热处理温度对锂氧气电池用Co-N/C催化剂催化性能的影响

doi:10.3866/PKU.WHXB201311142

Abstract

Abstract:

The development of low-cost and effective electrocatalysts for air electrodes is critical for practical applications of lithium/oxygen batteries. In the present work, phenanthroline (phen) was used as a ligand to prepare a Co(phen)₂ complex. The Co(phen)₂ complex was coated on BP2000 and then heat treated at 600, 700, 800, and 900 ℃, to obtain carbon-supported Co-N (Co-N/C) catalysts. The catalytic activities in oxygen reduction reaction/oxygen evolution reaction (ORR/OER) of the prepared catalysts were measured and compared with those of a typical carbon-supported cobalt tetramethoxyphenylporphyrin (CoTMPP/C) catalyst. The influence of the calcination temperature on the composition and structure of the Co-N/C catalysts was investigated. Electrochemical tests showed that the Co-N/C catalysts prepared at 700 and 800 ℃ gave better performances, comparable to that of the CoTMPP/C catalyst. The superior electrochemical performance of the prepared Co-N/C catalysts and the low cost of the phenanthroline chelating agent make Co-N/C a promising cheap catalyst for lithium/oxygen batteries.

Key words: Rechargeable lithium/oxygen battery, Oxygen electrode, ORR/OER catalyst, Cobalt phenanthroline complex, Calcination temperature

YANG Bing-Jian, WANG Hong, Li Lei, HUANG Bo-Wen, LIAO Xiao-Zhen, HE Yu-Shi, MA Zi-Feng. Influence of Calcination Temperature on Performances of Co-N/C Electrocatalysts for Li/O₂ Cells[J]. Acta Phys. -Chim. Sin. 2014, 30(1), 150-156. doi: 10.3866/PKU.WHXB201311142

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Influence of Calcination Temperature on Performances of Co-N/C Electrocatalysts for Li/O₂ Cells

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Influence of Calcination Temperature on Performances of Co-N/C Electrocatalysts for Li/O₂ Cells