硫酸根离子对铁在弱碱性溶液中阳极溶解和钝化行为的影响

doi:10.3866/PKU.WHXB201504032

Abstract

Abstract:

The effects of sulfate concentration on the open circuit state and anodic polarization behavior of iron in dilute bicarbonate solutions were investigated using immersion tests, electrochemical measurements, and surface analysis techniques. In the absence of sulfate or in the presence of a low concentration of sulfate in dilute bicarbonate solutions, iron was in a passive state, with a corrosion potential of (-0.225±0.005) V. A high electrochemical impedance and low corrosion rate were obtained. No obvious active-passive transition was observed in the anodic polarization curves. In the presence of a high concentration of sulfate in dilute bicarbonate solutions, iron was in an active dissolution state, with a corrosion potential of (-0.790±0.010) V. A low electrochemical impedance, high corrosion rate, and typical active-passive transition in anodic polarization curves were observed and related to the sulfate concentration. In the presence of a high concentration of sulfate, the anodic polarization curves showed current peaks as a result of iron activation by sulfate ions. Sulfate ions of sufficiently high concentration in solutions degraded previously formed oxide layers on iron or transformed oxide layers in bicarbonate solutions. The transition of the open circuit state from passivity to active dissolution occurs at a lower sulfate concentration in a deaerated solution than in an aerated solution.

Key words: Iron, Electrochemical behavior, Corrosion weightloss, Passivity, Anodic dissolution, X-ray photoelectron spectroscopy, Potential-pH diagram

CHEN Jun-Jie, XIAO Qian, Lü Zhan-Peng, AHSAN Ejaz, XIA Xiao-Feng, LIU Ting-Guang. Effects of Sulfate Ions on Anodic Dissolution and Passivity of Iron in Slightly Alkaline Solutions[J]. Acta Phys. -Chim. Sin. 2015, 31(6), 1093-1104. doi: 10.3866/PKU.WHXB201504032

References

(1) Fraunhofer, V. J. A. Corrosion Sci. 1970, 10, 245. doi: 10.1016/ S0010-938X(70)80084-1
(2) Thomas, J. G. N.; Nurse, T. J.; Walker, R. Br. Corros. J. 1970, 5, 87. doi: 10.1179/000705970798324829
(3) Pourbaix, M. Lectures on Electrochemical Corrosion; Plenum Press: New York-London, 1973.
(4) Davis, D. H.; Burstein, G. T. Corrosion 1980, 36, 416. doi: 10.5006/0010-9312-36.8.416
(5) Jelink, J.; Neufeld, P. Corrosion Sci. 1980, 20, 489. doi: 10.1016/ 0010-938X(80)90066-9
(6) Sutcliffe, J. M.; Fessler, R. R.; Boyd, W. K.; Parkins, R. N. Corrosion 1972, 28, 313. doi: 10.5006/0010-9312-28.8.313
(7) Stiksma, J.; Bradford, S. A. Corrosion 1985, 41, 446. doi: 10.5006/1.3583825
(8) Castro, E. B.; Valentini, C. R.; Moina, C. A.; Vilche, J. R.; Arvia, A. J. Corrosion Sci. 1986, 26, 781. doi: 10.1016/0010-938X(86)90063-6
(9) Rangel, C. M.; Leitao, R. A. Electrochim. Acta 1989, 34, 255. doi: 10.1016/0013-4686(89)87094-X
(10) Videm, K.; Koren, A. M. Corrosion 1993, 49, 746. doi: 10.5006/1.3316127
(11) Simard, S.; Drogowska, M.; Menard, H.; Brossard, L. J. App. Electrochem. 1997, 27, 317. doi: 10.1023/A:1018484814627
(12) Simard, S.; Menard, H. J. App. Electrochem. 1998, 28, 151.
(13) Legrand, L.; Savoye, S.; Chausse, A.; Messina, R. Electrochim. Acta 2000, 46, 111. doi: 10.1016/S0013-4686(00)00563-6
(14) Alves, V. A.; Brett, C. M. A. Electrochim. Acta 2002, 47, 2081. doi: 10.1016/S0013-4686(02)00077-4
(15) Lu, Z. P.; Huang, C. B.; Huang, D. L.; Yang, W. Corrosion Sci. 2006, 48, 3049. doi: 10.1016/j.corsci.2005.11.014
(16) Acosta, C. A.; Salvarezza, R. C.; Videla, H. A.; Arvia, A. J. Corrosion Sci. 1985, 25, 291. doi: 10.1016/0010-938X(85) 90108-8
(17) Zhao, J. M.; Zuo, Y.; Xiong, J. P.; Tian, L. P. Corros. Sci. Prot. Technol. 2001, 13, 77. [赵景茂, 左禹, 熊金平, 田连朋. 腐蚀科学与防护技术, 2001, 13, 77.]
(18) Vatankhah, G.; Drogowska, M.; Menard, H. J. App. Electrochem. 1998, 28, 173.
(19) Haruna, T.; Domoto, K.; Shibata, T. Corrosion Eng. 2002, 51, 350. doi: 10.3323/jcorr1991.51.350
(20) El-Naggar, M. M. App. Surf. Sci. 2006, 52, 6179.
(21) Lu, Z. P.; Chen, J. M. Br. Corros. J. 2000, 35, 224. doi: 10.1179/000705900101501281
(22) Waard, C.; Milliams, D. E. Corrosion 1975, 31, 177. doi: 10.5006/0010-9312-31.5.177
(23) Turgoose, S.; Cottis, R. A.; Lawson, K. Modeling of Electrode Processes and Surface Chemistry in Carbon Dioxide Containing Solutions. In Computer Modeling in Corrosion, ASTM STP 1154; Munn, R. S. Ed.; American Society for Testing and Materials: Philadephia, 1992; pp 67-81.
(24) Linter, B. R.; Burstein G. T. Corrosion Sci. 1999, 41, 117. doi: 10.1016/S0010-938X(98)00104-8
(25) Han, J. B.; Zhang, J. S.; Careya, J.W. Int. J. Greenhouse Gas Control 2011, 5, 1680. doi: 10.1016/j.ijggc.2011.08.003
(26) Marsh, G. P. Nucl. Energy 1982, 21, 253.
(27) Xiao, F.; Wang, J.; Guo, Y. H.; Wang, Z. M.; Su, R. Uranium Geol. 2011, 27, 185. [肖丰, 王驹, 郭永海, 王志明, 苏锐. 铀矿地质, 2011, 27, 185.]
(28) Yang, J. F.; Dong, J. H.; Ke, W. Acta Metall. Sin. (Chin. Ed.) 2011, 47, 1321. [阳靖峰, 董俊华, 柯伟. 金属学报, 2011, 47, 1321.]
(29) Andrade, C.; Alonso, C.; Sarria, J. Cem. Concr. Compos. 2002, 24, 55. doi: 10.1016/S0958-9465(01)00026-9
(30) Deodeshmukh, V.; Venugopal, A.; Chandra, D.; Yilmaz, A.; Daemen, J.; Jones, D. A.; Lea, S.; Engelhard, M. Corrosion Sci. 2004, 46, 2629. doi: 10.1016/j.corsci.2004.03.007
(31) Mao, X.; Liu, X.; Revie, R.W. Corrosion 1994, 50, 651. doi: 10.5006/1.3293540
(32) Liu, X.; Mao, X. Scr. Metall. Mater. 1995, 33, 145. doi: 10.1016/ 0956-716X(95)00112-9
(33) Guo, H.; Du, C.W.; Li, X. G.; Chen, Y. X. Equip. Environ. Eng. 2007, 4, 40. [郭昊, 杜翠薇, 李晓刚, 陈云祥. 装备环境工程, 2007, 4, 40.]
(34) Zhou, J. L.; Li, X. G.; Du, C.W.; Li, Y. L.; Li, T.; Pan, Y. Acta Metall. Sin. (Chin. Ed.) 2010, 46, 251. [周建龙, 李晓刚, 杜翠薇, 李云玲, 李涛, 潘莹. 金属学报, 2010, 46, 251.]
(35) Eliyan, F. F.; Mahdi, E.; Alfantazi, A. Corrosion Sci. 2012, 58, 181. doi: 10.1016/j.corsci.2012.01.015
(36) Hu, J. Y.; Cao, S. A.; Xie, J. L. Acta Phys. -Chim. Sin. 2012, 28, 1153. [胡家元, 曹顺安, 谢建丽. 物理化学学报, 2012, 28, 1153.] doi: 10.3866/PKU.WHXB201203022
(37) Parkins, R. N.; Zhou, S. Corrosion Sci. 1997, 39, 175. doi: 10.1016/S0010-938X(97)89248-7
(38) Heuer, J. K.; Stubins, J. F. Corrosion Sci. 1999, 41, 1231. doi: 10.1016/S0010-938X(98)00180-2
(39) Bockris, J. O. M.; Drazic, D. Electrochim. Acta 1962, 7, 293. doi: 10.1016/0013-4686(62)87007-8
(40) Shipley, H. J.; Gao, Y.; Kan, A. T.; Tomson, M. B. The Mobilization of Metals and Inorganic Compounds during Resuspension of Anoxic Sediment. In the 11th Annual International Petroleum Environmental Conference, Albuquerque, NM, USA, October 12-15, 2004.
(41) Castro, E. B.; Vilche, J. R. J. App. Electrochem. 1991, 21, 543. doi: 10.1007/BF01018608
(42) Zeng, Y. M.; Luo, J. L.; Norton, P. R. Electrochim. Acta 2004, 49, 703. doi: 10.1016/j.electacta.2003.09.024
(43) Florianovich, G. M.; Sokolova, L. A.; Kolotyrkin, Y. M. Electrochim. Acta 1967, 12, 879. doi: 10.1016/0013-4686(67)80124-5
(44) Pound, B. G.; Wright, G. A.; Sharp, R. M. Corrosion 1989, 45, 386. doi: 10.5006/1.3582033
(45) Szklarska-Smialowska, S.; Mrowczynski, G. Br. Corros. J. 1975, 10, 187. doi: 10.1179/000705975798320486
(46) Mills, P.; Sullivan, J. L. Journal of Physics D: Applied Physics 1983, 16, 723. doi: 10.1088/0022-3727/16/5/005
(47) Moulder, J. F.; Stickle, W. F.; Sobol, P. E.; Bomben K. D. Handbook of X-ray Photoelectron Spectroscopy; Perkin-Elmer Corporation: Eden Prairie, Minnesota, 1995.
(48) Tan, B. J.; Klabunde, K. J.; Sherwood, P. M. A. Chem. Mater. 1990, 2, 186. doi: 10.1021/cm00008a021
(49) Yamashita, T.; Hayes, P. App. Surf. Sci. 2008, 254, 2441. doi: 10.1016/j.apsusc.2007.09.063
(50) Allen, G. C.; Curtis, M. T.; Hooper, A. J.; Tucker, P. M. J. Chem. Society Dalton Transactions 1974, 14, 1525.
(51) Pitzer, K. S.; Peiper J. C. J. Phys. Chem. 1980, 84, 2396. doi: 10.1021/j100456a011
(52) Corrosion Mechanisms in Theory and Practice, 3rd ed.; Marcus, P. Ed.; CRC Press: Boca Raton, 2011.
(53) Chen, J. J.; Lu, Z. P.; Xiao, Q.; Xia, X. F.; Xia, S.; Yao, M. Y.; Zhou, B. X. ECS Trans. 2014, 59, 335. doi: 10.1149/05901.0335ecst

[1]	Tianmi Tang, Zhenlu Wang, Jingqi Guan. Electronic Structure Regulation of Single-Site M-N-C Electrocatalysts for Carbon Dioxide Reduction [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2208033-0.
[2]	Zhiyang Chen, Yating Tang, Ze Lü, Xiaohan Meng, Qianwei Liang, Jianguo Feng. Citronella Oil Nanoemulsion: Formulation, Characterization, Antibacterial Activity, and Cytotoxicity [J]. Acta Phys. -Chim. Sin., 2022, 38(12): 2205053-.
[3]	Yan Li, Xingsheng Hu, Jingwei Huang, Lei Wang, Houde She, Qizhao Wang. Development of Iron-Based Heterogeneous Cocatalysts for Photoelectrochemical Water Oxidation [J]. Acta Phys. -Chim. Sin., 2021, 37(8): 2009022-.
[4]	Haodong Shi, Yaguang Li, Pengfei Lu, Zhong-Shuai Wu. Single-Atom Cobalt Coordinated to Oxygen Sites on Graphene for Stable Lithium Metal Anodes [J]. Acta Phys. -Chim. Sin., 2021, 37(11): 2008033-.
[5]	Zilong Shao, Xiaofang Liu, Shunan Zhang, Hui Wang, Yuhan Sun. CO Hydrogenation to Ethanol over Supported Rh-Based Catalyst: Effect of the Support [J]. Acta Phys. -Chim. Sin., 2021, 37(10): 1911053-.
[6]	Jing Huang, Danyang Wang, Shuhua Li, Hong Fan, Louzhen Fan. Red Fluorescent Carbon Quantum Dots for Diagnosis of Acidic Microenvironment in Tumors [J]. Acta Phys. -Chim. Sin., 2021, 37(10): 1905067-.
[7]	Lu WANG, Wei SUN, Chao LIU. Homodinuclear Ferrous Group Metal Complexes and Their Application in Homogeneous Catalysis [J]. Acta Physico-Chimica Sinica, 2019, 35(7): 697-708.
[8]	Zhe ZHAO, Yue LU, Zhenhua ZHANG, Manling SUI. In situ Liquid Environmental TEM Observation of Self-Assembly of Oxide Nanoparticles Driven by Electric Charge [J]. Acta Physico-Chimica Sinica, 2019, 35(5): 539-545.
[9]	Yongzhong OUYANG,Shugui HUA,Jinlian DENG. Rapid Assessment of Atoms-in-Molecules Charges for Polypeptides by the Electronegativity Equalization Method [J]. Acta Phys. -Chim. Sin., 2019, 35(1): 58-68.
[10]	Yan WANG,Xiong LI,Shanwei HU,Qian XU,Huanxin JU,Junfa ZHU. Morphologies and Electronic Structures of Calcium-Doped Ceria Model Catalysts and Their Interaction with CO₂ [J]. Acta Phys. -Chim. Sin., 2018, 34(12): 1381-1389.
[11]	Chao LIAN,Kai ZHANG,Yuan WANG. Catalytic Properties of Platinum Nanoclusters Supported on Iron Oxides for the Solvent-Free Hydrogenation of Halonitrobenzene [J]. Acta Phys. -Chim. Sin., 2017, 33(5): 984-992.
[12]	Lan-Yi WANG,Xue-Hua YU,Zhen ZHAO. Synthesis of Inorganic Porous Materials and Their Applications in the Field of Environmental Catalysis [J]. Acta Phys. -Chim. Sin., 2017, 33(12): 2359-2376.
[13]	Xiao-Ning ZHANG,Valerie HOLLIMON,DaShan BRODUS. A Method for Attaching Thiol Groups Directly on a Silicon (111) Substrate [J]. Acta Phys. -Chim. Sin., 2016, 32(9): 2364-2368.
[14]	Xiu-Neng SONG,Guang-Wei WANG,Yan CHANG,Yong MA,Chuan-Kui WANG. Theoretical Study on X-Ray Spectroscopy of 1, 1, 2, 3, 4, 5-Hexaphenylsilole [J]. Acta Phys. -Chim. Sin., 2016, 32(4): 943-949.
[15]	Wei HAN,Nan JI,Mei LI,Shan-Shan WANG,Xiao-Guang YANG,Mi-Lin ZHANG,Yong-De YAN. Electrochemical Formation of Al-Tb Alloys from Tb₄O₇ Fluorinated by AlF₃ in NaCl-KCl Melts [J]. Acta Phys. -Chim. Sin., 2016, 32(10): 2538-2544.

Effects of Sulfate Ions on Anodic Dissolution and Passivity of Iron in Slightly Alkaline Solutions

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0