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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
2013 Vol. 29,No. 07
Published: 14 June 2013
Current column
Table of Contents
COMMUNICATION
REVIEW
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
THEORETICAL AND COMPUTATIONAL CHEMISTRY
ELECTROCHEMISTRY AND NEW ENERGY
SOFT MATTER
CATALYSIS AND SURFACE SCIENCE
BIOPHYSICAL CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.29 No. 7
2013, 29 (07): 0.
1058
Abstract/Metrics
1496
PDF(4474KB)
COMMUNICATION
Preparation, Characterization and Photocatalytic Activity of Cr-Doped Rutile TiO
2
(110) Single Crystal Thin Films
WANG Yang, SHAO Xiang, WANG Bing
The growth of Cr-doped rutile TiO2(110) homoepitaxial single crystal thin films was investigated using pulsed laser depo...
2013, 29 (07): 1363-1369.
DOI: 10.3866/PKU.WHXB201305221
3822
Abstract/Metrics
2441
PDF(2507KB)
REVIEW
Research Progress in Atomic Resolution Microscopy
YUAN Bing-Kai, CHEN Peng-Cheng, ZHANG Jun, CHENG Zhi-Hai, WANG Chen, QIU Xiao-Hui
Tremendous progress has been made in non-contact atomic force microscopy (NC-AFM) recently. The spatial resolution of NC...
2013, 29 (07): 1370-1384.
DOI: 10.3866/PKU.WHXB201304191
4384
Abstract/Metrics
5416
PDF(3793KB)
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
Small-Scale Chemical Kinetic Mechanism Models for Pyrolysis of
n
-Decane
YAO Tong, ZHONG Bei-Jing
n-Decane is a component of commonly used fuels, but so far studies into its pyrolysis mechanism are rare and the few exi...
2013, 29 (07): 1385-1395.
DOI: 10.3866/PKU.WHXB201304123
2934
Abstract/Metrics
1532
PDF(746KB)
Emergent Paramagnetism in D- and L-Alanine Crystals: Spin-Orbital Separation in Quasi-One-Dimensional N
+
H…O
?
Bonds
WANG Wen-Qing, SHEN Xin-Chun ZHANG Yu-Feng GONG Yan
We investigated the field-dependent magnetic properties of chiral alanine crystals, especially associated with the elect...
2013, 29 (07): 1396-1400.
DOI: 10.3866/PKU.WHXB201304163
3075
Abstract/Metrics
1058
PDF(842KB)
Direct Evidence for the Energy of Weak Interactions between Surfactant Molecules Using High Sensitivity Isothermal Titration Calorimetry
LOU Peng-Xiao, WANG Yu-Jie, BAI Guang-Yue, FAN Chao-Ying, Wang Yi-Lin
Calorimetry is a direct experimental method that can be used to study the thermodynamics of weak interactions between su...
2013, 29 (07): 1401-1407.
DOI: 10.3866/PKU.WHXB201304282
3863
Abstract/Metrics
2146
PDF(654KB)
Heterobinuclear Zn-Eu or Zn-Tb Complexes Formed from Benzimidazole Derivatives and Metal Salts: Synthesis, Structures and Photophysical Properties
ZHAO Shun-Sheng, ZHANG Zhao, SHI Guo-Xiang, FENG Wei-Xu, LÜ Xing-Qiang, LIU Xiang-Rong
Four isostructural heterobinuclear Zn-Ln (Ln=Eu or Tb) complexes are prepared through the self-assembly of benzimidazole...
2013, 29 (07): 1408-1414.
DOI: 10.3866/PKU.WHXB201305081
3403
Abstract/Metrics
Supporting Info
1787
PDF(3000KB)
THEORETICAL AND COMPUTATIONAL CHEMISTRY
Study on Mechanism of the Reduning Injection on the Influenza Virus Using Network Pharmacology Method
ZHANG Xin-Zhuang, XIAO Wei, XU Xiao-Jie, WANG Zhen-Zhong, CAO Ling, SUN Lan
The mechanisms of the Reduning injection on the influenza virus were studied by computer methods at the molecular level,...
2013, 29 (07): 1415-1420.
DOI: 10.3866/PKU.WHXB201304171
3648
Abstract/Metrics
Supporting Info
2032
PDF(1477KB)
Radical Scavenging Activity of Myricetin
XIE Hu-Jun, MOU Wang-Shu, LIN Fu-Rong, XU Jie-Hui, LEI Qun-Fang, FANG Wen-Jun
Density functional theory (DFT) calculations have been performed to explore the molecular structure, electronic structur...
2013, 29 (07): 1421-1432.
DOI: 10.3866/PKU.WHXB201304222
3226
Abstract/Metrics
1402
PDF(7180KB)
Structural, Electronic and Magnetic Properties of Ti
n
O
2
and Ti
n
O
2
-
(
n
=1-10) Clusters
NIE Jing, LU Zhang-Hui, YAO Jun, GUI Tian, CHEN Xiang-Shu
The structural, electronic, and magnetic properties of TinO2 and TinO2- (n=1-10) clusters are studied using density func...
2013, 29 (07): 1433-1440.
DOI: 10.3866/PKU.WHXB201304272
4056
Abstract/Metrics
Supporting Info
2238
PDF(7414KB)
Geometric Structures, Excitation Energies and Dipole Moments of the Ground and Excited States of TiO
2
WEI Mei-Ju, JIA De-Qiang, CHEN Fei-Wu
The geometries of the ground and excited states of titanium dioxide, 1A1, 1B2, 3B2, 1B1, 3B1, 1A2 and 3A2, have been opt...
2013, 29 (07): 1441-1452.
DOI: 10.3866/PKU.WHXB201304221
3263
Abstract/Metrics
1606
PDF(606KB)
Photophysical Properties and Photoinduced Electron Transfer Mechanism in a Near-IR Fluorescent Probe for Monitoring Peroxynitrite
ZHOU Dan-Hong, LI Miao-Miao, CUI Li-Li
A heptamethine cyanine dye containing an organoselenium functional group is a near-IR fluorescent probe that operates ba...
2013, 29 (07): 1453-1460.
DOI: 10.3866/PKU.WHXB201304244
4373
Abstract/Metrics
2344
PDF(1274KB)
Oxygen-Reduction Reaction of Pyromellitimide-Bridged Polyphthalocyanine Fe(II)
SUN Xiao-Ran, LI Guang-Yue, XIA Ding-Guo, ZHANG Li-Mei, LI Fan
The activity of a pyromellitimide-bridged polyphthalocyanine Fe(II) catalyst for O2 reduction is studied by density func...
2013, 29 (07): 1461-1466.
DOI: 10.3866/PKU.WHXB201304081
3746
Abstract/Metrics
1232
PDF(851KB)
Reaction Mechanism of Toluene Methylation with Dimethyl Carbonate or Methanol Catalyzed by H-ZSM-5
LI Ling-Ling, Janik J. Michael, NIE Xiao-Wa, SONG Chun-Shan, GUO Xin-Wen
Para-xylene is an important petrochemical that can be produced by the methylation of toluene. Here, the mechanism of tol...
2013, 29 (07): 1467-1478.
DOI: 10.3866/PKU.WHXB201304262
5328
Abstract/Metrics
8501
PDF(4452KB)
ELECTROCHEMISTRY AND NEW ENERGY
Electrochemical Preparation of Ni-Sn Active Cathode and Its Electrocatalytic Hydrogen Evolution Reaction Mechanisms in Alkaline Solution
CAO Yin-Liang, LI Zhi-Lin, WANG Feng, LIU Jing-Jun, JI Jing, WANG Jian-Jun, ZHANG Liang-Hu, QIN Shi-Yong
A simple galvanostatic electrodeposition method was used to synthesize an active Ni-Sn electrode on a Cu foil substrate....
2013, 29 (07): 1479-1486.
DOI: 10.3866/PKU.WHXB201305083
4237
Abstract/Metrics
1719
PDF(1120KB)
Nano-WO
3
Composite Materials as Electro-Catalyst for Methanol Oxidation
ZHOU Yang, LIU Wei-Ming, HU Xian-Chao, CHU You-Qun, MA Chun-An
Nano-WO3 modified carbon nanotube supported Pt nanoparticles (Pt/WO3-CNTs) with uniform dimension were prepared by impre...
2013, 29 (07): 1487-1493.
DOI: 10.3866/PKU.WHXB201304121
3218
Abstract/Metrics
1494
PDF(1167KB)
Synthesis and Electrochemical Performance of Microporous Carbon Using a Zinc(II)-Organic Coordination Polymer
QIAN Jia-Sheng, LIU Ming-Xian, GAN Li-Hua, LÜ Yao-Kang, CHEN Ling-Yan, YE Rui-Jie, CHEN Long-Wu
Microporous carbon was prepared using a novel procedure based on a zinc(II)-organic coordination polymer. The polymer wa...
2013, 29 (07): 1494-1500.
DOI: 10.3866/PKU.WHXB201304271
3586
Abstract/Metrics
1553
PDF(771KB)
Synthesis and Characterization of NiCo
2
O
4
Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties
WU Hong-Ying, WANG Huan-Wen
In the present work, NiCo2O4 nanowires grown directly on carbon fibers self-organize into a nanoflower morphology. The m...
2013, 29 (07): 1501-1506.
DOI: 10.3866/PKU.WHXB201304241
4354
Abstract/Metrics
2780
PDF(1127KB)
Synthesis and Electrochemical Properties of LiFe
1-
x
Nb
x
PO
4
/C Composite Cathode Material by Two-Step Synthesis Route
CAO Yan-Bing, LUO Liang, DU Ke, PENG Zhong-Dong, HU Guo-Rong, JIANG Feng
LiFePO4/C composite was prepared by two-step synthesis route, with LiH2PO4 and FeC2O4· 2H2O as starting materials...
2013, 29 (07): 1507-1514.
DOI: 10.3866/PKU.WHXB201304231
2858
Abstract/Metrics
1554
PDF(1170KB)
Sulfonated Poly(aryl ether ketone) on Side Chain/Sulfonated Poly(vinyl alcohol) Composite Proton Exchange Membrane for Direct Methanol Fuel Cells
CHENG Hai-Long, XU Jing-Mei, WANG Zhe, REN Chun-Li, BAI Hong-Wei, ZHAO Cheng-Ji, ZHANG Hui-Xuan
Poly(aryl ether ketone)/sulfated poly(vinyl alcohol) (S-SPAEK/SPVA) composite membranes with different mass fractions of...
2013, 29 (07): 1515-1523.
DOI: 10.3866/PKU.WHXB201304261
3143
Abstract/Metrics
1997
PDF(2442KB)
SOFT MATTER
Polyethylene Glycol/Fe
3
O
4
Nanoparticle Composite Materials: Structure, Physical Properties and Application
XIA Juan, SONG Le-Xin, DANG Zheng, SHAO Zhi-Cheng
Fe3O4 nanoparticles with a highly symmetric octadecahedral nanobox structure were fabricated using β-cyclodextrin a...
2013, 29 (07): 1524-1533.
DOI: 10.3866/PKU.WHXB201304273
4274
Abstract/Metrics
1929
PDF(1599KB)
A Highly Viscoelastic Anionic Wormlike Micellar System
XIE Dan-Hua, ZHAO Jian-Xi, LIU Lin, YOU Yi, WEI Xi-Lian
The rheological behavior of carboxylate gemini surfactant O,O'-bis(sodium 2- tetradecylcarboxylate)-p-dibenzenediol (ref...
2013, 29 (07): 1534-1540.
DOI: 10.3866/PKU.WHXB201304252
2722
Abstract/Metrics
1389
PDF(732KB)
CATALYSIS AND SURFACE SCIENCE
Influence of Adsorption Mode on Metastable-Equilibrium Adsorption of As(V) on TiO
2
Particles
LI Jing, ZHANG Mei-Yi, PAN Gang, CHEN Hao
Column and batch adsorptions of As(V) on TiO2 particles were conducted to investigate the influence of adsorption mode o...
2013, 29 (07): 1541-1549.
DOI: 10.3866/PKU.WHXB201304242
3227
Abstract/Metrics
1528
PDF(675KB)
Properties and Roles of Adsorbed NH
3
and NO
x
over Cu/SAPO-34 Zeolite Catalyst in NH
3
-SCR Process
SHI Lin, YU Tie, WANG Xin-Quan, WANG Jun, SHEN Mei-Qing
To investigate the adsorption properties and roles of different feed gases in the selective catalytic reduction by ammon...
2013, 29 (07): 1550-1557.
DOI: 10.3866/PKU.WHXB201304283
3681
Abstract/Metrics
1951
PDF(941KB)
Investigation on Photocatalytic Reduction of CO
2
into CH
4
Using SrB
2
O
4
/SrCO
3
Composite Catalyst
GUO Li-Mei KUANG Yuan-Jiang YANG Xiao-Dan YU Yan-Long YAO Jiang-Hong CAO Ya-An
An SrB2O4/SrCO3composite catalyst is synthesized by the simple sol-gel method. Reduction of carbon dioxide into methane ...
2013, 29 (07): 1558-1565.
DOI: 10.3866/PKU.WHXB201304161
3539
Abstract/Metrics
1747
PDF(1111KB)
Roles of (001) and (101) Facets of Anatase TiO
2
in Photocatalytic Reactions
WANG Xiang, LI Ren-Gui, XU Qian, HAN Hong-Xian, LI Can
Single crystals of anatase TiO2 with exposed (001) and (101) facets were synthesized by a hydrothermal method. We carrie...
2013, 29 (07): 1566-1571.
DOI: 10.3866/PKU.WHXB201304284
4592
Abstract/Metrics
3318
PDF(1269KB)
Asymmetric Hydrogenation of Aromatic Ketones Catalyzed by Cinchona-Modified Ir/SiO
2
JIANG He-Yan, WU Zhi-Feng, CHEN Hua
The asymmetric hydrogenation of aromatic ketones catalyzed by cinchona- and triphenylphosphine (tpp)-modified Ir/SiO2 wa...
2013, 29 (07): 1572-1581.
DOI: 10.3866/PKU.WHXB201304243
2529
Abstract/Metrics
1641
PDF(1000KB)
Nanotribological and Wear Properties of Graphene
ZHU Qi-Rong, LI Hui-Qin, LI Ning, CHAI Jing, GAO Run-Gang, LIANG Qi
We prepared few-layer graphene samples by liquid-phase exfoliation in ethanol. By controlling the solvent temperature, s...
2013, 29 (07): 1582-1587.
DOI: 10.3866/PKU.WHXB201305031
4146
Abstract/Metrics
2947
PDF(1745KB)
BIOPHYSICAL CHEMISTRY
Preparation of Freestanding Bilayer Lipid Membranes and the Effect of Temperature on Their Mechanical Properties
WANG Yang, YAN Jia-Wei, ZHU Zai-Wen, ZHAO Xue-Qin, ZHONG Yun-Xing, MAO Bing-Wei
Nanoporous silicon nitride membranes are fabricated by combining polystyrene colloidal lithography with Micro-Electro-Me...
2013, 29 (07): 1588-1594.
DOI: 10.3866/PKU.WHXB201304233
3334
Abstract/Metrics
1531
PDF(1466KB)
PHYSICAL CHEMISTRY OF MATERIALS
Effective Adsorption of Functional Biological Macromolecules on Stainless Steel Surface with Micro/Nanoporous Texture
YU Zhan-Jiang, CHEN Yong-Qiang, YANG Xiao-Da
Stainless steel (AISI 316L) is commonly used as a material in medical devices. Modification of the metal surface with bi...
2013, 29 (07): 1595-1602.
DOI: 10.3866/PKU.WHXB201305082
3455
Abstract/Metrics
1633
PDF(2053KB)
An Electrostatic Force Microscopy Investigation of the Dynamic Properties of Microscopic Interface in Nanocomposites
PENG Jin-Ping, ZHANG Dong-Dong, GUAN Li, ZHANG Hui, ZHANG Zhong, QIU Xiao-Hui
The microscopic structure and properties of the interfacial regions in nanocomposites considerably affect the dielectric...
2013, 29 (07): 1603-1608.
DOI: 10.3866/PKU.WHXB201305091
2912
Abstract/Metrics
1958
PDF(3321KB)