制备方法对Nd2O3上过氧物种光诱导生成的影响

doi:10.3866/PKU.WHXB201705103

物理化学学报 >> 2017, Vol. 33 >> Issue (10): 2064-2071.doi: 10.3866/PKU.WHXB201705103

制备方法对Nd₂O₃上过氧物种光诱导生成的影响

吴倩,翁维正*(),刘春丽,黄传敬,夏文生,万惠霖*()

厦门大学固体表面物理化学国家重点实验室,醇醚酯化工清洁生产国家工程实验室,化学化工学院化学系,福建厦门361005

收稿日期:2017-02-27 发布日期:2017-07-17
通讯作者: 翁维正,万惠霖 E-mail:wzweng@xmu.edu.cn;hlwan@xmu.edu.cn
基金资助:
国家重点基础研究发展规划项目（973）(2013CB933102);国家自然科学基金(21173173);国家自然科学基金(21473144);教育部创新研究团队项目(IRT_14R31)

Effect of Preparation Methods on Photo-Induced Formation of Peroxide Species on Nd₂O₃

Qian WU,Wei-Zheng WENG*(),Chun-Li LIU,Chuan-Jing HUANG,Wen-Sheng XIA,Hui-Lin WAN*()

State Key Laboratory of Physical Chemistry of Solid State Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received:2017-02-27 Published:2017-07-17
Contact: Wei-Zheng WENG,Hui-Lin WAN E-mail:wzweng@xmu.edu.cn;hlwan@xmu.edu.cn
Supported by:
the National Key Basic Research Program of China (973)(2013CB933102);National Natural Science Foundation of China(21173173);National Natural Science Foundation of China(21473144);Program for Innovative Research Team in University, China(IRT_14R31)

摘要/Abstract

摘要：

分别采用水解、水热和燃烧法制备了三种主要物相均为立方Nd₂O₃的样品。以325 nm激光为激发源，在室温和空气气氛下对上述样品上过氧物种的光诱导生成情况进行了比较考察。经Raman光谱仪的激光束照射后，三种样品上均可检测到过氧物种的生成，但燃烧法制备的样品上过氧的生成速率显著大于其他两种样品。O₂-和CO₂-TPD（程序升温脱附）的表征结果表明，与水解和水热法制备的立方Nd₂O₃相比，燃烧法制备的样品表面含有更多的低配位晶格氧物种，晶格氧的碱性也更强，因而更有利于在光诱导下与分子氧反应生成过氧物种。

关键词: 氧化钕, 制备方法, 光诱导反应, 过氧物种, 晶格氧

Abstract:

Three Nd₂O₃ samples with cubic phase being the main component phase, denoted as Nd₂O₃-H, Nd₂O₃-HT, and Nd₂O₃-C, were synthesized by hydrolysis, hydrothermal, and combustion methods, respectively. A comparative study of the photo-induced formation of peroxide species on the three Nd₂O₃ samples was carried out using Raman spectroscopy with a 325 nm laser as the excitation source. After irradiation with the laser of the Raman spectrometer at room temperature in air, peroxide species was detected in all Nd₂O₃ samples. However, the rate of peroxide formation over Nd₂O₃-C was much greater than that over the other two samples. This observation can be explained by the differences in the structure and basicity of the surface lattice oxygen (O^2-) species of the samples. As evidenced by the results of O₂-and CO₂-temperature-programmed desorption (TPD) characterizations, the Nd₂O₃-C sample contains greater number of surface lattice oxygen (O^2-) species with low coordination numbers than the other two samples. Moreover, the basicity of the surface O^2- species in Nd₂O₃-C is stronger than that in the Nd₂O₃-H and Nd₂O₃-HT samples. Both these factors are in favor of the reaction of lattice oxygen with molecular oxygen to generate peroxide species under photo irradiation.

Key words: Nd₂O₃, Preparation method, Photo-induced, Peroxide species, Lattice oxygen

吴倩,翁维正,刘春丽,黄传敬,夏文生,万惠霖. 制备方法对Nd₂O₃上过氧物种光诱导生成的影响[J]. 物理化学学报, 2017, 33(10), 2064-2071. doi: 10.3866/PKU.WHXB201705103

Qian WU,Wei-Zheng WENG,Chun-Li LIU,Chuan-Jing HUANG,Wen-Sheng XIA,Hui-Lin WAN. Effect of Preparation Methods on Photo-Induced Formation of Peroxide Species on Nd₂O₃[J]. Acta Phys. -Chim. Sin. 2017, 33(10), 2064-2071. doi: 10.3866/PKU.WHXB201705103

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201705103

https://www.whxb.pku.edu.cn/CN/Y2017/V33/I10/2064

参考文献

1	Panov G. I. ; Dubkov K. A. ; Starokon E. V. Catal. Today 2006, 117 (1), 148.
2	Guo Z. ; Liu B. ; Zhang Q. ; Deng W. ; Wang Y. ; Yang Y. Chem. Soc. Rev. 2014, 43 (10), 3480.
3	Weng W. Z. ; Wan H. L. ; Li J. M. ; Cao Z. X. Angew. Chem. Int. Ed. 2004, 43 (8), 975.
4	Jing X. L. ; Chen Q. C. ; He C. ; Zhu X. Q. ; Weng W. Z. ; Xia W. S. ; Wan H. L. Phys. Chem. Chem. Phys. 2012, 14 (19), 6898.
5	Jing X. L. ; She W. Y. ; Weng W. Z. ; Li J. M. ; Xia W. S. ; Wan H. L. Chin. J. Catal. 2014, 35 (8), 1385.
5	景孝廉; 佘雯瑜; 翁维正; 李建梅; 夏文生; 万惠霖. 催化学报, 2014, 35 (8), 1385.
6	Li J. M. ; Jing X. L. ; Weng W. Z. ; Chang Z. Y. ; An D. L. ; Xia W. S. ; Wan H. L. Scientia Sinica Chimica 2014, 44 (12), 1931.
6	李建梅; 景孝廉; 翁维正; 常泽英; 安冬丽; 夏文生; 万惠霖. 中国科学:化学, 2014, 44 (12), 1931.
7	Jing X. L. ; She W. Y. ; Li J. M. ; Chen Q. C. ; Weng W. Z. ; An D. L. ; Wan H. L. Chem. Asian J. 2015, 10 (10), 2162.
8	Bazzi R. ; Flores-Gonzalez M. A. ; Louis C. ; Lebbou K. ; Dujardin C. ; Brenier A. ; Zhang W. ; Tillement O. ; Bernstein E. ; Perriat P. J. Lumin. 2003, 102-103, 445.
9	Qian H. ; Lin G. ; Zhang Y. ; Gunawan P. ; Xu R. Nanotechnology 2007, 18 (35), 355602.
10	Zawadzki M. ; Kepinski L. J. Alloys Compd. 2004, 380 (1), 255.
11	Zeng W. W. ; Huang K. L. ; Yang Y. P. ; Liu S. Q. ; Liu R. S. Acta Phys. -Chim. Sin. 2008, 24 (2), 263.
11	曾雯雯; 黄可龙; 杨幼平; 刘素琴; 刘人生. 物理化学学报, 2008, 24 (2), 263.
12	Kepinski L. ; Zawadzki M. ; Mista W. Solid State Sci. 2004, 6 (12), 1327.
13	Hayashi H. ; Hakuta Y. Mater. 2010, 3 (7), 3794.
14	Hu H. F. ; He T. Acta Phys. -Chim. Sin. 2016, 32 (2), 543.
14	胡海峰; 贺涛. 物理化学学报, 2016, 32 (2), 543.
15	Chavan S. V. ; Sastry P. U. M. ; Tyagi A. K. J. Alloys Compd. 2008, 456 (1), 51.
16	Umesh B. ; Eraiah B. ; Nagabhushana H. ; Nagabhushana B.M. ; Nagaraja G. ; Shivakumara C. ; Chakradhar R. P. S. J. Alloys Compd. 2011, 509 (4), 1146.
17	Yu R. B. ; Yu K. H. ; Wei W. ; Xu X. X. ; Qiu X. M. ; Liu S. ; Huang W. ; Tang G. ; Ford H. ; Peng B. Adv. Mater. 2007, 19 (6), 838.
18	Sreethawong T. ; Chavadej S. ; Ngamsinlapasathian S. ; Yoshikawa S. Solid State Sci. 2008, 10 (1), 20.
19	Duhan S. ; Aghamkar P. Acta Phys. Pol. A 2008, 113 (6), 1671.
20	Shafer M. W. ; Roy R. J. Am. Ceram. Soc. 1959, 42 (11), 563.
21	Tong J. ; Eyring L. J. Alloys Compd. 1995, 225 (1-2), 139.
22	Ubaldini A. ; Carnasciali M. M. J. Alloys Compd. 2008, 454 (1-2), 374.
23	Abrashev M. V. ; Todorov N. D. ; Geshev J. J. Appl. Phys. 2014, 116 (10), 103508.
24	Lunsford J. H. ; Yang X. ; Haller K. ; Laane J. ; Mestl G. ; Knozinger H. J. Phys. Chem. 1993, 97 (51), 13810.
25	Boldish S. I. ; White W. B. Spectrochim. Acta 1979, 35 (11), 1235.
26	Gopinatht C. R. ; Brown I. D. J. Raman Spectrosc. 1982, 12 (3), 278.
27	Turcotte R. P. ; Sawyer J. O. ; Eyring L. J. Inorg. Chem. 1969, 8 (2), 238.
28	Klingenberg B. ; Vannice M. A. J. Chem. Mater. 1996, 8 (12), 2755.
29	Jiang G. J. ; Zhuang H. R. ; Li W. L. ; Wu F. Y. ; Zhang B. L. Prog. Chem. 1998, 10 (3), 327.
29	江国健; 庄汉锐; 李文兰; 邬凤英; 张宝林. 化学进展, 1998, 10 (3), 327.
30	Auroux A. ; Gervasini A. J. Phys. Chem. 1990, 94 (16), 6371.
31	Choudhary V. R. ; Uphade B. S. ; Mulla S. A. R. Ind. Eng. Chem. Res. 1997, 36 (9), 3594.
32	Choudhary V. R. ; Mulla S. A. R. ; Uphade B. S. Fuel 1999, 78 (4), 427.
33	Yamazoe N. ; Teraoka Y. ; Seiyama T. Chem. Lett. 1981, 10 (12), 1767.
34	Kung, H. H. Transition Metal Oxides: Surface Chemistry and Catalysis, Elsevier: Amsterdam, 1989; pp 112-113.
35	Ding W. ; Chen Y. ; Fu X. Catal. Lett. 1994, 23 (1), 69.
36	You R. ; Zhang Y. ; Liu D. ; Meng M. ; Zheng L. ; Zhang J. ; Hu T. J. Phys. Chem. C 2014, 118 (44), 25403.
37	Huang S. J. ; Walters A. B. ; Vannice M. A. J. Catal. 2000, 192 (1), 29.
38	Jiang X. Y. ; Zhou R. X. ; Pan P. ; Zhu B. ; Yuan X. X. ; Zheng X. M. Appl. Catal. A: Gen. 1997, 150 (1), 131.

[1]	张勇, 陆浩杰, 梁晓平, 张明超, 梁华润, 张莹莹. 蚕丝基智能纤维及织物：潜力、现状与未来展望[J]. 物理化学学报, 2022, 38(9): 2103034 - .
[2]	姜美慧, 盛利志, 王超, 江丽丽, 范壮军. 超级电容器用石墨烯薄膜：制备、基元结构及表面调控[J]. 物理化学学报, 2022, 38(2): 2012085 - .
[3]	刘晓婷, 张金灿, 陈恒, 刘忠范. 超洁净石墨烯薄膜的制备方法[J]. 物理化学学报, 2022, 38(1): 2012047 - .
[4]	郑倩, 曹玥晗, 黄南建, 张瑞阳, 周莹. BN诱导BiOI富氧{110}面的暴露并增强其可见光催化氧化性能[J]. 物理化学学报, 2021, 37(8): 2009063 - .
[5]	程飞,杨建,闫亮,赵军,赵华华,宋焕玲,丑凌军. 固体酸WO₃/TiO₂负载锂锰催化剂组成对其甲烷氧化偶联反应性能的影响[J]. 物理化学学报, 2019, 35(9): 1027 -1036 .
[6]	张英杰,朱子翼,董鹏,邱振平,梁慧新,李雪. LiFePO₄电化学反应机理、制备及改性研究新进展[J]. 物理化学学报, 2017, 33(6): 1085 -1107 .
[7]	张雪,韩洋,柴双志,胡南滔,杨志,耿会娟,魏浩. Cu₂ZnSn(S,Se)₄薄膜太阳电池研究进展[J]. 物理化学学报, 2016, 32(6): 1330 -1346 .
[8]	张洁, 张江浩, 张长斌, 贺泓. 不同晶相结构二氧化锰催化完全氧化乙醇[J]. 物理化学学报, 2015, 31(2): 353 -359 .
[9]	邓陶丽, 闫世润, 胡建国. GdAlO₃：Er³⁺，Yb³⁺荧光粉的制备与上转换发光性能[J]. 物理化学学报, 2014, 30(4): 773 -780 .
[10]	胡晓燕, 李春义, 杨朝合. V₂O₅负载量对V₂O₅/Al₂O₃氧化活化正庚烷催化裂解反应的影响[J]. 物理化学学报, 2011, 27(09): 2209 -2216 .
[11]	叶青, 赵建生, 李冬辉, 赵俊, 程水源, 康天放. SnO₂负载Au和M-Au(M=Pt, Pd)催化剂及其低温催化氧化CO性能[J]. 物理化学学报, 2011, 27(01): 169 -176 .
[12]	李雷, 詹瑛瑛, 陈崇启, 佘育生, 林性贻, 郑起. 不同方法制备的CeO₂载体对CuO/CeO₂催化剂水煤气变换活性和稳定性的影响[J]. 物理化学学报, 2009, 25(07): 1397 -1404 .
[13]	邓正华;李仁贵;王璐;邓佳闽;高建东;马志刚;杜鸿昌;索继栓. 锂离子电池隔膜的研究进展[J]. 物理化学学报, 2007, 23(Supp): 90 -93 .
[14]	胡义华;林家勇;武华;陈仁;王小涓;杨世和. 复合物Mg⁺-S₂(CH₃)₂的光诱导反应[J]. 物理化学学报, 2006, 22(06): 744 -746 .
[15]	王海水;王一兵;席时权. 电荷转移配合物薄膜制备方法和结构表征的研究进展[J]. 物理化学学报, 2004, 20(10): 1281 -1286 .

制备方法对Nd₂O₃上过氧物种光诱导生成的影响

Effect of Preparation Methods on Photo-Induced Formation of Peroxide Species on Nd₂O₃

RichHTML

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

推荐阅读 0