纳米金催化的绿色合成与清洁反应研究新进展

doi:10.3866/PKU.WHXB201511101

物理化学学报 >> 2016, Vol. 32 >> Issue (1): 61-74.doi: 10.3866/PKU.WHXB201511101

纳米金催化的绿色合成与清洁反应研究新进展

李舒爽,陶磊,张奇,刘永梅,曹勇*()

复旦大学化学系，上海市分子催化和功能材料重点实验室，上海 200433

收稿日期:2015-09-23 发布日期:2016-01-13
通讯作者: 曹勇 E-mail:yongcao@fudan.edu.cn
基金资助:
国家自然科学基金(21273044, 21473035);高等学校博士学科点专项科研基金(2012007000011);中石化校企联合基金(X514005);上海市科学技术委员会(08DZ2270500, 12ZR1401500)

Recent Advances in Nano-Gold-Catalyzed Green Synthesis and Clean Reactions

Shu-Shuang LI,Lei TAO,Qi ZHANG,Yong-Mei LIU,Yong CAO*()

Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China

Received:2015-09-23 Published:2016-01-13
Contact: Yong CAO E-mail:yongcao@fudan.edu.cn
Supported by:
the National Natural Science Foundation of China(21273044, 21473035);China Research Fund for the DoctoralProgram of Higher Education, China(2012007000011);SINOPEC, China(X514005);Science & Technology Commission of ShanghaiMunicipality, China(08DZ2270500, 12ZR1401500)

摘要/Abstract

摘要：

近年来,基于多相纳米金(Au)催化的绿色合成与清洁反应研究引起了人们的广泛关注。与传统的铂族金属催化剂相比,纳米Au催化剂在控制反应选择性、高收率获得目标产物以及实现高效简约的一锅法串联反应合成等符合"原子经济"及"步骤经济"等绿色化学理念的新反应及新过程方面展现了其独特的优势,已成为当前绿色催化领域研究的热点和前沿。主要综述了我们研究小组在纳米Au催化绿色合成领域,尤其是利用纳米Au催化高效制取含氮精细有机化合物及生物质资源高值化利用方面所取得的研究进展,介绍了各类反应的特点、优势及在合成中的应用。

关键词: 纳米Au催化剂, 铂族金属, 绿色合成, 清洁反应, 还原转化

Abstract:

There has been a surge of interest in using supported gold catalysts in green synthesis and clean reactions. Complementary to their traditional platinum-group metal counterparts, catalysis using nano-gold offers a unique opportunity to obtain target products in high yields, control the chemoselectivity, and access more complex organic molecules in a compact, atom-and step-efficient way. Therefore, it has emerged as a hot topic in the field of green catalysis. This review summarizes our research progress in the area of nano-Aucatalyzed green reactions and their versatility, application in clean chemical synthesis, especially for the construction of N-containing compounds as well as valorization of biomass-derived feedstocks via goldcatalyzed transformations.

Key words: Nano-gold catalyst, Platinum-group metal, Green synthesis, Clean reaction, Reductive transformation

李舒爽,陶磊,张奇,刘永梅,曹勇. 纳米金催化的绿色合成与清洁反应研究新进展[J]. 物理化学学报, 2016, 32(1), 61-74. doi: 10.3866/PKU.WHXB201511101

Shu-Shuang LI,Lei TAO,Qi ZHANG,Yong-Mei LIU,Yong CAO. Recent Advances in Nano-Gold-Catalyzed Green Synthesis and Clean Reactions[J]. Acta Phys. -Chim. Sin. 2016, 32(1), 61-74. doi: 10.3866/PKU.WHXB201511101

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201511101

https://www.whxb.pku.edu.cn/CN/Y2016/V32/I1/61

参考文献

1	Sheldon R. A. ; Arends I. ; Hanefeld U. Green Chemistry and Catalysis; Wiley-VCH: Weinheim 2007.
2	Bond, G. C.; Louis, C.; Thompson, D. T. Catalysis by Gold; Imperial College Press: London, 2006.
3	Palfray L. Bull. Soc. Chim. Fr 1945, 12, 692.
4	Chambers R. ; Boudart M. J. Catal 1966, 5 (3), 517.
5	Bond G. C. ; Sermon P. A. ; Webb G. ; Buchanan D. A. ; Wells P. B. J. Chem. Soc. Chem. Commun 1973, 13, 444.
6	Bond G. C. ; Sermon P. A. Gold Bull 1973, 6 (4), 102.
7	Haruta M. ; Kohayashi T. ; Sano H. ; Yamada N. Chem. Lett 1987, 2, 405.
8	Rodriguez J. A. ; Ma S. ; Liu P. ; Hrbek J. ; Evans J. ; Pérez M. Science 2007, 318 (5857)
9	Ueda A. ; Oshima T. ; Haruta M. Appl. Catal. B 1997, 12 (2\|3), 81.
10	Hayashi T. ; Tanaka K. ; Haruta M. J. Catal 1998, 178 (2), 566.
11	Mineral Commodity Summaries 2015, U.S. Geological Survey: Reston, VA, 2015.
12	Butler, J. Platinum 2012 Interim Review; Johnson Matthey: Royston, U.K., 2012.
13	Prati L. ; Rossi M. J. Catal 1998, 176 (2), 552.
14	Biella S. ; Prati L. ; Rossi M. J. Catal 2002, 206 (2), 242.
15	Landon P. ; Collier P. J. ; Papworth A. J. ; Kiely C. J. ; Hutchings G. J. Chem. Commun 2002, 18, 2058.
16	Corma A. ; Serna P. Science 2006, 313 (5785), 332.
17	Corma A. ; Garcia H. Chem. Soc. Rev 2008, 37 (9), 2096.
18	Stratakis M. ; Garcia H. Chem. Rev 2012, 112 (8), 4469.
19	Pina C. D. ; Falletta E. ; Rossi M. Chem. Soc. Rev 2012, 41 (1), 350.
20	Oliver-Meseguer J. ; Cabrero-Antonino J. R. ; Domínguez I. ; Leyva-Pérez A. ; Corma A. Science 2012, 338 (6113), 1452.
21	Wittstock A. ; Bäumer M. Accounts Chem. Res 2014, 47 (3), 731.
22	Liu X. ; He L. ; Liu Y. M. ; Cao Y. Accounts Chem. Res 2014, 47 (3), 793.
23	Yamazoe S. ; Koyasu K. ; Tsukuda T. Accounts Chem. Res 2014, 47 (3), 816.
24	Adams J. P. ; Paterson J. R. J. Chem. Soc., Perkin Trans. 1 2000, 22, 3695.
25	Haber F. ; Elektrochem Z. Angew. Phys. Chem 1898, 22, 506.
26	Kabalka, G. W.; Varma, R. S. In Comprehensive Organic Synthesis, Vol. 8; Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford, 1991; pp 363–388.
27	He L. ; Wang L. C. ; Sun H. ; Ni J. ; Cao Y. ; He H. Y. ; Fan K. N. Angew. Chem. Int. Edit 2009, 48 (50), 9538.
28	Liu L. Q. ; Qiao B. T. ; Chen Z. J. ; Zhang J. ; Deng Y. Q. Chem. Commun 2009.
29	Lou X. B. ; He L. ; Qian Y. ; Liu Y. M. ; Cao Y. ; Fan K. N. Adv. Synth. Catal 2011, 353
30	Yu L. ; Zhang Q. ; Li S. S. ; Huang J. ; Liu Y. M. ; He H. Y. ; Cao Y. ChemSusChem 2015, 8 (18), 3029.
31	Hunger, K. Industrial Dyes: Chemistry, Properties, Applications; Wiley: Chichester, 2007.
32	Lee K. M. ; White T. J. Polymers 2011, 3 (3), 1447.
33	Cusati T. ; Granucci G. ; Persico M. J. Am. Chem. Soc 2011, 133 (13), 5109.
34	Grirrane A. ; Corma A. ; García H. Science 2008, 322 (5908), 1661.
35	Zhang C. ; Jiao N. Angew. Chem. Int. Edit 2010, 49 (35), 6174.
36	Liu X. ; Ye S. ; Li H. Q. ; Liu Y. M. ; Cao Y. ; Fan K. N. Catal. Sci. Technol 2013, 3 (12), 3200.
37	Liu X. ; Li H. Q. ; Ye S. ; Liu Y. M. ; He H. Y. ; Cao Y. Angew. Chem. Int. Edit 2014, 53 (29), 7624.
38	Lindlar H. Helv. Chim. Acta 1952, 35 (2), 446.
39	Jia J. ; Haraki K. ; Kondo J. N. ; Domen K. ; Tamaru K. J. Phys. Chem. B 2000, 104 (47), 11153.
40	Segura Y. ; López N. ; Pérez-Ramírez J. J. Catal 2007, 247 (7), 383.
41	Yan M. ; Jin T. ; Ishikawa Y. ; Minato T. ; Fujita T. ; Chen L. Y. ; Bao M. ; Asao N. ; Chen M. W. ; Yamamoto Y. J. Am. Chem. Soc 2012, 134 (42), 17536.
42	Li S. S. ; Liu X. ; Liu Y. M. ; He H. Y. ; Fan K. N. ; Cao Y. Chem. Commun 2014, 50 (42), 5626.
43	Lowry T. H. ; Richardson K. S. Mechanism and Theory in Organic Chemistry; Harper and Row: New York 1987.
44	Rybtchinski B. ; Cohen R. ; Ben-David Y. ; Martin J. M. L. ; Milstein D. J. Am. Chem. Soc 2003, 125 (36), 11041.
45	Sridharan V. ; Suryavanshi P. A. ; Menéndez J. C. Chem. Rev 2011, 111 (11), 7157.
46	Garcia-Mota M. ; Gómez-Diaz J. ; Novell-Leruth G. ; Vargas-Fuentes C. ; Bellarosa L. ; Bridier B. ; Pérez-Ramírez J. ; López N. Theor. Chem. Acc 2011, 128 (4), 663.
47	Ren D. ; He L. ; Yu L. ; Ding R. S. ; Liu Y. M. ; Cao Y. ; He H. Y. ; Fan K. N. J. Am. Chem. Soc 2012, 134 (42), 17592.
48	Yan M. ; Jin T. ; Chen Q. ; Ho H. E. ; Fujita T. ; Chen L. Y. ; Bao M. ; Chen M. W. ; Asao N. ; Yamamoto Y. Org. Lett 2013, 15 (7), 1484.
49	Tao L. ; Zhang Q. ; Li S. S. ; Liu X. ; Liu Y. M. ; Cao Y. Adv. Synth. Catal 2015, 357 (4), 753.
50	Gomez S. ; Peters J. A. ; Maschmeyer T. Adv. Synth. Catal 2002, 344 (10), 1037.
51	Abdel-Magid A. F. ; Carson K. G. ; Harris B. D. ; Maryanoff C. A. ; Shah R. D. J. Org. Chem 1996, 61 (11), 3849.
52	Storer R. I. ; Carrera D. E. ; Ni Y. ; MacMillan D. W. C. J. Am. Chem. Soc 2006, 128 (1), 84.
53	Hoffmann S. ; Nicoletti M. ; List B. J. Am. Chem. Soc 2006, 128 (40), 13074.
54	Yamane Y. ; Liu X. H. ; Hamasaki A. ; Ishida T. ; Haruta M. ; Yokoyama T. ; Tokunga M. Org. Lett 2009, 11 (22), 5162.
55	Artiukha E. A. ; Nuzhdin A. L. ; Bukhtiyarova G. A. ; Zaytsev S.Y. ; Plyusnin P. E. ; Shubin Y. V. ; Bukhtiyarova V. I. Catal. Sci. Technol 2015, 5 (10), 4741.
56	Yang Q. ; Wang Q. F. ; Yu Z. K. Chem. Soc. Rev 2015, 44 (8), 2305.
57	Yang H. M. ; Cui X. J. ; Dai X. C. ; Shi F. Nat. Commun 2015, 6, 6478.
58	Shimizu K. Catal. Sci. Technol 2015, 5 (3), 1412.
59	Tang C. H. ; He L. ; Liu Y. M. ; Cao Y. ; He H. Y. ; Fan K. N. Chem. Eur. J 2011, 17 (26), 7172.
60	He L. ; Lou X. B. ; Ni J. ; Liu Y. M. ; Cao Y. ; He H. Y. ; Fan K. N. Chem. Eur. J 2010, 16 (47), 13965.
61	Bi Q. Y. ; Du X. L. ; Liu Y. M. ; Cao Y. ; He H. Y. ; Fan K. N. J. Am. Chem. Soc 2012, 134 (21), 8926.
62	Bi Q. Y. ; Lin J. D. ; Liu Y. M. ; Du X. L. ; Wang J. Q. ; He H. Y. ; Cao Y. Angew. Chem. Int. Edit 2015, 53 (49), 13583.
63	Reddy P. G. ; Kumar G. D. K. ; Baskaran S. Tetrahedron Lett 2000, 41 (47), 9149.
64	Kulkarni A. ; Gianatassio R. ; Török B. Synthesis 2011, 8, 1227.
65	Yan Z. P. ; Lin L. ; Liu S. J. Energy Fuels 2009, 23 (8), 3853.
66	Du X. L. ; He L. ; Zhao S. ; Liu Y. M. ; Cao Y. ; He H. Y. ; Fan K. N. Angew. Chem. Int. Edit 2011, 123 (34), 7961.
67	Du X. L. ; Bi Q. Y. ; Liu Y. M. ; Cao Y. ; Fan K. N. ChemSusChem 2011, 4 (12), 1838.

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纳米金催化的绿色合成与清洁反应研究新进展

Recent Advances in Nano-Gold-Catalyzed Green Synthesis and Clean Reactions

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