIAN Ran, LIU Zhen-Ming, JIN Hong-Wei, ZHANG Liang-Ren, LIN Wen-Han
A strategy combining structure alignment and comparation, target cluster, and invert-docking screening were undertaken t...
2011, 27 (05): 1214-1222.
DOI: 10.3866/PKU.WHXB20110525
4751
Abstract/Metrics
8460
PDF(10413KB)
Classification of Coenzyme-A Binding Proteins Based on Co-Factor Binding Modes
FAN Di, LIU Zhen-Ming, JIN Hong-Wei, ZHANG Liang-Ren
This study developed a mutual recognition of the proteins based on molecular classification, data mining strategies and ...
2011, 27 (05): 1223-1231.
DOI: 10.3866/PKU.WHXB20110439
4874
Abstract/Metrics
Supporting Info
1834
PDF(805KB)
PHYSICAL CHEMISTRY OF MATERIALS
Effects of Substrate-Target Distance and Si Co-Doping on the Properties of Al-Doped ZnO Films Deposited by Magnetron Sputtering
XU Hao, LU Fang, FU Zheng-Wen
Transparent conductive Al-doped ZnO (AZO) and Si-codoped AZO (AZO:Si) films were deposited on square quartz substrates b...
2011, 27 (05): 1232-1238.
DOI: 10.3866/PKU.WHXB20110422
4089
Abstract/Metrics
1998
PDF(872KB)
Preparation of PbS Quantum Dots Using Inorganic Sulfide as Precursor and Their Characterization
YUE Dong, ZHANG Jian-Wen, ZHANG Jing-Bo, LIN Yuan
PbS semiconductor quantum dots with different particle sizes were successfully prepared by the colloidal chemistry metho...
2011, 27 (05): 1239-1243.
DOI: 10.3866/PKU.WHXB20110513
6780
Abstract/Metrics
3472
PDF(761KB)
Facile Synthesis of Gold Nanoflowers in a Polyvinyl Pyrrolidone Alkaline Aqueous Solution
REN Yue-Ping, XU Cheng-Cheng, FANG Yun
Three-dimensional (3D) gold nanoflowers of 60-80 nm in diameter were successfully synthesized using polyvinyl pyrrolidon...
2011, 27 (05): 1244-1248.
DOI: 10.3866/PKU.WHXB20110441
6411
Abstract/Metrics
2863
PDF(1326KB)
Preparation of Sn
2
S
3
One-Dimensional Nanostructure Arrays by Chemical Vapor Deposition
PENG Yue-Hua, ZHOU Hai-Qing, LIU Xiang-Heng, HE Xiong-Wu, ZHAO Ding, HAI Kuo, ZHOU Wei-Chang, YUAN Hua-Jun, TANG Dong-Sheng
We prepared large-area, vertically aligned Sn2S3 one-dimensional nanostructure arrays using tin and sulfur powder as rea...
2011, 27 (05): 1249-1253.
DOI: 10.3866/PKU.WHXB20110430
4824
Abstract/Metrics
2293
PDF(866KB)
Preparation of BaTiO
3
-BaFe
12
O
19
Core-Shell Structure Particles by Homogeneous Coprecipitation
LIU Jian-Hua, YOU Dun, YU Mei, LI Song-Mei
BaTiO3-BaFe12O19 core-shell structure particles were obtained using the homogeneous coprecipitation method. The effects ...
2011, 27 (05): 1254-1260.
DOI: 10.3866/PKU.WHXB20110423
3993
Abstract/Metrics
2058
PDF(706KB)
Controlled Synthesis and Characterization of the Structure and Property of Fe
3
O
4
Nanoparticle-Graphene Oxide Composites
ZHANG Yi, CHEN Biao, YANG Zu-Pei, ZHANG Zhi-Jun
Fe3O4 nanoparticle-graphene oxide (MGO) composites were prepared by chemically binding carboxylic acid-modified Fe3O4 na...
2011, 27 (05): 1261-1266.
DOI: 10.3866/PKU.WHXB20110512
6196
Abstract/Metrics
3789
PDF(596KB)
Magnetic Polyacrylamide/Fe
3
O
4
Nanocomposite Hydrogel with High Mechanical Strength
XIANG Mei, HE Chang-Cheng, WANG Hui-Liang
Polyacrylamide (PAAm) hydrogels with very high mechanical strength were prepared using radiation-peroxidized micelles th...
2011, 27 (05): 1267-1272.
DOI: 10.3866/PKU.WHXB20110429
4924
Abstract/Metrics
2472
PDF(677KB)