表面活性离子液体溴化N-十二烷基异喹啉与非离子表面活性剂Triton X-100在水溶液中的混合胶束

doi:10.3866/PKU.WHXB201512012

Abstract

Abstract:

The critical micelle concentrations of binary systems of surface active ionic liquid lauryl isoquinolium bromide ([C₁₂iQuin]Br) with nonionic surfactant Triton X-100 in aqueous solution were investigated by isothermal titration calorimetry. The location of [C₁₂iQuin]Br and Triton X-100 in the mixed micelle was studied using ¹H nuclear magnetic resonance (NMR) and two-dimensional nuclear Overhauser enhancement spectroscopy (2D NOESY). It was found that the polyoxyethylene chain of Triton X-100 forms random coils around the isoquinolinium ring. The interaction of molecules in the mixed micelle of [C₁₂iQuin]Br-Triton X-100 was also studied using regular solution theory and the cloud point measurement technique, with comparison to the interaction of doceyl trimethyl ammonium bromide (DTAB)-Triton X-100.

Key words: Surface active ionic liquid, Lauryl isoquinolinium bromide, Triton X-100, Mixed micelle

Xiao-Hong ZHANG,Hong-Yan XU,Ling-Ling GE,Rong GUO. Mixed Micelle of Surface Active Ionic Liquid Lauryl Isoquinolinium Bromide and Nonionic Surfactant Triton X-100 in Aqueous Solutions[J]. Acta Phys. -Chim. Sin. 2016, 32(1), 356-364. doi: 10.3866/PKU.WHXB201512012

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Mixed Micelle of Surface Active Ionic Liquid Lauryl Isoquinolinium Bromide and Nonionic Surfactant Triton X-100 in Aqueous Solutions

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