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Acta Phys. -Chim. Sin.
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中文
Current Issue
2012 Vol. 28,No. 02
Published:11 January 2012
Date of publication: 11 January 2012
Current column
Table of Contents
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
THEORETICAL AND COMPUTATIONAL CHEMISTRY
ELECTROCHEMISTRY AND NEW ENERGY
SOFT MATTER
CATALYSIS AND SURFACE SCIENCE
PHOTOCHEMISTRY AND RADIATION CHEMISTRY
BIOPHYSICAL CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.28 No. 2
2012, 28 (02): 0.
1487
Abstract/Metrics
1559
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THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
Mirror Symmetry Breaking of
cis
-[Ni(NCS)
2
tren]: Special Chiral Conformations of Chelate Rings
LIU Cheng-Yong, YAN Jian-Xin, LIN Yi-Ji, LI Dan, FANG Xue-Ming, ZHANG Hui
In order to explore the chiral origin of cis-[Ni(NCS)2tren] [tren: tris(2-aminoethyl) amine], a pair of chiral crystals ...
2012, 28 (02): 257-264.
DOI: 10.3866/PKU.WHXB201112091
3248
Abstract/Metrics
Supporting Info
1640
PDF(786KB)
Synthesis, Characterization and Properties of Salen-Type Complexes
LIU Jia, GUO Li-Qin, ZHANG Xiao-Hong, RUAN Wen-Juan, ZHU Zhi-Ang
Two new Salen ligands H2L1 (N,N'-bis(3-dimethoxy-salicylidene)-4,5-dimethoxy-1,2- phenylenediamine) and H2L2 (N,N'-bis(3...
2012, 28 (02): 265-272.
DOI: 10.3866/PKU.WHXB201111251
3765
Abstract/Metrics
1662
PDF(689KB)
Interlayer Reaction of Thiosulfate in a Confined Region of Layered Double Hydroxides
WANG Li-Geng, YUAN Ting, LI Yuan, SHI Wei, NI Zhe-Ming
The thiosulfate anion (S2O32-) was intercalated into a ZnAl layered double hydroxide (LDH), and its oxidation reaction w...
2012, 28 (02): 273-282.
DOI: 10.3866/PKU.WHXB201111243
4526
Abstract/Metrics
1756
PDF(2843KB)
Formation and Spectral Properties of Perylene Oligomers
LIU Li-Min, ZHANG Xian-Fu
We report the conditions required for the formation of perylene oligomers, which are closely related to the crystal nucl...
2012, 28 (02): 283-289.
DOI: 10.3866/PKU.WHXB201111292
3226
Abstract/Metrics
1710
PDF(2837KB)
Synthesis, Characterization and Thermal Decomposition Mechanism of Rare Earth Complexes with 5-Chloro-2-methoxybenzoic Acid and 1,10-Phenanthroline
ZHANG Jie, WANG Juan-Fen, ZHANG Jian-Jun
Three rare earth complexes of [Ln(5-Cl-2MOBA)3phen]2 (Ln=Nd(1), Eu(2), Ho(3); 5-Cl- 2MOBA: 5-chloro-2-methoxybenzoate; p...
2012, 28 (02): 290-296.
DOI: 10.3866/PKU.WHXB201112121
2669
Abstract/Metrics
1694
PDF(784KB)
Solvo-Thermal Synthesis of Cu
2
O Micro-Spheres and Their Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate
LUO Xiao-Lin, HAN Yin-Feng, YANG De-Suo, CHEN Ya-Shao
Cu2O micro-spheres were fabricated by a solvothermal method using poly vinylpyrrolidone (PVP) as an additive. The influe...
2012, 28 (02): 297-302.
DOI: 10.3866/PKU.WHXB201112012
3218
Abstract/Metrics
1723
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THEORETICAL AND COMPUTATIONAL CHEMISTRY
Effects of Mode-Mode Coupling on Vibrational Frequency Blue Shift in Improper H-Bonded Systems
KONG Xiang-Lei
Bond shortening of NH/CH due to improper hydrogen bonding is always thought to be accompanied by a blue shift in its cor...
2012, 28 (02): 303-308.
DOI: 10.3866/PKU.WHXB201112013
3298
Abstract/Metrics
1370
PDF(840KB)
Monte Carlo Simulation on the Structures of a Nanoparticle/ Copolymer Mixed System
LIU Guan-Feng, HUANG Jian-Hua
The structures of a nanoparticle/copolymer mixed system were studied using lattice dynamic Monte Carlo simulations. Each...
2012, 28 (02): 309-314.
DOI: 10.3866/PKU.WHXB201111211
3234
Abstract/Metrics
2082
PDF(2056KB)
Adsorption Structure and Energy of Pyridine Confined inside Zeolite Pores
HAN Bing, CHU Yue-Ying, ZHENG An-Min, DENG Feng
The performance of different exchange-correlation functionals for the description of the interaction of pyridine with di...
2012, 28 (02): 315-323.
DOI: 10.3866/PKU.WHXB201111232
4070
Abstract/Metrics
1894
PDF(2361KB)
Electronic Structures and Optical Properties of Cu:MgF
2
Crystal
ZHANG Zhi-Yu, HAN Pei-De, ZHANG Cai-Li, ZHANG Xue, SUN Xiang-Lei, LI Yu-Ping
Based on the density functional pseudopotential method, the geometries, electronic structures, and optical properties of...
2012, 28 (02): 324-330.
DOI: 10.3866/PKU.WHXB201112061
4909
Abstract/Metrics
2339
PDF(1698KB)
Enhanced Bonding between Noble Metal Adatoms and Graphene with Point Defects
XIE Peng-Yang, ZHUANG Gui-Lin, LÜ Yong-An, WANG Jian-Guo, LI Xiao-Nian
The adhesion of Ag, Au, and Pt adatoms on pristine graphene and that containing point defects including N-substitution, ...
2012, 28 (02): 331-337.
DOI: 10.3866/PKU.WHXB201111021
8985
Abstract/Metrics
2666
PDF(1552KB)
ELECTROCHEMISTRY AND NEW ENERGY
Effect of Doping with Ti
4+
Ion on the Electrochemical Performance of LiFe
0.6
Mn
0.4
PO
4
/C
GAO Ping, TAN Zhuo, CHENG Fu-Quan, ZHOU Heng-Hui, TAN Song-Ting
Ti-doped LiFe0.6Mn0.4PO4/C materials were synthesized by a solid-state method. The structures, morphologies, and electro...
2012, 28 (02): 338-342.
DOI: 10.3866/PKU.WHXB201111242
3191
Abstract/Metrics
1865
PDF(2071KB)
Synthesis and Electrochemical Performance of LiCoPO
4
by Sol-Gel Method
WANG Shao-Liang, TANG Zhi-Yuan, SHA Ou, YAN Ji
High potential cathode material LiCoPO4 was synthesized by sol-gel method. The effects of different sintering conditions...
2012, 28 (02): 343-348.
DOI: 10.3866/PKU.WHXB201111031
3119
Abstract/Metrics
1808
PDF(1051KB)
High Rate Capability and Cycling Stability of Li
1.07
Mn
1.93
O
4
Nanoflakes Synthesized via Gel-Combustion Method
MAO Jing, DAI Ke-Hua, ZHAI Yu-Chun
Li1.07Mn1.93O4 nanoflakes were synthesized by a gel-combustion method using polyvinylpyrrolidone (PVP) as the polymer ch...
2012, 28 (02): 349-354.
DOI: 10.3866/PKU.WHXB201112052
3524
Abstract/Metrics
1580
PDF(716KB)
Application of Nanoporous Perovskite La
1-
x
Ca
x
CoO
3
in an Al-H
2
O
2
Semi Fuel Cell
ZHUANG Shu-Xin, LIU Su-Qin, ZHANG Jin-Bao, TU Fei-Yue, HUANG Hong-Xia, HUANG Ke-Long, LI Yan-Hua
Perovskite-type series of compounds La1-xCaxCoO3 (x=0.2, 0.4, 0.5) were synthesized by a modified amorphous citrate prec...
2012, 28 (02): 355-360.
DOI: 10.3866/PKU.WHXB201111293
2841
Abstract/Metrics
1480
PDF(1022KB)
Restructured Carbon Aerogels and Their Electrochemical Performances
XU Zi-Jie, JI Tao, ZHAO Lei, WANG Wei-Yan, YANG Chun-Yan, GAN Li-Hua
Restructured carbon aerogels (RCAs) were obtained by annealing carbon aerogels (CAs) in sodium melt at 800 °C for 3 ...
2012, 28 (02): 361-366.
DOI: 10.3866/PKU.WHXB201112063
3310
Abstract/Metrics
1778
PDF(954KB)
Activated Carbon-Based Supercapacitors Using Li
2
SO
4
Aqueous Electrolyte
SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei
In this work, we prepared activated carbon-based symmetric supercapacitors using Li2SO4 aqueous electrolyte instead of H...
2012, 28 (02): 367-372.
DOI: 10.3866/PKU.WHXB201112131
4017
Abstract/Metrics
2820
PDF(730KB)
Electropolymerization and Characterization of Fast Charge-Discharge PPy/F-SWNTs Composite Materials
ZHU Jian-Bo, XU You-Long, WANG Jie, WANG Jing-Ping
Fast charge-discharge composite materials of conducting polypyrrole and functionalized single-walled carbon nanotubes do...
2012, 28 (02): 373-380.
DOI: 10.3866/PKU.WHXB201112021
7082
Abstract/Metrics
2757
PDF(3650KB)
Photoelectric Properties of Mo Doped TiO
2
Thin Films Deposited by DC Reactive Magnetron Sputtering
YAN Bing-Xi, LUO Sheng-Yun, SHEN Jie
Nanocrystalline TiO2 thin films doped with different concentrations of Mo were deposited by direct current (DC) reactive...
2012, 28 (02): 381-386.
DOI: 10.3866/PKU.WHXB201112123
3288
Abstract/Metrics
1640
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Glycerol-Assisted Synthesis and Electrochemical Properties of Co
3
O
4
Nanowires
ZHANG Guo-Liang, ZHAO Dan, GUO Pei-Zhi, WEI Zhong-Bin, ZHAO Xiu-Song
Cobalt oxide (Co3O4) nanowires were controllably synthesized using glycerol and Co(NO3)2 as reagents and adjustment of t...
2012, 28 (02): 387-392.
DOI: 10.3866/PKU.WHXB201111241
4073
Abstract/Metrics
1990
PDF(1052KB)
Anticorrosion Properties of Modified Nano-TiO
2
Films Prepared by Sol-Gel Method
ZHU Yan-Feng, ZHANG Juan, ZHANG Yi-Yong, DING Min, QI Hai-Qing, DU Rong-Gui, LIN Chang-Jian
TiO2 and B-Fe-Ce-modified TiO2 films were synthesized on the surfaces of 316L stainless steel (316L SS) substrates using...
2012, 28 (02): 393-398.
DOI: 10.3866/PKU.WHXB201112163
3829
Abstract/Metrics
1610
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Steric Effect of Alkyl Substituted Piperidin-4-one Oximes for Corrosion Control of Mild Steel in H
2
SO
4
Medium
SENTHILKUMAR Annamalai, THARINI Kumaravel, SETHURAMAN Mathur Gopalakrishnan
Three synthesized piperidin-4-one oximes, 3-ethyl-2,6-diphenyl-piperidin-4-one oxime (A), 1- methyl-3-isopropyl-2,6-diph...
2012, 28 (02): 399-406.
DOI: 10.3866/PKU.WHXB201112142
2392
Abstract/Metrics
1520
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Corrosion Protection of Ceria Particles in Mg-Rich Primer on AZ91D Magnesium Alloy
WANG Ya-Ping, ZHAO Xu-Hui, LU Xiang-Yu, ZUO Yu
The effect of ceria particles on the corrosion resistance of Mg-rich primer on AZ91D magnesium alloy was studied using t...
2012, 28 (02): 407-413.
DOI: 10.3866/PKU.WHXB201112164
3205
Abstract/Metrics
1395
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Initial Behavior of the Electroless Nickel Deposition on Pretreated Aluminum
YANG Li-Kun, YANG Fang-Zu, TIAN Zhong-Qun, ZHOU Shao-Min
The initial behavior of electroless nickel deposition on aluminum pretreated by nickel immersion and electroless nickel ...
2012, 28 (02): 414-420.
DOI: 10.3866/PKU.WHXB201112011
3089
Abstract/Metrics
1732
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Electrochemical Oxidation of
p
-Methoxy Toluene in BMIMBF4 Ionic Liquid
ZHU Ying-Hong, ZENG Hong-Yan, LI Shan-Shan, LU Zai-Xiang, MA Chun-An
The electrochemical oxidation behavior of p-methoxy toluene was studied in an ionic liquid of 1-butyl-3-methylimidazoliu...
2012, 28 (02): 421-426.
DOI: 10.3866/PKU.WHXB201112122
3659
Abstract/Metrics
1446
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SOFT MATTER
Preparation and Micro-Tribological Study on Dually Mixed Self-Assembled Monolayers
LIU Lei, SONG Shi-Yong, ZHANG Ping-Yu
A series of dually mixed self-assembled monolayers were prepared by a simple step-by-step method. Four carbonyl chloride...
2012, 28 (02): 427-432.
DOI: 10.3866/PKU.WHXB201111213
2933
Abstract/Metrics
1303
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CATALYSIS AND SURFACE SCIENCE
In situ
Infrared Characterization of Methanol Adsorption on ZrO
2
Modified Cu Catalysts
WU Gui-Sheng, MAO Dong-Sen, LU Guan-Zhong, CAO Yong, FAN Kang-Nian
The adsorption and reaction of methanol on Cu and ZrO2/Cu were investigated using in situ infrared diffuse reflectance s...
2012, 28 (02): 433-436.
DOI: 10.3866/PKU.WHXB201112062
3273
Abstract/Metrics
1056
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Enhanced MnO
2
Nanorods to CO and Volatile Organic Compounds Oxidative Activity by Platinum Nanoparticles
WU Xiao-Qin, ZONG Rui-Long, ZHU Yong-Fa
Pure-phase α-MnO2 and δ-MnO2 nanorods were synthesized through an easy solution-based hydrothermal method. P...
2012, 28 (02): 437-444.
DOI: 10.3866/PKU.WHXB201112082
4815
Abstract/Metrics
1633
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Preferential Oxidation of CO over Photoreduced Pt/TiO
2
Catalysts in H
2
-Rich Stream
WANG Fang, WANG Cai-Hong, LIU Guo-Xia
The optimum reaction parameters for CO oxidation in the presence and absence of H2 have been investigated by photoreduct...
2012, 28 (02): 445-449.
DOI: 10.3866/PKU.WHXB201111244
2909
Abstract/Metrics
1452
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Hydrogen Evolution by Photocatalytic Steam Reforming of Methane over Pt/TiO
2
LI Cao-Long, CHEN Wei, YUAN Jian, SHANGGUAN Wen-Feng
Photocatalytic reaction of CH4 gas with H2O vapor over Pt/TiO2 at around room temperature (ca 323 K) was examined in a f...
2012, 28 (02): 450-456.
DOI: 10.3866/PKU.WHXB201112141
3451
Abstract/Metrics
2507
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Photocatalytic Property and Reaction Mechanism of (Ni-Mo)/TiO
2
Nano Thin Film Evaluated with Congo Red
LI Ai-Chang, LI Gui-Hua, ZHENG Yan, FENG Ling-Ling, ZHENG Yan-Jun
(Ni-Mo)/TiO2 composite thin films were prepared by composite electroplating at a constant current. The surface morpholog...
2012, 28 (02): 457-464.
DOI: 10.3866/PKU.WHXB201112081
3890
Abstract/Metrics
1785
PDF(873KB)
PHOTOCHEMISTRY AND RADIATION CHEMISTRY
Synthesis, Fluorescence and DNA Photocleavage Activity of Phenothiazine-Corrole Gallium(III) Complexes
SHI Lei, JIANG Huan-Feng, YIN Wei, WANG Hua-Hua, WANG Hui, ZHANG Lei, JI Liang-Nian, LIU Hai-Yang
Phenothiazine (PTZ)-corrole dyads 1-3 and their gallium(III) complexes 4-6 have been synthesized and characterized. The ...
2012, 28 (02): 465-469.
DOI: 10.3866/PKU.WHXB201111291
3393
Abstract/Metrics
1409
PDF(607KB)
BIOPHYSICAL CHEMISTRY
Effects of Rare Earth Ions on the Interaction between Nano TiO
2
and Bovine Serum Albumin in the Presence of Ultrasound
GAO Xiao-Ya, WEN Wen, SONG Zhi-Ying, ZHANG Ai-Ping, HAO Juan, HUANG Qian
The effects of rare earth ions (La3+ , Gd3+ , Yb3+ ) on the interactions between nano TiO2 and bovine serum albumin (BSA...
2012, 28 (02): 470-478.
DOI: 10.3866/PKU.WHXB201112051
3221
Abstract/Metrics
1524
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Effect of α-Synuclein (1-17) Peptide for Cu
2+
-Bound and Metal-Free Forms by Molecular Dynamics Simulations
CAO Jian, CAO Zan-Xia, ZHAO Li-Ling, WANG Ji-Hua
The Cu2+-bound and metal-free α-synuclein (1-17) peptides were simulated with the GROMOS 43A1 force field in the G...
2012, 28 (02): 479-488.
DOI: 10.3866/PKU.WHXB201111231
3455
Abstract/Metrics
2081
PDF(1807KB)
PHYSICAL CHEMISTRY OF MATERIALS
Microstructure, Electrical and Gas Sensing Properties of Meso-Porous Silicon and Macro-Porous Silicon
SUN Peng, HU Ming, LI Ming-Da, MA Shuang-Yun
Two different kinds of porous silicon (PS) were grown by electrochemical corrosion in a double-tank cell on the surface ...
2012, 28 (02): 489-493.
DOI: 10.3866/PKU.WHXB201111212
3425
Abstract/Metrics
1787
PDF(701KB)
An Optical Microscopy Study on the Solvent-Induced Crystalline Morphology of Ladder Polyphenylsilsesquioxane
LI Pei-Fang, YAN Shou-Ke, REN Zhong-Jie
Spherulites of rigid chain ladder polyphenylsilsesquioxane (PPSQ) were produced through solvent-induced crystallization....
2012, 28 (02): 494-498.
DOI: 10.3866/PKU.WHXB201111233
3064
Abstract/Metrics
1376
PDF(1158KB)