物理化学学报 >> 1994, Vol. 10 >> Issue (01): 6-8.doi: 10.3866/PKU.WHXB19940102

通讯 上一篇    下一篇

杂多酸柱水滑石的合成及其上烯烃烷基化反应

徐征, 贺鹤鸣, 蒋大振, 吴越   

  1. 吉林大学化学系，长春 130023| 中国科学院长春应用化学研究所，长春 130022
  • 收稿日期:1993-08-16 修回日期:1993-10-12 发布日期:1994-01-15
  • 通讯作者: 徐征

Alrylation Over Layered Double Hydrotalcites Pillared by Heteropolyoxometalate Catalysts

Xu Zheng, He He-Ming, Jiang Da-Zhen, Wu Yue   

  1. Department of Chemistry, Jilin University, Changchun 130023| Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun 130022
  • Received:1993-08-16 Revised:1993-10-12 Published:1994-01-15
  • Contact: Xu Zheng

PDF

2881

赞

关键词: 水滑石, 烷基化, 合成

Abstract:

Layered double hydroxides (LDHs) pillared with heteropolyoxo-metalate have been synthesized via both restructuring of hydrotalcite-like compounds and direct anion exchange under microwave field. LDHs and their derivatives are both found to be efficiency for alkylation of iso-butane and butene with a higher butene conversion and selectivity towards C_8~o.

Key words: Hydrotalcite, Alkylation, Synthesis