Table of Contents

• Cover and Table of Contents for Vol.31 No. 3
• 2015, 31 (3): 0.

• 1326Abstract/Metrics
• 1284 PDF(7668KB)

REVIEW

• Functional Applications of Ordered Honeycomb-Patterned Porous Films Based on the Breath Figure Technique
• LI Zhi-Guang, MA Xiao-Yan, HONG Qing, GUAN Xing-Hua
• The breath figure (BF) technique is regarded as a powerful tool for the fabrication of strictly ordered and closely pack...
• 2015, 31 (3): 393-411. DOI: 10.3866/PKU.WHXB201412261

• 4602Abstract/Metrics
• 3432 PDF(2086KB)

THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY

• Low Temperature Heat Capacities of Uracil and 5-Bromouracil
• ZHANG Xiao-Ye, XUE Bin, CHENG Ze, TAN Zhi-Cheng, SHI Quan
• The heat capacities of uracil and 5-bromouracil were measured using a quantum design physical property measurement syste...
• 2015, 31 (3): 412-418. DOI: 10.3866/PKU.WHXB201501122

• 2784Abstract/Metrics
• 1143 PDF(742KB)

• Photochemical Reaction Kinetics of Duroquinone in a Mixture of Ionic Liquid [BPy][BF₄] and Acetonitrile
• ZHU Guang-Lai, WANG Yu, ZHANG Liang-Wei, LIU Yan-Cheng, WU Guo-Zhong
• Photochemical reactions of duroquinone (DQ) in solutions consisting of mixtures of the ionic liquid N-butylpyridinium te...
• 2015, 31 (3): 419-424. DOI: 10.3866/PKU.WHXB201501222

• 3199Abstract/Metrics
• 1025 PDF(1024KB)

THEORETICAL AND COMPUTATIONAL CHEMISTRY

• Nitrous Oxide Decomposition Catalyzed by Au₁₉Pd and Au₁₉Pt Clusters
• YU Wei-Ling, ZUO Hui-Wen, LU Chun-Hai, LI Yi, ZHANG Yong-Fan, CHEN Wen-Kai
• The catalytic decomposition of N2O using Au19Pd and Au19Pt clusters as catalysts with optimized geometries was studied u...
• 2015, 31 (3): 425-434. DOI: 10.3866/PKU.WHXB201501191

• 2757Abstract/Metrics
• 1382 PDF(1164KB)

• Theoretical Analysis of Pnicogen and Chalcogen Bonds in H₂XP…SHY Complexes
• LIU Yu-Zhen, LI An-Yong
• The MP2 and CCSD(T) ab initio quantum chemistry methods were applied to study the pnicogen bonds X―P…S and chalco...
• 2015, 31 (3): 435-440. DOI: 10.3866/PKU.WHXB201501211

• 2768Abstract/Metrics
• Supporting Info
• 1238 PDF(1292KB)

• Prediction of Native Point Defects in HfO₂ Crystals Using First Principles and Thermodynamic Calculations
• LIU Feng-Ming, LIU Ting-Yu, LIU Jian, LI Hai-Xin
• Based on first principles and thermodynamics the intrinsic point defect formation energy was calculated at different tem...
• 2015, 31 (3): 441-447. DOI: 10.3866/PKU.WHXB201412301

• 3070Abstract/Metrics
• 1547 PDF(1217KB)

ELECTROCHEMISTRY AND NEW ENERGY

• Dye-Sensitized Solar Cells Based on MWCNT/TiO₂ Counter Electrode and Thiolate/Disulfide Non-Iodine Redox Couple
• WANG Yu-Qiao, WANG Pan-Pan, LU Jing, BAI Yi-Chao, GU Yun-Liang, SUN Yue-Ming
• Multi-walled carbon nanotube (MWCNT)/TiO2 composites were prepared using acid-treated MWCNT and titanium (IV) isopropoxi...
• 2015, 31 (3): 448-456. DOI: 10.3866/PKU.WHXB201412302

• 2863Abstract/Metrics
• 1486 PDF(1411KB)

• Photoelectric Properties of Graphene Oxide Film Prepared with the Electrochemical Method Using Varying Levels of Reduction
• LI Wen-You, HE Yun-Qiu, LI Yi-Ming
• This article details a quick and simple method to prepare graphene oxide (GO) film and tune its energy level by adjustin...
• 2015, 31 (3): 457-466. DOI: 10.3866/PKU.WHXB201501093

• 4254Abstract/Metrics
• Supporting Info
• 2280 PDF(3320KB)

• Corrosion Behavior of Alloy 690 in Simulated Alkaline Water Chemistries Containing Sulfur at 300 ℃
• XIA Da-Hai, LUO Jing-Li
• Alloy 690 is one of the steam generator (SG) tubing materials in pressurized water reactors (PWR). The degradation of th...
• 2015, 31 (3): 467-475. DOI: 10.3866/PKU.WHXB201501053

• 2833Abstract/Metrics
• 1220 PDF(1720KB)

• Enhanced Electrochromic Performance of Ordered Porous Monolayer PBTB Film Using Amine-Modified Polystyrene Spheres as a Template
• OUYANG Mi, HUANG Sen-Biao, HAN Yan-Gang, Lü Xiao-Jing, YANG Yuan, DAI Yu-Yu, Lü Yao-Kang, ZHANG Cheng
• Poly(1,4-bis(2- thienyl)-benzene) (PBTB) with a highly ordered porous nanostructure was successfully made using monolaye...
• 2015, 31 (3): 476-482. DOI: 10.3866/PKU.WHXB201501121

• 3270Abstract/Metrics
• 1043 PDF(1029KB)

• Effects of Gold Nanoparticles on Quantum Dot Electrochemiluminescence Obtained Using a DNA Electrochemiluminescence Sensor
• LU Li-Ping, LI Jiao, WU Jing, KANG Tian-Fang, CHENG Shui-Yuan
• Gold nanoparticles (AuNPs) have a high extinction coefficient and a strong surface plasmon resonance, the latter of whic...
• 2015, 31 (3): 483-488. DOI: 10.3866/PKU.WHXB201501151

• 3550Abstract/Metrics
• 1368 PDF(899KB)

• Simulation of Sphere-Microstructure Model of the Catalyst Layer in a PEMFC
• ZHANG Jie-Jing, WANG Yu-Xin, XU Li
• The catalyst layer in a proton-exchange-membrane fuel cell (PEMFC) was simulated based on a sphere-microstructure model ...
• 2015, 31 (3): 489-497. DOI: 10.3866/PKU.WHXB201501221

• 2936Abstract/Metrics
• 1088 PDF(1203KB)

• Preparation and Electrocatalytic Performance of Iron Based Nitrogen Doped Carbon Nanotubes
• LI Li-Xiang, ZHAO Hong-Wei, XU Wei-Wei, ZHANG Yan-Qiu, AN Bai-Gang, GENG Xin
• Polypyrrole coated carbon nanotubes (PPy/CNTs) were synthesized by the in-situ chemical polymerization of pyrroles on CN...
• 2015, 31 (3): 498-504. DOI: 10.3866/PKU.WHXB201412162

• 3292Abstract/Metrics
• 1350 PDF(975KB)

SOFT MATTER

• Formation of Colloidal Spheres from a Lignin-Based Azo Polymer
• DENG Yong-Hong, LIU You-Fa, ZHANG Wei-Jian, QIU Xue-Qing
• 2-(4-Ethyl formate phenyl azo) phenol lignin-modified polymer (AL-azo-COOEt), a novel ligninbased azo polymer, has been ...
• 2015, 31 (3): 505-511. DOI: 10.3866/PKU.WHXB201501192

• 3156Abstract/Metrics
• 1177 PDF(986KB)

CATALYSIS AND SURFACE SCIENCE

• Enhanced Effect of O/N Groups on the Hg0 Removal Efficiency over the HNO₃-Modified Activated Carbon
• TONG Li, XU Wen-Qing, QI Hao, ZHOU Xuan, LIU Rui-Hui, ZHU Ting-Yu
• HNO3-modified activated carbon (AC) was prepared to determine its mercury removal ability on a fixed-bed reactor. In thi...
• 2015, 31 (3): 512-518. DOI: 10.3866/PKU.WHXB201412251

• 3356Abstract/Metrics
• 1197 PDF(954KB)

• Preparation and Photocatalytic Activity of Mixed Phase TiO₂-Graphene Composites
• YU Jian-Hua, FAN Min-Guang, LI Bin, DONG Li-Hui, ZHANG Fei-Yue
• A series of composites consisting of anatase-rutile TiO2 and graphene (TrG) were synthesized by a hydrothermal route. Th...
• 2015, 31 (3): 519-526. DOI: 10.3866/PKU.WHXB201412291

• 3726Abstract/Metrics
• 1569 PDF(1221KB)

• Preparation of Amorphous Co-B/γ-Al₂O₃ Catalyst and Its Performance in Catalytic Liquid Phase Hydrogenation of Ethyl Lactate
• ZHAO Feng-Wei, SHEN Mei-Yu, WANG Lin, DU Chang-Hai
• Supported cobalt amorphous catalysts Co-B/γ-Al2O3 were prepared using an impregnation-chemical reduction method fo...
• 2015, 31 (3): 527-532. DOI: 10.3866/PKU.WHXB201501052

• 2525Abstract/Metrics
• 932 PDF(970KB)

• Preparation, Characterization and Hydrodesulfurization Catalytic Performances of Mo-Ni₂P/SBA-15 Catalysts
• WANG Zhou-Jun, WU Ping-Yi, LAN Ling, LIU Kun-Hong, HU Ya-Qiong, JI Sheng-Fu
• A series of Mo-Ni2P/SBA-15 catalysts with various Mo loadings were prepared by impregnating nickel nitrate, diammonium h...
• 2015, 31 (3): 533-539. DOI: 10.3866/PKU.WHXB201501094

• 2990Abstract/Metrics
• 1161 PDF(1053KB)

• Improved Photocatalytic Degradation of Phenol over β-Bi₂O₃ Modified Bi₂WO₆ and Possible Mechanism
• LI Xiao-Jin, SHENG Jia-Yi, CHEN Hai-Hang, XU Yi-Ming
• In this study, a series of Bi2O3-containing Bi2WO6 catalysts were prepared by a simple mixing method. We used the oxidat...
• 2015, 31 (3): 540-544. DOI: 10.3866/PKU.WHXB201501131

• 3044Abstract/Metrics
• 1514 PDF(818KB)

• Effect of H₂S Concentration on MoO₃/Al₂O₃ and CoO-MoO₃/Al₂O₃ Catalysts for Sulfur-Resistant Methanation
• WANG Bao-Wei, LIU Si-Han, HU Zong-Yuan, LI Zhen-Hua, MA Xin-Bin
• The activities of 25% (mass fraction, w) MoO3/Al2O3 and 5% (w) CoO-25%MoO3/Al2O3 catalysts in a sulfur-resistant methana...
• 2015, 31 (3): 545-551. DOI: 10.3866/PKU.WHXB201501202

• 2707Abstract/Metrics
• 918 PDF(561KB)

PHOTOCHEMISTRY AND RADIATION CHEMISTRY

• Antimicrobial Drug Levofloxacin Applied to an Organic Light-Emitting Diode
• MIAO Yan-Qin, GAO Zhi-Xiang, WU Yu-Ling, DU Xiao-Gang, LI Yuan-Hao, LIU Hui-Hui, JIA Hu-Sheng, WANG Hua, LIU Xu-Guang
• Levofloxacin (LOFX) is a well-known and inexpensive antimicrobial drug that can be easily synthesized and purified. We r...
• 2015, 31 (3): 552-558. DOI: 10.3866/PKU.WHXB201501051

• 3392Abstract/Metrics
• 1176 PDF(1085KB)

• Effect of HNO₃ on the γ Radiolysis and Radiolytic Liquid Products of N, N-Dimethylhydroxylamine
• WANG Jin-Hua, CAO Xiao-Jun, LI Chun, WU Ming-Hong, BAO Bo-Rong, ZHENG Wei-Fang, HE Hui, ZHANG Sheng-Dong
• N,N-dimethylhydroxylamine (DMHA) is a novel salt-free reductant used for the separation of U from Pu and Np in the repro...
• 2015, 31 (3): 559-565. DOI: 10.3866/PKU.WHXB201501092

• 3224Abstract/Metrics
• 920 PDF(620KB)

BIOPHYSICAL CHEMISTRY

• Molecular Dynamics Simulation and Antibacterial Mechanism of 3MBA Derivatives as FtsZ Protein Inhibitors
• ZHANG He, LU Jun-Rui, MU Jiang-Bei, LIU Jin-Biao, YANG Xu-Yun, WANG Mei-Jun, ZHANG Rui-Bo
• In this paper, the complex stability, secondary structure, protein conformation, residue distance, active site volume, a...
• 2015, 31 (3): 566-575. DOI: 10.3866/PKU.WHXB201501061

• 3669Abstract/Metrics
• 2203 PDF(1462KB)

PHYSICAL CHEMISTRY OF MATERIALS

• Optical and Electrical Properties of CH₃NH₃PbI₃ Perovskite Thin Films Transformed from PbO-PbI₂ Hybrid Films
• DING Xu-Kun, LI Xiao-Min, GAO Xiang-Dong, ZHANG Shu-De, HUANG Yu-Di, LI Hao-Ran
• Organic-inorganic halide perovskites have been shown to be outstanding photovoltaic materials, achieving remarkably high...
• 2015, 31 (3): 576-582. DOI: 10.3866/PKU.WHXB201501201

• 2870Abstract/Metrics
• 2302 PDF(1203KB)

• Preparation and Structure Regulation of Silicon Carbide-Derived Carbon/ Spherical Natural Graphite Composites
• DU Xue-Lian, CONG Ye, JIANG Lu, LI Xuan-Ke, CUI Zheng-Wei, DONG Zhi-Jun, YUAN Guan-Ming, ZHANG Jiang
• To meet the requirements of the energy storage materials for high energy density and high power density, porous silicon ...
• 2015, 31 (3): 583-588. DOI: 10.3866/PKU.WHXB201501212

• 3018Abstract/Metrics
• 1211 PDF(973KB)

NEWS AND COMMENTS

• 我国物理化学领域2014 年典型研究进展及其对科技工作者的启示
• YANG Jun-Lin
• 本文介绍了我国物理化学领域在2014年取得的14个典型研究进展, 通过分析这些进展取得的关键因素, 进而阐述了对科技工作者的几点启示.
• 2015, 31 (3): 589-504. DOI: 10.3866/PKU.WHXB201503029

• 4073Abstract/Metrics
• 2855 PDF(454KB)