吡啶基离子液体[C6py][DCA]热力学性质及利用新Eötvös方程预测其表面张力

doi:10.3866/PKU.WHXB201510303

Abstract

Abstract:

The pyridinium-based ionic liquids [C₆py][DCA] (N-hexyl-pyridinium dicyanamide) was prepared and characterized using [1]H and [13]C nuclear magnetic responancec (NMR) spectroscopies, Fourier transform infrared (FT-IR) spectroscopy, and differential scanning calorimetry (DSC). The density (ρ), surface tension (γ), and refractive indices (n_D) were measured at the temperature range from 288.15 to 338.15 K. Molecular volume (V_m), energy of surface (E_a), molar polarization (R_m), and polarization coefficient of [C₆py][DCA] (α_p) were calculated from the experimental data. E_a, R_m, and α_p were approximately temperature-independent. The concept of molar surface Gibbs free energy (g_s) was conceived, for which a new Eötvös equation was derived. The g_s, critical temperature (T_c), and Eötvös empirical parameter related to polarity (k_E) were also obtained. The new Eötvös equation was used to predict the surface tension and the predicted values of [C₆py][DCA] are in close agreement with the corresponding experimental ones.

Key words: Pyridinium-based ionic liquid, Density, Surface tension, Molar surface Gibbs free energy, Eötvös equation

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Xiao-Xue BU,Ben-Han FAN,Jie WEI,Nan-Nan XING,Xiao-Xue MA,Wei GUAN. Thermodynamic Properties and Predicting the Surface Tension of Pyridinium-Based Ionic Liquids of [C₆py][DCA] Using a New Eötvös Equation[J]. Acta Phys. -Chim. Sin. 2016, 32(1), 267-273. doi: 10.3866/PKU.WHXB201510303

References

1	Seddon K. R. J. Chem. Tech. Biotechnol 1997, 68 (4), 351.
2	Tao G. H. ; He L. ; Liu W. S. ; Xu L. ; Xiong W. ; Wang T. ; Kou Y. Green Chem 2006, 8, 639.
3	Muhammad N. ; Omar W. N. ; Man Z. ; Bustam M. A. ; Rafiq S. ; Uemura Y. Ind. Eng. Chem. Res 2012, 51 (5), 2280.
4	Rout A. ; Binnemans K. Ind. Eng. Chem. Res 2014, 53 (8), 6500.
5	Zhong H. X. ; Zhao C. B. ; Luo H. ; Zhang L. Z. Acta Phys. -Chim. Sin 2012, 28 (11), 2641.
5	仲皓想; 赵春宝; 骆浩; 张灵志. 物理化学学报, 2012, 28 (11), 2641.
6	Wang H. ; Xu X. Q. ; Shi J. F. ; Xu G. Acta Phys. -Chim. Sin 2013, 29 (3), 525.
6	王海; 徐雪青; 史继富; 徐刚. 物理化学学报, 2013, 29 (3), 525.
7	Zhao D. B. ; Fei Z. F. ; Geldbach T. J. ; Scopelliti R. ; Dyson P. J. J. Am. Chem. Soc 2004, 126 (48), 15876.
8	Yunus N. M. ; Abdul Mutalib M. I. ; Man Z. ; Bustam M. A. ; Murugesan T. Chemical Engineering Journal 2012, 189, 94.
9	Calvar, N.; Gomez, E.; Macedo, E. A.; Dominguez, A. Thermochimica Acta 2013, 565, 178. doi: 10.1016/j.tca.2013.05.007
10	Crosthwaite J. M. ; Muldoon M. J. ; Dixon J. K. ; Anderson J. L. ; Brennecke J. F. Journal of Chemical Thermodynamics 2005, 37 (6), 559.
11	Xu F. ; Gao H. S. ; Dong H. F. ; Wang Z. L. ; Zhang X. P. ; Ren B. Z. ; Zhang S. J. Fluid Phase Equilibria 2014, 365, 80.
12	Ye Q. ; Gao T. T. ; Wan F. ; Yu B. ; Pei X. M. ; Zhou F. ; Xue Q. J. Journal of Materials Chemistry 2012, 22 (26), 13123.
13	Zeng S. J. ; Gao H. S. ; Zhang X. C. ; Dong H. F. ; Zhang X. P. ; Zhang S. J. Chemical Engineering Journal 2014, 251, 248.
14	Jie X. M. ; Chau J. ; Obuskovic G. ; Obuskovic G. ; Sirkar K. K. Industrial & Engineering Chemistry Research 2014, 53 (8), 3305.
15	Schneider S. ; Hawkins T. ; Rosander M. ; Vaghjiani G. ; Chambreau S. ; Drake G. Energy & Fuels 2008, 22 (4), 2871.
16	Bedrov D. ; Borodin O. Journal of Physical Chemistry B 2010, 114 (40), 12802.
17	Tokuda H. ; Hayamizu K. ; Ishii K. ; Susan M. A. B. H. ; Watanabe M. Journal of Physical Chemistry B 2004, 108 (42), 16593.
18	Krossing I. ; Slattery J. M. ; Daguenet C. ; Dyson P. J. ; Oleinikova A. ; Weingärtner H. J. Am. Chem. Soc 2006, 128 (41), 13427.
19	Jenkins H. D. B. ; Glasser L. Inorganic Chemistry 2002, 41 (17), 4378.
20	Jenkins H. D. B. ; Glasser L. Inorganic Chemistry 2003, 42 (26), 8702.
21	Ma X. X. ; Wei J. ; Zhang Q. B. ; Tian F. ; Feng Y. Y. ; Guan W. Ind. Eng. Chem. Res 2013, 52, 9490.
22	Wei J. ; Chang C. ; Zhang Y. Y. ; Hou S. Y. ; Fang D. W. ; Guan W. J. Chem. Thermodynamics 2015, 90, 310.
23	Wei J. ; Zhang Q. B. ; Tian F. ; Zheng L. ; Guan W. ; Yang J.Z. Fluid Phase Equilibria 2014, 371, 1.
24	Guan W. ; Zhang Q. B. ; Ma X. X. ; Wei J. ; Pan Y. ; Yang J. Z. Fluid Phase Equilibria 2013, 360, 63.
25	Ma X. X. ; Wei J. ; Guan W. ; Pan Y. ; Zheng L. ; Wu Y. ; Yang J. Z. J. Chem. Thermodynamics 2015, 89, 51.
26	Guan W. ; Wang C. X. ; Wang Z. ; Chen S. P. ; Gao S. L. Acta Chim. Sin 2011, 69 (11), 1280.
26	关伟; 王彩霞; 王珍; 陈三平; 高胜利. 化学学报, 2011, 69 (11), 1280.
27	Earle M. J. ; Gordon C. M. ; Plechkova N. V. ; Seddon K. R. ; Welton T. Analytical Chemistry 2007, 79 (2), 758.
28	Gordon, C. M.; Muldoon, M. J.; Wagner, M. Ionic Liquids in Synthesis; Wiley-VCH Verlag GmbH & Co. KGaA: Weinheim, 2002.
29	Zhang S. G. ; Qi X. J. ; Ma X. Y. ; Lu L. J. ; Deng Y. Q. J. Phys. Chem. B 2010, 114 (11), 3912.
30	Lide, D. R. Handbook of Chemistry and Physics, 82nd ed.; CRC Press: Boca Raton, FL, 2001.
31	Glasser L. Thermochimica Acta 2004, 421 (1–2), 87.
32	Adamson, A. W. Physical Chemistry of Surfaces, 3rd ed.; John Wiley: New York, 1976; translated by Gu, T. R. Science Press: Beijing, 1986. Adamson, A. W.
32	表面物理化学.第三版.顾惕人译.北京:科学出版社, 1986.
33	Ersfeld B. ; Felderhof B. U. Phys. Rev. E 1998, 57 (1), 1118.
34	Tong J. ; Liu Q. S. ; Zhang P. ; Yang J. Z. J. Chem. Eng. Data 2007, 52 (4), 1497.

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Thermodynamic Properties and Predicting the Surface Tension of Pyridinium-Based Ionic Liquids of [C₆py][DCA] Using a New Eötvös Equation

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Thermodynamic Properties and Predicting the Surface Tension of Pyridinium-Based Ionic Liquids of [C₆py][DCA] Using a New Eötvös Equation