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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
2015 Vol. 31,No. 3
Published: 06 March 2015
Current column
Table of Contents
REVIEW
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
THEORETICAL AND COMPUTATIONAL CHEMISTRY
ELECTROCHEMISTRY AND NEW ENERGY
SOFT MATTER
CATALYSIS AND SURFACE SCIENCE
PHOTOCHEMISTRY AND RADIATION CHEMISTRY
BIOPHYSICAL CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
NEWS AND COMMENTS
Table of Contents
Cover and Table of Contents for Vol.31 No. 3
2015, 31 (3): 0.
1241
Abstract/Metrics
1272
PDF(7668KB)
REVIEW
Functional Applications of Ordered Honeycomb-Patterned Porous Films Based on the Breath Figure Technique
LI Zhi-Guang, MA Xiao-Yan, HONG Qing, GUAN Xing-Hua
The breath figure (BF) technique is regarded as a powerful tool for the fabrication of strictly ordered and closely pack...
2015, 31 (3): 393-411.
DOI: 10.3866/PKU.WHXB201412261
4154
Abstract/Metrics
3273
PDF(2086KB)
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
Low Temperature Heat Capacities of Uracil and 5-Bromouracil
ZHANG Xiao-Ye, XUE Bin, CHENG Ze, TAN Zhi-Cheng, SHI Quan
The heat capacities of uracil and 5-bromouracil were measured using a quantum design physical property measurement syste...
2015, 31 (3): 412-418.
DOI: 10.3866/PKU.WHXB201501122
2617
Abstract/Metrics
1087
PDF(742KB)
Photochemical Reaction Kinetics of Duroquinone in a Mixture of Ionic Liquid [BPy][BF
4
] and Acetonitrile
ZHU Guang-Lai, WANG Yu, ZHANG Liang-Wei, LIU Yan-Cheng, WU Guo-Zhong
Photochemical reactions of duroquinone (DQ) in solutions consisting of mixtures of the ionic liquid N-butylpyridinium te...
2015, 31 (3): 419-424.
DOI: 10.3866/PKU.WHXB201501222
2993
Abstract/Metrics
994
PDF(1024KB)
THEORETICAL AND COMPUTATIONAL CHEMISTRY
Nitrous Oxide Decomposition Catalyzed by Au
19
Pd and Au
19
Pt Clusters
YU Wei-Ling, ZUO Hui-Wen, LU Chun-Hai, LI Yi, ZHANG Yong-Fan, CHEN Wen-Kai
The catalytic decomposition of N2O using Au19Pd and Au19Pt clusters as catalysts with optimized geometries was studied u...
2015, 31 (3): 425-434.
DOI: 10.3866/PKU.WHXB201501191
2583
Abstract/Metrics
1332
PDF(1164KB)
Theoretical Analysis of Pnicogen and Chalcogen Bonds in H
2
XP…SHY Complexes
LIU Yu-Zhen, LI An-Yong
The MP2 and CCSD(T) ab initio quantum chemistry methods were applied to study the pnicogen bonds X―P…S and chalco...
2015, 31 (3): 435-440.
DOI: 10.3866/PKU.WHXB201501211
2550
Abstract/Metrics
Supporting Info
1203
PDF(1292KB)
Prediction of Native Point Defects in HfO
2
Crystals Using First Principles and Thermodynamic Calculations
LIU Feng-Ming, LIU Ting-Yu, LIU Jian, LI Hai-Xin
Based on first principles and thermodynamics the intrinsic point defect formation energy was calculated at different tem...
2015, 31 (3): 441-447.
DOI: 10.3866/PKU.WHXB201412301
2858
Abstract/Metrics
1483
PDF(1217KB)
ELECTROCHEMISTRY AND NEW ENERGY
Dye-Sensitized Solar Cells Based on MWCNT/TiO
2
Counter Electrode and Thiolate/Disulfide Non-Iodine Redox Couple
WANG Yu-Qiao, WANG Pan-Pan, LU Jing, BAI Yi-Chao, GU Yun-Liang, SUN Yue-Ming
Multi-walled carbon nanotube (MWCNT)/TiO2 composites were prepared using acid-treated MWCNT and titanium (IV) isopropoxi...
2015, 31 (3): 448-456.
DOI: 10.3866/PKU.WHXB201412302
2683
Abstract/Metrics
1424
PDF(1411KB)
Photoelectric Properties of Graphene Oxide Film Prepared with the Electrochemical Method Using Varying Levels of Reduction
LI Wen-You, HE Yun-Qiu, LI Yi-Ming
This article details a quick and simple method to prepare graphene oxide (GO) film and tune its energy level by adjustin...
2015, 31 (3): 457-466.
DOI: 10.3866/PKU.WHXB201501093
4047
Abstract/Metrics
Supporting Info
2223
PDF(3320KB)
Corrosion Behavior of Alloy 690 in Simulated Alkaline Water Chemistries Containing Sulfur at 300 ℃
XIA Da-Hai, LUO Jing-Li
Alloy 690 is one of the steam generator (SG) tubing materials in pressurized water reactors (PWR). The degradation of th...
2015, 31 (3): 467-475.
DOI: 10.3866/PKU.WHXB201501053
2611
Abstract/Metrics
1173
PDF(1720KB)
Enhanced Electrochromic Performance of Ordered Porous Monolayer PBTB Film Using Amine-Modified Polystyrene Spheres as a Template
OUYANG Mi, HUANG Sen-Biao, HAN Yan-Gang, Lü Xiao-Jing, YANG Yuan, DAI Yu-Yu, Lü Yao-Kang, ZHANG Cheng
Poly(1,4-bis(2- thienyl)-benzene) (PBTB) with a highly ordered porous nanostructure was successfully made using monolaye...
2015, 31 (3): 476-482.
DOI: 10.3866/PKU.WHXB201501121
2967
Abstract/Metrics
997
PDF(1029KB)
Effects of Gold Nanoparticles on Quantum Dot Electrochemiluminescence Obtained Using a DNA Electrochemiluminescence Sensor
LU Li-Ping, LI Jiao, WU Jing, KANG Tian-Fang, CHENG Shui-Yuan
Gold nanoparticles (AuNPs) have a high extinction coefficient and a strong surface plasmon resonance, the latter of whic...
2015, 31 (3): 483-488.
DOI: 10.3866/PKU.WHXB201501151
3261
Abstract/Metrics
1315
PDF(899KB)
Simulation of Sphere-Microstructure Model of the Catalyst Layer in a PEMFC
ZHANG Jie-Jing, WANG Yu-Xin, XU Li
The catalyst layer in a proton-exchange-membrane fuel cell (PEMFC) was simulated based on a sphere-microstructure model ...
2015, 31 (3): 489-497.
DOI: 10.3866/PKU.WHXB201501221
2743
Abstract/Metrics
1037
PDF(1203KB)
Preparation and Electrocatalytic Performance of Iron Based Nitrogen Doped Carbon Nanotubes
LI Li-Xiang, ZHAO Hong-Wei, XU Wei-Wei, ZHANG Yan-Qiu, AN Bai-Gang, GENG Xin
Polypyrrole coated carbon nanotubes (PPy/CNTs) were synthesized by the in-situ chemical polymerization of pyrroles on CN...
2015, 31 (3): 498-504.
DOI: 10.3866/PKU.WHXB201412162
3011
Abstract/Metrics
1297
PDF(975KB)
SOFT MATTER
Formation of Colloidal Spheres from a Lignin-Based Azo Polymer
DENG Yong-Hong, LIU You-Fa, ZHANG Wei-Jian, QIU Xue-Qing
2-(4-Ethyl formate phenyl azo) phenol lignin-modified polymer (AL-azo-COOEt), a novel ligninbased azo polymer, has been ...
2015, 31 (3): 505-511.
DOI: 10.3866/PKU.WHXB201501192
2951
Abstract/Metrics
1118
PDF(986KB)
CATALYSIS AND SURFACE SCIENCE
Enhanced Effect of O/N Groups on the Hg0 Removal Efficiency over the HNO
3
-Modified Activated Carbon
TONG Li, XU Wen-Qing, QI Hao, ZHOU Xuan, LIU Rui-Hui, ZHU Ting-Yu
HNO3-modified activated carbon (AC) was prepared to determine its mercury removal ability on a fixed-bed reactor. In thi...
2015, 31 (3): 512-518.
DOI: 10.3866/PKU.WHXB201412251
3145
Abstract/Metrics
1119
PDF(954KB)
Preparation and Photocatalytic Activity of Mixed Phase TiO
2
-Graphene Composites
YU Jian-Hua, FAN Min-Guang, LI Bin, DONG Li-Hui, ZHANG Fei-Yue
A series of composites consisting of anatase-rutile TiO2 and graphene (TrG) were synthesized by a hydrothermal route. Th...
2015, 31 (3): 519-526.
DOI: 10.3866/PKU.WHXB201412291
3498
Abstract/Metrics
1515
PDF(1221KB)
Preparation of Amorphous Co-B/
γ
-Al
2
O
3
Catalyst and Its Performance in Catalytic Liquid Phase Hydrogenation of Ethyl Lactate
ZHAO Feng-Wei, SHEN Mei-Yu, WANG Lin, DU Chang-Hai
Supported cobalt amorphous catalysts Co-B/γ-Al2O3 were prepared using an impregnation-chemical reduction method fo...
2015, 31 (3): 527-532.
DOI: 10.3866/PKU.WHXB201501052
2278
Abstract/Metrics
892
PDF(970KB)
Preparation, Characterization and Hydrodesulfurization Catalytic Performances of Mo-Ni
2
P/SBA-15 Catalysts
WANG Zhou-Jun, WU Ping-Yi, LAN Ling, LIU Kun-Hong, HU Ya-Qiong, JI Sheng-Fu
A series of Mo-Ni2P/SBA-15 catalysts with various Mo loadings were prepared by impregnating nickel nitrate, diammonium h...
2015, 31 (3): 533-539.
DOI: 10.3866/PKU.WHXB201501094
2750
Abstract/Metrics
1093
PDF(1053KB)
Improved Photocatalytic Degradation of Phenol over
β
-Bi
2
O
3
Modified Bi
2
WO
6
and Possible Mechanism
LI Xiao-Jin, SHENG Jia-Yi, CHEN Hai-Hang, XU Yi-Ming
In this study, a series of Bi2O3-containing Bi2WO6 catalysts were prepared by a simple mixing method. We used the oxidat...
2015, 31 (3): 540-544.
DOI: 10.3866/PKU.WHXB201501131
2841
Abstract/Metrics
1440
PDF(818KB)
Effect of H
2
S Concentration on MoO
3
/Al
2
O
3
and CoO-MoO
3
/Al
2
O
3
Catalysts for Sulfur-Resistant Methanation
WANG Bao-Wei, LIU Si-Han, HU Zong-Yuan, LI Zhen-Hua, MA Xin-Bin
The activities of 25% (mass fraction, w) MoO3/Al2O3 and 5% (w) CoO-25%MoO3/Al2O3 catalysts in a sulfur-resistant methana...
2015, 31 (3): 545-551.
DOI: 10.3866/PKU.WHXB201501202
2495
Abstract/Metrics
870
PDF(561KB)
PHOTOCHEMISTRY AND RADIATION CHEMISTRY
Antimicrobial Drug Levofloxacin Applied to an Organic Light-Emitting Diode
MIAO Yan-Qin, GAO Zhi-Xiang, WU Yu-Ling, DU Xiao-Gang, LI Yuan-Hao, LIU Hui-Hui, JIA Hu-Sheng, WANG Hua, LIU Xu-Guang
Levofloxacin (LOFX) is a well-known and inexpensive antimicrobial drug that can be easily synthesized and purified. We r...
2015, 31 (3): 552-558.
DOI: 10.3866/PKU.WHXB201501051
3158
Abstract/Metrics
1123
PDF(1085KB)
Effect of HNO
3
on the γ Radiolysis and Radiolytic Liquid Products of
N, N
-Dimethylhydroxylamine
WANG Jin-Hua, CAO Xiao-Jun, LI Chun, WU Ming-Hong, BAO Bo-Rong, ZHENG Wei-Fang, HE Hui, ZHANG Sheng-Dong
N,N-dimethylhydroxylamine (DMHA) is a novel salt-free reductant used for the separation of U from Pu and Np in the repro...
2015, 31 (3): 559-565.
DOI: 10.3866/PKU.WHXB201501092
3012
Abstract/Metrics
884
PDF(620KB)
BIOPHYSICAL CHEMISTRY
Molecular Dynamics Simulation and Antibacterial Mechanism of 3MBA Derivatives as FtsZ Protein Inhibitors
ZHANG He, LU Jun-Rui, MU Jiang-Bei, LIU Jin-Biao, YANG Xu-Yun, WANG Mei-Jun, ZHANG Rui-Bo
In this paper, the complex stability, secondary structure, protein conformation, residue distance, active site volume, a...
2015, 31 (3): 566-575.
DOI: 10.3866/PKU.WHXB201501061
3340
Abstract/Metrics
2138
PDF(1462KB)
PHYSICAL CHEMISTRY OF MATERIALS
Optical and Electrical Properties of CH
3
NH
3
PbI
3
Perovskite Thin Films Transformed from PbO-PbI
2
Hybrid Films
DING Xu-Kun, LI Xiao-Min, GAO Xiang-Dong, ZHANG Shu-De, HUANG Yu-Di, LI Hao-Ran
Organic-inorganic halide perovskites have been shown to be outstanding photovoltaic materials, achieving remarkably high...
2015, 31 (3): 576-582.
DOI: 10.3866/PKU.WHXB201501201
2621
Abstract/Metrics
2235
PDF(1203KB)
Preparation and Structure Regulation of Silicon Carbide-Derived Carbon/ Spherical Natural Graphite Composites
DU Xue-Lian, CONG Ye, JIANG Lu, LI Xuan-Ke, CUI Zheng-Wei, DONG Zhi-Jun, YUAN Guan-Ming, ZHANG Jiang
To meet the requirements of the energy storage materials for high energy density and high power density, porous silicon ...
2015, 31 (3): 583-588.
DOI: 10.3866/PKU.WHXB201501212
2792
Abstract/Metrics
1155
PDF(973KB)
NEWS AND COMMENTS
我国物理化学领域2014 年典型研究进展及其对科技工作者的启示
YANG Jun-Lin
本文介绍了我国物理化学领域在2014年取得的14个典型研究进展, 通过分析这些进展取得的关键因素, 进而阐述了对科技工作者的几点启示.
2015, 31 (3): 589-504.
DOI: 10.3866/PKU.WHXB201503029
3864
Abstract/Metrics
2788
PDF(454KB)