铜电极表面铜锡合金电结晶机理

doi:10.3866/PKU.WHXB201310092

Abstract

Abstract:

The co-deposition and electrocrystallization of Cu-Sn alloy in a weak acidic citrate bath were studied by linear sweep voltammetry (LSV), cyclic voltammetry (CV), and chronoamperometry. The Scharifker- Hill (SH) theory model and Heerman-Tarallo (HT) theory model were applied to analyze the chronoamperometry data. The results show that the Cu-Sn alloy co-deposited on copper electrode, following instantaneous nucleation with three-dimensional (3D) growth under diffusion control. The kinetic parameters were obtained using the HT model. As the step potential shifted from -0.80 to -0.85 V, the nucleation rate constant (A) increased from 20.19 to 177.67 s^-1, the density of active nucleation sites (N₀) increased from 6.10×10⁵ to 1.42×10⁶ cm^-2, and the diffusion coefficient (D) was (6.13±0.62)×10^-6 cm²·s^-1.

Key words: Cu-Sn alloy, Electrocrystallization, Cyclic voltammetry, Chronoamperometry

Click here to download Supporting Info material in PDF type

SHI Ji-Peng, YANG Fang-Zu, TIAN Zhong-Qun, ZHOU Shao-Min. Electrocrystallization of Cu-Sn Alloy on Copper Electrode Surface[J]. Acta Phys. -Chim. Sin. 2013, 29(12), 2579-2584. doi: 10.3866/PKU.WHXB201310092

References

(1) Hoffacker, G.; Kaiser, H.; Reissmueller, K.;Wirth, G. Cyanidic-Alkaline Baths for the Galvanic Deposition of Copper-tin AlloyCoatings, Uses Thereof, and Metallic Bases Coated with SaidCopper-tin Alloy Coating. US Patent: US 5534129, 1996-07-09.
(2) Correia, A. N.; Façanha, M. X.; de Lima-Neto, P. Surf. Coat. Technol. 2007, 201 (16), 7216.
(3) Hovestad, A.; Tacken, R. A. Physica Status Solidi (c) 2008, 5 (11), 3506. doi: 10.1002/pssc.v5:11
(4) Sürme, Y.; Gürten, A. A.; Bayol, E.; Ersoy, E. J. Alloy. Compd.2009, 485 (1), 98.
(5) Finazzi, G. A.; De Oliveira, E. M.; Carlos, I. A. Surf. Coat. Technol. 2004, 187 (2), 377.
(6) Low, C. T. J.;Walsh, F. C. Surf. Coat. Technol. 2008, 202 (8),1339. doi: 10.1016/j.surfcoat.2007.06.032
(7) Scharifker, B.; Hills, G. Electrochim. Acta 1983, 28 (7), 879.doi: 10.1016/0013-4686(83)85163-9
(8) Palomar-Pardavé, M.; Scharifker, B. R.; Arce, E. M.; Romero-Romo, M. Electrochim. Acta 2005, 50 (24), 4736. doi: 10.1016/j.electacta.2005.03.004
(9) Ballesteros, J. C.; Chainet, E.; Ozil, P.; Meas, Y.; Trejo, G. Int. J. Electrochem. Sci. 2011, 6, 2632.
(10) Gu, M.; Zhong, Q. J. Appl. Electrochem. 2011, 41 (7), 765. doi: 10.1007/s10800-011-0293-0
(11) Rudnik, E.;Wojnicki, M.;Wιoch, G. Surf. Coat. Technol. 2012,207, 375. doi: 10.1016/j.surfcoat.2012.07.027
(12) Garfias-García, E.; Romero-Romo, M.; Ramírez-Silva, M. T.;Palomar-Pardavé, M. Int. J. Electrochem. Sci. 2012, 7, 3102.
(13) Scharifker, B. R.; Mostany, J. J. Electroanal. Chem. 1984, 177,13. doi: 10.1016/0022-0728(84)80207-7
(14) Sluyters-Rehbach, M.;Wijenberg, J. H. O. J.; Bosco, E.;Sluyters, J. H. J. Electroanal. Chem. 1987, 236 (1), 1.
(15) Heerman, L.; Tarallo, A. J. Electroanal. Chem. 1998, 451 (1),101.
(16) Heerman, L.; Tarallo, A. J. Electroanal. Chem.1999, 470 (1),70. doi: 10.1016/S0022-0728(99)00221-1
(17) Yue, J. P.; Yang, F. Z.; Tian, Z. Q.; Zhou, S. M. Acta Phys. -Chim.Sin. 2011, 27 (6), 1446. [岳俊培, 杨防祖, 田中群, 周绍民. 物理化学学报, 2011, 27 (6), 1446.] doi: 10.3866/PKU.WHXB20110620
(18) Zhou, L.; Dai, Y.; Zhang, H.; Jia, Y.; Zhang, J.; Li, C. Bull. Korean Chem. Soc. 2012, 33 (5), 1541. doi: 10.5012/bkcs.2012.33.5.1541
(19) Lomax, D. J.; Kinloch, I. A.; Dryfe, R. A.W. AuElectrodeposition on Carbon Materials. In Nanotechnology (IEEE-NANO), 2012 12th IEEE Conference onNanotechnology, Birmingham, United Kingdom, Aug 20-23,2012; IEEE; 2012; pp 1-4.
(20) Granados-Ner, M.; Huizar, L. H. M.; Rios-Reyes, C. H.Química Nova 2011, 34 (3), 439.
(21) Emekli, U.;West, A. C. Electrochim. Acta 2009, 54 (4),1177. doi: 10.1016/j.electacta.2008.08.065
(22) Zhang, Q. B.; Hua, Y. X. J. Appl. Electrochem. 2011, 41 (6),705. doi: 10.1007/s10800-011-0283-2
(23) Pewnim, N.; Roy, S. Electrochim. Acta 2013, 90, 498. doi: 10.1016/j.electacta.2012.12.053
(24) Fletcher, S. Electrochim. Acta 1983, 28 (7), 917. doi: 10.1016/0013-4686(83)85167-6
(25) Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamental and Applications, 2nd ed.; JohnWiley: New York,2001; pp 234-236.
(26) Ying, R. Y. J. Electrochem. Soc. 1988, 135 (12), 2957. doi: 10.1149/1.2095469
(27) Barry, F. J.; Cunnane, V. J. J. Electroanal. Chem. 2002, 537 (1),151.
(28) Hu,W.; Tan, C. Y.; Cui, H.; Zheng, Z. Q. The Chinese Journal of Nonferrous Metals 2010, 20 (5), 1006. [胡炜, 谭澄宇,崔航, 郑子樵. 中国有色金属学报, 2010, 20 (5), 1006.]
(29) Michailova, E.; Milchev, A. J. Appl. Electrochem. 1991, 21 (2),170. doi: 10.1007/BF01464299

[1]	Hong-Mei QU,Ze-Peng CHONG,Xu CHEN,Yi-Can MEN,Hai-Jiao SHEN. Synthesis and Properties of a Series of Dinaphthosiloles [J]. Acta Phys. -Chim. Sin., 2017, 33(6): 1253-1260.
[2]	Xiao-Ying. WU,Li-Kun. YANG,Hui. YAN,Fang-Zu. YANG,Zhong-Qun. TIAN,Shao-Min. ZHOU. Electrochemical Nucleation of Au on n-Type Semiconductor Silicon Electrode Surface [J]. Acta Phys. -Chim. Sin., 2015, 31(9): 1708-1714.
[3]	PENG Zhong, YAN Wen-Yi, WANG Shao-Na, ZHENG Shi-Li, DU Hao, ZHANG Yi. Effect of Alkali Concentration, Oxygen Partial Pressure and Temperature on Oxygen Reduction Reaction on Pt Electrode in NaOH Solution [J]. Acta Phys. -Chim. Sin., 2014, 30(1): 67-74.
[4]	SONG Han, WANG Na-Na, LI Yue, RUAN Wen-Juan. Synthesis, Characterization and Properties of Terminal Alkynylate Modified Salen-Type Complexes [J]. Acta Phys. -Chim. Sin., 2013, 29(11): 2300-2307.
[5]	ZHANG Chao, AO Jian-Ping, WANG Li, JIANG Tao, SUN Guo-Zhong, HE Qing, ZHOU Zhi-Qiang, SUN Yun. Electrodepositied Gallium on Gallium and Copper/Indium Substratess [J]. Acta Phys. -Chim. Sin., 2012, 28(08): 1913-1922.
[6]	JIN Rong-Rong, LI Li-Fang, XU Xue-Feng, LIAN Ying-Hui, ZHAO Fan. Layered Double Hydroxide Supported Palladium Nanoparticles for Electrocatalytic Oxidation of Hydrazine [J]. Acta Phys. -Chim. Sin., 2012, 28(08): 1929-1935.
[7]	WANG Yan-Yan, JIANG Yan-Xia, SUSHAAndrei, ROGACH Andrey, SUN Shi-Gang. Effect of pH and Au Nanoparticles on Cytochrome c Investigated by Electrochemistry and UV-Vis Absorption Spectroscopy [J]. Acta Phys. -Chim. Sin., 2012, 28(05): 1127-1133.
[8]	CHEN Xu-Hai, LIU Shao-Li, CHEN Jing-Hua, DU Min, LIN Xin-Hua. Numerical Simulation Based Accurate Models of Improved Chronoamperometry and Its Experimental Validation [J]. Acta Phys. -Chim. Sin., 2012, 28(04): 877-884.
[9]	YAN Bing-Xi, LUO Sheng-Yun, SHEN Jie. Photoelectric Properties of Mo Doped TiO₂ Thin Films Deposited by DC Reactive Magnetron Sputtering [J]. Acta Phys. -Chim. Sin., 2012, 28(02): 381-386.
[10]	TU Xiao-Hua, CHU You-Qun, MA Chun-An. Electrochemical Behavior of Nitroaromatics on Pt Microelectrode in an Aprotic Medium [J]. Acta Phys. -Chim. Sin., 2011, 27(09): 2148-2152.
[11]	BASLAK Canan, BINGOL Haluk, COSKUN Ahmet, ATALAY Tevfik. Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb²⁺ Transfer across Water/1,2-Dichloroethane Interface [J]. Acta Phys. -Chim. Sin., 2011, 27(08): 1859-1862.
[12]	YUE Jun-Pei, YANG Fang-Zu, TIAN Zhong-Qun, ZHOU Shao-Min. Electrocrystallization of Pd-Ni Alloys on Glassy Carbon Electrode [J]. Acta Phys. -Chim. Sin., 2011, 27(06): 1446-1450.
[13]	WANG Lian-Yan, LU Feng, WU Fu-Quan, GU Ren-Ao, YAO Jian-Lin, ZHANG Hai-Lu, DENG Zong-Wu. Electrosynthesis and Characterization of Metal Chelate Imprinted Poly-o-Phenylenediamine Films [J]. Acta Phys. -Chim. Sin., 2011, 27(06): 1451-1456.
[14]	WANG Zhi-Ping, LUO Hong, GAO Li-Hua, WANG Ke-Zhi. Electrostatically Self-Assembled Films Prepared Using Bipolar Thiophene Hemicyanine and Prussian Blue [J]. Acta Phys. -Chim. Sin., 2011, 27(03): 754-758.
[15]	JIANG Min, ZHANG Hong-Yu, ZHAO Xue-Bo. Effect of Alkyl Chain Length on the Structure of Viologen Adsorbed on a Cu(100) Electrode [J]. Acta Phys. -Chim. Sin., 2011, 27(01): 163-168.

Electrocrystallization of Cu-Sn Alloy on Copper Electrode Surface

PDF

Like

Knowledge

Abstract

Supporting Info

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0