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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
2014 Vol. 30,No. 9
Published: 29 August 2014
Current column
Table of Contents
REVIEW
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
THEORETICAL AND COMPUTATIONAL CHEMISTRY
ELECTROCHEMISTRY AND NEW ENERGY
SOFT MATTER
CATALYSIS AND SURFACE SCIENCE
PHOTOCHEMISTRY AND RADIATION CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.30 No. 9
2014, 30 (9): 0.
1370
Abstract/Metrics
1450
PDF(9697KB)
REVIEW
Research Progress in Radiation Effects on Ionic Liquids
WANG Shuo-Jue, AO Yin-Yong, ZHOU Han-Yang, YUAN Li-Yong, PENG Jing, ZHAI Mao-Lin
Ionic liquids (ILs) are regarded as a new generation of green solvents in spent nuclear fuel reprocessing, because of th...
2014, 30 (9): 1597-1604.
DOI: 10.3866/PKU.WHXB201406271
3615
Abstract/Metrics
1871
PDF(809KB)
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
Hydrogen-Bonding Interactions between Ionic Liquid 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate and Water
SONG Da-Yong, CHEN Jing
Attenuated total reflectance infrared (ATR-IR) spectroscopy, two- dimensional correlation spectroscopy, and quantum chem...
2014, 30 (9): 1605-1610.
DOI: 10.3866/PKU.WHXB201407012
3831
Abstract/Metrics
1662
PDF(989KB)
Low-Temperature Synthesis of Superconductor Ba
1-
x
K
x
BiO
3
LIU Meng, LI Guo-Bao, WANG Jia-Guo, LIAO Fu-Hui, LIN Jian-Hua
Ba1-xKxBiO3 (BKBO) was synthesized using a topotactic reaction, which involves a conventional solidstate synthesis of pu...
2014, 30 (9): 1611-1615.
DOI: 10.3866/PKU.WHXB201406201
3348
Abstract/Metrics
Supporting Info
1781
PDF(1642KB)
THEORETICAL AND COMPUTATIONAL CHEMISTRY
Quantitative Structure-Property Relationship Studies on the Adsorption of Aromatic Contaminants by Carbon Nanotubes
LIU Fen, ZOU Jian-Wei, HU Gui-Xiang, JIANG Yong-Jun
Ab initio calculations have been performed for a group of 59 aromatic compounds at the HF/6-31G* level of theory. Electr...
2014, 30 (9): 1616-1624.
DOI: 10.3866/PKU.WHXB201406182
3253
Abstract/Metrics
1574
PDF(974KB)
Molecular Dynamics Simulation Study of Structural and Transport Properties of Methanol-Water Mixture in Carbon Nanotubes
GAO Wen-Xiu, WANG Hong-Lei, LI Shen-Min
Molecular dynamics simulations of a methanol-water mixture (molar ratio 1:1) were performed to determine the differences...
2014, 30 (9): 1625-1633.
DOI: 10.3866/PKU.WHXB201407031
4095
Abstract/Metrics
1680
PDF(1139KB)
ELECTROCHEMISTRY AND NEW ENERGY
Pyrazolyl Magnesium Halide/Tetrahydrofuran Solutions for Rechargeable Magnesium Battery Electrolytes
FEILURE Tuerxun, ZULIPIYA Shadike, NULI Yan-Na, YANG Jun, WANG Jiu-Lin
Pyrazolyl magnesium halide/tetrahydrofuran (THF) solutions were obtained by the simple reaction of pyrazole compounds wi...
2014, 30 (9): 1634-1640.
DOI: 10.3866/PKU.WHXB201407101
3409
Abstract/Metrics
1634
PDF(680KB)
Preparation and Electrochemical Performances of Li
1.2
Mn
0.54-
x
Ni
0.13
Co
0.13
Zr
x
O
2
Cathode Materials for Lithium-Ion Batteries
REN Xiang-Zhong, LIU Tao, SUN Ling-Na, ZHANG Pei-Xin
To improve the cycling performance of lithium-rich cathode materials, Li1.2Mn0.54Ni0.13Co0.13O2 and Li1.2Mn0.54-xNi0.13C...
2014, 30 (9): 1641-1649.
DOI: 10.3866/PKU.WHXB201406172
3032
Abstract/Metrics
1442
PDF(1433KB)
Fe
3
O
4
/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries
LIU Jian-Hua, LIU Bin-Hong, LI Zhou-Peng
Fe3O4/graphene composites with a conductive, porous three-dimensional (3D) graphene network were synthesized through a f...
2014, 30 (9): 1650-1658.
DOI: 10.3866/PKU.WHXB201406181
3598
Abstract/Metrics
1960
PDF(1336KB)
Preparation and Electrochemical Properties of Functionalized Graphene/Polyaniline Composite Electrode Materials
WANG Li-Li, XING Rui-Guang, ZHANG Bang-Wen, HOU Yuan
Octadecylamine functionalized graphene (ODA-G) was synthesized by the grafting of graphene oxide (GO) with ODA followed ...
2014, 30 (9): 1659-1666.
DOI: 10.3866/PKU.WHXB201406162
3928
Abstract/Metrics
1957
PDF(729KB)
Effects of Surface Modification with Ag/C on Electrochemical Properties of Li[Li
0.2
Mn
0.54
Ni
0.13
Co
0.13
]O
2
XUE Qing-Rui, LI Jian-Ling, XU Guo-Feng, HOU Peng-Fei, YAN Gang, DAI Yu, WANG Xin-Dong, GAO Fei
A lithium-rich solid-solution layered cathode material, Li[Li0.2Mn0.54Ni0.13Co0.13]O2, was synthesized using a fast co-p...
2014, 30 (9): 1667-1673.
DOI: 10.3866/PKU.WHXB201406251
3321
Abstract/Metrics
1391
PDF(1657KB)
Electrochemical Co-Reduction Extraction of Neodymium in LiCl-KCl-ZnCl
2
Molten Salt System
XUE Yun, ZHOU Zhi-Ping, YAN Yong-De, ZHANG Mi-Lin, LI Xing, JI De-Bin, HAN Wei, ZHANG Meng
This work focused on the electrochemical behavior of Nd(Ⅲ) and the formation of Zn-Nd alloys on Mo electrodes in LiCl-KC...
2014, 30 (9): 1674-1680.
DOI: 10.3866/PKU.WHXB201407022
2859
Abstract/Metrics
1612
PDF(853KB)
Anomalous IR Optical Properties of Monodispersed PtNi Nanoparticles
ZHOU Xin-Wen, DU Juan-Juan, SUN Shi-Gang
Monodispersed PtNi nanoparticles were synthesized by galvanic displacement reaction and chemical reduction. The monodisp...
2014, 30 (9): 1681-1687.
DOI: 10.3866/PKU.WHXB201406193
3039
Abstract/Metrics
1180
PDF(968KB)
SOFT MATTER
Two-Component Supramolecular Organogels Formed from
L
-Phenylalanine Derivatives and Aliphatic Amines
ZHONG Jin-Lian, PAN Hong, LUO Xu-Zhong, HONG San-Guo, ZHANG Ning, HUANG Jian-Bin
A series of monochain L-phenylalanine derivatives were synthesized. L-Phenylalanine derivatives have no gelation abiliti...
2014, 30 (9): 1688-1696.
DOI: 10.3866/PKU.WHXB201407041
2985
Abstract/Metrics
Supporting Info
1365
PDF(1702KB)
CATALYSIS AND SURFACE SCIENCE
Photocatalytic Oxidation of Ammonia via an Activated Carbon-Nickel Ferrite Hybrid Catalyst under Visible Light Irradiation
XIAO Bo, LIU Shou-Qing
The nickel atoms in a metal ferrite lattice inhibit photocatalytic activity with hydrogen peroxide. However, activated c...
2014, 30 (9): 1697-1705.
DOI: 10.3866/PKU.WHXB201407111
3843
Abstract/Metrics
1359
PDF(1089KB)
Preparation of Fe-Doped Graphitic Carbon Nitride with Enhanced Visible-Light Photocatalytic Activity
JIN Rui-Rui, YOU Ji-Guang, ZHANG Qian, LIU Dan, HU Shao-Zheng, GUI Jian-Zhou
A series of Fe-doped graphitic carbon nitride (g-C3N4) photocatalysts were prepared using ferric nitrate and melamine as...
2014, 30 (9): 1706-1712.
DOI: 10.3866/PKU.WHXB201406272
4919
Abstract/Metrics
4602
PDF(1053KB)
Synthesis of Single-Crystalline Cu
3
B
2
O
6
/CuB
2
O
4
and Their Photocatalytic Degradation of Methylene Blue under Visible-Light Irradiation
CHEN Ai-Min, BO Ying-Ying, SHAO Chen-Yi, WANG Jing, HU Jun
Single-crystalline Cu3B2O6/CuB2O4 was successfully prepared by a sol-gel method fromcupric nitrate/ cupric acetate and b...
2014, 30 (9): 1713-1719.
DOI: 10.3866/PKU.WHXB201407011
3480
Abstract/Metrics
1551
PDF(957KB)
Facile Synthesis of Graphene-Cobalt Hydroxide Nanocomposite and Application in Degradation of Acid Orange 7
LI Jie-Bing, YI Yu, SHI Peng-Hui, WANG Qian, LI Deng-Xin, ASIF Hussain, YANG Ming
In this study, a cobalt hydroxide-reduced graphene oxide (Co(OH)2/rGO) composite was synthesized by one-step self-assemb...
2014, 30 (9): 1720-1726.
DOI: 10.3866/PKU.WHXB201407021
3104
Abstract/Metrics
1292
PDF(907KB)
Synthesis of Micro-Sized MEL-Type Zeolite Aggregates
CHEN Hong-Li, ZHU Shu-Yan, HE Jian-Qin, WANG Yi-Meng
Hierarchical micro-sized zeolite aggregates with the MEL structure were prepared hydrothermally froma tetrabutylammonium...
2014, 30 (9): 1727-1735.
DOI: 10.3866/PKU.WHXB201407081
3459
Abstract/Metrics
1215
PDF(1005KB)
Selective Oxidation of Ethane to Aldehydes over Potassium-Promoted SBA-15-Supported Molybdenum Oxide Catalysts
LI Jian-Mei, LIU Jian, REN Li-Wei, LIU Qing-Long, ZHAO Zhen, WEI Yue-Chang, DUAN Ai-Jun, JIANG Gui-Yuan
Potassium-modified SBA-15-supported molybdenum oxide catalysts were prepared using a twostep impregnation method. The ph...
2014, 30 (9): 1736-1744.
DOI: 10.3866/PKU.WHXB201407091
2420
Abstract/Metrics
1247
PDF(986KB)
Effect of Trace Amounts of Li Doping on Performance of Co/AC Catalysts for Syntheses of Mixed Linear
α
-Alcohols
DONG Wen-Da, ZHU He-Jun, DING Yun-Jie, PEI Yan-Peng, DU Hong, WANG Tao
15CoxLi/AC catalysts promoted by different trace amounts of Li doping were prepared by incipientwetness impregnation. Th...
2014, 30 (9): 1745-1751.
DOI: 10.3866/PKU.WHXB201405301
2952
Abstract/Metrics
1175
PDF(713KB)
PHOTOCHEMISTRY AND RADIATION CHEMISTRY
Fluorescent Emissions (1800 nm) of LiLuF
4
Single Crystals Doped with Various Tm
3+
Concentrations
LI Shan-Shan, XIA Hai-Ping, FU Li, DONG Yan-Ming, ZHANG Jia-Zhong, GU Xue-Mei, ZHANG Jian-Li, WANG Dong-Jie, JIANG Hao-Chuan, CHEN Bao-Jiu
LiLuF4 single crystals doped with molar fractions of 0.45%, 0.90%, 1.63%, and 3.25% (x, molar fraction) Tm3+ ions were f...
2014, 30 (9): 1752-1757.
DOI: 10.3866/PKU.WHXB201406183
2906
Abstract/Metrics
1207
PDF(1004KB)
Influence of Different Pyramidal Structural Morphologies of Crystalline Silicon Wafers for Surface Passivation and Heterojunction Solar Cells
WANG Li-Guo, ZHANG Xiao-Dan, WANG Feng-You, WANG Ning, JIANG Yuan-Jian, HAO Qiu-Yan, XU Sheng-Zhi, WEI Chang-Chun, ZHAO Ying
Silicon heterojunction (SHJ) solar cells consisting of a hydrogenated amorphous silicon (a-Si:H) film deposited on a cry...
2014, 30 (9): 1758-1763.
DOI: 10.3866/PKU.WHXB201406301
3131
Abstract/Metrics
1807
PDF(768KB)
PHYSICAL CHEMISTRY OF MATERIALS
Effects of Pore-Size Range and Composition of Polysaccharide Gels on Flow Behaviors and Selective Sorting of Single-Walled Carbon Nanotubes
YANG Peng, TAN Fu-Rui, ZHANG Jing, JIN He-Hua, LI Hong-Bo, LIU Chun-Hua, LI Qing-Wen
We used gel-column chromatography to show the effects of the pore-size range and chemical composition of porous polysacc...
2014, 30 (9): 1764-1770.
DOI: 10.3866/PKU.WHXB201407032
3108
Abstract/Metrics
1540
PDF(825KB)
Wavelength-Interrogated Surface Plasmon Resonance Sensor Based on Au-Ag Alloy Film
ZHANG Zhe, LIU Jie, LU Dan-Feng, QI Zhi-Mei
An Au-Ag alloy film surface plasmon resonance (SPR) sensor was studied experimentally and theoretically. SPR chips were ...
2014, 30 (9): 1771-1777.
DOI: 10.3866/PKU.WHXB201407071
3117
Abstract/Metrics
1636
PDF(1077KB)
Preparation of Nitrogen-Doped Graphene and Its Electrocatalytic Activity for Oxygen Reduction Reaction
PENG San, GUO Hui-Lin, KANG Xiao-Feng
Nitrogen-doped graphene (NG) was prepared by chemical reduction of graphene oxide (GO) using dimethyl ketoxime (DMKO) as...
2014, 30 (9): 1778-1786.
DOI: 10.3866/PKU.WHXB201407112
4226
Abstract/Metrics
2806
PDF(1301KB)