石墨烯基复合材料应用于光电二氧化碳还原的基本原理，研究进展和发展前景

doi:10.3866/PKU.WHXB201706263

物理化学学报 >> 2017, Vol. 33 >> Issue (12): 2404-2423.doi: 10.3866/PKU.WHXB201706263

所属专题：高被引科学家专刊

石墨烯基复合材料应用于光电二氧化碳还原的基本原理，研究进展和发展前景

全泉¹,谢顺吉²,王野^2,*(),徐艺军^1,*()

¹ 福州大学化学学院,能源与环境光催化国家重点实验室,福州350116
² 厦门大学化学化工学院,固体表面物理化学国家重点实验室,能源材料化学协同创新中心,福建厦门361005

收稿日期:2017-06-05 发布日期:2017-09-05
通讯作者: 王野,徐艺军 E-mail:wangye@xmu.edu.cn;yjxu@fzu.edu.cn
作者简介:QUAN Quan is now pursuing her PhD degree under the supervision of Prof. XU Yi-Jun at the State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, P. R. China. Her current research interests include composite materials synthesis and their applications in energy conversion and storage such as photocatalytic and photoelectrochemical redox processes|XIE Shun-Ji received his BS and MSc degrees from Hunan University of China in 2008 and 2011, and obtained his PhD degree from Xiamen University in 2014. He is currently an iChEM Fellow in the Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, China. He focuses on photocatalytic energy conversion, especially CO₂ reduction|WANG Ye obtained his PhD degree in 1996 from Tokyo Institute of Technology. He then worked at Tokyo Institute of Technology, Tohoku University and Hiroshima University during 1996-2000. He was promoted to associate professor at Hiroshima University in 2001. He became a professor of Xiamen University in the August of 2001. He is currently the director of State Key Laboratory of Physical Chemistry of Solid Surfaces and the director of Institute of Catalysis Science and Technology of Xiamen University. The group of Professor Wang works on catalysis for efficient utilization of carbon resources including the selective transformation of methane, syngas, biomass and CO2 into fuels and chemicals|XU Yi-Jun received his PhD degree in heterogeneous catalysis at School of Chemistry, Cardiff University, U.K. in 2006 with the supervision of Prof. Graham J. Hutchings (FLSW FRS). From 2007 to 2009, he worked as a postdoctoral fellow at the Fritz-Haber Institute of the Max Planck Society, Berlin, Germany. After that, he became a full professor working at State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, P.R. China. He is a Fellow of Royal Society of Chemistry (FRSC) and his current research interests primarily focus on the assembly and applications of composite materials, such as graphene-based semiconductor composites, core-shell composites and metal-based nanostructured materials, in the field of heterogeneous photocatalysis
基金资助:
国家自然科学基金(U1463204);国家自然科学基金(20903023);国家自然科学基金(21173045);闽江学者特聘教授科研启动基金;福建省杰出青年自然科学基金(2012J06003);能源与环境光催化国家重点实验室自主课题(2014A05);福建省首批特支人才“双百计划”青年拔尖创新人才;厦门大学固体表面物理化学国家重点实验室开放课题(201519);教育部留学回国人员科研启动基金项目;福建省杰出青年自然科学基金滚动资助项目(2017J07002)

Photoelectrochemical Reduction of CO₂ Over Graphene-Based Composites:Basic Principle, Recent Progress, and Future Perspective

Quan QUAN¹,Shun-Ji XIE²,Ye WANG^2,*(),Yi-Jun XU^1,*()

¹ State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China
² State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received:2017-06-05 Published:2017-09-05
Contact: Ye WANG,Yi-Jun XU E-mail:wangye@xmu.edu.cn;yjxu@fzu.edu.cn
Supported by:
the National Natural Science Foundation of China(U1463204);the National Natural Science Foundation of China(20903023);the National Natural Science Foundation of China(21173045);the Award Program for Minjiang Scholar Professorship;the Natural Science Foundation of Fujian Province for Distinguished Young Investigator Grant(2012J06003);the Independent Research Project of State Key Laboratory of Photocatalysis on Energy and Environment(2014A05);the first Program of Fujian Province for Top Creative Young Talents;the Open Research Project of State Key Laboratory of Physical Chemistry of Solid Surfaces of Xiamen University(201519);the Program for Returned High-Level Overseas Chinese Scholars of Fujian province;the Natural Science Foundation of Fujian Province for Distinguished Young Investigator Rolling Grant(2017J07002)

摘要/Abstract

摘要：

面对日益严重的化石能源消耗和温室效应问题，二氧化碳还原正成为一个重要的全球性研究课题，其通过消耗二氧化碳来生成可用于能源供应的产物。光电催化技术同时利用光能和外部电压，是一种用于二氧化碳还原的可行且有效的途径。因为石墨烯具有增强二氧化碳吸附和促进光生电子转移的特性能够提升石墨烯基复合电极的性能，所以引入石墨烯用于调优光电催化二氧化碳还原体系已经引起了广泛关注。本篇综述详细陈述了石墨烯基复合材料应用于光电二氧化碳还原的基本原理，电极制备方法以及目前的研究进展。我们也对这个蓬勃发展的领域未来可能会遇到的机遇和挑战进行了展望，同时提出了潜在可行的革新策略用于提升光电二氧化碳还原方面的研究。

关键词: 光电催化, 二氧化碳还原, 石墨烯基复合材料

Abstract:

In response to aggravated fossil resources consuming and greenhouse effect, CO₂ reduction has become a globally important scientific issue because this method can be used to produce value-added feedstock for application in alternative energy supply. Photoelectrocatalysis, achieved by combining optical energy and external electrical bias, is a feasible and promising system for CO₂ reduction. In particular, applying graphene in tuning photoelectrochemical CO₂ reduction has aroused considerable attention because graphene is advantageous for enhancing CO₂ adsorption, facilitating electrons transfer, and thus optimizing the performance of graphene-based composite electrodes. In this review, we elaborate the fundamental principle, basic preparation methods, and recent progress in developing a variety of graphene-based composite electrodes for photoelectrochemical reduction of CO₂ into solar fuels and chemicals. We also present a perspective on the opportunities and challenges for future research in this booming area and highlight the potential evolution strategies for advancing the research on photoelectrochemical CO₂ reduction.

Key words: Photoelectrochemical, CO₂ reduction, Graphene-based composite

全泉,谢顺吉,王野,徐艺军. 石墨烯基复合材料应用于光电二氧化碳还原的基本原理，研究进展和发展前景[J]. 物理化学学报, 2017, 33(12), 2404-2423. doi: 10.3866/PKU.WHXB201706263

Quan QUAN,Shun-Ji XIE,Ye WANG,Yi-Jun XU. Photoelectrochemical Reduction of CO₂ Over Graphene-Based Composites:Basic Principle, Recent Progress, and Future Perspective[J]. Acta Phys. -Chim. Sin. 2017, 33(12), 2404-2423. doi: 10.3866/PKU.WHXB201706263

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201706263

https://www.whxb.pku.edu.cn/CN/Y2017/V33/I12/2404

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Photoelectrochemical Reduction of CO₂ Over Graphene-Based Composites:Basic Principle, Recent Progress, and Future Perspective

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石墨烯基复合材料应用于光电二氧化碳还原的基本原理，研究进展和发展前景

Photoelectrochemical Reduction of CO2 Over Graphene-Based Composites:Basic Principle, Recent Progress, and Future Perspective

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Photoelectrochemical Reduction of CO₂ Over Graphene-Based Composites:Basic Principle, Recent Progress, and Future Perspective