基于离子交换跃迁模型和实验法对离子液体Walden乘积的研究

doi:10.3866/PKU.WHXB201607292

Abstract

Abstract:

A new theory has been developed to evaluate the Walden product, W, of ionic liquids using an ion exchange transition model. This model showed that the product (Walden) of molar conductivity and dynamic viscosity is related to the average diameters of the ion pairs and ion clusters of ionic liquids (ILs) with 1:1 charge ratios, namely, different ILs have different W values. Several experiments were conducted to evaluate the validity of this model. Eight different ILs, including five N-alkyl-pyridinium dicyanamide ILs[C_npy] [DCA] (n=2-6) and three N-alkyl-3-methyllimidazolium serine ILs[C_nmim] [Ser] (n=2-4) were successfully synthesized and evaluated in terms of their conductivity and dynamic viscosity properties. The W values of 33 different ILs were calculated based on their experimentally determined molar conductivity and dynamic viscosity values, and the results revealed that these values were consistent with those of the ion exchange transition model. Taken together, these results demonstrate that W is a key physical parameter for ILs.

Key words: Ionic liquid, Conductivity, Viscosity, Transition model, Walden product

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Ling ZHENG,Yi PAN,Hong-Xiang JI,Xiao-Xue MA,Nan-Nan XING,Wei GUAN. Evaluation of the Walden Product of Ionic Liquids Using Experiments and a New Theory: An Ion Exchange Transition Model[J]. Acta Phys. -Chim. Sin. 2016, 32(11), 2663-2670. doi: 10.3866/PKU.WHXB201607292

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Evaluation of the Walden Product of Ionic Liquids Using Experiments and a New Theory: An Ion Exchange Transition Model

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