基于单原子催化剂的光热催化转化：原理和应用

doi:10.3866/PKU.WHXB202212038

摘要/Abstract

摘要：

在以碳中和为目标的全球共识下，太阳能作为一种取之不竭用之不尽的绿色环保能源被认为是替代传统化石燃料最有潜力的方式。在各种太阳能转换技术中，光热催化不仅可以最大化利用太阳能，在光场和热场双重驱动力作用下，还可以显著提升化学反应速率，引起广泛的研究兴趣。以孤立的单个原子均匀分散在载体上形成的单原子催化剂具有100%原子利用率、优异的催化活性、热稳定性等优势。因此，将单原子催化剂应用于光热催化开始受到越来越多的关注。本综述介绍了光催化、热催化和光热催化的基本原理和特征，同时列举一些典型的例子。随后以不同载体作为分类标准，总结了单原子光热催化应用的前沿研究进展。最后，提出了该催化体系所面临的挑战和未来的发展方向。本文旨在全面了解单原子催化剂在太阳能驱动光热催化领域的研究现状并为未来发展提供可行的建议。

关键词: 光热催化, 光催化, 热催化, 单原子催化剂, 太阳能

Abstract:

To achieve the stated goal of carbon neutrality, solar energy is regarded as the most promising alternative to traditional fossil fuels as a sustainable and clean resource. The key prerequisite for improving the efficiency of solar conversion is to maximize solar energy utilization. As a promising technology, photothermal catalysis can harness full-spectrum sunlight to activate photocatalysis and thermocatalysis through hot carrier generation and local heating. These synergistic catalytic effects driven by both light and heat can overcome the challenges associated with the low catalytic efficiency of photocatalysis and high energy consumption of thermocatalysis as well as modulate the reaction pathways to achieve desirable activity and selectivity. To achieve outstanding catalytic performance, photothermal materials should meet the requirements for sufficient electron-hole separation, efficient solar thermal generation, and abundant exposed active sites. Common fabrication strategies are based on the integration of materials with photo-active and photothermal conversion capabilities that often suffer from buried active sites, high temperature-induced deactivation, and complicated synthetic procedures. Single-atom catalysts (SACs) with isolated single atoms uniformly dispersed on a solid surface are advantageous for 100% atomic utilization and excellent catalytic activity. Therefore, these materials have received increasing attention for a wide range of applications. Many SAC substrates are endowed with hot carrier generation and photothermal conversion abilities under illumination. The strong chemical interaction between metal atoms and supports or surface lattice reconstruction can also prevent catalyst sintering even in long-term high-temperature environments. These unique features make SACs highly suitable for photothermal catalytic processes. Therefore, it is important to summarize recent advances in this field and provide in-depth insights into SACs-based photothermal catalysis to accelerate solar conversion technology development. Herein, the fundamental mechanisms and characteristics of photocatalysis, thermocatalysis, and photothermal catalysis are introduced and three photothermal catalysis modes categorized by driving force (including photo-driven thermocatalysis, thermal-assisted photocatalysis, and photo-thermal co-catalysis) are described and compared along with representative examples. The photothermal properties of SACs supported by carbon, semiconductors, and plasmonic materials are reviewed and pioneering studies for different applications are discussed in detail. Finally, the challenges and future research directions are proposed. This review aims to give a comprehensive understanding of photothermal catalytic processes driven by solar energy based on SACs and provide accessible guidelines for future development to achieve carbon neutrality targets.

Key words: Photothermal catalysis, Photocatalysis, Thermocatalysis, Single atom catalysts, Solar energy

宋千伟, 何观朝, 费慧龙. 基于单原子催化剂的光热催化转化：原理和应用[J]. 物理化学学报, 2023, 39(9), 2212038. doi: 10.3866/PKU.WHXB202212038

Qianwei Song, Guanchao He, Huilong Fei. Photothermal Catalytic Conversion Based on Single Atom Catalysts: Fundamentals and Applications[J]. Acta Phys. -Chim. Sin. 2023, 39(9), 2212038. doi: 10.3866/PKU.WHXB202212038

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202212038

https://www.whxb.pku.edu.cn/CN/Y2023/V39/I9/2212038

图/表 11

图1

图2

表1

图3

图4

图5

图6

图7

图8

图9

图10

参考文献 85

1	Ciriminna, R.; Falletta, E.; Della Pina, C.; Teles, J. H.; Pagliaro, M. Angew. Chem. Int. Ed. 2016, 55, 14209. doi: 10.1002/anie.201604656
2	Schlummer, B. Chem. unserer Zeit 2016, 50, 114. doi: 10.1002/ciuz.201500705
3	Rusdan, N. A.; Timmiati, S. N.; Isahak, W. N. R. W.; Yaakob, Z.; Lim, K. L.; Khaidar, D. Nanomaterials 2022, 12, 3877. doi: 10.3390/nano12213877
4	Hashimoto, K.; Irie, H.; Fujishima, A. Jpn. J. Appl. Phys. Part 1 - Regul. Pap. Brief Commun. Rev. Pap. 2005, 44, 8269. doi: 10.1143/jjap.44.8269
5	Wu, H.; Tan, H. L.; Toe, C. Y.; Scott, J.; Wang, L. Z.; Amal, R.; Ng, Y. H. Adv. Mater. 2020, 32, 21. doi: 10.1002/adma.201904717
6	Bora, L. V.; Mewada, R. K. Renew. Sust. Energ. Rev. 2017, 76, 1393. doi: 10.1016/j.rser.2017.01.130
7	Wu, K.; Chen, J.; McBride, J. R.; Lian, T. Science 2015, 349, 632. doi: 10.1126/science.aac5443
8	Mateo, D.; Cerrillo, J. L.; Durini, S.; Gascon, J. Chem. Soc. Rev. 2021, 50, 2173. doi: 10.1039/d0cs00357c
9	Li, Z.; Liu, J.; Zhao, Y.; Waterhouse, G. I. N.; Chen, G.; Shi, R.; Zhang, X.; Liu, X.; Wei, Y.; Wen, X. D.; et al. Adv. Mater. 2018, 30, e1800527. doi: 10.1002/adma.201800527
10	Jia, J.; O'Brien, P. G.; He, L.; Qiao, Q.; Fei, T.; Reyes, L. M.; Burrow, T. E.; Dong, Y.; Liao, K.; Varela, M.; et al. Adv. Sci. 2016, 3, 1600189. doi: 10.1002/advs.201600189
11	Zhang, H.; Wang, T.; Wang, J.; Liu, H.; Dao, T. D.; Li, M.; Liu, G.; Meng, X.; Chang, K.; Shi, L.; et al. Adv. Mater. 2016, 28, 3703. doi: 10.1002/adma.201505187
12	Yang, Y.; Zhao, S.; Cui, L.; Bi, F.; Zhang, Y.; Liu, N.; Wang, Y.; Liu, F.; He, C.; Zhang, X. Green Energy Environ. 2022, doi: 10.1016/j.gee.2022.02.006
13	Zhu, L. L.; Gao, M. M.; Peh, C. K. N.; Ho, G. W. Mater. Horiz. 2018, 5, 323. doi: 10.1039/c7mh01064h
14	Zhou, S.; Shang, L.; Zhao, Y.; Shi, R.; Waterhouse, G. I. N.; Huang, Y. C.; Zheng, L.; Zhang, T. Adv. Mater. 2019, 31, e1900509. doi: 10.1002/adma.201900509
15	Fei, H. L.; Dong, J. C.; Arellano-Jimenez, M. J.; Ye, G. L.; Kim, N. D.; Samuel, E. L. G.; Peng, Z. W.; Zhu, Z.; Qin, F.; Bao, J. M.; et al. Nat. Commun. 2015, 6, 8. doi: 10.1038/ncomms9668
16	Yan, H.; Zhao, M.; Feng, X.; Zhao, S.; Zhou, X.; Li, S.; Zha, M.; Meng, F.; Chen, X.; Liu, Y.; et al. Angew. Chem. Int. Ed. 2022, 61, e202116059. doi: 10.1002/anie.202116059
17	Zhang, F. F.; Zhu, Y. L.; Lin, Q.; Zhang, L.; Zhang, X. W.; Wang, H. T. Energy Environ. Sci. 2021, 14, 2954. doi: 10.1039/d1ee00247c
18	Yin, P. Q.; Yao, T.; Wu, Y.; Zheng, L. R.; Lin, Y.; Liu, W.; Ju, H. X.; Zhu, J. F.; Hong, X.; Deng, Z. X.; et al. Angew. Chem. Int. Ed. 2016, 55, 10800. doi: 10.1002/anie.201604802
19	Li, X. Y.; Wang, C.; Tang, J. W. Nat. Rev. Mater. 2022, 7, 617. doi: 10.1038/s41578-022-00422-3
20	Li, X.; Wang, W.; Dong, F.; Zhang, Z.; Han, L.; Luo, X.; Huang, J.; Feng, Z.; Chen, Z.; Jia, G.; et al. ACS Catal. 2021, 11, 4739. doi: 10.1021/acscatal.0c05354
21	Chong, M. N.; Jin, B.; Chow, C. W. K.; Saint, C. Water Res. 2010, 44, 2997. doi: 10.1016/j.watres.2010.02.039
22	Zhou, P.; Yu, J.; Jaroniec, M. Adv. Mater. 2014, 26, 4920. doi: 10.1002/adma.201400288
23	Pokrant, S. Nature 2020, 581, 386. doi: 10.1038/d41586-020-01455-w
24	Zhao, Y.; Gao, W.; Li, S.; Williams, G. R.; Mahadi, A. H.; Ma, D. Joule 2019, 3, 920. doi: 10.1016/j.joule.2019.03.003
25	Tian, J.; Han, R.; Guo, Q.; Zhao, Z.; Sha, N. Catalysts 2022, 12, 612. doi: 10.3390/catal12060612
26	Meng, X. G.; Cui, X. J.; Rajan, N. P.; Yu, L.; Deng, D. H.; Bao, X. H. Chem 2019, 5, 2296. doi: 10.1016/j.chempr.2019.05.008
27	Wu, H. L.; Li, X. B.; Tung, C. H.; Wu, L. Z. Adv. Mater. 2019, 31, 23. doi: 10.1002/adma.201900709
28	Zhu, Z. Z.; Guo, W. Y.; Zhang, Y.; Pan, C. S.; Xu, J.; Zhu, Y. F.; Lou, Y. Carbon Energy 2021, 3, 519. doi: 10.1002/cey2.127
29	Wang, J.; Gao, X. X.; Wang, Y. J.; Wang, S. Y.; Xie, Z. W.; Yang, B. Z.; Zhang, Z. G.; Yang, Z.; Kang, L.; Yao, W. Q. Appl. Catal. B: Environ. 2022, 317, 19. doi: 10.1016/j.apcatb.2022.121789
30	Ge, H.; Kuwahara, Y.; Kusu, K.; Bian, Z.; Yamashita, H. Appl. Catal. B: Environ. 2022, 317, 121734. doi: 10.1016/j.apcatb.2022.121734
31	Guo, S.; Li, X.; Li, J.; Wei, B. Nat. Commun. 2021, 12, 1343. doi: 10.1038/s41467-021-21526-4
32	Wang, X.; Wu, L.; Wang, Z.; Feng, Y.; Liu, Y.; Dai, H.; Wang, Z.; Deng, J. Appl. Catal. B: Environ. 2023, 322, 122075. doi: 10.1016/j.apcatb.2022.122075
33	Feng. Y.; Dai, L.; Wang, Z.; Peng, Y.; Duan, E.; Liu, Y.; Jing, L.; Wang, X.; Rastegarpanah, A.; Dai, H.; et al. Environ. Sci. Technol. 2022, 56, 8722. doi: 10.1021/acs.est.1c08643
34	Feng, Y.; Ma, P.; Wang, Z.; Shi, Y.; Wang, Z.; Peng, Y.; Jing, L.; Liu, Y.; Yu, X.; Wang, X.; et al. Environ. Sci. Technol. 2022, 56, 17341. doi: 10.1021/acs.est.2c07146
35	Song, L.; Zhao, T.; Yang, D.; Wang, X.; Hao, X.; Liu, Y.; Zhang, S.; Yu, Z. Z. J. Hazard. Mater. 2020, 393, 122332. doi: 10.1016/j.jhazmat.2020.122332
36	Ma, R.; Sun, J.; Li, D. H.; Wei, J. J. Int. J. Hydrog. Energy 2020, 45, 30288. doi: 10.1016/j.ijhydene.2020.08.127
37	Cheng, P.; Wang, D.; Schaaf, P. Adv. Sustain. Syst 2022, 46, 1900. doi: 10.1002/adsu.202200115
38	Wu, Z.; Li, C.; Li, Z.; Feng, K.; Cai, M.; Zhang, D.; Wang, S.; Chu, M.; Zhang, C.; Shen, J.; et al. ACS Nano 2021, 15, 5696. doi: 10.1021/acsnano.1c00990
39	Yue, X. Y.; Liu, X.; Wang, K.; Yang, Z.; Chen, X.; Dai, W. X.; Fu, X. Z. Inorg. Chem. Front. 2022, 9, 1258. doi: 10.1039/d2qi00004k
40	Li, S.; Miao, P.; Zhang, Y.; Wu, J.; Zhang, B.; Du, Y.; Han, X.; Sun, J.; Xu, P. Adv. Mater. 2021, 33, e2000086. doi: 10.1002/adma.202000086
41	Liang, C.; Li, C.; Zhu, Y.; Du, X.; Zeng, Y.; Zhou, Y.; Zhao, J.; Li, S.; Liu, X.; Yu, Q.; et al. Appl. Surf. Sci. 2022, 601, 154144. doi: 10.1016/j.apsusc.2022.154144
42	Xiong, R.; Tang, C.; Li, K.; Wan, J.; Jia, W.; Xiao, Y.; Cheng, B.; Lei, S. J. Mater. Chem. A 2022, 10, 22819. doi: 10.1039/d2ta05712c
43	Li, P. Y.; Liu, L.; An, W. J.; Wang, H.; Guo, H. X.; Liang, Y. H.; Cui, W. Q. Appl. Catal. B: Environ. 2020, 266, 14. doi: 10.1016/j.apcatb.2020.118618
44	Li, L.; Li, Y.; Jiao, L.; Liu, X.; Ma, Z.; Zeng, Y.-J.; Zheng, X.; Jiang, H.-L. J. Am. Chem. Soc. 2022, 144, 17075. doi: 10.1021/jacs.2c06720
45	Liu, Y.; Zhang, Z.; Fang, Y.; Liu, B.; Huang, J.; Miao, F.; Bao, Y.; Dong, B. Appl. Catal. B: Environ. 2019, 252, 164. doi: 10.1016/j.apcatb.2019.04.035
46	Zhang, L.; Pan, J.; Liu, L.; Zhang, S.; Wang, X.; Song, S.; Zhang, H. Small 2022, 18, e2201271. doi: 10.1002/smll.202201271
47	Song, C.; Liu, X.; Xu, M.; Masi, D.; Wang, Y.; Deng, Y.; Zhang, M.; Qin, X.; Feng, K.; Yan, J.; et al. ACS Catal. 2020, 10, 10364. doi: 10.1021/acscatal.0c02244
48	Ding, X.; Liu, X.; Cheng, J.; Kong, L.; Guo, Y. Catal. Sci. Technol. 2022, 12, 4740. doi: 10.1039/D2CY00439A
49	Zhang, Z.; Mao, C.; Meira, D. M.; Duchesne, P. N.; Tountas, A. A.; Li, Z.; Qiu, C.; Tang, S.; Song, R.; Ding, X.; et al. Nat. Commun. 2022, 13, 1512. doi: 10.1038/s41467-022-29222-7
50	Ding, X.; Liu, X.; Cheng, J. H.; Kong, L. Z.; Guo, Y. Catal. Sci. Technol. 2022, 12, 4740. doi: 10.1039/d2cy00439a
51	Li, Y.; Liu, Z.; Rao, Z.; Yu, F.; Bao, W.; Tang, Y.; Zhao, H.; Zhang, J.; Wang, Z.; Li, J.; et al. Appl. Catal. B: Environ. 2022, 319, 121903. doi: 10.1016/j.apcatb.2022.121903
52	Qiao, B. T.; Wang, A. Q.; Yang, X. F.; Allard, L. F.; Jiang, Z.; Cui, Y. T.; Liu, J. Y.; Li, J.; Zhang, T. Nat. Chem. 2011, 3, 634. doi: 10.1038/nchem.1095
53	Zhu, Y.; Wang, W. Y.; Cheng, J. J.; Qu, Y. T.; Dai, Y.; Liu, M. M.; Yu, J. N.; Wang, C. M.; Wang, H. J.; Wang, S. C.; et al. Angew. Chem. Int. Ed. 2021, 60, 9480. doi: 10.1002/anie.202017152
54	Lu, X. Y.; Gao, S. S.; Lin, H.; Yu, L. D.; Han, Y. H.; Zhu, P. A.; Bao, W. C.; Yao, H. L.; Chen, Y.; Shi, J. L. Adv. Mater. 2020, 32, 9. doi: 10.1002/adma.202002246
55	Kerketta, U.; Tesler, A. B.; Schmuki, P. Catalysts 2022, 12, 1223. doi: 10.3390/catal12101223
56	Jin, X. X.; Wang, R. Y.; Zhang, L. X.; Si, R.; Shen, M.; Wang, M.; Tian, J. J.; Shi, J. L. Angew. Chem. Int. Ed. 2020, 59, 6827. doi: 10.1002/anie.201914565
57	Li, Z.; Liu, F. N.; Jiang, Y. Y.; Ni, P. J.; Zhang, C. H.; Wang, B.; Chen, C. X.; Lu, Y. Z. Nano Res. 2022, 15, 4411. doi: 10.1007/s12274-021-4029-0
58	Xi, J. B.; Jung, H. S.; Xu, Y.; Xiao, F.; Bae, J. W.; Wang, S. Adv. Funct. Mater. 2021, 31, 39. doi: 10.1002/adfm.202008318
59	Cui, X. J.; Li, W.; Ryabchuk, P.; Junge, K.; Beller, M. Nat. Catal. 2018, 1, 385. doi: 10.1038/s41929-018-0090-9
60	Lang, R.; Du, X.; Huang, Y.; Jiang, X.; Zhang, Q.; Guo, Y.; Liu, K.; Qiao, B.; Wang, A.; Zhang, T. Chem. Rev. 2020, 120, 11986. doi: 10.1021/acs.chemrev.0c00797
61	Shi, Q.; Yu, T.; Wu, R.; Liu, J. ACS Appl. Mater. Interfaces 2021, 13, 60815. doi: 10.1021/acsami.1c18797
62	Speranza, G. Nanomaterials 2021, 11, 99. doi: 10.3390/nano11040967
63	Li, Z.; Lei, H.; Kan, A.; Xie, H.; Yu, W. Energy 2021, 216, 119262. doi: 10.1016/j.energy.2020.119262
64	Yang, Q.; Yang, C. C.; Lin, C. H.; Jiang, H. L. Angew. Chem. Int. Ed. 2019, 58, 3511. doi: 10.1002/anie.201813494
65	Gong, L.; Sun, J.; Liu, Y. S.; Yang, G. C. J. Mater. Chem. A 2021, 9, 21689. doi: 10.1039/d1ta06159c
66	Liu, Y.; Wang, X. C.; Li, Q. Y.; Yan, T. R.; Lou, X. X.; Zhang, C. Y.; Cao, M. H.; Zhang, L.; Sham, T. K.; Zhang, Q.; et al. Adv. Funct. Mater. 2022, 2210283. doi: 10.1002/adfm.202210283
67	Guo, Y. C.; Chen, W. J.; Feng, L.; Fan, Y. C.; Liang, J. S.; Wang, X. M.; Zhang, X. J. Mater. Chem. A 2022, 10, 12418. doi: 10.1039/d2ta02885a
68	Tan, K. W.; Yap, C. M.; Zheng, Z. Y.; Haw, C. Y.; Khiew, P. S.; Chiu, W. S. Adv. Sustain. Syst. 2022, 6, 29. doi: 10.1002/adsu.202100416
69	Yang, J.; Wang, D.; Han, H.; Li, C. Acc. Chem. Res. 2013, 46, 1900. doi: 10.1021/ar300227e
70	Zhou, L. A.; Martirez, J. M. P.; Finzel, J.; Zhang, C.; Swearer, D. F.; Tian, S.; Robatjazi, H.; Lou, M. H.; Dong, L. L.; Henderson, L.; et al. Nat. Energy 2020, 5, 61. doi: 10.1038/s41560-019-0517-9
71	Liu, P. G.; Huang, Z. X.; Gao, X. P.; Hong, X.; Zhu, J. F.; Wang, G. M.; Wu, Y. E.; Zeng, J.; Zheng, X. S. Adv. Mater. 2022, 34, 2200057. doi: 10.1002/adma.202200057
72	Li, X. J.; Zhao, S. Y.; Duan, X. G.; Zhang, H. Y.; Yang, S. Z.; Zhang, P. P.; Jiang, S. P.; Liu, S. M.; Sun, H. Q.; Wang, S. B. Appl. Catal. B: Environ. 2021, 283, 119660. doi: 10.1016/j.apcatb.2020.119660
73	Cai, S.; Zhang, M.; Li, J.; Chen, J.; Jia, H. Sol. RRL 2020, 5, 2000313. doi: 10.1002/solr.202000313
74	Zheng, J.; Lu, L.; Lebedev, K.; Wu, S.; Zhao, P.; McPherson, I. J.; Wu, T. -S.; Kato, R.; Li, Y.; Ho, P. -L.; et al. Chem. Catal. 2021, 1, 162. doi: 10.1016/j.checat.2021.03.002
75	Dao, T. D.; Chen, K.; Ishii, S.; Ohi, A.; Nabatame, T.; Kitajima, M.; Nagao, T. ACS Photonics 2015, 2, 964. doi: 10.1021/acsphotonics.5b00195
76	Li, Y. G.; Hao, J. C.; Song, H.; Zhang, F. Y.; Bai, X. H.; Meng, X. G.; Zhang, H. Y.; Wang, S. F.; Hu, Y.; Ye, J. H. Nat. Commun. 2019, 10, 9. doi: 10.1038/s41467-019-10304-y
77	Li, Y. G.; Guan, Q. Q.; Huang, G. Y.; Yuan, D. C.; Xie, F.; Li, K. L.; Zhang, Z. B.; San, X. Y.; Ye, J. H. Adv. Energy Mater. 2022, 12, 2202459. doi: 10.1002/aenm.202202459
78	Wang, Z.; Xie, S.; Feng, Y.; Ma, P.; Zheng, K.; Duan, E.; Liu, Y.; Dai, H.; Deng. J. Appl. Catal. B: Environ. 2021, 298, 120612. doi: 10.1016/j.apcatb.2021.120612
79	Li, X.; Zhu, J.; Wei, B. Chem. Soc. Rev. 2016, 45, 3145. doi: 10.1039/c6cs00195e
80	Zhao, J.; Xue, S.; Ji, R. R.; Li, B.; Li, J. H. Chem. Soc. Rev. 2021, 50, 12070. doi: 10.1039/d1cs00237f
81	Shao, T.; Wang, X.; Dong, H.; Liu, S.; Duan, D.; Li, Y.; Song, P.; Jiang, H.; Hou, Z.; Gao, C.; et al. Adv. Mater. 2022, 34, e2202367. doi: 10.1002/adma.202202367
82	Han, L.; Zhang, L.; Wu, H.; Zu, H.; Cui, P.; Guo, J.; Guo, R.; Ye, J.; Zhu, J.; Zheng, X.; et al. Adv. Sci. 2019, 6, 1900006. doi: 10.1002/advs.201900006
83	Zhou, L. A.; Martirez, J. M. P.; Finzel, J.; Zhang, C.; Swearer, D. F.; Tian, S.; Robatjazi, H.; Lou, M. H.; Dong, L. L.; Henderson, L.; et al. Nat. Energy 2020, 5, 61. doi: 10.1038/s41560-019-0517-9
84	Yang, J. L.; Wang, H. J.; Zhu, Z.; Yue, M. F.; Yang, W. M.; Zhang, X. G.; Ruan, X.; Guan, Z.; Yang, Z. L.; Cai, W.; et al. Angew. Chem. Int. Ed. 2022, 61, e202112749. doi: 10.1002/anie.202112749
85	Li, Y.; Bai, X.; Yuan, D.; Zhang, F.; Li, B.; San, X.; Liang, B.; Wang, S.; Luo, J.; Fu, G. Nat. Commun. 2022, 13, 776. doi: 10.1038/s41467-022-28364-y

Catalyts	Application	Mode	Reference
HPC	CO₂ cycloaddition	PTCC	64
Zn SA-NC	CO₂ cycloaddition	PTCC	65
Pd₁/N-graphene	Hydrogenation of acetylene to ethylene	PDTC	14
Co SSCs	Glycolysis of polyesters	PDTC	66
Ni-BNCNTs	CO₂ cycloaddition	PTCC	67
SAAg-g-CN	Hydrogen evolution reaction	PTCC	72
Ru/CdS	CO₂ reduction	PTCC	73
Fe-sMoS₂	Nitrogen fixation to ammonia	TAPC	74
SA Ni/CeO₂	Splitting NH₃ to H₂	PDTC	77
Pt₁/Fe₂O₃	Toluene oxidation	PDTC	78
ASA-c-Ag₈Cu₁	CO₂ reduction	PTCC	81
Pt/Te	Dehydrogenation of formic acid	TAPC	82
Cu-Ru	Methane dry reforming	TAPC	83

[1]	曹玥晗, 郭瑞, 马敏智, 黄泽皑, 周莹. 活性位点电子密度变化对光催化CO₂活化和选择转化的影响[J]. 物理化学学报, 2024, 40(1): 2303029 - .
[2]	张珹博, 陶晓萍, 蒋文超, 郭俊雪, 张鹏飞, 李灿, 李仁贵. 微波辅助合成促进铬酸铋晶体的光生电荷分离[J]. 物理化学学报, 2024, 40(1): 2303034 - .
[3]	张城城, 吴之怡, 沈家辉, 何乐, 孙威. 硅纳米结构阵列：光热CO₂催化的新兴平台[J]. 物理化学学报, 2024, 40(1): 2304004 - .
[4]	赖可溱, 李丰彦, 李宁, 高旸钦, 戈磊. 金属-有机骨架衍生的Ni-CNT/ZnIn₂S₄异质结用于光催化产氢及其电荷转移途径的确定[J]. 物理化学学报, 2024, 40(1): 2304018 - .
[5]	朱锐杰, 康磊磊, 李林, 潘晓丽, 王华, 苏杨, 李广亿, 程鸿魁, 李仁贵, 刘晓艳, 王爱琴. WO₃-TiO₂负载的Pt单原子催化剂光热协同催化丙烷和丙烯氧化[J]. 物理化学学报, 2024, 40(1): 2303003 - .
[6]	何展军, 黄敏, 林铁军, 钟良枢. 光热催化甲烷干重整研究进展[J]. 物理化学学报, 2023, 39(9): 2212060 -0 .
[7]	罗耀武, 王定胜. 单原子催化剂电子结构调控实现高效多相催化[J]. 物理化学学报, 2023, 39(9): 2212020 -0 .
[8]	梁秋菊, 常银霞, 梁朝伟, 祝浩雷, 郭子宾, 刘剑刚. 结晶动力学策略在非富勒烯体系太阳能电池形貌调控领域的应用[J]. 物理化学学报, 2023, 39(7): 2212006 -0 .
[9]	张珂瑜, 李云锋, 袁仕丹, 张洛红, 王倩. S型异质结H₂O₂光催化剂的研究进展[J]. 物理化学学报, 2023, 39(6): 2212010 - .
[10]	罗铖, 龙庆, 程蓓, 朱必成, 王临曦. Pt-C₃N₄/BiOCl S型异质结应用于光催化CO₂还原的理论计算研究[J]. 物理化学学报, 2023, 39(6): 2212026 - .
[11]	孙涛, 李晨曦, 鲍钰鹏, 樊君, 刘恩周. S-型MnCo₂S₄/g-C₃N₄异质结光催化产氢性能研究[J]. 物理化学学报, 2023, 39(6): 2212009 - .
[12]	吴新鹤, 陈郭强, 王娟, 李金懋, 王国宏. S-Scheme异质结光催化产氢研究进展[J]. 物理化学学报, 2023, 39(6): 2212016 -0 .
[13]	张怡宁, 高明, 陈松涛, 王会琴, 霍鹏伟. Ag/CN/ZnIn₂S₄ S型异质结等离子体光催化剂的制备及其增强光还原CO₂研究[J]. 物理化学学报, 2023, 39(6): 2211051 - .
[14]	王中辽, 汪静, 张金锋, 代凯. 光激发电荷在光催化氧化还原反应中的全利用[J]. 物理化学学报, 2023, 39(6): 2209037 - .
[15]	王吉超, 乔秀, 史维娜, 贺景, 陈军, 张万庆. 多面体状Cu₂O修饰片状BiOI的S型异质结构筑及光催化水蒸气中CO₂转化性能研究[J]. 物理化学学报, 2023, 39(6): 2210003 - .