新形金纳米片的简单制备与生长机制

doi:10.3866/PKU.WHXB201311053

Abstract

Abstract:

When a sticky gel consisting of an aqueous HAuCl₄ solution mixed with poly-vinylpyrrolidone (PVP) surfactant is kept at room temperature (about 30 ℃), the HAuCl₄ is reduced by the PVP, resulting in the formation of nanostructures. In this study, gold nanoplates with new shapes, which were single crystalline, several micrometers wide, and tens of nanometers thick, were mass-synthesized by adjusting the crystal growth conditions. For example, through inducing temperature decrease (10-20 ℃) in the early stage of crystal growth, the product is dominated by star-like gold nanoplates, together with other new shapes such as shields, concave and convex triangles, corner snipped shapes, triple branched shapes, and shapes that are step-rich in the side plane. Based on theoretical calculations, we present the growth mechanism of these new gold nanoplates. Under certain growth conditions, the (111) plane of the gold crystal can grow not only along the <110> direction into regular triangular or hexagonal nanoplates, but also along other directions such as <211> and <321>, to give new nanoplates with high-index side facets.

Key words: Gold nanoplate, Poly-vinylpyrrolidone, Star-like shape, Growth mechanism, High-index facet

WANG Chang-Shun, KAN Cai-Xia, NI Yuan, XU Hai-Ying. Facile Preparation and Growth Mechanism of New-Type Gold Nanoplates[J]. Acta Phys. -Chim. Sin. 2014, 30(1), 194-204. doi: 10.3866/PKU.WHXB201311053

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Facile Preparation and Growth Mechanism of New-Type Gold Nanoplates

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