Table of Contents

• Cover and Table of Contents for Vol.27 No. 11
• 2011, 27 (11): 0-0

• 1377Abstract/Metrics
• 1571 PDF(3031KB)

THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY

• Energy Characterization of Effect for Ions on the Structure of Water
• HE Jin-Song, YANG Hong-Wei, GAN Xiao-Ling, CAI Ran, ZHU Song-Ming, YU Yong, LI Jian-Ping, MU Tai-Hua, ZHU Wan-Peng
• At a concentration of 0-1.0 mol·L^-1 the effect of salts (KCl, MgCl₂, and CaCl₂) on the str...
• 2011, 27 (11): 2499-2504 DOI: 10.3866/PKU.WHXB20111102

• 4155Abstract/Metrics
• 1594 PDF(1140KB)

• ¹H NMR Investigation on Effect of Solute Concentration on the Hydrogen Bonding and Glass Transition of Three-Carbon Polyalcohol Aqueous Solutions
• YE Bin, GAO Cai, ZHAO Han, CHEN Kai-Song, YANG Suo, LIU Xiang-Nong
• We investigated the effects of solute concentration on the hydrogen bonding interactions of three-carbon polyalcohol aqueous solut...
• 2011, 27 (11): 2505-2511 DOI: 10.3866/PKU.WHXB20111103

• 2589Abstract/Metrics
• 1245 PDF(550KB)

• Preparation and Physicochemical Properties of Imidazolium Acetates and the Conductivities of Their Aqueous and Ethanol Solutions
• HOU Hai-Yun, HUANG Yin-Rong, WANG Sheng-Ze, BAI Bo-Feng
• The ionic liquids 1-methylimidazolium acetate ([Mim]Ac), 1,3-dimethylimidazolium acetate ([Mmim]Ac), and 1-ethyl-3-methylimidazoli...
• 2011, 27 (11): 2512-2520 DOI: 10.3866/PKU.WHXB20111120

• 4359Abstract/Metrics
• 1773 PDF(671KB)

• High Temporal and Spatial Resolution Measurements of the Rapid Efflorescence of Sea Salt Droplets
• TONG Hai-Jie, QIAN Zheng-Gang, REID Jonathan P., ZHANG Yun-Hong
• The rapid efflorescence of individual seawater droplets on polytetrafluoroethylene (PTFE, hydrophobic) and quartz (hydrophilic) su...
• 2011, 27 (11): 2521-2527 DOI: 10.3866/PKU.WHXB20111121

• 2121Abstract/Metrics
• 1245 PDF(1523KB)

• Mechanism of Rare Earth Cations on the Stability and Acidity of Y Zeolites
• YU Shan-Qing, TIAN Hui-Ping, ZHU Yu-Xia, DAI Zhen-Yu, LONG Jun
• The influences of rare earth (RE) cations on the stability and acidity of Y zeolites were studied by X-ray powder diffraction (XRD...
• 2011, 27 (11): 2528-2534 DOI: 10.3866/PKU.WHXB20111101

• 4418Abstract/Metrics
• 1778 PDF(843KB)

• Analysis and Assignment of the Fluorescence Spectra of a Salt/Methanol System
• WU Xiao-Jing, DAI Yun, ZHANG Nan, LI Jing
• Fluorescence spectra of CaCl₂, LiCl, and Ca(NO₃)₂ in methanol were investigated and the structure...
• 2011, 27 (11): 2535-2540 DOI: 10.3866/PKU.WHXB20111006

• 2597Abstract/Metrics
• 1201 PDF(1726KB)

• Spectral Research into Intramolecular Photoinduced Electron Transfer of Porphyrin-Anthraquinone Hybrids
• ZHAO Ping, XU Lian-Cai, MA Li
• A series of covalently linked porphyrin (Por)-anthraquinone (AQ) hybrids Por-C_n-AQ (n=1, 4, 10) with ...
• 2011, 27 (11): 2541-2546 DOI: 10.3866/PKU.WHXB20111021

• 3164Abstract/Metrics
• 1726 PDF(1576KB)

THEORETICAL AND COMPUTATIONAL CHEMISTRY

• Hydrogen Bond Lifetime Definitions and the Relaxation Mechanism in Water Solutions
• ZHANG Xia, ZHANG Qiang, ZHAO Dong-Xia
• The molecular dynamics behaviors in water solutions are determined by the hydrogen bond (H-bond) relaxations. The H-bond lifetime,...
• 2011, 27 (11): 2547-2552 DOI: 10.3866/PKU.WHXB20111107

• 3766Abstract/Metrics
• 1719 PDF(557KB)

• Calculation of the Binding Energies of Different Types of Hydrogen Bonds Using GGA Density Functional and Its Long-Range, Empirical Dispersion Correction Methods
• SUN Tao, WANG Yi-Bo
• We investigated eleven exchange-correlation energy density functionals including generalized gradient approximation (GGA) (PBE, PW...
• 2011, 27 (11): 2553-2558 DOI: 10.3866/PKU.WHXB20111017

• 4794Abstract/Metrics
• 3008 PDF(956KB)

• Dynamics Simulation of Photophysical Deactivation Pathway for Stacked Thymines
• DOU Yu-Sheng, LI Wei, YUAN Shuai, ZHANG Wen-Ying, LI An-Yang, SHU Kun-Xian, TANG Hong
• A semiclassical dynamics simulation study was undertaken to determine the photophysical deactivation of the lowest excited state o...
• 2011, 27 (11): 2559-2564 DOI: 10.3866/PKU.WHXB20111115

• 2314Abstract/Metrics
• 1091 PDF(930KB)

• Interaction between Mg-Porphyrin and Nitrogen, Oxygen Heterocyclic Compounds
• XU Hui-Ying, WANG Wei
• The interaction between nitrogen-oxygen heterocyclic compounds and a host (magnesium porphyrin) was investigated. The results show...
• 2011, 27 (11): 2565-2570 DOI: 10.3866/PKU.WHXB20111127

• 3186Abstract/Metrics
• 1781 PDF(1419KB)

ELECTROCHEMISTRY AND NEW ENERGY

• All-Lead Redox Flow Battery in a Fluoroboric Acid Electrolyte
• LIU Dong-Yang, CHENG Jie, PAN Jun-Qing, WEN Yue-Hua, CAO Gao-Ping, YANG Yu-Sheng
• An all-lead redox flow battery in a fluoroboric acid electrolyte is proposed. The same electrolyte was used as both the negative a...
• 2011, 27 (11): 2571-2576 DOI: 10.3866/PKU.WHXB20111105

• 2372Abstract/Metrics
• 1253 PDF(511KB)

• Optimization of the Photoelectric Performance of Large-Scale All-Flexible Dye-Sensitized Solar Cells
• LIN Xiao, WU Ming-Xing, AN Jiang, MIAO Qing-Qing, QIN Da, MA Ting-Li
• Highly efficient large scale flexible dye-sensitized solar cells (DSCs) were successfully designed and fabricated. By the introduc...
• 2011, 27 (11): 2577-2582 DOI: 10.3866/PKU.WHXB20111112

• 2795Abstract/Metrics
• 1290 PDF(693KB)

• Improved Graphene Film by Reducing Restacking for Lithium Ion Battery Applications
• YANG Xiao-Wei, HE Yu-Shi, LIAO Xiao-Zhen, MA Zi-Feng
• We prepared improved graphene films by freeze drying solvated graphene films, which greatly reduced the serious restacking of grap...
• 2011, 27 (11): 2583-2586 DOI: 10.3866/PKU.WHXB20111123

• 3765Abstract/Metrics
• 1712 PDF(531KB)

• Calcination Temperature Effects on the Electrochemical Performance of Li₂MnSiO₄/C Cathode Material for Lithium Ion Batteries
• WEI Yi, WANG Li-Juan, YAN Ji, SHA Ou, TANG Zhi-Yuan, MA Li
• As a new potential cathode material for lithium ion batteries, Li₂MnSiO₄/C was synthesized by a solution met...
• 2011, 27 (11): 2587-2592 DOI: 10.3866/PKU.WHXB20111124

• 2813Abstract/Metrics
• 1339 PDF(2231KB)

• Improvement of LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Materials by Nano-MgO Doping
• LI Jie-Bin, XU You-Long, XIONG Li-Long, WANG Jing-Ping
• Nano-sized M₃O₄ (M=Ni_1/3Co_1/3Mn_1/3) powder with a spinel structure was prep...
• 2011, 27 (11): 2593-2599 DOI: 10.3866/PKU.WHXB20111104

• 2437Abstract/Metrics
• 1322 PDF(2573KB)

• Electrochemical Behavior of LiV₃O₈ in Aqueous Li₂SO₄ Solution
• LIU Li, TIAN Fang-Hua, WANG Xian-You, ZHOU Meng
• Nanostructured LiV₃O₈ powder was synthesized by a low-temperature solid-state method. Scanning election micr...
• 2011, 27 (11): 2600-2604 DOI: 10.3866/PKU.WHXB20111126

• 2209Abstract/Metrics
• 1760 PDF(568KB)

• Self-supporting Macroscopic Carbon/Ni-Fiber Hybrid Electrodes Prepared by Catalytic Chemical Vapor Deposition Using Various Carbonaceous Compounds and Their Capacitive Deionization Performance
• WANG Xi-Wen, JIANG Fang-Ting, SUO Quan-Ling, FANG Yu-Zhu, LU Yong
• We prepared a series of self-supported macroscopic C/Ni-fiber hybrid electrodes by catalytic chemical vapor deposition (CCVD) usin...
• 2011, 27 (11): 2605-2612 DOI: 10.3866/PKU.WHXB20111116

• 2560Abstract/Metrics
• 1315 PDF(1768KB)

• Synthesis of ZnO on ITO and Etched Pattern Characterization by Scanning Electrochemical Microscopy
• TANG Jing, ZHENG Jing-Jing, XU Wei, TIAN Xiao-Chun, LIN Jian-Hang
• We report a direct electrochemical deposition process to produce ZnO nanorods or a ZnO thin film on an indium tin oxide (ITO) subs...
• 2011, 27 (11): 2613-2617 DOI: 10.3866/PKU.WHXB20111117

• 2986Abstract/Metrics
• 1705 PDF(1981KB)

• Effect of Rare Earth Ce³⁺ on the Microbial Induced Corrosion Behavior of Aluminum Alloy LY12CZ
• ZHAO Yong, XUE Wen-Bin, LIU Hong-Fang
• The effect of rare earth Ce³⁺ on the growth of sulfate reducing bacterial (SRB) and the microbial induced corrosion (MI...
• 2011, 27 (11): 2618-2624 DOI: 10.3866/PKU.WHXB20111109

• 2418Abstract/Metrics
• 1817 PDF(2760KB)

• Synthesis and Characterization of Nd₂Fe₁₄B/PANI and Its Function during the Oxygen Transfer Process
• SHI Ji-Cheng, XU Hong-Feng, LU Lu, FU Jie
• Nd₂Fe₁₄B/PANI magnetic powder was prepared by ball milling and in-situ polymerization. The samples were char...
• 2011, 27 (11): 2625-2631 DOI: 10.3866/PKU.WHXB20111133

• 1774Abstract/Metrics
• 1038 PDF(828KB)

CATALYSIS AND SURFACE SCIENCE

• Effect of Fe/Co Mass Ratio on Catalytic Performances of Cu-Fe-Co Based Catalysts for Mixed Alcohols Synthesis
• GUO Hai-Jun, XIONG Lian, LUO Cai-Rong, DING Fei, CHEN Xin-De, CHEN Yong
• A series of Cu-Fe-Co based catalysts with different mass fractions of Fe and Co were prepared by co-impregnation method. The catal...
• 2011, 27 (11): 2632-2638 DOI: 10.3866/PKU.WHXB20111114

• 2350Abstract/Metrics
• 1516 PDF(626KB)

• Effect of Cerium Addition on the Catalytic Performance of Cu-Fe/SiO₂ for the Synthesis of Lower Alcohols from Syngas
• MAO Dong-Sen, GUO Qiang-Sheng, YU Jun, HAN Lu-Peng, LU Guan-Zhong
• A series of Ce-Cu-Fe/SiO₂ catalysts with different Ce contents (mole fraction relative to SiO₂, 0-20%) were ...
• 2011, 27 (11): 2639-2645 DOI: 10.3866/PKU.WHXB20111125

• 2268Abstract/Metrics
• 1133 PDF(592KB)

• Effect of Preparation Methods on the Catalytic Activity of Ag-Ru/CeO₂ Catalyst for Ammonia Synthesis
• ZHANG Liu-Ming, LIN Jian-Xin, WANG Rong, WEI Ke-Mei
• Ag-Ru/CeO₂ catalysts were prepared by co-precipitation (CP), modified deposition precipitation (MDP), and incipient-wet...
• 2011, 27 (11): 2646-2650 DOI: 10.3866/PKU.WHXB20111129

• 2320Abstract/Metrics
• 1316 PDF(614KB)

• Dimethyl Ether Synthesis from CO₂ Hydrogenation over CuO-TiO₂-ZrO₂/HZSM-5 Catalysts
• WANG Song, MAO Dong-Sen, GUO Xiao-Ming, LU Guan-Zhong
• A series of CuO-TiO₂-ZrO₂ mixed oxides with different CuO mass fractions (50%-80%) were prepared by co-preci...
• 2011, 27 (11): 2651-2658 DOI: 10.3866/PKU.WHXB20111018

• 2398Abstract/Metrics
• 1346 PDF(618KB)

• Selective Oxidation Performance of Propane over Supported Vanadium Oxide Catalysts
• LIU Jian, ZHAO Zhen, WANG Hong-Xuan, DUAN Ai-Jun, JIANG Gui-Yuan
• A series of SBA-15 supported vanadium oxide catalysts with different active components were prepared by the method of incipient-we...
• 2011, 27 (11): 2659-2664 DOI: 10.3866/PKU.WHXB20111108

• 2968Abstract/Metrics
• 1051 PDF(849KB)

• Synthesis and Properties of Chemically Cross-Linked Poly(vinyl alcohol) Modified Quaterized Hydroxyethylcellulose Ethoxylate as Novel Alkaline Anion-Exchange Membrane
• LIU Ling-Ling, DING Lei, XU Li, QIAO Jin-Li, SHENG Jia-Wei
• Much attention has been paid to alkaline ion-exchange membranes with high alkaline stability. In this work, chemically cross-linke...
• 2011, 27 (11): 2665-2670 DOI: 10.3866/PKU.WHXB20111106

• 2692Abstract/Metrics
• 1525 PDF(1670KB)

• High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate
• LI Shuo-Qi, LIU Lu, TIAN Hui-Feng, HU Jing-Bo
• An effective approach to attach silver nanoparticles (AgNPs) directly onto an indium tin oxide (ITO) surface with high density was...
• 2011, 27 (11): 2671-2676 DOI: 10.3866/PKU.WHXB20111135

• 2519Abstract/Metrics
• 1027 PDF(2884KB)

• Preparation and Application of a Cr₂O₃-α-AlF₃ Catalyst with a High Specific Surface Area
• YU Hong-Bo, JIAWen-Zhi, PU Zhi-Ying, WANG Yue-Juan, LU Ji-Qing, TENG Bo-Tao, LUO Meng-Fei
• A high specific surface area Cr₂O₃-α-AlF₃ catalyst was prepared using a carbon hard templat...
• 2011, 27 (11): 2677-2681 DOI: 10.3866/PKU.WHXB20111014

• 2273Abstract/Metrics
• 1266 PDF(772KB)

PHOTOCHEMISTRY AND RADIATION CHEMISTRY

• Photophysical and Photobiological Properties of Coordination Polymers of Hypocrellin B Complexes Containing Magnesium and Zinc
• GUO Chuang-Long, OU Zhi-Ze, GAO Yun-Yan, WANG Zhong-Li, JIN He-Lin, LI Hai-Xia
• Hypocrellin B (HB) can chelate with Mg²⁺ and Zn²⁺ ions to form the coordination complexes Mg²⁺-HB...
• 2011, 27 (11): 2682-2690 DOI: 10.3866/PKU.WHXB20111132

• 2544Abstract/Metrics
• 1428 PDF(956KB)

• Inclusion Behavior of β-Cyclodextrin and Amphiphilic Telechelic Polymer C-PDMAEMA
• JIANG Jin-Qiang, JIANG Tao, ZHANG Cheng-Bang, CHENG Hao, LIU Xiao-Ya, ZHANG Sheng-Wen, CHEN Ming-Qing
• A novel photosensitive telechelic polymer C-PDMAEMA was prepared using 2-(dimethylamino) ethyl methacrylate (DAMEMA) as a monomer,...
• 2011, 27 (11): 2691-2696 DOI: 10.3866/PKU.WHXB20111019

• 2415Abstract/Metrics
• 1206 PDF(687KB)

BIOPHYSICAL CHEMISTRY

• Action Mechanism of Secondary Bond Forces on Chemical Immobilization of Horseradish Peroxidase
• LEI Qing-Juan, GAO Bao-Jiao, ZHANG Zheng-Guo
• Glycidyl methacrylate (GMA) was graft-polymerized onto micron-sized silica gel particles. Ethylenediamine (EDA) was bonded to the ...
• 2011, 27 (11): 2697-2704 DOI: 10.3866/PKU.WHXB20111122

• 3123Abstract/Metrics
• 1340 PDF(2774KB)

• Brownian Dynamics Simulation of Three Nonlinear Interactions on the Folding Process of Single Completely Stretched DNA Chain
• ZHANG Yong, XIAO Zhong-Dang
• The folding dynamics of a completely stretched dexoxyribonucleic acid (DNA) molecule chain is an important feature of single DNA m...
• 2011, 27 (11): 2705-2710 DOI: 10.3866/PKU.WHXB20111111

• 2062Abstract/Metrics
• 841 PDF(841KB)

PHYSICAL CHEMISTRY OF MATERIALS

• One-Step Synthesis of Fe@SiO₂ and Its Application in Cr(VI) Removal
• LI Yong-Chao, LI Tie-Long, WANG Xue, JIN Zhao-Hui
• Without using aqueous ammonia and a surface modifier, a facile one-step method was developed to fabricate Fe nanoparticles coated ...
• 2011, 27 (11): 2711-2718 DOI: 10.3866/PKU.WHXB20111134

• 2372Abstract/Metrics
• 1510 PDF(877KB)

• Confined Synthesis and Properties of Porous Silicon from Silica Aerogel Templates by Magnesiothermic Reduction
• CHEN Ke, BAO Zhi-Hao, LIU Dong, ZHU Xiu-Rong, ZHANG Zhi-Hua, ZHOU Bin
• Novel nanoporous silicon was successfully converted from SiO₂ aerogels by a template-confined magnesiothermic reduction...
• 2011, 27 (11): 2719-2725 DOI: 10.3866/PKU.WHXB20111110

• 3069Abstract/Metrics
• 1544 PDF(1434KB)

• Preparation of TiO₂ Nanotube Arrays with Different Cerium Mixing Morphology and Their Photoelectrochemical Response in Visible Light
• ZHANG Sheng-Han, LIANG Ke-Xin, TAN Yu
• Well-ordered TiO₂ nanotube arrays were prepared by electrochemical anodization onto a pure Ti sheet in an organic solut...
• 2011, 27 (11): 2726-2732 DOI: 10.3866/PKU.WHXB20111131

• 2451Abstract/Metrics
• 1413 PDF(1083KB)