Loading...
Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
Home
About Journal
About Journal
Editorial Board
Database Included
Impact Factor
Reader Center
Online First
Special Issue
Most Cited
Most Read
Most Downloaded
Volumn Content
Subject Content
Archive
Elsevier
Email Alert
Author Center
Online Submission
Submission Information
Review Online
Contact Us
中文
Current Issue
2011 Vol. 27,No. 11
Published: 27 October 2011
Current column
Table of Contents
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
THEORETICAL AND COMPUTATIONAL CHEMISTRY
ELECTROCHEMISTRY AND NEW ENERGY
CATALYSIS AND SURFACE SCIENCE
PHOTOCHEMISTRY AND RADIATION CHEMISTRY
BIOPHYSICAL CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.27 No. 11
2011, 27 (11): 0.
1952
Abstract/Metrics
1932
PDF(3031KB)
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
Energy Characterization of Effect for Ions on the Structure of Water
HE Jin-Song, YANG Hong-Wei, GAN Xiao-Ling, CAI Ran, ZHU Song-Ming, YU Yong, LI Jian-Ping, MU Tai-Hua, ZHU Wan-Peng
At a concentration of 0-1.0 mol·L-1 the effect of salts (KCl, MgCl2, and CaCl2) on the structure of water was stu...
2011, 27 (11): 2499-2504.
DOI: 10.3866/PKU.WHXB20111102
6667
Abstract/Metrics
1942
PDF(1140KB)
1
H NMR Investigation on Effect of Solute Concentration on the Hydrogen Bonding and Glass Transition of Three-Carbon Polyalcohol Aqueous Solutions
YE Bin, GAO Cai, ZHAO Han, CHEN Kai-Song, YANG Suo, LIU Xiang-Nong
We investigated the effects of solute concentration on the hydrogen bonding interactions of three-carbon polyalcohol aqu...
2011, 27 (11): 2505-2511.
DOI: 10.3866/PKU.WHXB20111103
5138
Abstract/Metrics
1676
PDF(550KB)
Preparation and Physicochemical Properties of Imidazolium Acetates and the Conductivities of Their Aqueous and Ethanol Solutions
HOU Hai-Yun, HUANG Yin-Rong, WANG Sheng-Ze, BAI Bo-Feng
The ionic liquids 1-methylimidazolium acetate ([Mim]Ac), 1,3-dimethylimidazolium acetate ([Mmim]Ac), and 1-ethyl-3-methy...
2011, 27 (11): 2512-2520.
DOI: 10.3866/PKU.WHXB20111120
6893
Abstract/Metrics
2474
PDF(671KB)
High Temporal and Spatial Resolution Measurements of the Rapid Efflorescence of Sea Salt Droplets
TONG Hai-Jie, QIAN Zheng-Gang, REID Jonathan P., ZHANG Yun-Hong
The rapid efflorescence of individual seawater droplets on polytetrafluoroethylene (PTFE, hydrophobic) and quartz (hydro...
2011, 27 (11): 2521-2527.
DOI: 10.3866/PKU.WHXB20111121
3990
Abstract/Metrics
1627
PDF(1523KB)
Mechanism of Rare Earth Cations on the Stability and Acidity of Y Zeolites
YU Shan-Qing, TIAN Hui-Ping, ZHU Yu-Xia, DAI Zhen-Yu, LONG Jun
The influences of rare earth (RE) cations on the stability and acidity of Y zeolites were studied by X-ray powder diffra...
2011, 27 (11): 2528-2534.
DOI: 10.3866/PKU.WHXB20111101
7904
Abstract/Metrics
2465
PDF(843KB)
Analysis and Assignment of the Fluorescence Spectra of a Salt/Methanol System
WU Xiao-Jing, DAI Yun, ZHANG Nan, LI Jing
Fluorescence spectra of CaCl2, LiCl, and Ca(NO3)2 in methanol were investigated and the structures and excitation energy...
2011, 27 (11): 2535-2540.
DOI: 10.3866/PKU.WHXB20111006
5099
Abstract/Metrics
1869
PDF(1726KB)
Spectral Research into Intramolecular Photoinduced Electron Transfer of Porphyrin-Anthraquinone Hybrids
ZHAO Ping, XU Lian-Cai, MA Li
A series of covalently linked porphyrin (Por)-anthraquinone (AQ) hybrids Por-Cn-AQ (n=1, 4, 10) with flexible different ...
2011, 27 (11): 2541-2546.
DOI: 10.3866/PKU.WHXB20111021
5770
Abstract/Metrics
2527
PDF(1576KB)
THEORETICAL AND COMPUTATIONAL CHEMISTRY
Hydrogen Bond Lifetime Definitions and the Relaxation Mechanism in Water Solutions
ZHANG Xia, ZHANG Qiang, ZHAO Dong-Xia
The molecular dynamics behaviors in water solutions are determined by the hydrogen bond (H-bond) relaxations. The H-bond...
2011, 27 (11): 2547-2552.
DOI: 10.3866/PKU.WHXB20111107
8119
Abstract/Metrics
2606
PDF(557KB)
Calculation of the Binding Energies of Different Types of Hydrogen Bonds Using GGA Density Functional and Its Long-Range, Empirical Dispersion Correction Methods
SUN Tao, WANG Yi-Bo
We investigated eleven exchange-correlation energy density functionals including generalized gradient approximation (GGA...
2011, 27 (11): 2553-2558.
DOI: 10.3866/PKU.WHXB20111017
8958
Abstract/Metrics
4582
PDF(956KB)
Dynamics Simulation of Photophysical Deactivation Pathway for Stacked Thymines
DOU Yu-Sheng, LI Wei, YUAN Shuai, ZHANG Wen-Ying, LI An-Yang, SHU Kun-Xian, TANG Hong
A semiclassical dynamics simulation study was undertaken to determine the photophysical deactivation of the lowest excit...
2011, 27 (11): 2559-2564.
DOI: 10.3866/PKU.WHXB20111115
4785
Abstract/Metrics
1442
PDF(930KB)
Interaction between Mg-Porphyrin and Nitrogen, Oxygen Heterocyclic Compounds
XU Hui-Ying, WANG Wei
The interaction between nitrogen-oxygen heterocyclic compounds and a host (magnesium porphyrin) was investigated. The re...
2011, 27 (11): 2565-2570.
DOI: 10.3866/PKU.WHXB20111127
6280
Abstract/Metrics
2642
PDF(1419KB)
ELECTROCHEMISTRY AND NEW ENERGY
All-Lead Redox Flow Battery in a Fluoroboric Acid Electrolyte
LIU Dong-Yang, CHENG Jie, PAN Jun-Qing, WEN Yue-Hua, CAO Gao-Ping, YANG Yu-Sheng
An all-lead redox flow battery in a fluoroboric acid electrolyte is proposed. The same electrolyte was used as both the ...
2011, 27 (11): 2571-2576.
DOI: 10.3866/PKU.WHXB20111105
4985
Abstract/Metrics
1675
PDF(511KB)
Optimization of the Photoelectric Performance of Large-Scale All-Flexible Dye-Sensitized Solar Cells
LIN Xiao, WU Ming-Xing, AN Jiang, MIAO Qing-Qing, QIN Da, MA Ting-Li
Highly efficient large scale flexible dye-sensitized solar cells (DSCs) were successfully designed and fabricated. By th...
2011, 27 (11): 2577-2582.
DOI: 10.3866/PKU.WHXB20111112
5198
Abstract/Metrics
1872
PDF(693KB)
Improved Graphene Film by Reducing Restacking for Lithium Ion Battery Applications
YANG Xiao-Wei, HE Yu-Shi, LIAO Xiao-Zhen, MA Zi-Feng
We prepared improved graphene films by freeze drying solvated graphene films, which greatly reduced the serious restacki...
2011, 27 (11): 2583-2586.
DOI: 10.3866/PKU.WHXB20111123
6160
Abstract/Metrics
2049
PDF(531KB)
Calcination Temperature Effects on the Electrochemical Performance of Li
2
MnSiO
4
/C Cathode Material for Lithium Ion Batteries
WEI Yi, WANG Li-Juan, YAN Ji, SHA Ou, TANG Zhi-Yuan, MA Li
As a new potential cathode material for lithium ion batteries, Li2MnSiO4/C was synthesized by a solution method. The the...
2011, 27 (11): 2587-2592.
DOI: 10.3866/PKU.WHXB20111124
4689
Abstract/Metrics
1800
PDF(2231KB)
Improvement of LiNi
1/3
Co
1/3
Mn
1/3
O
2
Cathode Materials by Nano-MgO Doping
LI Jie-Bin, XU You-Long, XIONG Li-Long, WANG Jing-Ping
Nano-sized M3O4 (M=Ni1/3Co1/3Mn1/3) powder with a spinel structure was prepared by sintering co-precipitated M(OH)2 at 5...
2011, 27 (11): 2593-2599.
DOI: 10.3866/PKU.WHXB20111104
4847
Abstract/Metrics
1922
PDF(2573KB)
Electrochemical Behavior of LiV
3
O
8
in Aqueous Li
2
SO
4
Solution
LIU Li, TIAN Fang-Hua, WANG Xian-You, ZHOU Meng
Nanostructured LiV3O8 powder was synthesized by a low-temperature solid-state method. Scanning election microscopy (SEM)...
2011, 27 (11): 2600-2604.
DOI: 10.3866/PKU.WHXB20111126
4215
Abstract/Metrics
2134
PDF(568KB)
Self-supporting Macroscopic Carbon/Ni-Fiber Hybrid Electrodes Prepared by Catalytic Chemical Vapor Deposition Using Various Carbonaceous Compounds and Their Capacitive Deionization Performance
WANG Xi-Wen, JIANG Fang-Ting, SUO Quan-Ling, FANG Yu-Zhu, LU Yong
We prepared a series of self-supported macroscopic C/Ni-fiber hybrid electrodes by catalytic chemical vapor deposition (...
2011, 27 (11): 2605-2612.
DOI: 10.3866/PKU.WHXB20111116
4994
Abstract/Metrics
1997
PDF(1768KB)
Synthesis of ZnO on ITO and Etched Pattern Characterization by Scanning Electrochemical Microscopy
TANG Jing, ZHENG Jing-Jing, XU Wei, TIAN Xiao-Chun, LIN Jian-Hang
We report a direct electrochemical deposition process to produce ZnO nanorods or a ZnO thin film on an indium tin oxide ...
2011, 27 (11): 2613-2617.
DOI: 10.3866/PKU.WHXB20111117
5757
Abstract/Metrics
2364
PDF(1981KB)
Effect of Rare Earth Ce
3+
on the Microbial Induced Corrosion Behavior of Aluminum Alloy LY12CZ
ZHAO Yong, XUE Wen-Bin, LIU Hong-Fang
The effect of rare earth Ce3+ on the growth of sulfate reducing bacterial (SRB) and the microbial induced corrosion (MIC...
2011, 27 (11): 2618-2624.
DOI: 10.3866/PKU.WHXB20111109
5038
Abstract/Metrics
2358
PDF(2760KB)
Synthesis and Characterization of Nd
2
Fe
14
B/PANI and Its Function during the Oxygen Transfer Process
SHI Ji-Cheng, XU Hong-Feng, LU Lu, FU Jie
Nd2Fe14B/PANI magnetic powder was prepared by ball milling and in-situ polymerization. The samples were characterized by...
2011, 27 (11): 2625-2631.
DOI: 10.3866/PKU.WHXB20111133
3886
Abstract/Metrics
1487
PDF(828KB)
CATALYSIS AND SURFACE SCIENCE
Effect of Fe/Co Mass Ratio on Catalytic Performances of Cu-Fe-Co Based Catalysts for Mixed Alcohols Synthesis
GUO Hai-Jun, XIONG Lian, LUO Cai-Rong, DING Fei, CHEN Xin-De, CHEN Yong
A series of Cu-Fe-Co based catalysts with different mass fractions of Fe and Co were prepared by co-impregnation method....
2011, 27 (11): 2632-2638.
DOI: 10.3866/PKU.WHXB20111114
4909
Abstract/Metrics
2274
PDF(626KB)
Effect of Cerium Addition on the Catalytic Performance of Cu-Fe/SiO
2
for the Synthesis of Lower Alcohols from Syngas
MAO Dong-Sen, GUO Qiang-Sheng, YU Jun, HAN Lu-Peng, LU Guan-Zhong
A series of Ce-Cu-Fe/SiO2 catalysts with different Ce contents (mole fraction relative to SiO2, 0-20%) were prepared by ...
2011, 27 (11): 2639-2645.
DOI: 10.3866/PKU.WHXB20111125
4453
Abstract/Metrics
1533
PDF(592KB)
Effect of Preparation Methods on the Catalytic Activity of Ag-Ru/CeO
2
Catalyst for Ammonia Synthesis
ZHANG Liu-Ming, LIN Jian-Xin, WANG Rong, WEI Ke-Mei
Ag-Ru/CeO2 catalysts were prepared by co-precipitation (CP), modified deposition precipitation (MDP), and incipient-wetn...
2011, 27 (11): 2646-2650.
DOI: 10.3866/PKU.WHXB20111129
4378
Abstract/Metrics
1859
PDF(614KB)
Dimethyl Ether Synthesis from CO
2
Hydrogenation over CuO-TiO
2
-ZrO
2
/HZSM-5 Catalysts
WANG Song, MAO Dong-Sen, GUO Xiao-Ming, LU Guan-Zhong
A series of CuO-TiO2-ZrO2 mixed oxides with different CuO mass fractions (50%-80%) were prepared by co-precipitation and...
2011, 27 (11): 2651-2658.
DOI: 10.3866/PKU.WHXB20111018
4397
Abstract/Metrics
1770
PDF(618KB)
Selective Oxidation Performance of Propane over Supported Vanadium Oxide Catalysts
LIU Jian, ZHAO Zhen, WANG Hong-Xuan, DUAN Ai-Jun, JIANG Gui-Yuan
A series of SBA-15 supported vanadium oxide catalysts with different active components were prepared by the method of in...
2011, 27 (11): 2659-2664.
DOI: 10.3866/PKU.WHXB20111108
5777
Abstract/Metrics
1371
PDF(849KB)
Synthesis and Properties of Chemically Cross-Linked Poly(vinyl alcohol) Modified Quaterized Hydroxyethylcellulose Ethoxylate as Novel Alkaline Anion-Exchange Membrane
LIU Ling-Ling, DING Lei, XU Li, QIAO Jin-Li, SHENG Jia-Wei
Much attention has been paid to alkaline ion-exchange membranes with high alkaline stability. In this work, chemically c...
2011, 27 (11): 2665-2670.
DOI: 10.3866/PKU.WHXB20111106
5424
Abstract/Metrics
2186
PDF(1670KB)
High Density Attachment of Silver Nanoparticles onto an NH
2
+
Ion Implanted Indium Tin Oxide Glass Substrate
LI Shuo-Qi, LIU Lu, TIAN Hui-Feng, HU Jing-Bo
An effective approach to attach silver nanoparticles (AgNPs) directly onto an indium tin oxide (ITO) surface with high d...
2011, 27 (11): 2671-2676.
DOI: 10.3866/PKU.WHXB20111135
4954
Abstract/Metrics
1445
PDF(2884KB)
Preparation and Application of a Cr
2
O
3
-α-AlF
3
Catalyst with a High Specific Surface Area
YU Hong-Bo, JIAWen-Zhi, PU Zhi-Ying, WANG Yue-Juan, LU Ji-Qing, TENG Bo-Tao, LUO Meng-Fei
A high specific surface area Cr2O3-α-AlF3 catalyst was prepared using a carbon hard template method. The synthesis...
2011, 27 (11): 2677-2681.
DOI: 10.3866/PKU.WHXB20111014
5087
Abstract/Metrics
1665
PDF(772KB)
PHOTOCHEMISTRY AND RADIATION CHEMISTRY
Photophysical and Photobiological Properties of Coordination Polymers of Hypocrellin B Complexes Containing Magnesium and Zinc
GUO Chuang-Long, OU Zhi-Ze, GAO Yun-Yan, WANG Zhong-Li, JIN He-Lin, LI Hai-Xia
Hypocrellin B (HB) can chelate with Mg2+ and Zn2+ ions to form the coordination complexes Mg2+-HB and Zn2+-HB, which con...
2011, 27 (11): 2682-2690.
DOI: 10.3866/PKU.WHXB20111132
5197
Abstract/Metrics
1880
PDF(956KB)
Inclusion Behavior of
β
-Cyclodextrin and Amphiphilic Telechelic Polymer C-PDMAEMA
JIANG Jin-Qiang, JIANG Tao, ZHANG Cheng-Bang, CHENG Hao, LIU Xiao-Ya, ZHANG Sheng-Wen, CHEN Ming-Qing
A novel photosensitive telechelic polymer C-PDMAEMA was prepared using 2-(dimethylamino) ethyl methacrylate (DAMEMA) as ...
2011, 27 (11): 2691-2696.
DOI: 10.3866/PKU.WHXB20111019
4551
Abstract/Metrics
1550
PDF(687KB)
BIOPHYSICAL CHEMISTRY
Action Mechanism of Secondary Bond Forces on Chemical Immobilization of Horseradish Peroxidase
LEI Qing-Juan, GAO Bao-Jiao, ZHANG Zheng-Guo
Glycidyl methacrylate (GMA) was graft-polymerized onto micron-sized silica gel particles. Ethylenediamine (EDA) was bond...
2011, 27 (11): 2697-2704.
DOI: 10.3866/PKU.WHXB20111122
5707
Abstract/Metrics
1926
PDF(2774KB)
Brownian Dynamics Simulation of Three Nonlinear Interactions on the Folding Process of Single Completely Stretched DNA Chain
ZHANG Yong, XIAO Zhong-Dang
The folding dynamics of a completely stretched dexoxyribonucleic acid (DNA) molecule chain is an important feature of si...
2011, 27 (11): 2705-2710.
DOI: 10.3866/PKU.WHXB20111111
4242
Abstract/Metrics
1230
PDF(841KB)
PHYSICAL CHEMISTRY OF MATERIALS
One-Step Synthesis of Fe@SiO
2
and Its Application in Cr(VI) Removal
LI Yong-Chao, LI Tie-Long, WANG Xue, JIN Zhao-Hui
Without using aqueous ammonia and a surface modifier, a facile one-step method was developed to fabricate Fe nanoparticl...
2011, 27 (11): 2711-2718.
DOI: 10.3866/PKU.WHXB20111134
4880
Abstract/Metrics
1955
PDF(877KB)
Confined Synthesis and Properties of Porous Silicon from Silica Aerogel Templates by Magnesiothermic Reduction
CHEN Ke, BAO Zhi-Hao, LIU Dong, ZHU Xiu-Rong, ZHANG Zhi-Hua, ZHOU Bin
Novel nanoporous silicon was successfully converted from SiO2 aerogels by a template-confined magnesiothermic reduction ...
2011, 27 (11): 2719-2725.
DOI: 10.3866/PKU.WHXB20111110
5709
Abstract/Metrics
2164
PDF(1434KB)
Preparation of TiO
2
Nanotube Arrays with Different Cerium Mixing Morphology and Their Photoelectrochemical Response in Visible Light
ZHANG Sheng-Han, LIANG Ke-Xin, TAN Yu
Well-ordered TiO2 nanotube arrays were prepared by electrochemical anodization onto a pure Ti sheet in an organic soluti...
2011, 27 (11): 2726-2732.
DOI: 10.3866/PKU.WHXB20111131
4864
Abstract/Metrics
1881
PDF(1083KB)