高覆盖率氟代癸基三氯硅烷自组装单分子膜的制备

doi:10.3866/PKU.WHXB201602175

Abstract

Abstract:

In this work, 1H, 1H, 2H, 2H-perfluorodecyltrichlorosilane (FDTS) self-assembled monolayers (SAMs) were prepared using liquid-phase deposition. To prepare the FDTS SAMs, the FDTS solution was first hydrolyzed for 15 min at room temperature, and then mica was immersed into the FDTS solution for self-assembly for 30 min. It was confirmed that the new method can effectively prevent aggregation of FDTS in the liquid phase deposition using atomic force microscopy (AFM). The FDTS SAMs were successfully prepared with a high surface coverage of (85% ± 2%) and low root mean square surface roughness (0.58 nm). The growth process of the SAMs can be described using the Langmuir first-order adsorption kinetics model. However, if hydrolysis and assembly occur at the same time and these processes last more than 30 min, the FDTS would be aggregated in the liquid-phase deposition process, which would greatly reduce the quality of the SAMs.

Key words: 1H, 1H, 2H, 2H-perfluorodecyltrichlorosilane, Self-assembled monolayer, Coverage, Aggregation, Atomic force microscope

Jia-Dong ZHOU,Yi-Hui DONG,Shuai-Hui ZHANG,Yuan-Yuan ZHAO,Xiao-Fei GUO,Xiao-Hua LU,Chang-Song WANG. Preparation of High-Coverage Fluorinated Decyltrichlorosilane Self-Assembled Monolayers[J]. Acta Phys. -Chim. Sin. 2016, 32(5), 1221-1226. doi: 10.3866/PKU.WHXB201602175

References

1	Pu J. B. ; Jiang D. ; Mo Y. F. ; Wang L. P. ; Xue Q. J. Surface & Coatings Technology 2011, 205, 4855.
2	Ewers B.W. ; Batteas J. D. RSC Advances 2014, 4, 16803.
3	Xu L. H. ; Wang L. M. ; Shen Y. ; Ding Y. ; Cai Z. S. Fibers and Polymers 2015, 16, 1082.
4	Wilson K. A. ; Finch C. A. ; Anderson P. ; Vollmer F. ; Hickman J. J. Biomaterials 2012, 33, 225.
5	Wang D. ; Ni Y. ; Huo Q. ; Tallman D. E. Thin Solid Films 2005, 471 (1-2), 177.
6	Desbief S. ; Patrone L. ; Goguenheim D. ; Guérin D. ; Vuillaume D. Phys. Chem. Chem. Phys. 2011, 13, 2870.
7	Raza M. A. ; Kooij E. S. ; van Silfhout A. ; Poelsema B. Langmuir 2010, 26, 12962.
8	Kristalyn C. B. ; Watt S. ; Spanninga S. A. ; Barnard R. A. ; Nguyen K. ; Chen Z. Journal of Colloid and Interface Science 2011, 353, 322.
9	Ling F. Z. ; De Coster J. ; Lin W. Y. ; Witvrouw A. ; Celis J. P. ; DeWolf I. Sensors and Actuators A-Physical 2012, 188, 320.
10	Frechette J. ; Maboudian R. ; Carraro C. Journal of Microelectromechanical Systems 2006, 15, 737.
11	Hoque E. ; DeRose J. A. ; Hoffmann P. ; Mathieu H. J. Surface and Interface Analysis 2006, 38, 62.
12	Pan Z. H. ; Zhang W. ; Kowalski A. ; Zhao B. X. Langmuir 2015, 31, 9901.
13	Wang A. ; Cao T. ; Tang H. ; Liang X. ; Black C. ; Salley S. O. ; Mcallister J. P. ; Auner G.W. ; Ng K. Y. S. Colloids & Surfaces B: Biointerfaces 2006, 47, 57.
14	Hu J. M. ; Liu L. ; Zhang J. Q. ; Cao C. N. Progress in Organic Coatings 2007, 58, 265.
15	Kushmerick J. G. ; Hankins M. G. ; de Boer M. P. ; Clews P. J. ; Carpick R.W. ; Bunker B. C. Tribology Letters 2001, 10, 103.
16	Bunker B. C. ; Carpick R.W. ; Assink R. A. ; Thomas M. L. ; Hankins M. G. ; Voigt J. A. ; Sipola D. ; de Boer M. P. ; Gulley G. L. Langmuir 2000, 16, 7742.
17	Tan M. ; Zhang H. ; Wang Y. ; Ma H. ; Zhu J. ; Han J. Applied Surface Science 2008, 254, 6332.
18	Pellerite M. J. ; Wood E. J. ; Jones V. W. Journal of Physical Chemistry B 2002, 106, 4746.
19	Choi J. ; Sakurai K. ; Kato T. Surface and Interface Analysis 2010, 42, 1373.
20	Rozlosnik N. ; Gerstenberg M. C. ; Larsen N. B. Langmuir 2003, 19, 1182.
21	Balgar T. ; Bautista R. ; Hartmann N. ; Hasselbrink E. Surface Science 2003, 532- 535, 963.
22	Major R. C. ; Zhu X. Y. Langmuir 2001, 17, 5576.
23	Carraro C. ; Yauw O.W. ; Sung M. M. ; Maboudian R. Journal of Physical Chemistry B 1998, 102, 4441.
24	Iimura K. I. ; Nakajima Y. ; Kato T. Thin Solid Films 2000, 379, 230.
25	Wang C. S. ; Feng X. ; Lu X. H. Acta Phys. -Chim. Sin. 2005, 21, 586.
25	王昌松; 冯新; 陆小华. 物理化学学报, 2005, 21, 586.
26	Zhou Z.W. ; Xu G. H. ; An Y. ; He C. H. Acta Phys. -Chim. Sin. 2014, 30, 1509.
26	朱志文; 徐国华; 安越; 何潮洪. 物理化学学报, 2014, 30, 1509.
27	Stevens M. J. Langmuir 1999, 15, 2773.
28	Robinson G. N. ; Kebabian P. L. ; Freedman A. ; Depalma V. Thin Solid Films 1997, 310, 24.
29	Vallant T. ; Brunner H. ; Mayer U. ; Hoffmann H. ; Leitner T. ; Resch R. ; Friedbacher G. Journal of Physical Chemistry B 1998, 102, 7190.
30	Resch R. ; Grasserbauer M. ; Friedbacher G. ; Vallant T. ; Brunner H. ; Mayer U. ; Hoffmann H. Applied Surface Science 1999, 140, 168.
31	Witten T. A. ; Sander L. M. Physical Review Letters 1981, 47, 1400.
32	Meakin P. Physical Review Letters 1983, 51, 1119.
33	Paso K. ; Helberg R. M. L. ; Raaen S. ; Sj?blom J. Journal of Colloid & Interface Science 2008, 325, 228.

[1]	Miaomiao Liu, Wenjuan Wang, Xiuping Hao, Xiaoyan Dong. Seeding and Cross-Seeding Aggregations of Aβ40 and hIAPP in Solution and on Surface [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 2002024-.
[2]	Changsheng Zhang,Luhua Lai. Physiochemical Mechanisms of Biomolecular Liquid-Liquid Phase Separation [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1907053-.
[3]	Jianmei JIAO,Guiying XU,Xia XIN. Effect of Bile Salts on Self-Assembly and Construction of Micro-/nanomaterials [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 684-696.
[4]	Xiaohong GUO,Ying ZHOU,Lihong SHI,Yan ZHANG,Caihong ZHANG,Chuan DONG,Guomei ZHANG,Shaomin SHUANG. Luminescence Emission of Copper Nanoclusters by Ethanol-induced Aggregation and Aluminum Ion-induced Aggregation [J]. Acta Phys. -Chim. Sin., 2018, 34(7): 818-824.
[5]	Noriyuki YOSHII,Mika KOMORI,Shinji KAWADA,Hiroaki TAKABAYASHI,Kazushi FUJIMOTO,Susumu OKAZAKI. Free Energy Change of Micelle Formation for Sodium Dodecyl Sulfate from a Dispersed State in Solution to Complete Micelles along Its Aggregation Pathways Evaluated by Chemical Species Model Combined with Molecular Dynamics Calculations [J]. Acta Phys. -Chim. Sin., 2018, 34(10): 1163-1170.
[6]	Yi-Jian CHEN,Hong-Tao ZHOU,Ji-Jiang GE,Gui-Ying XU. Aggregation Behavior of Double-Chained Anionic Surfactant 1-C_m-C₉-SO₃Na at Air/Liquid Interface: Molecular Dynamics Simulation [J]. Acta Phys. -Chim. Sin., 2017, 33(6): 1214-1222.
[7]	Hui WANG,De-Chun ZOU. Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source [J]. Acta Phys. -Chim. Sin., 2017, 33(5): 1027-1032.
[8]	Andrew SCHLERETH,Panae NOOMUNA,Pei GAO. Mesoscale Protein Patterning on a Self-Assembled Monolayer Coated Silicon Surface through Nanosphere Lithography [J]. Acta Phys. -Chim. Sin., 2017, 33(4): 810-815.
[9]	Rong WANG,Ming DUAN,Yan XIONG,Xian-Yu SONG,Shen-Wen FANG. Aggregation Behaviour of Reversed Demulsifiers SP169 and DMEA169 in Aqueous Solution [J]. Acta Phys. -Chim. Sin., 2016, 32(6): 1482-1488.
[10]	Teng LIU,Hai-Yang WANG,Gui-Ying XU. Aggregation Behavior of PEO-PPO Block Polyethers and Their Application as a Drug Carrier [J]. Acta Phys. -Chim. Sin., 2016, 32(5): 1072-1086.
[11]	Li-Juan WANG,Qi LI,Yan-Zhong HAO,Shi-Gang SHEN,Dong-Sheng XU. Improvement of Quantum Dot Coverage of CdS/CdSe/TiO₂ Hierarchical Hollow Sphere Photoanodes [J]. Acta Phys. -Chim. Sin., 2016, 32(4): 983-989.
[12]	Ya-Xun FAN,Yu-Chun HAN,Yi-Lin WANG. Effects of Molecular Structures on Aggregation Behavior of Gemini Surfactants in Aqueous Solutions [J]. Acta Phys. -Chim. Sin., 2016, 32(1): 214-226.
[13]	LI Hao, DENG Yong-Hong, ZHANG Xiao-Hong, QIU Xue-Qing. Influence of Temperature on Microstructure and Physicochemical Properties of Alkali Lignin in Aqueous Solution [J]. Acta Phys. -Chim. Sin., 2015, 31(6): 1118-1128.
[14]	ZHU Zhi-Wen, XU Guo-Hua, ANYue, HE Chao-Hong. Characterization of a Homogeneously Mixed Octyltriethoxyilane/Octadecyltrichlorosilane Self-Assembled Monolayer and Analysis of Its Formation Mechanism [J]. Acta Phys. -Chim. Sin., 2014, 30(8): 1509-1517.
[15]	FAN Zhong-Xiang, HUANG Jian-Hua. Dissipative Particle Dynamics Simulation on Aggregation of Rod-Coil-Rod Triblock Copolymer in Dilute Solution [J]. Acta Phys. -Chim. Sin., 2014, 30(3): 408-412.

Preparation of High-Coverage Fluorinated Decyltrichlorosilane Self-Assembled Monolayers

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0