Kopsia Singapurensis 提取物对酸性介质中低碳钢的缓蚀效应

doi:10.3866/PKU.WHXB20100646

Abstract

Abstract:

The influence of the alkaloid extract of Kopsia singapurensis on the corrosion behavior of mild steel (MS) in 1 mol·L^-1 HCl and 1 mol·L^-1 H₂SO₄ was studied using electrochemical techniques, viz., potentiodynamic polarization and AC impedance. The experimental results clearly show that the plant extract effectively inhibits corrosion in both acid media and the inhibition efficiency obtained from the electrochemical techniques is in good agreement. Furthermore, the polarization technique indicates that the extract acts as an anodic type inhibitor in HCl and as a mixed type in H₂SO₄. Scanning electron microscopy (SEM) was carried out to examine the surface morphological changes of metal specimens in both the inhibited and uninhibited solutions. SEM images show the formation of an adsorbed layer over the metal surface by the inhibitor molecule. The presence of alkaloidal constituents in the plant extract was confirmed by Fourier transform infrared (FTIR) spectroscopy and chemical analysis.

Key words: Corrosion inhibitor, Kopsia singapurensis, Mild steel, Polarization, Impedance, SEM, FTIR

RAJA Pandian Bothi, RAHIM Afidah Abdul, OSMAN Hasnah, AWANG Khalijah. Inhibitory Effect of Kopsia Singapurensis Extract on the Corrosion Behavior ofMild Steel in AcidMedia[J]. Acta Phys. -Chim. Sin. 2010, 26(08), 2171-2176. doi: 10.3866/PKU.WHXB20100646

References

[1]. Uhlig, H. H.; Revie, R. W. Corrosion and corrosion control. New York: Wiley, 1985
[2]. õzcan, M.; Karadag, F.; Dehri, I. Acta Physico-Chimica Sinica, 2008, 24: 1387
[3]. Solmaz, R.; Mert, M. E.; Kardas, G.; Yazici, B.; Erbil, M. Acta Physico-Chimica Sinica, 2008, 24: 1185
[4]. Raja, P. B.; Sethuraman, M. G. Materials Letters, 2008, 62: 1602
[5]. Bentiss, F.; Traisnel, M.; Lagrenee, M. Corrosion Science, 2000, 42: 127
[6]. Raja, P. B.; Sethuraman, M. G. Materials Letters, 2008, 62: 2977
[7]. Raja, P. B.; Sethuraman, M. G. Materials and Corrosion, 2009, 22: 23
[8]. Oguzie, E. E. Corrosion Science, 2007, 49: 1527
[9]. Raja, P. B.; Sethuraman. M. G. Pigment and Resin Technology, 2005, 34: 327
[10]. Raja, P. B.; Sethuraman. M. G. Pigment and Resin Technology, 2009, 38: 33
[11]. Raja, P. B.; Sethuraman. M. G. Surface Review and Letters, 2007, 14: 1157
[12]. El-Etre, A. Y.; Abdallah, M. Corrosion Science, 2000, 42: 731
[13]. Raja, P. B.; Sethuraman. M. G. Materials Letters, 2008, 62: 113
[14]. Rahim, A. A.; Rocca, E.; Steinmetz, J.; Kassim, J. M.; Adnan, R.; Ibrahim, S. M. Corrosion Science, 2007, 49: 402
[15]. Rahim, A. A.; Rocca, E.; Steinmetz, J.; Kassim, J. M. Corrosion Science, 2008, 50: 1546
[16]. Rahim, A. A.; Kassim, J. M. Recent Patents on Materials Science, 2008, 1: 223
[17]. Kam, T. S. Alkaloids from malaysian flora, in alkaloids: chemical and biological perspectives. Pelletier, S. W. Ed. Amsterdam: Pergamon, 1999, 14: 285-435
[18]. Subramanian, G.; Kam, T. S. Helvetica Chimica-Acta, 2008, 91: 930
[19]. Subramaniam, G.; Choo, Y. M.; Hiraku, O.; Komiyama, K.; Kam, T. S. Tetrahedron, 2008, 64: 1397
[20]. Tang, Y.; Yang, X.; Yang, W.; Wan, R.; Chen, Y.; Yin, X. Corrosion Science, 2010, 52: 1801
[21]. Umoren, S.; Li, Y.; Wang, F. H. Corrosion Science, 2010, 52: 1777
[22]. Musa, A. H.; Kadhum, A. A. H.; Mohamad, A. B.; Daud, A. R.; Takriff, M. S.; Kamarudin, S. K. Corrosion Science, 2009, 51: 2393
[23]. Khaled, K. F.; Amin, M. A. Corrosion Science, 2009, 51: 1964
[24]. McCafferty, E.; Hackerman, N. Journal of Electrochemical Society, 1972, 119: 146
[25]. Prabhu, R. A.; Shanbhag, A. V.; Venkatesha, T. V. Journal of Applied Electrochemistry, 2007, 37: 491
[26]. Subramaniam, G.; Hiraku, O.; Hayashi, M; Koyano, T.; Komiyama, K.; Kam, T. S. Journal of Natural Products, 2008, 71: 53
[27]. Vajpei, A. C.; Uma; Saraswat, I. P.; Chandra, K. Journal of Material Science, 1984, 19: 3341

Inhibitory Effect of Kopsia Singapurensis Extract on the Corrosion Behavior ofMild Steel in AcidMedia

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