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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
2012 Vol. 28,No. 10
Published: 26 September 2012
Current column
Table of Contents
Preface
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
THEORETICAL AND COMPUTATIONAL CHEMISTRY
ELECTROCHEMISTRY AND NEW ENERGY
SOFT MATTER
CATALYSIS AND SURFACE SCIENCE
BIOPHYSICAL CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.28 No. 10
2012, 28 (10): 0.
1457
Abstract/Metrics
1520
PDF(8444KB)
Preface
Physical Chemistry at Peking University: Retrospect and Prospect
LIU Zhong-Fan
2012, 28 (10): 2231-2236.
DOI: 10.3866/PKU.WHXB201209181
3140
Abstract/Metrics
1947
PDF(364KB)
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
Construction and Conductance Measurement of Single Molecule Junctions
AI Yong, ZHANG Hao-Li
Molecular electronics has become an important research field in the past decade, and molecular devices can be used as mo...
2012, 28 (10): 2237-2248.
DOI: 10.3866/PKU.WHXB201209102
5248
Abstract/Metrics
2407
PDF(3135KB)
THEORETICAL AND COMPUTATIONAL CHEMISTRY
An Empirical Additive Model for Aqueous Solubility Computation: Success and Limitations
DUAN Bao-Gen, LI Yan, LI Jie, CHENG Tie-Jun, WANG Ren-Xiao
We have developed a new empirical model, namely XLOGS, for computing aqueous solubility (logS) of organic compounds. Thi...
2012, 28 (10): 2249-2257.
DOI: 10.3866/PKU.WHXB201209171
3560
Abstract/Metrics
1383
PDF(1431KB)
ELECTROCHEMISTRY AND NEW ENERGY
Influence of Ionic Strength on DNA Mediated Charge Transport——Experiments and the Related Debye-Hückel Theory
JI Zhong-Hua, ZHU Bin, LI Jing-Jian, CAI Sheng-Min, YUAN Gu, XU Dong-Sheng
The ionic strength dependence of DNA mediated charge transport was studied on a DNA binding polyamide-modified electrode...
2012, 28 (10): 2258-2262.
DOI: 10.3866/PKU.WHXB201208281
3931
Abstract/Metrics
1537
PDF(782KB)
Nanocomposite Cathode Catalyst with High Methanol Tolerance and Durability
ZHENG Ning, ZHU Chun-Mei, SUN Bin, SHI Zu-Jin, LIU Yan, WANG Yuan
We report the preparation, characterization and elelctrocatalytic properties of a novel nanocomposite cathode catalyst (...
2012, 28 (10): 2263-2268.
DOI: 10.3866/PKU.WHXB201208171
4396
Abstract/Metrics
1525
PDF(1714KB)
Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor
HUANG Wen, ZHAO Jin, KANG Qi, XU Kaichen, YU Zhen, WANG Jian, MA Yan-Wen, HUANG Wei
Carbon microtubes (CMTs) were prepared by the carbonization of poplar catkins according to their natural microtubular st...
2012, 28 (10): 2269-2275.
DOI: 10.3866/PKU.WHXB201209061
4889
Abstract/Metrics
1749
PDF(947KB)
Preparation and Photoelectrocatalytic Water Oxidation Properties of FeO(OH)-TiO
2
/CoPi Composite Photoanodes
JIN Tao, XU Di, DIAO Peng, XIANG Min
TiO2 nanocrystals were synthesized using a sol-gel method, and then the impregnation technique was used to modify the su...
2012, 28 (10): 2276-2284.
DOI: 10.3866/PKU.WHXB201209101
4401
Abstract/Metrics
2611
PDF(1433KB)
SOFT MATTER
Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants
WANG Xian-Zhong, KANG Wan-Li, MENG Xiang-Can, FAN Hai-Ming, XU Hai, HUANG Jing-Wei, FU Jian-Bin, ZHANG Yi-Nuo
The present work investigates the use of synergistic interactions between zwitterionic and anionic surfactants to obtain...
2012, 28 (10): 2285-2290.
DOI: 10.3866/PKU.WHXB201206291
5226
Abstract/Metrics
1574
PDF(713KB)
Fluorescent Microcapsules Based on Coordination Supramolecular Polymers of Rare Earth Metal Ions
WANG Jia-Rui, YANG Yang, YAN Yun, HUANG Jian-Bin
Fluorescent microcapsules based on coordination supramolecular polymers of rare earth metal ions were prepared via a lay...
2012, 28 (10): 2291-2297.
DOI: 10.3866/PKU.WHXB201208131
3861
Abstract/Metrics
1070
PDF(1565KB)
Investigation of the Mechanism of Temperature-Responsiveness of Metal-Cholate Supramolecular Hydrogels
CAI Long-Cheng, WANG Yi-Jie, LI Juan, HUANG Jian-Bin
Temperature-promoted hydrogel formation was investigated in a mixed solution of sodium cholate and metal ions. Transmiss...
2012, 28 (10): 2298-2304.
DOI: 10.3866/PKU.WHXB201209112
4284
Abstract/Metrics
1434
PDF(1899KB)
Alkoxysulfonate-Functionalized Poly(3,4-ethylenedioxythiophene) Hydrogels
DU Ran, ZHANG Xue-tong
Conducting polymer hydrogels based on alkoxysulfonate-functionalized poly(3, 4-ethylenedioxythiophene) have been synthes...
2012, 28 (10): 2305-2314.
DOI: 10.3866/PKU.WHXB201209142
5000
Abstract/Metrics
1352
PDF(1735KB)
CATALYSIS AND SURFACE SCIENCE
Relationship between the Structures of Metal Oxide Catalysts and Their Properties in Selective Oxidation of Methanol
CHEN Wen-Long, LIU Hai-Chao
Methanol is an important platform molecule for the production of energy and chemicals. For its efficient utilization, it...
2012, 28 (10): 2315-2326.
DOI: 10.3866/PKU.WHXB201209146
4763
Abstract/Metrics
2140
PDF(903KB)
Applications of Monolayer-Dispersed Organic Compounds in the Preparation of Related Materials
WANG Yu, JIANG Jun-Cong, ZHU Yue-Xiang, XIE You-Chang
Many organic compounds will spontaneously disperse on the surface of a solid support to form monolayers, in a manner sim...
2012, 28 (10): 2327-2335.
DOI: 10.3866/PKU.WHXB201207303
4398
Abstract/Metrics
1558
PDF(901KB)
Modification of Carbon Nitride Photocatalysts by Copolymerization with Diaminomaleonitrile
ZHENG Hua-Rong, ZHANG Jin-Shui, WANG Xin-Chen, FU Xian-Zhi
g-C3N4photocatalysts were synthesized by copolymerization of diaminomaleonitrile (DMNA) with dicyanodiamide (DCDA) at hi...
2012, 28 (10): 2336-2342.
DOI: 10.3866/PKU.WHXB201209104
5543
Abstract/Metrics
2403
PDF(1137KB)
Selective Degradation of Organosolv Lignin over Noble Metal Catalyst in a Two-Step Process
LIU Ling-Tao, ZHANG Bin, LI Jing, MA Ding, KOU Yuan
Dioxane lignin, a typical organosolv lignin, was degraded by supported noble metal catalysts and phosphoric acid by a tw...
2012, 28 (10): 2343-2348.
DOI: 10.3866/PKU.WHXB201206152
4793
Abstract/Metrics
Supporting Info
1487
PDF(799KB)
One-Pot Catalytic Conversion of Xylose to Furfural on Mesoporous Niobium Phosphate
LI Xiang-Cheng, ZHANG Yu, XIA Yin-Jiang, HU Bi-Cheng, ZHONG-Lin, WANG Yan-Qin, LU Guan-Zhong
The conversion of xylose to furfural normally involves two steps: the isomerization of xylose to xylulose catalyzed by a...
2012, 28 (10): 2349-2354.
DOI: 10.3866/PKU.WHXB201207312
4959
Abstract/Metrics
1858
PDF(728KB)
Investigation of the Adsorption Behavior of PbPc on Graphene by Raman Spectroscopy
LING Xi, ZHANG Jin
Using graphene-enhanced Raman scattering, the Raman signals of molecules attached to graphene can be obtained. For diffe...
2012, 28 (10): 2355-2362.
DOI: 10.3866/PKU.WHXB201208242
3770
Abstract/Metrics
1767
PDF(852KB)
BIOPHYSICAL CHEMISTRY
Protein-Protein Interaction: Prediction, Design, and Modulation
ZHANG Chang-Sheng, LAI Lu-Hua
Protein-protein interactions are the essential events in life at the molecular level. The three-dimensional structures o...
2012, 28 (10): 2363-2380.
DOI: 10.3866/PKU.WHXB201209172
7136
Abstract/Metrics
2968
PDF(1098KB)
Folding Mechanism of
De novo
Designed Proteins
ZHANG Zhu-Qing
Protein de novo design and protein folding are two different means to investigate“sequencestructure- function&rdqu...
2012, 28 (10): 2381-2389.
DOI: 10.3866/PKU.WHXB201209144
4316
Abstract/Metrics
1610
PDF(1554KB)
Protein-RNA Interaction Interface Prediction and Design
HUANG Yang-Yu, YANG Xiu-Feng, LI Hao-Tian, JI Xiao-Feng, CHENG Hong-Li, ZHAO Yun-Jie, GUO Da-Chuan, LI Lin, LIU Shi-Yong
RNA-protein interactions play key roles in many biological processes. The three dimensional (3D) structure of protein-RN...
2012, 28 (10): 2390-2400.
DOI: 10.3866/PKU.WHXB201209111
5834
Abstract/Metrics
3683
PDF(1793KB)
Characterization and Comparative Analysis of Chemical Libraries for Drug Discovery
DING Xin-Qiang, WU Zhi-Yin, JIN Hong-Wei, LIU Zhen-Ming
With the development of computer technology and software for molecular modeling, virtual screening plays an important ro...
2012, 28 (10): 2401-2410.
DOI: 10.3866/PKU.WHXB201208241
4180
Abstract/Metrics
1903
PDF(1045KB)
Mechanism of 3D Domain Swapping for M
pro
-C: Clues from Molecular Simulations
HUANG Yong-Qi, KANG Xue, XIA Bing, LIU Zhi-Rong
SARS coronavirus main protease (Mpro) is a key enzyme involved in the extensive proteolytic processing of the virus? pol...
2012, 28 (10): 2411-2417.
DOI: 10.3866/PKU.WHXB201209072
4383
Abstract/Metrics
1454
PDF(1243KB)
Isatin Dual Functional Inhibitors: Modulating the Aggregation State and Enzyme Activity of SARS-3CL Proteinase
ZHOU Lu, JIN Feng, LIU Ying SHANG Er-Chang, WEI Ping, LI Chun-Mei, LAI Lu-Hua
The 1-(2-naphthlmethyl) isatin-5-formamide compounds can inhibit SARS-3CL proteinase by binding to its substrate pocket,...
2012, 28 (10): 2418-2422.
DOI: 10.3866/PKU.WHXB201209143
4154
Abstract/Metrics
1178
PDF(915KB)
PHYSICAL CHEMISTRY OF MATERIALS
Two-Dimensional Nanostructures of Topological Insulators and Their Devices
LI Hui, PENG Hai-Lin, LIU Zhong-Fan
Three-dimensional (3D) topological insulators are a new state of quantum matter that are insulating in the bulk but have...
2012, 28 (10): 2423-2435.
DOI: 10.3866/PKU.WHXB201208312
6398
Abstract/Metrics
4164
PDF(2662KB)
Recent Progress in Electrochemical Synthesis and Morphological Control of Metal Oxide Nanostructures
JIAO Shu-Hong, XU Dong-Sheng, XU Li-Fen, ZHANG Xiao-Guang
There has been considerable focus on the synthesis of metal oxide nanostructures because of their extensive structures, ...
2012, 28 (10): 2436-2446.
DOI: 10.3866/PKU.WHXB201209145
6455
Abstract/Metrics
3050
PDF(2408KB)
Separation Techniques of Single-Walled Carbon Nanotubes with Single Electrical Type and Chirality
LI Hong-Bo, ZHANG Jing, JIN He-Hua, LI Qing-Wen
Based on the solution post-synthesis method, we reviewed the process in the separation techniques of single-walled carbo...
2012, 28 (10): 2447-2455.
DOI: 10.3866/PKU.WHXB201209041
4186
Abstract/Metrics
1710
PDF(1601KB)
Controlled Growth of Graphene on Metal Substrates and STM Characterizations for Microscopic Morphologies
ZHANG Yan-Feng, GAO Teng, ZHANG-Yu, LIU Zhong-Fan
Recently, chemical vapor deposition (CVD) has been widely applied to the large-scale synthesis of graphene on various me...
2012, 28 (10): 2456-2464.
DOI: 10.3866/PKU.WHXB201209062
4847
Abstract/Metrics
2895
PDF(4995KB)
Solution-Processable, Highly Conductive, Permanently Rippled Graphene Sheets
FAN Cheng-Wei, ZHANG Xin, CHEN Sheng, WANG Hai-Fang, CAO Ao-Neng
The single atom thick sp2 carbon structure of graphene gives rise to its unique properties and potential applications. H...
2012, 28 (10): 2465-2470.
DOI: 10.3866/PKU.WHXB201209103
4361
Abstract/Metrics
1223
PDF(1045KB)
New Spiropyran Derivatives: Ion Sensing and Information Processing at the Molecular Level
LI Ying-Ruo, ZHANG Hong-Tao, QI Chuan-Min, GUO Xue-Feng
We have designed and synthesized a new class of spiropyran derivatives (SP1-SP4) with functional chelating groups, such ...
2012, 28 (10): 2471-2479.
DOI: 10.3866/PKU.WHXB201205155
5587
Abstract/Metrics
Supporting Info
1914
PDF(865KB)
Nanoprobes with Enhanced Two-Photon-Sensitized Eu
3+
Luminescence Properties for Live Cell Imaging
FU Xiao-Yi, SHAO Guang-Sheng, HAN Rong-Cheng, MA Yan, XUE Fu-Min, YANG Fan, FU Li-Min, ZHANG Jian-Ping, WANG Yuan
Luminescent nanospheres (EuPHS, dav=45 nm) containing 40% (w) of Eu(tta)3dpbt (tta= thenoyltrifluoroacetonato;dpbt=2-(N,...
2012, 28 (10): 2480-2486.
DOI: 10.3866/PKU.WHXB201208161
4438
Abstract/Metrics
Supporting Info
1791
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Synthesis of Silver Sulfide Hollow Sphere-Silver Nanoparticle Heterostructures Based on Reactive Templates
GAO Ji-Ning, ZHAO Hua-Bo, QI Li-Min
Silver sulfide hollow sphere-silver nanoparticle heterostructures were prepared by the simultaneous cation exchange and ...
2012, 28 (10): 2487-2492.
DOI: 10.3866/PKU.WHXB201209031
4479
Abstract/Metrics
1670
PDF(1464KB)
Controlled Synthesis of Cobalt-Doped Magnetic Iron Oxide Nanoparticles
LI Zhen-Hu, MA Yu-Rong, QI Li-Min
Uniform sphere-like Co-doped iron oxide nanoparticles were synthesized by the thermolysis of iron oleate and cobalt olea...
2012, 28 (10): 2493-2499.
DOI: 10.3866/PKU.WHXB201209071
5345
Abstract/Metrics
2094
PDF(1984KB)
Bifilar Helix-Like Nanobelt of Single Crystalline Zn
2
SnO
4
Fabricated by Aluminothermal Reaction Approach
WANG Yu, CHEN Jing, LIAO Qing, SUN Wei, LI Jianlong, ZHANG Jianping, WU Kai
This paper reports the preparation in large quantity of bifilar helix-like nanobelts of single crystalline Zn2SnO4, a fa...
2012, 28 (10): 2500-2506.
DOI: 10.3866/PKU.WHXB201209113
3530
Abstract/Metrics
Supporting Info
1621
PDF(1862KB)