物理化学学报 >> 1995, Vol. 11 >> Issue (02): 167-170.doi: 10.3866/PKU.WHXB19950214

研究简报 上一篇    下一篇

一种含稀土半菁的二阶非线性光学材料的研究

李辉, 王科志, 黄春辉, 黎甜楷, 徐灵戈, 赵新生, 谢晓明   

  1. 北京大学稀土材料化学剂应用国家重点实验室|北京100871|中国科学院感光所光化学开放实验室|北京 100101|北京大学化学系|北京 100871
  • 收稿日期:1993-11-19 修回日期:1994-03-02 发布日期:1995-02-15
  • 通讯作者: 黄春辉

Studies on Non-linear Optical Material of a Hemicyanine Dye Containing Rare Earth

Li Hui, Wang Ke-Zhi, Huang Chun-Hui, Li Tian-Kai, Xu Ling-Ge, Zhao Xin-Sheng, Xie Xiao-Ming   

  1. State Key Laboratory of Rare Earth Material Chemistry and Applications,Peking University,Beijing 100871|Institute of Photographic Chemistry,Academia Sinica,Beijing 100101|Chemistry Department,Peking University,Beijing 100871
  • Received:1993-11-19 Revised:1994-03-02 Published:1995-02-15
  • Contact: Huang Chun-Hui

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关键词: 光学二次谐波, LB膜, 稀土;配合物

Abstract:

A hemicyanine dye containing an amphiphilic rare earth complex anion 4-[(4-N,N’ -(diethyl amino)phenyl)ethenyl]-1-hexadecyl-pyridinnium-Tri(1-phenyl-3-methyl-4-benzyol-pyrazolone-5)-(4-dodeconoyl-1-phenyl-3-methyl-pyrozone-5) dysprosium been designed, synthesized and characterized. Its floating monolayer film was spread by a dilute chloroform solution onto the pure water subphase by using a NIMA Technology LB Though at room temperature. The π-A isotherm shows that the film formation property is improved and the multilayer films are homogeneous. The molecular second order hyperpolarizability(β) is evaluated to be 5.4×10-28e.s.u. which is one of largest SHG material reported.

Key words: SHG, LB films, Rare earth, Complex