三聚氰胺与蜜勒胺在Au (111)表面的自组装和氢键识别

doi:10.3866/PKU.WHXB201611033

Abstract

Abstract:

Melamine and melem molecules are widely used precursors for synthesizing graphitic carbon nitride (g-C₃N₄), the latter also a hot two-dimensional material with photocatalytic applications. The molecular structures of both are respectively identical to the repeating units of two distinct g-C₃N₄ phases. In this work, the adsorption and self-assembly of melamine and melem on an Au(111) surface were investigated with low-temperature scanning tunneling microscopy (STM). Particularly, the patterns of hydrogen bonds (HBs) in their assemblies were identified and compared. It was found that melamine can only form one type of HB and two kinds of assembly structures, whereas melem can form three types of HBs and six kinds of assembly structures in total. Moreover, the involved HBs can be transformed by tip manipulation. These findings may provide a new strategy for tuning the functionality of surface self-assemblies by manipulating intermolecular hydrogen bonds. This also paves a route for the in situ synthesis of g-C₃N₄ on metallic surfaces and subsequent investigations of their physicochemical properties.

Key words: Melamine, Melem, Au(111), Scanning tunneling microscopy, Hydrogen bond, Selfassembly

Li WANG,He-Xia SHI,Wen-Yuan WANG,Hong SHI,Xiang SHAO. Identifying the Hydrogen Bonding Patterns of Melamine and Melem Self-Assemblies on Au(111) Surface[J]. Acta Phys. -Chim. Sin. 2017, 33(2), 393-398. doi: 10.3866/PKU.WHXB201611033

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Identifying the Hydrogen Bonding Patterns of Melamine and Melem Self-Assemblies on Au(111) Surface

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